Chapter 6. Practice Problems: 1 1 2 2 1 1 1 1 2 2 2 2 1 1 2 2 1 1 2 2 1 1 2 2 Total 1 2 1 1 T

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CHAPTER 6.

PRACTICE PROBLEMS
Units:
1 atm = 760 mmHg = 760 torr = 101 325 Pa = 101.3 kPa

Use the following equations:


P1V1 = P2V2 (Boyle’s Law) P1V1/T1n1 = P2V2/T2n2 (Combined Gas Law)
P1/T1 = P2T2 (Gay Lussac’s Law) PV = nRT (Ideal Gas Law)
V1/T1 = V2T2 (Charles’ Law) STP = 273.15K at 1 atm: 1 mole of any gas occupies 22.4L
V1/n1 = V2/n2 (Avogadro’s Law) PTotal = P1+ P2 + … (Dalton’s Law of Partial Pressures)
P1 = X1PT (mole fraction x total pressure)

Part I. Solve. Show all work.


1. A gas with a volume of 4.0L at a 4. A gas occupies 900.0 mL at a
pressure of 205kPa is allowed to expand temperature of 27.0 °C. What is the volume
to a volume of 12.0L. What is the at 132.0 °C?
pressure in the container if the
temperature remains constant?

5. The gases in a hair spray can are at a


temperature of 27oC and a pressure of
790mmHg. If the gases in the can reach a
pressure of 820 mmHg, the can will
explode. To what temperature must the
2. 6.0 L of gas in a piston at a pressure of gases be raised in order for the can to
1.0 atm are compressed until the explode?
volume is 3.5 L.What is the new pressure
inside the piston?

6. How many liters of N2 are occupied by


70.05 grams of N2 at STP?

3. A container containing 5.00 L of a gas is


collected at 100 K and then allowed to
expand to 20.0 L. What must the new
temperature be in order to maintain the
same pressure?
7. What is the density (g/L) of CO2 at STP?
8. A balloon that can hold 85 L of air is 12. A container has three gases: CO2 , H2,
inflated with 3.5 moles of gas at a pressure and CO. If CO2 is 30.0% by volume, H2 is
of 1.0 atm. What is the temperature in 0oC 10.0% by volume, and CO occupies 60.0%
of the balloon? by volume. Calculate the partial pressures
of each gases if the total pressure is 20.0
atm.

9. If 25 L of a certain gas sample is


collected at 12000oC, what will the volume
of this gas after it cools to 250oC?

13. What is the partial pressure of CO2 in a


container that holds the following: 5.0
moles of CO2, 3.0 moles of H2O, and 2.0
moles of H2 if the total pressure is 20.0 atm.

10. Two flasks are connected with a


stopcock. Flask #1 has a volume of 2.5 L
and contains O2 at a pressure of 0.70 atm.
Flask #2 has a volume of 3.8 L and contains
H2 at a pressure of 1.25 atm. When the
stopcock between the two flasks is
opened and the gases are allowed to mix,
what will the resulting pressure of the gas
mixture be? 14. A weather balloon has a volume of 35 L
at sea level (1.0 atm). After the balloon is
released it rises to where the air pressure is
0.75 atm. What will the new volume of the
weather balloon be?

11. If I have 72 liters of gas held at a


pressure of 3.4 atm and a temperature of
225 K, how many moles of gas do I have?
15. A 35 L tank of oxygen is at 315 K with an
internal pressure of 190 atmospheres. How
many moles of gas does the tank contain?
 

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