SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

SECTION 1. IDENTIFICATION

Product name : GOJO® NATURAL* ORANGE™ Pumice Hand Cleaner

Manufacturer or supplier's details

Company name of supplier : GOJO Industries, Inc.

Address : One GOJO Plaza, Suite 500

Akron OH 44311

Telephone : 1 (330) 255-6000

Emergency telephone : 1-800-424-9300 CHEMTREC

Recommended use of the chemical and restrictions on use

Recommended use : Skin-care

Restrictions on use : This is a personal care or cosmetic product that is safe for
consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products,
specifically defined by regulations around the world, are
exempt from the requirement of an SDS for the consumer.
While this material is not considered hazardous, this SDS
contains valuable information critical to the safe handling and
proper use of the product for industrial workplace conditions
as well as unusual and unintended exposures such as large
spills. This SDS should be retained and available for
employees and other users of this product. For specific
intended-use guidance, please refer to the information
provided on the package or instruction sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Eye irritation : Category 2A

GHS Label element

Hazard pictograms :

Signal Word : Warning

Hazard Statements : H319 Causes serious eye irritation.

Precautionary Statements : Prevention:

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

P264 Wash skin thoroughly after handling.

P280 Wear eye protection/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical Name CAS-No. Concentration (%)
1-Methyl 4-(1-Methylethenyl) Cyclohexene 5989-27-5 >= 5 - < 10
Alcohols, C12-15, ethoxylated propoxylated 68551-13-3 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.

If inhaled : If inhaled, remove to fresh air.

Get medical attention if symptoms occur.

In case of skin contact : Wash with water and soap as a precaution.

Get medical attention if symptoms occur.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention.

If swallowed : If swallowed, DO NOT induce vomiting.

Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.

Most important symptoms : Causes serious eye irritation.

and effects, both acute and
delayed

Protection of first-aiders : First Aid responders should pay attention to self-protection,

and use the recommended personal protective equipment
when the potential for exposure exists.

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

Notes to physician : Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray

Alcohol-resistant foam
Dry chemical
Carbon dioxide (CO2)

Unsuitable extinguishing : None known.

media

Specific hazards during fire : Exposure to combustion products may be a hazard to health.
fighting

Hazardous combustion prod- : Carbon oxides

ucts

Specific extinguishing : Use extinguishing measures that are appropriate to local

methods circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Use personal protective equipment.

protective equipment and Follow safe handling advice and personal protective
emergency procedures equipment recommendations.

Environmental precautions : Discharge into the environment must be avoided.

Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Soak up with inert absorbent material.

containment and cleaning up For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

employed in the cleanup of releases. You will need to

determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE

CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Avoid inhalation of vapor or mist.

Do not swallow.
Do not get in eyes.
Avoid prolonged or repeated contact with skin.
Handle in accordance with good industrial hygiene and safety
practice.
Take care to prevent spills, waste and minimize release to the
environment.

Conditions for safe storage : Keep in properly labeled containers.

Store in accordance with the particular national regulations.

Materials to avoid : Do not store with the following product types:

Strong oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.
Hazardous components without workplace control parameters
Ingredients CAS-No.
1-Methyl 4-(1-Methylethenyl) 5989-27-5
Cyclohexene
Alcohols, C12-15, ethoxylated 68551-13-3
propoxylated
Engineering measures : Ensure adequate ventilation, especially in confined areas.
Minimize workplace exposure concentrations.
Dust formation may be relevant in the processing of this
product. In addition to substance-specific OELs, general
limitations of concentrations of particulates in the air at
workplaces have to be considered in workplace risk
assessment. Relevant limits include: OSHA PEL for
Particulates Not Otherwise Regulated of 15 mg/m3 - total
dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for
Particles (insoluble or poorly soluble) Not Otherwise
Specified of 3 mg/m3 - respirable particles, 10 mg/m3 -
inhalable particles.

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

Personal protective equipment

Respiratory protection : General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.

Hand protection
Material : Impervious gloves

Remarks : Choose gloves to protect hands against chemicals depending

on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.

Eye protection : Wear the following personal protective equipment:

Safety goggles

Skin and body protection : Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).

Hygiene measures : Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : gray, opaque

Odor : citrus

Odor Threshold : No data available

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

pH : 5.0 - 8.0

Melting point/freezing point : No data available

Initial boiling point and boiling : 95 °C

range

Flash point : > 100 °C

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : No data available

Relative vapor density : No data available

Density : 1.0390 g/cm3

Solubility(ies)
Water solubility : soluble

Partition coefficient: n- : Not applicable

octanol/water

Autoignition temperature : No data available

Decomposition temperature : The substance or mixture is not classified self-reactive.

Viscosity
Viscosity, kinematic : 10,000 - 50,000 mm2/s (20 °C)

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Can react with strong oxidizing agents.

tions

Conditions to avoid : None known.

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

Incompatible materials : Oxidizing agents

Hazardous decomposition : No hazardous decomposition products are known.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Assessment: The substance or mixture has no acute oral
toxicity
Remarks: Based on data from similar materials

Alcohols, C12-15, ethoxylated propoxylated:

Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Remarks: Based on data from similar materials

Acute inhalation toxicity : LC50 (Rat): > 1.6 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute
inhalation toxicity
Remarks: Based on data from similar materials

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Based on data from similar materials

Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation

Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Species: Rabbit
Result: Skin irritation

Alcohols, C12-15, ethoxylated propoxylated:

Species: Rabbit
Method: OECD Test Guideline 404

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

Result: No skin irritation

Remarks: Based on data from similar materials

Serious eye damage/eye irritation

Causes serious eye irritation.
Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Species: Rabbit
Result: No eye irritation

Alcohols, C12-15, ethoxylated propoxylated:

Result: Irreversible effects on the eye
Remarks: Based on data from similar materials

Respiratory or skin sensitization

Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Product:
Assessment: Does not cause skin sensitization.

Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Test Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Result: positive

Assessment: Probability or evidence of skin sensitization in humans

Alcohols, C12-15, ethoxylated propoxylated:

Test Type: Maximization Test (GPMT)
Routes of exposure: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: negative
Remarks: Based on data from similar materials

Germ cell mutagenicity

Not classified based on available information.
Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test
Result: negative

Genotoxicity in vivo : Test Type: Transgenic rodent somatic cell gene mutation as-
say
Species: Rat
Application Route: Ingestion

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

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Result: negative

Alcohols, C12-15, ethoxylated propoxylated:

Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Remarks: Based on data from similar materials

Genotoxicity in vivo : Test Type: Mutagenicity (in vivo mammalian bone-marrow

cytogenetic test, chromosomal analysis)
Species: Rat
Application Route: Ingestion
Result: negative
Remarks: Based on data from similar materials

Carcinogenicity
Not classified based on available information.
Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Species: Mouse
Application Route: Ingestion
Exposure time: 103 weeks
Result: negative

IARC No ingredient of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcino-
gen by OSHA.

NTP No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Not classified based on available information.
Ingredients:
Alcohols, C12-15, ethoxylated propoxylated:
Effects on fertility : Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: Skin contact
Result: negative
Remarks: Based on data from similar materials

Effects on fetal development : Test Type: Two-generation reproduction toxicity study

Species: Rat
Application Route: Skin contact
Result: negative
Remarks: Based on data from similar materials

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Repeated dose toxicity

Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Species: Rat
NOAEL: 600 mg/kg
Application Route: Ingestion
Exposure time: 13 w

Alcohols, C12-15, ethoxylated propoxylated:

Species: Rat
NOAEL: 500 mg/kg
Application Route: Ingestion
Exposure time: 90 d
Remarks: Based on data from similar materials

Aspiration toxicity
Not classified based on available information.
Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be
regarded as if it causes a human aspiration toxicity hazard.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.36 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l

Exposure time: 72 h
Test substance: Water Accommodated Fraction
Remarks: Based on data from similar materials

M-Factor (Acute aquatic tox- : 1

icity)

Alcohols, C12-15, ethoxylated propoxylated:

Toxicity to fish : LC50 (Scophthalmus maximus (turbot)): 3.1 mg/l

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

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Exposure time: 96 h
Remarks: Based on data from similar materials

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.14 mg/l
aquatic invertebrates Exposure time: 48 h
Remarks: Based on data from similar materials

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 0.75

mg/l
Exposure time: 72 h
Remarks: Based on data from similar materials

M-Factor (Acute aquatic tox- : 1

icity)

Toxicity to bacteria : EC50 (Pseudomonas putida): > 10,000 mg/l

Exposure time: 16.9 h
Remarks: Based on data from similar materials

Persistence and degradability

Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Biodegradability : Result: Readily biodegradable.
Biodegradation: 80 %
Exposure time: 28 d
Remarks: Based on data from similar materials

Alcohols, C12-15, ethoxylated propoxylated:

Biodegradability : Result: Readily biodegradable.
Biodegradation: 80 - 88 %
Exposure time: 28 d
Remarks: Based on data from similar materials

Bioaccumulative potential

Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Partition coefficient: n- : log Pow: 4.38
octanol/water

Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

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Contaminated packaging : Dispose of as unused product.

Empty containers should be taken to an approved waste
handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulation

UNRTDG
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(1-Methyl 4-(1-Methylethenyl) Cyclohexene)
Class : 9
Packing group : III
Labels : 9
IATA-DGR
UN/ID No. : UN 3082
Proper shipping name : Environmentally hazardous substance, liquid, n.o.s.
(1-Methyl 4-(1-Methylethenyl) Cyclohexene)
Class : 9
Packing group : III
Labels : Miscellaneous
Packing instruction (cargo : 964
aircraft)
Packing instruction : 964
(passenger aircraft)
IMDG-Code
UN number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(1-Methyl 4-(1-Methylethenyl) Cyclohexene)
Class : 9
Packing group : III
Labels : 9
EmS Code : F-A, S-F
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

Domestic regulation

49 CFR
UN/ID/NA number : UN 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(1-Methyl 4-(1-Methylethenyl) Cyclohexene)
Class : 9

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

1.0 03/02/2015 68057-00001 Date of first issue: 03/02/2015

Packing group : III

Labels : CLASS 9
ERG Code : 171
Marine pollutant : yes (1-Methyl 4-(1-Methylethenyl) Cyclohexene)
Remarks : Shipment by ground under DOT is non-regulated; however it
may be shipped per the applicable hazard classification to
facilitate multi-modal transport involving ICAO (IATA) or IMO.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Acute Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting

requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

US State Regulations

Pennsylvania Right To Know

Water 7732-18-5 70 - 90 %
Pumice 1332-09-8 5 - 10 %
1-Methyl 4-(1-Methylethenyl) Cyclohexene 5989-27-5 5 - 10 %
New Jersey Right To Know
Water 7732-18-5 70 - 90 %
Pumice 1332-09-8 5 - 10 %
1-Methyl 4-(1-Methylethenyl) Cyclohexene 5989-27-5 5 - 10 %
Alcohols, C12-15, ethoxylated propoxylated 68551-13-3 1-5%

California Prop 65 This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other
reproductive defects.

The ingredients of this product are reported in the following inventories:

REACH : All ingredients (pre-)registered or exempt.

TSCA : All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory

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GOJO® NATURAL* ORANGE™ Pumice Hand

Cleaner

Version Revision Date: MSDS Number: Date of last issue: -

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exemption.

DSL : All chemical substances in this product comply with the CEPA
1999 and NSNR and are on or exempt from listing on the
Canadian Domestic Substances List (DSL).

AICS : All ingredients listed or exempt.

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA
(USA)

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III:

Flammability

HEALTH 2
1
Instability
Health

2 0 FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
Special hazard.
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Sources of key data used to : Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/

Revision Date : 03/02/2015

The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-
formation and belief at the date of its publication. The information is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provid-
ed relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or in any process, un-
less specified in the text. Material users should review the information and recommendations
in the specific context of their intended manner of handling, use, processing and storage, in-
cluding an assessment of the appropriateness of the SDS material in the user’s end product, if
applicable.

US / Z8

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