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    1A, Exam1 StudyGuide

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    This document provides a study guide for an exam covering chapters 1-5 of a chemistry textbook. It lists the topics covered in each chapter and the key sections and concepts to study. These include the classification of matter, states of matter, physical and chemical changes, atomic theory, stoichiometry, thermochemistry, and aqueous reactions and solutions. The document also provides example problems for additional practice in these areas and covers the relevant laboratory experiments.

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    1A, Exam1 StudyGuide

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    Terry Chan Tr
    247 views2 pages
    This document provides a study guide for an exam covering chapters 1-5 of a chemistry textbook. It lists the topics covered in each chapter and the key sections and concepts to study. These include the classification of matter, states of matter, physical and chemical changes, atomic theory, stoichiometry, thermochemistry, and aqueous reactions and solutions. The document also provides example problems for additional practice in these areas and covers the relevant laboratory experiments.

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    This document provides a study guide for an exam covering chapters 1-5 of a chemistry textbook. It lists the topics covered in each chapter and the key sections and concepts to study. These include the classification of matter, states of matter, physical and chemical changes, atomic theory, stoichiometry, thermochemistry, and aqueous reactions and solutions. The document also provides example problems for additional practice in these areas and covers the relevant laboratory experiments.

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    247 views2 pages

    1A, Exam1 StudyGuide

    Uploaded by

    Terry Chan Tr
    This document provides a study guide for an exam covering chapters 1-5 of a chemistry textbook. It lists the topics covered in each chapter and the key sections and concepts to study. These include the classification of matter, states of matter, physical and chemical changes, atomic theory, stoichiometry, thermochemistry, and aqueous reactions and solutions. The document also provides example problems for additional practice in these areas and covers the relevant laboratory experiments.

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    Chemistry 1A Brown & LeMay, 11th ed

    EXAM 1 STUDY GUIDE

    Chapter 1 - Introduction: Matter and Measurement


    Classification of Matter, States of Matter, Physical and Chemical Changes, Scientific
    Method: The Periodic Table, Properties of Matter, System International and Metric Units,
    Dimensional Analysis (Factor-Label Method); Scientific Notation and Significant
    Figures, Temperature Conversions and Scales; Calculations involving Density.

    Suggested Exercises: 1.1, 1.4, 1.8, 1.11, 1.14, 1.16, 1.17, 1.19, 1.23, 1.25, 1.27, 1.31,
    1.37, 1.43, 1.45, 1.47, 1.61, 1.70, 1.76, 1.81.

    Chapter 2 - Atoms, Molecules, and Ions [Omit Section 2.9]


    Atomic Theory (Know Contributions of Dalton, Thomson, Rutherford, Millikan);
    Radioactivity, Atomic Structure, Isotopes, Moles, Molar Mass, Nomenclature,
    Ions, (Ionic Compounds); Molecules, (Covalent Compounds), Hydrates, Allotropes.

    Suggested Exercises: 2.1, 2.13, 2.15, 2.17, 2.21, 2.23, 2.25, 2.26, 2.27, 2.31, 2.35, 2.37, 2.39,
    2.49, 2.50, 2.51, 2.55, 2.57, 2.61, 2.63, 2.67, 2.69, 2.71, 2.79, 2.87, 2.88,
    2.98, 2.99, 2.102, 2.104.

    Chapter 3 - Stoichiometry: Calculations with Chemical Formulas and Equations


    Writing Chemical Equations, Predicting Products, Balancing Chemical Equations.
    Avogadroʼs Number, Empirical and Molecular Formulas, Percent Composition.
    Stoichiometry (Mole-Mole and Mass-Mass problems), Limiting Reagents,
    Yields of Reactions (Actual, Theoretical, Percent Yield),

    Suggested Exercises: 3.1, 3.10, 3.11, 3.12, 3.17, 3.19, 3.20, 3.23, 3.25, 3.27, 3.31, 3.33,
    3.35, 3.37, 3.43, 3.47, 3.49, 3.51, 3.52, 3.53, 3.57, 3.59, 3.61, 3.63, 3.65,
    3.69, 3.71, 3.73, 3.77, 3.79, 3.89, 3.93, 3.97, 3.101.

    Chapter 4- Aqueous Reactions and Solution Stoichiometry [Omit Sections 4.1 and 4.2]
    Neutralization Reactions, Concentration of Solutions (Molarity and percent by mass);
    Dilution Problems, Solution Stoichiometry and Chemical Analysis.

    Suggested Exercises: 4.61, 4.67, 4.69, 4.73, 4.75, 4.77, 4.79, 4.81, 4.83, 4.99, 4.106, 4.109.

    Chapter 5 - Thermochemistry
    Energy and Energy Changes (calories & Joules), Enthalpy, Standard Enthalpies
    {Heats} of Reaction (ΔHreaction) and Standard Enthalpies of Formation (ΔH°f );
    Calorimetry, Specific Heat, Hessʼs Law, Heats of Solution, Thermodynamics.
    Suggested Exercises: 5.4, 5.9, 5.29, 5.33, 5.17, 5.18, 5.19, 5.20, 5.22, 5.23, 5.26, 5.28, 5.29,
    5.32, 5.36, 5.38, 5.39, 5.41, 5.45, 5.49, 5.51, 5.53, 5.59, 5.61, 5.62, 5.63,
    5.65, 5.69, 5.71, 5.73, 5.77, 5.79, 5.103, 5.105.

    Laboratory Experiments: Problem solving skills like those required by most problems in the
    Experiment Reports and Study Assignments- N and A will be needed for the exam. However, no
    specific calculations from Experiment 1 will be on the exam.
    Additional Practice Problems for Exam #1
    1. An unknown organic compound is known to contain only the elements carbon, hydrogen, and oxygen.
    When 6.60 g of this organic were burned in an excess of oxygen gas, 9.90 g of carbon dioxide and 2.70 g of
    water vapor were produced. In a second experiment the molecular weight of this unknown compound was
    estimated to be 180 ± 20. What is the molecular formula of this organic compound?

    2. 186 g of sodium oxide, a basic anhydride, are to be neutralized in a 2-step method. First, the solid is
    added to excess water to produce an aqueous solution of sodium hydroxide. Second, phosphoric acid is
    added to the basic solution to completely neutralize the base, leaving an aqueous solution of sodium
    phosphate. How many milliliters of 6.00 M phosphoric acid solution would be required to accomplish this
    neutralization?

    3. 76.8 g of citric acid (MW = 192) are mixed in water with 31.4 g of calcium oxide (MW = 56.1). When
    the reaction reaches completion, how many grams of the "reagent in excess" will remain unreacted?
    2 H3C6H5O7 + 3 CaO ----> Ca3(C6H5O7)2 + 3 H2O

    4. Nutrasweet is the brand name for the sweetener Aspartame. This molecule is the ester of a dipeptide that
    contains the amino acids phenylalanine and aspartic acid. If Aspartame is known to be 27.2 % oxygen, by
    weight, and it has a molecular weight of 292 g/mole, how many oxygen atoms must be found in each
    molecule of Aspartame?

    5. Use standard heats of formation, ΔHf°, to calculate the "fuel value" of table sugar, sucrose (C12H22O11).
    The standard heat of formation of sucrose is -2221 kJ/mole. (Fuel value is the heat (kJ) produced when one
    gram of a fuel is burned.)

    6.Nitrogen oxide is known to react with ozone: NO + O3 ----> NO2 + O2. Given the information
    below, Calculate ΔH for this ozone destroying reaction.
    NO2 ----> NO + O ΔH = +304.1 kJ
    2 O ----> O2 ΔH = -495.0 kJ
    2 O3 ----> 3 O2 ΔH = -284.6 kJ

    7. If a 20 g piece of iron (S.H. = 0.45 J/g °C) is heated to 250°C and then submerged in 100 mL of water at
    •

    18°C, what will be the final temperature of this heterogeneous mixture (assuming no heat is lost to the
    surroundings and no water is lost by evaporation)?

    Answers: 1) C6H8O6 2) 333mL 3) 5.1 g citric acid 4) 5 atoms of O per molecule


    5) 16.5 kJ/g 6) –198.9 kJ 7) 23oC

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