Colloidal System: by Msc. Dua'A M. Hadi

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15.

3 Heterogeneous Aqueous Systems >

Lecture 1
Colloidal system
By
MSc. Dua’a M. Hadi

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15.3 Heterogeneous Aqueous Systems >

Dispersed Systems:
Dispersed systems consist of particulate
matter (dispersed phase), distributed
throughout a continuous phase
(dispersion medium).

They are classified according to the


particle diameter of the dispersed
material:

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15.3 Heterogeneous Aqueous Systems >

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15.3 Heterogeneous Aqueous Systems > Suspensions

• A solution is a homogeneous mixture.


• Suspensions are heterogeneous
because at least two substances can be
clearly identified.

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15.3 Heterogeneous Aqueous Systems > Suspensions

The difference between a solution and suspension


is easily seen when the type of mixture is filtered.

The small size of the The particles of a


solute particles in a suspension can be
solution allows them to removed by filtration.
pass through filter paper.
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15.3 Heterogeneous Aqueous Systems >

Explain why a mixture of sand and


water can be separated by filtration,
but a mixture of salt and water cannot.

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15.3 Heterogeneous Aqueous Systems >

Explain why a mixture of sand and


water can be separated by filtration,
but a mixture of salt and water cannot.

A mixture of sand and water is a suspension,


and a mixture of salt and water is a solution.
The particles in the sand mixture are much
larger than the ions in the salt mixture. The
sand particles are too large to pass through
filter paper; the ions are not.

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15.3 Heterogeneous Aqueous Systems > Colloids

Colloids

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15.3 Heterogeneous Aqueous Systems > Colloids

A colloid is a heterogeneous mixture


containing particles that range in size from 1
nm to 1000 nm.
In other words,a colloid is a microscopically
small substance that is equally dispersed
throughout another material.
• The particles are spread, throughout the
dispersion medium, which can be a solid,
liquid, or gas.

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15.3 Heterogeneous Aqueous Systems >

There are three sub classifications of colloidal


solutions: foams, emulsions, and sols.

A foam in this context is formed by trapping a gas


in a liquid. The material being distributed would
be the gas, causing the liquid to become foamy.
An example of this would be shaving cream.

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15.3 Heterogeneous Aqueous Systems >

An emulsion is a mixture of liquids; it’s


essentially when one liquid is evenly
distributed throughout another liquid.
An example of this would be milk or
mayonnaise.
The third form is called a sol, which is
when a solid is evenly distributed
throughout a liquid. Examples of sols
include blood, paint

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15.3 Heterogeneous Aqueous Systems > Colloids

Colloids have particles smaller


than those in suspensions and
larger than those in solutions.
• These intermediate-sized particles cannot
be retained by filter paper as are the
larger particles of a suspension.
• They do not settle out with time.

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15.3 Heterogeneous Aqueous Systems >

Colloidal solutions are very important


in the medical field because they can
be used to manipulate blood
conditions. More specifically, they
are often used to regulate colloidal
osmotic pressure.

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15.3 Heterogeneous Aqueous Systems > Colloids

The Tyndall Effect


The scattering of visible light by colloidal
particles is called the Tyndall effect.

Flashlight
Solution Colloid Suspension

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15.3 Heterogeneous Aqueous Systems > Colloids

• Suspensions also exhibit the Tyndall


effect.
• The particles in solutions are too small
to scatter light.

Flashlight
Solution Colloid Suspension

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15.3 Heterogeneous Aqueous Systems > Colloids

Coagulation
All the colloidal particles in a particular
colloidal system will have the same
charge, although the colloidal system is
neutral.
• The repulsion between the like-charged
particles prevents the particles from forming
heavier aggregates that would have a
greater tendency to settle out.

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15.3 Heterogeneous Aqueous Systems > Colloids

Coagulation
A colloidal system can be destroyed or
coagulated by the addition of
electrolytes.
• The added ions neutralize the charged
colloidal particles.
• The particles can clump together to form
heavier aggregates and settle out from the
dispersion.

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15.3 Heterogeneous Aqueous Systems > Colloids

This table summarizes the properties of solutions,


colloids, and suspensions.
Properties of Solutions, Colloids, and Suspensions
System
Property Solution Colloid Suspension
Ions, atoms, Large molecules or Large particles or
Particle type
small molecules particles aggregates
Particle size 0.1–1 nm 1–1000 nm 1000 nm and larger
Effect of light No scattering Exhibits Tyndall effect Exhibits Tyndall effect
Effect of Stable, does Stable, does not Unstable, sediment
gravity not separate separate forms
Particles not Particles not retained Particles retained on
Filtration
retained on filter on filter filter
Uniformity Homogeneous Heterogeneous Heterogeneous

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15.3 Heterogeneous Aqueous Systems >

Which of the following is a colloidal


system?

A. mud
B. gasoline
C. blood
D. a mixture of sugar and water

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15.3 Heterogeneous Aqueous Systems > Key Concepts

A suspension differs from a solution


because the particles of a suspension
are much larger and do not stay
suspended indefinitely.
Colloids have particles smaller than
those in suspensions and larger than
those in solutions.

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15.3 Heterogeneous Aqueous Systems > Glossary Terms

• suspension: a mixture from which


some of the particles settle out slowly
upon standing
• colloid: a mixture which particles are
intermediate in size between those of a
suspension and a solute solution
• Tyndall effect: scattering of light by
particles in a colloid or suspension,
which causes a beam of light to become
visible
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15.3 Heterogeneous Aqueous Systems >

END OF lecture 1

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