Scribd Logo
Upload

Welcome to Scribd!

  • 131 views

    Thermochemistry: Chemistry DPP 4 by Garima Verma (Chemistry Faculty) - Referral Code: "Cgvmam"

    Uploaded by

    Tanisha Subudhi
    1. The document provides a chemistry DPP (detailed problem practice) with 18 multiple choice questions related to thermochemistry, enthalpy, heat of reactions, neutralization reactions and heats of formation. 2. The questions cover various topics including standard heats of formation, heats of combustion, heats of reaction, heat of hydrogenation, heat of dissociation, heat of neutralization and calculation of enthalpies from given thermochemical data. 3. The document is authored by Garima Verma, a chemistry faculty member and provides her referral code for the DPP.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Thermochemistry: Chemistry DPP 4 by Garima Verma (Chemistry Faculty) - Referral Code: "Cgvmam"

    Uploaded by

    Tanisha Subudhi
    131 views6 pages
    1. The document provides a chemistry DPP (detailed problem practice) with 18 multiple choice questions related to thermochemistry, enthalpy, heat of reactions, neutralization reactions and heats of formation. 2. The questions cover various topics including standard heats of formation, heats of combustion, heats of reaction, heat of hydrogenation, heat of dissociation, heat of neutralization and calculation of enthalpies from given thermochemical data. 3. The document is authored by Garima Verma, a chemistry faculty member and provides her referral code for the DPP.

    Original Description:

    Original Title

    Thermochemistry+DPP+4.docx-1

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    1. The document provides a chemistry DPP (detailed problem practice) with 18 multiple choice questions related to thermochemistry, enthalpy, heat of reactions, neutralization reactions and heats of formation. 2. The questions cover various topics including standard heats of formation, heats of combustion, heats of reaction, heat of hydrogenation, heat of dissociation, heat of neutralization and calculation of enthalpies from given thermochemical data. 3. The document is authored by Garima Verma, a chemistry faculty member and provides her referral code for the DPP.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    131 views6 pages

    Thermochemistry: Chemistry DPP 4 by Garima Verma (Chemistry Faculty) - Referral Code: "Cgvmam"

    Uploaded by

    Tanisha Subudhi
    1. The document provides a chemistry DPP (detailed problem practice) with 18 multiple choice questions related to thermochemistry, enthalpy, heat of reactions, neutralization reactions and heats of formation. 2. The questions cover various topics including standard heats of formation, heats of combustion, heats of reaction, heat of hydrogenation, heat of dissociation, heat of neutralization and calculation of enthalpies from given thermochemical data. 3. The document is authored by Garima Verma, a chemistry faculty member and provides her referral code for the DPP.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    CHEMISTRY DPP 4

    BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

    THERMOCHEMISTRY

    1 Δ𝐻𝑓0 298 K of methanol is given by the chemical equation:


    1
    (a) 𝐶𝐻4 (𝑔) + 𝑂2 (𝑔) → 𝐶𝐻3 𝑂𝐻(𝑔)
    2
    1
    (b) 𝐶(𝑔𝑟𝑎𝑝ℎ𝑖𝑡𝑒) + 𝑂2 (𝑔) + 2𝐻2 (𝑔) → 𝐶𝐻3 𝑂𝐻(𝑙)
    2
    1
    (c) 𝐶(𝑑𝑖𝑎𝑚𝑜𝑛𝑑) + 𝑂2 (𝑔) + 2𝐻2 (𝑔) → 𝐶𝐻3 𝑂𝐻(𝑙)
    2
    (d) 𝐶𝑂(𝑔) + 2𝐻2 (𝑔) → 𝐶𝐻3 𝑂𝐻(𝑙)

    2 The standard molar heats of formation of ethane, 𝐶𝑂2 and 𝐻2 𝑂(𝑙) are
    respectively – 21.1, - 94.1 and – 68.3 kcal. The standard molar heat of combustion of
    ethane will be:
    (a) – 372 kcal (b) – 240 kcal (c) 162 kcal (d) 183.5 kcal

    3 When ethyne is passed through a red hot tube, then formation of benzene takes
    place:
    0 0
    Δ𝐻𝑓(𝐶2 𝐻2 )(𝑔)
    = 230 𝑘𝐽 𝑚𝑜𝑙 −1 ; Δ𝐻𝑓(𝐶6 𝐻6 )(𝑔)
    = 85 𝑘𝐽 𝑚𝑜𝑙 −1
    Calculate the standard heat of trimerisation of ethyne to benzene.
    3𝐶2 𝐻2 (𝑔) → 𝐶6 𝐻6 (𝑔)
    (a) 205 𝑘𝐽 𝑚𝑜𝑙 −1 (b) 605 𝑘𝐽 𝑚𝑜𝑙 −1
    (c) −605 𝑘𝐽 𝑚𝑜𝑙 −1 (d) −205 𝑘𝐽 𝑚𝑜𝑙 −1

    4 𝐹2 (𝑔) + 2𝐻𝐶𝑙(𝑔) → 2𝐻𝐹(𝑔) + 𝐶𝑙2 (𝑔); Δ𝐻0 = −352.18 𝑘𝐽


    Δ𝐻𝑓0(𝐻𝐹) = −268.3 𝑘𝐽
    The heat of formation of HCl will be :
    (a) −22 𝑘𝐽 𝑚𝑜𝑙 −1 (b) 88 𝑘𝐽 𝑚𝑜𝑙 −1
    (c) −92.21 𝑘𝐽 𝑚𝑜 −1 (d) −183.8 𝑘𝐽 𝑚𝑜𝑙 −1

    5 Given two processes :


    1
    𝑃 (𝑠) + 3𝐶𝑙2 (𝑔) → 2𝑃𝐶𝑙3 (𝑙); Δ𝐻 = −635 𝑘𝐽
    2 4
    𝑃𝐶𝑙3 (𝑙) + 𝐶𝑙2 (𝑔) → 𝑃𝐶𝑙5 (𝑠); Δ𝐻 = −137 𝑘𝐽
    The value of Δ𝐻𝑓 of 𝑃𝐶𝑙5 is:
    CHEMISTRY DPP 4

    BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

    (a) 454.5 𝑘𝐽 𝑚𝑜𝑙 −1 (b) −454.5 𝑘𝐽


    (c) −772 𝑘𝐽 𝑚𝑜𝑙 −1 (d) −498 𝑘𝐽 𝑚𝑜𝑙 −1

    6 The enthalpies of combustion at 250 𝐶 of 𝐻2 , cyclohexane (𝐶6 𝐻12 ) and


    cyclohexene 𝐶6 𝐻10 ) are – 241, −3920 and −3800 kJ/mol respectively. The heat of
    hydrogenation of cyclohexene is :
    (a) −121 𝑘𝐽/𝑚𝑜𝑙 (b) +121 𝑘𝐽/𝑚𝑜𝑙
    (c) −242 𝑘𝐽/𝑚𝑜𝑙 (d) +242 𝑘𝐽/𝑚𝑜𝑙

    7 Given that:
    3
    2𝐹𝑒(𝑠) + 𝑂2 (𝑔) → 𝐹𝑒2 𝑂3 (𝑠) (Δ𝐻 = −193.4 𝑘𝐽) …..(i)
    2
    1
    𝑀𝑔(𝑠) + 𝑂2 (𝑔) → 𝑀𝑔𝑂(𝑠) ( Δ𝐻 = −140.2 𝑘𝐽) …..(ii)
    2
    What is Δ𝐻 of the reaction?
    3𝑀𝑔 + 𝐹𝑒2 𝑂3 → 3𝑀𝑔𝑂 + 2𝐹𝑒
    (a) −227.2 𝑘𝐽 (b) −272.3 𝑘𝐽 (c) 227.2 𝑘𝐽 (d) 272.3 𝑘𝐽

    8 Given that:
    2𝐶(𝑠) + 2𝑂2 (𝑔) → 2𝐶𝑂2 (𝑔) (Δ𝐻 = −787 𝑘𝐽) …....(i)
    1
    𝐻2 (𝑔) + 𝑂2 (𝑔) → 𝐻2 𝑂(𝑙) (Δ𝐻 = −286 𝑘𝐽) ……(ii)
    2
    5
    𝐶2 𝐻2 (𝑔) + 𝑂2 (𝑔) → 2𝐶𝑂2 (𝑔) + 𝐻2 𝑂(𝑙) (Δ𝐻 = −1301 𝑘𝐽) ……(iii)
    2

    Heat of formation of acetylene is:


    (a) −1802 𝑘𝐽 (b) +1802 𝑘𝐽 (c) −800 𝑘𝐽 (d) +228 𝑘𝐽

    9 The enthalpy changes for two reactions are given by the equations:
    3
    2𝐶𝑟(𝑠) + 𝑂2 (𝑔) → 𝐶𝑟2 𝑂3 (𝑠); Δ𝐻 = −1130 𝑘𝐽
    2
    1
    𝐶(𝑠) + 𝑂2 (𝑔) → 𝐶𝑂(𝑔); Δ𝐻 = −110 𝑘𝐽
    2
    What is the enthalpy in kJ for the following reaction?
    3𝐶(𝑠) + 𝐶𝑟2 𝑂3 (𝑠) → 2𝐶𝑟(𝑠) + 3𝐶𝑂(𝑔)
    (a) −1460 𝑘𝐽 (b) −800 𝑘𝐽 (c) +800 𝑘𝐽
    (d) +1020 𝑘𝐽 (e) +1460 𝑘𝐽
    CHEMISTRY DPP 4

    BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

    10 The enthalpy change Δ𝐻 for the neutralisation of 1 M HCl by caustic potash in


    dilute solution at 298 K is :
    (a) 68 kJ (b) 65 kJ (c) 57.3 kJ (d) 50 kJ

    11 Enthalpy of neutralisation of the reaction between 𝐶𝐻3 𝐶𝑂𝑂𝐻 (aq) and NaOH(aq)
    is – 13.2 kcal 𝑒𝑞 −1 and that of the reaction between 𝐻2 𝑆𝑂4 (𝑎𝑞) and KOH(aq0 is –
    13.7 kcal 𝑒𝑞 −1 . The enthalpy of dissociation of 𝐶𝐻3 𝐶𝑂𝑂𝐻(𝑎𝑞. ) is :
    (a) −0.5 𝑘𝑐𝑎𝑙 𝑒𝑞 −1 (b) +0.5 𝑘𝑐𝑎𝑙 𝑒𝑞 −1
    (c) −26.9 𝑘𝑐𝑎𝑙 𝑒𝑞 −1 (d) +13.45 𝑘𝑐𝑎𝑙 𝑒𝑞 −1

    12 Calculate the enthalpy change when 50 mL of 0.01 M 𝐶𝑎(𝑂𝐻)2 reacts with 25 mL


    of 0.001 M HCl. Given that Δ𝐻0 neutralization of a strong acid and a strong base is
    140 kcal 𝑚𝑜𝑙 −1 .
    (a) 14 kcal (b) 35 cal (c) 10 cal (d) 7.5 cal

    13 Equal volumes of 1 M HCl and 1 M 𝐻2 𝑆𝑂4 are neutralised by 1 M NaOH solution


    and x and y kJ/equivalent of heat are liberated respectively. Which of the following
    relations is correct?

    (a) 𝑥 = 2𝑦 (b) 𝑥 = 3𝑦 (c) 𝑥 = 4𝑦 (d) 𝑥 = 1⁄2 𝑦

    14 Which of the following acid will release maximum amount of heat when
    completely neutralised by strong base NaOH?
    (a) 1 M HCl (b) 1 M 𝐻𝑁𝑂3 (c) 1 𝑀 𝐻𝐶𝑙𝑂4 (d) 1 𝑀 𝐻2 𝑆𝑂4

    15 Determine the heat of the following reaction:


    𝐹𝑒𝑂(𝑠) + 𝐹𝑒2 𝑂3 (𝑠) → 𝐹𝑒3 𝑂4 (𝑠)
    Given informations :
    2𝐹𝑒(𝑠) + 𝑂2 (𝑔) → 2𝐹𝑒𝑂(𝑠); Δ𝐻0 = −544 𝑘𝐽
    4𝐹𝑒(𝑠) + 3𝑂2 (𝑔) → 2𝐹𝑒2 𝑂3 (𝑠); Δ𝐻0 = −1648.4 𝑘𝐽
    CHEMISTRY DPP 4

    BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

    𝐹𝑒3 𝑂4 (𝑠) → 3𝐹𝑒(𝑠) + 2𝑂2 (𝑔); Δ𝐻0 = +1118.4 𝑘𝐽


    (a) −1074 𝑘𝐽 (b) −22.2 𝑘𝐽
    (c) +249.8 𝑘𝐽 (d) +2214.6 𝑘𝐽

    16 Calculate the enthalpy of formation of Δ𝐻𝑓 𝑓𝑜𝑟 𝐶2 𝐻5 𝑂𝐻 from tabulated data


    and its heat of combustion as represented by the following equations:

    𝐻2 (𝑔) + 1⁄2 𝑂2 (𝑔) → 𝐻2 𝑂(𝑔) (Δ𝐻0 = −241.8 𝑘𝐽 𝑚𝑜𝑙 −1 ) ……..(i)


    𝐶(𝑠) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔) (Δ𝐻0 = −393.5 𝑘𝐽 𝑚𝑜𝑙 −1 ) ……..(ii)
    𝐶2 𝐻5 𝑂𝐻(𝑙) + 3𝑂2 (𝑔) → 3𝐻2 𝑂(𝑔) + 2𝐶𝑂2 (𝑔) (Δ𝐻0 = −1234.7 𝑘𝐽)…….(iii)

    (a) −2747.1 𝑘𝐽 𝑚𝑜𝑙 −1 (b) −277.7 𝑘𝐽 𝑚𝑜𝑙 −1


    (c) 277.7 𝑘𝐽 𝑚𝑜𝑙 −1 (d) 2747.1 𝑘𝐽 𝑚𝑜𝑙 −1

    17 Given that
    𝐶(𝑠) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔); Δ𝐻0 = −𝑥𝑘𝐽
    2𝐶𝑂(𝑔) + 𝑂2 (𝑔) → 2𝐶𝑂2 (𝑔); Δ𝐻0 = −𝑦𝑘𝐽
    The enthalpy of formation of CO will be :
    𝑦−2𝑥 𝑦−2𝑥 2𝑥−𝑦 𝑥−𝑦
    (a) (b) (c) (d)
    3 2 2 2

    18 Heats of combustion of diamond and graphite are – 94.5 kcal and – 94 kcal/mol
    respectively. What will be the heat of transition from diamond to graphite?
    (a) −0.5 𝑘𝑐𝑎𝑙 (b) +0.5 𝑘𝑐𝑎𝑙 (c) 1 kcal (d) −1 𝑘𝑐𝑎𝑙

    19 For the reaction,


    3𝑁2 𝑂(𝑔) + 2𝑁𝐻3 (𝑔) → 4𝑁2 (𝑔) + 3𝐻2 𝑂(𝑔); Δ𝐻0 = −879.6 𝑘𝐽
    If Δ𝐻𝑓0 [𝑁𝐻3 (𝑔)] = −45.9 𝑘𝐽 𝑚𝑜𝑙 −1 ;
    Δ𝐻𝑓0 [𝐻2 𝑂(𝑔)] = −241.8 𝑘𝐽 𝑚𝑜𝑙 −1
    Then Δ𝐻𝑓0 [𝑁2 𝑂(𝑔)] will be :
    (a) +246 𝑘𝐽 (b) +82 𝑘𝐽 (c) −82 𝑘𝐽 (d) −246 𝑘𝐽

    20 The bond energies of 𝐶 = 𝐶 and 𝐶 − 𝐶 at 298 K are 590 and 331 kJ 𝑚𝑜𝑙 −1
    respectively. The enthalpy of polymerization per mole of ethylene is
    CHEMISTRY DPP 4

    BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

    (a) −70 𝑘𝐽 (b) −72 𝑘𝐽 (c) 72 kJ (d) −68 𝑘𝐽

    21 For the reaction,


    2𝐻2 (𝑔) + 𝑂2 (𝑔) → 2𝐻2 𝑂(𝑔); Δ𝐻 = −571 𝑘𝐽
    bond energy of (𝐻 − 𝐻) = 435 kJ; of (𝑂 = 𝑂) = 498 kJ; then calculate the average
    bond energy of (𝑂 − 𝐻) bond using the above data.
    (a) 484 kJ (b) – 484 kJ
    (c) 271 kJ (d) – 271 kJ

    22 Use the bond energies in the table to estimate Δ𝐻 for this reaction:
    𝐶𝐻2 = 𝐶𝐻2 + 𝐶𝑙2 → 𝐶𝑙𝐶𝐻2 − 𝐶𝐻2 𝐶𝑙
    Bond 𝑪−𝑪 𝑪=𝑪 𝑪 𝑪 𝑪𝒍
    − 𝑪𝒍 − 𝑯 − 𝑪𝒍
    Bond 347 612 331 414 243
    energy
    (𝑘𝐽⁄𝑚𝑜𝑙 )
    (a) Δ𝐻 = −684 𝑘𝐽 (b) Δ𝐻 = −154 𝑘𝐽
    (c) Δ𝐻 = +89 𝑘𝐽 (d) Δ𝐻 = +177 𝑘𝐽

    23 Heat of formation of 2 moles of 𝑁𝐻3 (𝑔) is – 90 kJ; bond energies of 𝐻 − 𝐻 and


    𝑁 − 𝐻 bonds are 435 kJ and 390 kJ 𝑚𝑜𝑙 −1 respectively. The value of the bond
    energy of 𝑁 ≡ 𝑁 will be:
    (a) −472.5 𝑘𝐽 (b) −945 𝑘𝐽 (c) 472.5 𝑘𝐽 (d) 945 𝑘𝐽 𝑚𝑜𝑙 −1

    24 If values of Δ𝐻𝑓0 of 𝐼𝐶𝑙(𝑔), 𝐶𝑙(𝑔) 𝑎𝑛𝑑 𝐼(𝑔) are respectively 17.57, 121.34 and
    106.96 J 𝑚𝑜𝑙 −1 . The value of 𝐼 − 𝐶𝑙 (bond energy) in J 𝑚𝑜𝑙 −1 is:
    (a) 17.57 (b) 210.73 (c) 35.15 (d) 106.96

    25 Calculate the Δ𝐻 in joules for:


    𝐶(𝑔𝑟𝑎𝑝ℎ𝑖𝑡𝑒) → 𝐶 (𝑑𝑖𝑎𝑚𝑜𝑛𝑑)
    from the following data:
    𝐶(𝑔𝑟𝑎𝑝ℎ𝑖𝑡𝑒) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔); Δ𝐻0 = −393.5 𝑘𝐽
    𝐶(𝑑𝑖𝑎𝑚𝑜𝑛𝑑) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔); Δ𝐻0 = −395.4 𝑘𝐽
    (a) 1900 (b) −788.9 × 103
    CHEMISTRY DPP 4

    BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

    (c) 190000 (d) +788.9 × 103

    26 The enthalpy changes for the following processes are listed below:
    𝐶𝑙2 (𝑔) → 2𝐶𝑙(𝑔); Δ𝐻 = 242.3 𝑘𝐽 𝑚𝑜𝑙 −1
    𝐼2 (𝑔) → 2𝐼(𝑔); Δ𝐻 = 151.0 𝑘𝐽 𝑚𝑜𝑙 −1
    𝐼𝐶𝑙(𝑔) → 𝐼(𝑔) + 𝐶𝑙(𝑔); Δ𝐻 = 211.3 𝑘𝐽 𝑚𝑜𝑙 −1
    𝐼2 (𝑠) → 𝐼2 (𝑔); Δ𝐻 = 62.76 𝑘𝐽 𝑚𝑜𝑙 −1
    Given that, the standard states for iodine and chorine are 𝐼2 (𝑠)𝑎𝑛𝑑 𝐶𝑙2 (𝑔), the
    standard enthalpy of formation for ICl (g) is :
    (a) −14.6 𝑘𝐽 𝑚𝑜𝑙 −1 (b) −16.8 𝑘𝐽 𝑚𝑜𝑙 −1
    (c) +16.8 𝑘𝐽 𝑚𝑜𝑙 −1 (d) +244.8 𝑘𝐽 𝑚𝑜𝑙 −1

    27 Given that:
    2𝐶(𝑠) + 𝑂2 (𝑔) → 2𝐶𝑂2 (𝑔) (Δ𝐻 = −787 𝑘𝐽) ……..(i)
    𝐻2 (𝑔) + 1⁄2 𝑂2 (𝑔) → 𝐻2 𝑂(𝑙) (Δ𝐻 = −286 𝑘𝐽) ……..(ii)
    𝐶2 𝐻2 (𝑔) + 2 1⁄2 𝑂2 (𝑔) → 2𝐶𝑂2 (𝑔) + 𝐻2 𝑂(𝑙) (Δ𝐻 = −1310 𝑘𝐽) …….(iii)

    The heat of formation of acetylene is:


    (a) −1802 𝑘𝐽 𝑚𝑜𝑙 −1 (b) +1802 𝑘𝐽 𝑚𝑜𝑙 −1
    (c) +237 𝑘𝐽 𝑚𝑜𝑙 −1 (d) −800 𝑘𝐽 𝑚𝑜𝑙 −1

    28 If the bond energies of 𝐻 − 𝐻, 𝐵𝑟 − 𝐵𝑟 𝑎𝑛𝑑 𝐻 − 𝐵𝑟 are 433, 192 and 364 kJ


    𝑚𝑜𝑙 −1 respectively, then Δ𝐻0 for the reaction:
    𝐻2 (𝑔) + 3𝐵𝑟2 (𝑔) → 2𝐻𝐵𝑟(𝑔) is :
    (a) −261 𝑘𝐽 (b) +103 𝑘𝐽 (c) +261 𝑘𝐽 (d) −103 𝑘𝐽

    ANSWER KEYS
    1. B 2. A 3. C 4. C 5. B 6. A 7. A
    8. D 9. C 10. C 11. B 12. B 13.D 14.D
    15. B 16. B 17. B 18. B 19.B 20.B 21.A
    22. B 23. D 24. B 25. A 26.C 27.C 28.D

    You might also like