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Examination
S i m u l a t e d

Highly Class
XII
A CBSE Max. Marks: 70

Time 3 hrss
on given
type based
compulsory.

are
questions
All A s s e r t i o n - R e a s o n
carrvina
I n s t r u c t i o n s

in
this
question
paper.

having
or
four MCQs A s s e r t i o n - R e a s o n type
questions

questjons
are 33 questions and
1
There case-based
MCQs
3 to 16
are
1-2 are

2
Section A:Q no. I mark and Question each. y21
marks
each carrying
2
passage and carry 2f
I mark each
short
answer typeI questions and 3 carry
marks
each. s

17 to 25 are
questions
8 Section B:Q no. short
answer type II marks each.
5
26 to 30
are
carrying
4
Section C:Q no. long
answer
questions
provided.
31 to 33 are
have been
5 Section D:Q no.
an
internal
choices

choice. However,
no
overall
There 1s
not permitted.
log tables is
6
and
7Use
of calculators (1 Marks
SECTIONA: Objective Questions

Passage Based Questions (1x4-4 Marts

below and answer the following questions
1. Read the passagegiven
atom or group (X) by another (Y):
the replacement of
one
Substitution reactions involve

RX +Y RY +X
hydrogen atom is replaced oy
substitution reaction, in which a
The halogenation of alkanes is a
halogen atom (X =H, Y=halogen).
Reactions of this radical-chain mechanisms in which the
bonds are broKEL
type proceed by in whicn
formed by atoms or radicals as reactive intermediates. This mode of bond-breaking,
electron goes with R and the other with X, is called homolytic bond cleavage:
R : X +Y'--> X*'+ R:Y (a homolytic substitution reaction
ms
There are a large number of reactions, usually occurring in solution, that do not involve a
noly
radicals but rather involve ions. They occur by heterolytic cleavage as opposed to hoia
s i d e r e

cleavage of electron-pair bonds. In heterolytic bond cleavage, the electron pair can be co1
to go with one or the other of the groups R and X when the bond is broken. As one example
sample
Question Paper 2 47
that it has an unshare electron pair (iii) The reagent which can react with
groupsuch
negative 1on. A heterolytic 2-bromopropane to give mainlya
nd
and also is a

substitution reaction in which the R : X bonding substitution product is

Dait goes with Xwould
lead to RY and:X° (a) sodium sulphate (b) sodium cyanide
R:X +:Y X +R:Y (c) sodium chloride (d) sodium ethoxide
Ans. (b) Cyanide ions mainly acts as nucleophile therefore
(aheterolytic substitution reaction.) give substitution with 2-bromopropane. (1)
Substitution reactions can proceed by ionic or iv) n-butane on monobromination gives
which the bonds cleave
nolar mechanism in three isomers. The product obtained
heterolytically elimination reactions that result when the major monobromo product is
in the formation of carbon-carbon multiple heated with alc. KOH will be
bonds: (a) but-1-ene (b) but-2-ene
(c) 2-ethoxybutane (d) butan-2-ol
-Y+ X Substitution
Or
H X
c-C+HY + X Elimination Reaction of tert-butyl bromide with
aqueous sodium hydroxide follows
These reactions often are influenced profoundly (a) Sy1 mechanism
by seemingly minor variations in the structure (b) Sy2 mechanism
of the reactants, in the solvent, or in the (c) Any of the above two depending upon
temperature. temperature of reaction
(d) E mechanism
The following questions (i-iv) are multiple choice
Ans. (b) CH,CHCHCH3 Br2
questions. Choose the most appropriate answer: nbutane Heat

6) In a nucleophilic substitution reaction, the Br

least reactive compound is
(a) CH CH,Ci (b) (CH) CCl
CH3-CH2--CHa+ CH3-CH2--CH
Br H
(c) CH=CHCI (d) CH =CHCH,C 1bromobutane (minor) 2-bromobutane (majon)
Ans. (c) Vinyl halides (CH2=CHCI) are least reactive
towards nucleophilic reaction because of double bond
character inC-X bond. (1) CHa-C=C-
KOH/A CH3
But-2-ene (1)
CH pr
(a) SN1 reaction occurs between tert-butyl bromide
1) CHC-CHX, on treatment with a and hydroxide ion and tert-butyl alcohol is formed.

CH CHa
CH Nu HC-C-Br+ NaOH(ag) HCÇ-OH
Sy1
nucleophile gives CH CH,CH CH3 CH3
tert butylbromide
(1) tert butyl acohol

CH3 2. Read the passage given below and answer

nbe which condition, the product yield will the following questions (1x4-4 Marks)
maximum?
In crystalline solids, atoms or molecules are
(a) cCl as a solvent, X = Cl arranged in a regular and long range order
(6) H,O as a solvent, X = Cl
fashion in a three dimensional pattern. These
c) CCl as a solvent, X =I
have sharp melting point, flat faces, sharp
ld) H,O as a solvent, X = I
Ans. edges, bounded by well defined planes. A large
(d) Given action is unimolecular nucleophilic
Substitution (S1) reaction. Rate of Sy1 will be more in number of unit cells, each of which possess a
polar protic solvent definite geometry bounded by plane faces
along with good leaving group. ( give
 crystal, the
sodium
chloride
coorclin

ions form fcc latice,

ation numt
Ans. (b) In crystal lattice,
Ci
is 6. In dtthe
at
the
of Na octahedralvoids and
48 ofa
crystal.
A
point

of
each
Nat ions occupy
all
n u m b e r for
tions and anions i n the
catior
formation
for 1/8 coordination
contributes
the an
edge is 6 : 6
rise
to cell along structure
unit point cell. packed
corner
of
unit
cell. A
point
to
unit
(A) Zinch and wurtz
blende
to
a r r a n g e m e n t of Sion
such each
e ach
Assertion

such
point
for 1/4 ofeach contributes
for 1
is
(i1)
both have fcc ions.
Reason (R) Zinc blende has 4 formula uni
contribute
number

centred
point Coordination

A body e a c h ion

points
to unit
cel.
neighbours
that
Wurtzite has 6 for) ormula units.
such ions. whereas

the
number
ofnearest oppositely
charged
a are
incorrect bUt
Heason is correct
by an
Ans.() Assertion blende has fcc arrangement ofs2.
bcc is
surrounded

is
cell in sc,
fcc and 2' 22 statement. Zinc
has hep arrangement
of S< ions
Radius ofunit while wurtzite
ofcel hcp 1s more closely packed
andwhere a is edge
length
(ii) Assertion (A)
than ccp.
in ccp and has COordination
When particles
are closely packed
generated.
Reason (R) hcp and ccp
voids are
number 12.
structure, two types of
hcp in a lattice
octahedral voids present incorrect and Reason is correct.
Number of Ans.
Ans (d) Assertion is
number of close packed particles. closest packed since space
is equal to the hep and cop are equally
voids is twice the
ocCupied in both 70%.
tetrahedral
The number of
voids. number 12.
Both have coordination
=

number of octahedral
In ionic solids, the bigger ions (anions) form (v) Assertion (A) The total number of atoms

this close packed structure while

the smaller cubic unit cell is one.
present in a simple
ions (usually cations) occupy these voids.
Reason (R) Simple cubic unit cell has
Depending on the size of smaller ion, voids are atoms at its corners, each of which is
occupied. If the ion is small enough then shared between eight adjacent unit cells.
tetrahedral voids are occupied, if bigger then Or Assertion (A) The packing efficiency of
octahedral voids are occupied. Not all1 hcp and fcc arrangement is equal.
tetrahedral or octahedral voids are
completely Reason (R) In hcp packing, each spheres
occupied.
surrounded by twelve other spheres.
In these
questions (Q.No. i-iv)
statement ofa Ans. (a) Both Assertion and Reason
correct
Assertion followed by a
statement of Reason is and the Reason is correct
are
statements
given. ChoOse the correct Or
explanation for Assertion.
answer out of the (b)In hcp as well as ccp packing each
followingchoices: Surrounded by twelve other sphere is
(a) Assertion and spheres. Thus, the packl
Reason both are correct efficiency of hop and foc arrangement is
statements and Reason is
Thus, both equal.
for Assertion. correct Assertion
(b) Assertion and explanation Reason is not the
correct
and Reason are correct wherea
statements butReason both are correct
T explanation of Assertion.
Reason is not
explanation for Assertion. correct Multiple Choice Questions
(c) Assertion is correct Following questions (No.
(d)
Wrong statement. statement but Reason
is
choice questions carrying 1 3-11) are mulu
Assertion is wrong 3. mark each:
correct statement. statement but Reason
is
Reduction
given potentials of some ions are
()Assertion below.
the (A) In
sodium order of Arrange them
em in decreasing
coordination number chloride crystal, oxidising power.
Reason (R) of
sodium atomNasis is 6.
lon
than chlorineTheatom. Reduction potential E°N CIO BrO4
smaller 104
(a) Cio 1.19 1.65 1.74

(c)
IO > BrO; (b) IO >BrOs CI0
BrO>10 >ClO >
(d) BrO >CIO >104
BrO>CIO4 °
 ole Question Paper 2
49
Or Which.
f the following are peroxoacids of
6. Which of the
sulphur? following elements can be
H, S,O
and involved in p,-d, bonding?
a) H,SO, (a) Carbon
and H,S,O,
(b) H, SOs (b) Nitrogen
and H,S,Og
(c) HS,0, (c) Phosphorus
and H,S,O,
(d) HS,O (d) Boron
c) Higher
Ans. () Higher is the reduction potential, higher will be its
Ans. (c) Phosphorus is involved in
oxidising power. p,d, bonding. (1)
Therefore, correct order is
7. Halogenation, sulphonation,
BOg (1.74 V)> 104 (1.65 V)> CI0g (1.19v) Friedel-Craft's reaction of haloarene
(1)
Or Comes under
a)Peroxoacids ofsulphur are (a) nucleophilic substitution reaction of
Peroxodisuphuric acid-H,S0g benzene
Peroxomonosulphuric acid-HSO (1) (b) electrophilic substitution reaction of
benzene
4, IUPAC name of the compound
(c) addition reaction of benzene
CH-CH-OCH, is
(d) elimination reaction of benzene

Or
CH3
Consider the following reaction,
(a) 1-methoxy-l-methylethane
(b) 2-methOxy-2-methylethane A(Major)
(c) 2-methoxypropane Cla, Anhyd. FeCl3
(d) isopropyl methyl ether CI

Principal
Conc. H2SO4
Ans.o)CHg-CH-OCH3 chain CH3,Cl
Anhyd.
AlGB (Major)
(Major)
CH3
2methoxypropane
CH3,COCI,
Anhyd. AICl3
The lUPAC name of the above compound is
2-methoxypropane and correct option is (c). (1) (Major)

5. Which of the following represents the Products A, B, C andDrespectively are

expression for 5/6 life of a first order (a) 1, 4-dichloro benzene, 1-chloro-4-methyl
benzene, 4-chloro acetophenone,
reaction?
4-chloro benzene sulphonic acid
k
a) log (b) 1-dichloro benzene, 2-chlorobenzene
2.303
sulphonic acid, 1-chloro-2-methyl
(b)2.303 5 benzene, 4-chloro acetophenone.
k (c) 1, 2-chloro-benzen 1-chloro-4-methyl
c)2.303
log 6 benzene, 4-chloroacetophenone
k 4-chlorobenzene sulphonic acid.
(d) 1, 2-dichloro benzene, 4-chlorobenzene,
d 1og 5
k 2-chloroacetophenone, 1-chloro-2-methyl
benzene
Ans.(o) sI2303o9/6 k Ans. (b) Haloarenes undergo electrophilic substitution
reactions of benzene ring such as halogenation,
2.305K 1og6
t=
(1) nitration, sulphonation and Friedel-Crafts reaction. (1)
50 O
C

reactions are as
follows,
C C
aComplete
(Minor)

CI
Major Cly FeC C
C
C CH
C CHC
SOH Cone conc H |Anhyd.AIC
(Minor) CH3
CHa,COC
Anhyd. AlC (Major)
Mino SOgH C
CI
(Major)
COCH3

(Minor) COCH3
(Major)

oxidation state is Ans. (a)

NP*= (Ar130®|1 1 1 1 1
8. Which of the following electrons 2
for all lanthanoids? Number of unpaired
common

(a) +2 (b) +3 (c) +4 (d) +5

Hence, magnetic momentu =/nn +2) =V8
oxidation state which is = 2.84 BM
Ans. (6) Al lanthanoids have +3
common for lanthanoids (1) Or
4
when
9. Adsorption attains the equilibrium, (c) Oxidation state of Ti in TiF=Ti*
(a) TAS=AH = [Ne]3s, 3p° (no unpaired electrons)
(b) AH = +ve
C) AG=- ve or +ve Oxidation state of Cu in CuCl2 = Cu
(d) AS= -ve and AH = + ve
=[Ar]3d (no unpaired electrons)
Ans. a) Adsorption attains the equilibrium, when TAS =AH
At equilibrium, AG = 0 (1)
Both are colourless species
10. The 11. Which of the two properties of solids a
'spin-only' magnetic moment [in illustrated in the figures A and Bbelow
units of Bohr magneton,
(u)] of Ni* in
aqueous solution would be
(atomic number of Ni 28) =
(Nat
(a) 2.84 (b) 4.90 (c) 0 (d) 1.73
Or
Out of
(At. no.
TiF,CoF,Cu,Cl,
of Ti= 22, Co=
and NiCl
27, Cu=29 and
Ni 28), the colourless
(a) TiF and species are (cr) (va(cr)Na
CoF A) (B)
(b) Cu,Cl and NiCl
(A) (B)
(c) TiFand Cu,Cl (a) impurity defect F-centre
(d) CoF and (b) F-centre
NiCi impurity defect
(c) Schottky defect impurity defect
(d) Schottky defect Frenkel defect
 3 N 6

mple Question Paper 2

51
Or
13. Assertion
Ifa is the length of the side of a cube, the Decomposition of gaseous
ammonia on a hot platinum surface is a
distance between the body centred atomn
zero order reaction at
and one corner atom in the cube will be high pressure.
Reason At high pressure, the metal
2 (b) a
surface gets saturated with gas
V3
molecules.
(c)a Ans. (a) Decomposition of
gaseous ammonia on a hot Pt
is a zero order reaction at
high pressure,
Ans. (a) The figure A is of impurity defect while figure B is of
F-centre. 2NHg g)1130 K N2(g)+ 3H29)
Pt catalyst
Impurity defect arises when foreign atoms or ions are
present in the lattice site or in the interstitial sites. Rate=k [NH31° =k
The anionic sites occupied by unpaired electrons are In this reaction, Pt acts as a
called F-centres.
catalyst. The metal
(1) Surface gets saturated with gas molecules at
high
Or pressure. Thus, a further change in reaction
(dIn bcc, 2 atoms are present. One atom lie at the conditions does not alter the amount of ammonia on
centre of cube while, other lies at the corner of the the surface of the catalyst makirng rate of the reaction
cube. Hence, the distance between the body centred independent of its concentration.
and one corner atom is half of the body diagonal, Hence, both Assertion and Reason are correct and
Reason is the correct explanation of Assertion.
iea (1)
(1)
14. Assertion [Fe(CN),P ion shows
Assertion-Reason magnetic moment corresponding to two
In the following questions (Q.No. 12-16) a statement unpaired electrons.
of Assertion followed by a statement of Reason is
given. Choose the correct answer ouf of the Reason [Fe(CN), has d' sp' type
choices.
following hybridisation.
(a) Assertion and Reason both are correct Ans. () Assertion is incorrect but Reason is correct.
statèments and Reason is correct explanation FeCN)E shows d 'sp type of hybridisation.
for Assertion. It has one unpaired electrons. Hence, it shows
(b) Assertion and Reason both are correct magnetic moment.
statements but Reason is not correct Hence, Assertion is incorrect but Reason is correct. (1)
explanation for Assertion.
c) Assertion is correct statement but Reason is 15. Assertion Carboxylic acids are more acidic
than phenols.
wTong statement.
d) Assertion is wrong statement but Reason is Reason The carboxylate ion is less
correct statement. stabilised than phenoxide ion.
12/Assertion When scuba divers come towards Or
Surface, their capillaries get blocked which Assertion (A) Ester
hydrolysis is fast in
1S painful and dangerous to life. the beginning and becomes slow after
Reason There occurred release of sometimme.
dissolved gases as the pressure decreases Reason (R) The rate of ester
and leads to the formation of bubbles of
hydrolysis
increases with the increase in the amount
nitrogen in the blood. of carboxylic acid produced.
ns. (a) When scuba divers Ans. (c) Carboxylate ion is more stable than phenoxide ion
come towards Surtace,
pressure gradually decreases. This releases the due to two equivalent resonating structures in which
dissolved gases and leads to the formation of negative charge is at the O-atom. In phenoxide ioon,
bubbles of nitrogen in the blood. negative charge is at the less-electronegative carbon
atom. Therefore,
Hence, both Assertion and Reason are correct and corresponding acid of the carboxylate
ion, i.e. carboxylic acid is more acidic than
Heason is the correct (1) phenol.
explanation of Assertion. Hence, Assertion is correct but Reason is incorrect.
(1)
 iSucceed Chemistr
try Class
Reason Nitrogen of
aniline
52 positive charge ini the presen acqui
ce otre:A
Or
beginning
and
Aniline does
not undergo Friede
(a)
and acetylation) due to a t s
in the small Ans.
is slow a
hydrolysis (alkylation
iomalion
because

(0) Ester sometime

added in
the Lewis acid) whichis
becomes
faster after
acid is with AlClg, (the
dilute sulphuric
reaction
a
amount of reaction. As the ester
catalyst.
start the rate of nitrogen of aniline acquires
Due to this
beginning
to The es positive the
is produced.
amount
the
proceeds,
RCOOH

with the
i n c r e a s e in
and hence,
act as a stron
deactivating group
hydrolysis
increases
further reaction. t
acid produced. Reason is correct. (1) Assertion and Reason ara
of carboxylic but Hence, both
Hence,
Assertion is
incorrect

undergo Reason is the correct lanation of Asser corect and

Aniline
does not
Assertion
16. alkylation and acetylation.

1 Questions n.

SECTIONB:Short
Answer Type Mar
Also, the materials
and
of
made up
decorative than those ofiron
aluminium l0ok mog
aluminium

Dow's process.
attractive
Describe the Is also not required,
17. Besides this, painting
Or
copper not replace hydr
for the following:
reason 19. () Why does roga
Assign of phenol, from acids?
reaction, instead
i) In Kolbe's for Mn, Ni and Zn
phenoxide ion is
treated with CO. (i) Why E° values than expected?
are
negative
is an acid, yet it
more

(i) Although, phenol sodium Or

does not react
with
ionisation enthalpy of Cris
bicarbonate.
) Why first
fusion with NaOH at 623
K and lower than that of Zn?
Ans. Chlorobenzene on which on
sodium phenoxide which is mon
320 atm pressure gives
known as (i) Out of Cu, Cl2 and CuCl,
reaction is
acidification phenol. This
yields stable and why?
Dow's prOcess. from acids
ONa OH Ans. ) Copper does not replace hydrogen less reacthe
because Cu has positive E° value, i.e.
Cl

+NaOH 320
623K
atm O -NaCl
HCI O J
than hydrogen which has electrode potenital 00OV
(i) Negative values of Mn and Zn are related
Chlorobenzene Sodium Phenoi stabilities of half-filled and completely filled
phenoxide E° valuel
2) configuration respectively. But for Ni,
of
Or related to the highest negative enthalpy
hydration. Hence, E° values for Mn, Ni and Zn a
) Phenoxide ion is more reactive than phenol
towards electrophilic aromatic substitution and, more negative than expected
thus it undergoes electrophilic substitution with Or
CO2 which is a weak electrophile. (1) (0 First ionisation enthalpy of Cr is less than tnai
Gi) Phenol is a weaker acid than carbonic acid. because after the removal of first electron,
Therefore, It does not liberate CO2 from sodium Cr acquires stabled configuration. In case
bicarbonate which is again a weak base.
(1) electron comes out from completely
filled 45
18. Why doors/windows made up ofare So, removal of electron from zinc req
aluminium instead of iron? energy as compared to that in chromiu
Stab
Ans. When exposed to air and moisture, iron ) Among CuCl2 and CuCl is more staoief
s of
gets ofcomplex can be
corroded, therefore to protect it from rusting, explained on ti
hility o
iron doors/windows have to be stability of oxidation state of copper. o h
In contrast, when aluminium
painted periodically Cus (ag) rather than Cu (ag) is due to
exposed to air and
moisture, it forms an impervious layer of negative value of [Avd H of Cu2 (ag)te
protects the metal from further corrosion.AlO3
which
second

which more than

compensates for the so
ionisation enthalpy of Cu.
 mple Question Paper2 53
structure of product formed
rite the
20. Write 22. The measured resistance of a
CH,CHNH, +CHCl, +alc.KOH- conductance cell containing 7.5 x10"M
NH solution of KCl at 25°C was 1005 ohms.
Calculate (i) specific conductance
NaNO,/HC ii) molar conductance of the solution cell
i) Constant =125 cm
Ans. Specific conductance, k =*Cell constant
Resistance
Ans. CHCHNH2 + CHCl3 +3KOH(alc.)A
Ethyl amine Chloroform
125
CH,CH-N C+ 3KCI +3H,0
124x10
1005 ohm
ohm cm
Ethyl isocyanide 1000 K
Molar conductance,
(1) mMolarity of the solution
NH2 N=NCI 1000x124 x10 ohm1 cm2 mol 1

7.5 x 10d
NaNO,/HCI
() 273-278K Am 166.3ohm em mol
= 165.3S cm mol-1
Aniline Benzene (2)
diazonium
chloride
(1) 23. For a first order reaction, show that the
21. Both (Co(NH, )," and [CoF, are time required for 99.9% completion is
10 times, the time required for the
octahedral complexes. Predict the
magneticn ature of thee two complexes completion of half of the reaction.
using CFT Or
The reaction between A and B is of first
Ans. InCoNHal6", Co has oxidation state +3 and its
order with respect to A and of zero order
electronic configuration is 3d. Since, NHg is a strong
with respect to B. Fill in the blanks in the
fieldligand and A>P, the pairing of electrons occur following table.
and electronic configuration ist2geg
Thus, all electrons are paired and the complex is Experiment [A]/M B]/M Initial Rate/M min

diamagnetic. 0.1 0.1 2.0x 102

0.2 4.0x 10-
d2 d2-y2 0.4 0.4
111- Ao V 0.2 2.0x 10
Degenerate
Ans. Time required to complete 99.9% of reaction.
3d-orbital 1 11 a
Oy yz G
(1) T99.9% 2.305
k
og 100100
99.9
2 k log 1000
In [CoFo the oxidation state of Co is + 3 and 6.909
electronic configuration is 3d. Since, F" is a weak ..) log 10 =3]
K

field ligand and A <P, so pairing up of electrons

does not take place and electronic configuration is
231o9 00-
k
100
50
2.305 og2
K
2g e. Since, there are four unpaired electrons, the
0.693
complex is paramagnetic. (:log2 0.301). ()
k
1a,2 On dividing Eq. () by Eq. (i), we get

99966.909
1111 /2 k 0.693
Degenerate
30-orbital Therefore, t999 is 10 times that is required for the
completion of half of the reaction (2)
ay Oyz zx (1)
 iSucceed Chemistry C
54
Ans.
Clas
oyO/Zn-H,O 2
Rate A]A=4|A
2ero Order wr1B
herce any
=0
S the r e a t n is of ) BH
efect on the
hanpe in he canntration of E
has no
(u) HO2/0OH
() =CH2 (i) PCC
rPm expRerimer! i -CHO
20 10 M min= x(0 M)
1
k
25. Compound 'A' with molecular
20 10 Mm C,HBr is treated with aq. KOHormula
02 min
olution
=
The rate of this reaction

From experiment i,
01M
concentration of the depends
compound 'A pon
only t
When another optically active
40x 10 M min =02 minx{A] this compound was treated isomer
solution, the rate of reactio
with aq. KOH
40x 10 M min was
A 02 min
= 02 M
be dependent
on
concentration of found
compound and KOH both.
For experment l,
Write down the structural formula
Rate 02 minx(0.4 M) compounds 'A' and 'B'.
of hn
=0 08 M min Ans. As, the rate of reaction depends upon the
For experiment V concentration of compound 'A' (CHgBr) only
therefore, the reaction proceeas oy SNl
and the given compound will be tertiary mechanism
20x 10 M min=0.2 minx [A
alkyl
20x 10 M min halide, i.e. 2-bromo-2-methylpropane and the
A= 0.1M
0.2 min structure is as follows:
(2) CHa
24. Complete the following reaction HgC-C-Br
statements by giving the missing starting
CHa
material, reagent as required A)
Optically active isomer of (A) is 2-bromobutane (8
1) and its structural formula is
Zn-H,O
CH3-CH-CHCH3
=CH2 CHO Br
(B)

SECTIONC: Short Answer Type ll Questions (3 Marks

26. Write the structural and functional (c) a-helix formation
differences between RNA and DNA. (d) B-sheet structure
Or Ans. Structural differences between DNA and RNA are:
G) What are the different types of RNA (a) In DNA, the pentose sugar is B-D-2-deoxyribose
but in RNA it is B-D-ribose. (1/2
found in cell?
(6) The pyrimidine bases in DNA are cytosine
ii) Mention the type of linkages
and thymine, while in RNA, these are cytosine
responsible for the formation of the
uracil.
following ()DNA has double stranded a-helix structure, w
(a) Primary structure of proteins HNAhas single stranded a-helix structure
(b) Cross-linking of polypeptide chain (a) Molecular mass of DNA is higher than that or
 Ans. Os/Zn-H0 2
s4 O

law s, ( BHs
The rate Rate-A{4)'8=kA]
hence any (i) HOp/OH
w.rt. B,

the
reaction
is ofzero
order

ofBhas
no
effect on
the
=CH2 PCC -CHO
Since, concentration

change
in the
r a t e o fr e a c t i o n .
'A' with molecular form
Compound
25. CH,Br
From experiment, is treated with aq. KOH solution
x(0.1 M
The rate of this reaction depends upo th
1 0 M m i n = k

2.0x

20x10
M min= 0.2 min concentration ofthe compound 'A only
So, k= 0.1 M When another opticaly active isomer 'B.
this compound was treated with ag. KOH
From experimentI, this
40x102Mmin=0.2minx[A] solution, the rate of reaction was nd

on concentration of
4.0x10 Mmin=02 M be dependent
and KOH both.
A 0.2 min compound
structural formula of bot
Write down the
For experiment , and B.
Compounds 'A'
Rate =0.2 minx (0.4
M)
reaction depends upon the
Ans. As, the rate of
=0.08Mmin concentration of compound A' (C4HgBr) only
therefore, the reaction proceeds by Sy1
For experiment , mechanism
will be tertiary alkyl
2.0x 10 M min= 0.2 minx[A and the given compound
2-bromo-2-methylpropane and the
halide, i.e.
2.0x 10 Mmin= 0.1M structure is as follows:
0.2 min CH3
(2)
H3C-C-Br
24. Complete the following reaction
statements by giving the missing starting CHs
material, reagent as required (A)
Optically active isomer of (A) is 2-bromobutane (B)
and its structural formula is
i O2
Zn-H,O
CH-CH2-CHCH3
-CHO Br
(6) (2)

SECTION C: Short Answer Type ll Questions (3 Marks

26. Write the structural and functional (c) a-helix formation
differences between RNA and DNA. (d) B-sheet structure
Or Ans. Structural differences between DNA and
RNA are:
) What are the different types of RNA (a) In DNA, the pentose sugar is
found in cell? but in RNA it is B-D-2-deoxyribose
B-D-ribose. (1/2)
i) Mention the type of linkages (b) The pyrimidine bases in DNA
and thymine, while in
are
cytosine
responsible for the formation of
the uracil.
RNA, these are cytosine and
following: (c) DNA has double (1/2)
(a) Primary structure of stranded a-helix structure, while
(b) Cross-linking of proteins RNA has single
stranded a-helix structure.
polypeptide chain (d) Molecular mass of DNA is (1/2)
higher than that of RNA
(1/2)
 ample
Question Paper 2 55
Son

Functional ferences between DNA and RNA are:

28. Account for the
(a)DNA
has unique property of replication, while RNA following:
generally does
not have this
property. (1/2) ) How is aniline obtained from benzene?
the transmission of hereditary
(b) DNA controls i) Silver chloride dissolvesin
characters, while RNA controls protein synthesis. methylamine solution. Why?
a Three types
of RNA present in the cell are
(1/2) ii) Write the chemical reaction for the
o
(a) ribosomal
RNA (7-RNA) reduction of nitroethane by LiAlH.
RNA (m-RNA) Ans. )
(b)messenger
NO2 NH2
RNA (-RNA)
(C) transfer
(1)
Structural HNO Sn/HCI
()
characteristic of Type of linkages O|
biomolecule
Benzene Nitrobenzene Aniline
(a) Primary structure of Peptide bond or (1)
1) Silver chloride dissolves in methylamine due to the
proteins peptide linkage formation of soluble complex salt.
(b) Cross-linking of Disulphide bonds,
polypeptide chains hydrogen bonds
AgCIs)+2CH,NH2 -
Ag(CHNHalC (1)
LiAlH4
(c)-helixformation NH .-0=C (ii)CHgCHNO2 + 6[H]ether
ether
Nitroethane
hydrogen bonds
(d) P-sheet structure Intermolecular
CHCHNH2 +2H20
Ethanamine
hydrogen bonds (1)
(2) 29. i) What happens, when electric field is
27. How are the following conversions applied to colloidal solution and the
carried out? process involved in it?
(4) Propane to propan-2-ol i) Describe a conspicuous change
observed when a solution of NaCl is
(i) Benzyl chloride to benzyl alcohol
added to a sol of hydrated ferric oxide.
ii) Methyl magnesium bromide to
Or
2-methylpropan-2-ol
Br2 Give answer for the following
Ans. ) CHCHCHg HBr CHCHCHBr i) Wliat is an adsorption isotherm?
Propane 1-bromopropane
(ii) Give one main difference between
Alc. KOH, cHCH=CH, CHCH-CH3 lyophilic and lyophobic colloids.
Propene
OH (ii) Why does bleeding stop by rubbing
Propan-2ol (1) moist alunm the
on injured part?
CHC CHOH Ans. () When electric potential is applied to colloidal
solution, the colloidal particles move towards one
or the other electrode. Positively charged particles
O aq. KOH
O +aq. KCI
move towards the cathode, while negatively
charged particles move towards the anode.
Benzyl chloride Benzyl alcohol (1) The movement of colloidal particles under an
applied electric potential is called electrophoresis.
(00) CH C CH Ether When electrophoresis is prevented by some
+CHMgBr means, then the dispersion medium begins to
Acetone Methyl magnesium move in an electric field. This phenomenon is
bromide
termed as electroosmosis. (2)
H
(CHgla-C-OMgBr- (i) When a solution of NaCl added to a sol of
hydrated ferric oxide, it gets coagulated, i.e. the
OH
colloidal particles of hydrated ferric oxide get
+(CHa)g-C-OH coagulated and settle down. (1)
2-methylpropan-2-ol (1)
 when
happens,
What
(il) Ieacts with SbF
(a) XeF
amount

the
in
vanation
at reacts
with O,
56
(b) Al
pressure

he
isothem with
able. FClg dteg
it is stable
means

adsorbent
because
expressedby formed
Adsorption
bythe is
adsorbed can
be isotherm.
Ans. ) (a)CIFg because CI hasvaca
Or
ofgas temperature
exist actually
not
adsorption

by can show an
an oxidalio
constant
as expressed
and hence,
known

be d-orbitals
ofa
curve
isotherms
can
state of+3 but F has nod-orbitals, therefore
F r e u n d l i c ha d s o p t i o ni s o t h e r m .

Adsorption
Oxidation states
cannot show positive
195K - .

only-1 oxidation of
can show
since F
its highest electronega Therefore t fom
244 K only CF or CFa
273 K molecules are
held by
together weakkvan
(b)O because of small sizeand
forces
der Waals'
electronegativity
or oxygen. These van
high can be easily
Adsorption isotherm
(1) Waals' forces of attraction
the molecules at
colloid A
colloidal solution in
which overcome by collisions of
exists as a =
@Lyophilic
and dispersion
medium attract
room temperature theretore, O2
dispersed phase (1/2) In contrast, sulphur
called lyophilic
colloid.
at room temperature.
each other is and forms stronger S-s
solution in which shows catenation
colloid A colloidal
Lyophobic forms
phase and dispersion
medium repel
bonds. Due to catenation, suilphur
dispersed (1/2)
each other is called
lyophobic colloid. Sg molecules having eight
octa-atomic
When we rub the injured structure.
colloidal sol. membered puckered ring
i) Blood is a then coagulation of blood
part with moist alum, Because of its bigger size, the forces of
which stops the
takes place. Hence, clot is formed, attraction holding Sg molecules
are much
(1) is solid at room
bleeding. stronger. Hence, sulphur
a
30. (i) Give reasons: temperature.
(a) When Cl, reacts with excess of F,
CIF is formed and not FCl . i) (a) XeFa+ SbFs XeF%l" [SbF
(b) Dioxygen is a gas while sulphur is a
(b) 4A1+302 2A0D3
solid at room temperature. (1/2+1

SECTION D: Long Answer Type Questions (5 Marks

31. () Following rate data were obtained at Or ) The decomposition of phosphine, PH
300 K for the reaction: proceeds according to the following
2A+B C+D equation
Exp. Initial rate of 4PH,(g) P, (g)+6H,9)
No. A]mol L-B]mol L formation of [C] It is found, that the reaction follows tne
mol L min
03 0.2
following rate equation:
0.3
72x10 Rate = k{PH,)
0.4
3. 0.4
2.88 x 101 Half-life of PH, is 37.9 s at 120'C
0.1 2.4 x 10-2
4 0.1
(a) How much time is required for 3/
0.1 of
If the 60 x103 PH, to
decompose?
concentration of A =05 mol b) What fraction of the
and B =02 mol L- original samp
rate of formation
L then, calculate the of PH, remains behind after
of D. 1 minute?
i)
Decomposition of NH, on
surface is zero order platinum
i) Consider a certain
reaction,
the rates reaction.
of production What are Aproducts with k =20x10s
k =2.5x10 Ms of N2 and
H, if Calculate the concentration of
A
remaining after 100 s, if the initial
concentration of Ais 1.0 mol L
 57

stion Paper2 behind

of PHg left
S a m p l eQ u e s t i o n P a p e r 2

concentration

is the
(b) If [PH3i,
min, then
k[4jB1 after 1 0.693 x 60 S -0.476
of D
=

formation
kt
ANS 0 Let.
Le
rate
of
PHab 303
2.303x37.9s
Q
k(01'(01 (a)
10=K[AY[B
=
Then
(3)
E x p4. 6 0 x 1 0
6 - K(0 4y'(0 1y"
A[AIBr
(tb) PHalt 0334
24
10=
PHa L"
=
100s
Exp.3 (a) Ah =1.0rnol
(b) by Eq 20x 10 s
Eq (0 4
A(0 4 (01
Dvnding :4

10 2 30 og [Alo
24
6010
AO1 (01" (01
A
(A
44 n=1
Therefore 1.0 molL
log
A
2 0 x 1 0 s - ' = 2 3 0 3

Similarty, from
A(03'(02)
(c) 100 s

Exp.1
72 10 = (d) [A])
288 r
10
=
k{0.3) (0.4) 20x 10s '= 100 s (og 1-log
Exp. 2
(c)
(d) by Eq.
Dviding Eq
2.0x 10s'= 100 s (0 -log [A])
288x 10 k(0.3) (0.4
100 sS
k(03)'(0.2) 10s'x
72 x
10 [A]=E0x
=2
-

log 2.303
4 2 m

of D k[A][B]f = k[A] [B? = 2.0x 102 s'x100 s

formation
Rate of A]=antilog 2.303
mol L").(e)
=
K(05 mol L") (0.2
mol L- (2)
Using data of exp.
4
Or [A]=0.135
min= k{0.1) (0.1
60 x
10 mol L How will you bring the followingg
32. (i)
Dividing Eq. (e) by Eq. () conversions?
ethanoic acid
formation of D k(0.5) (02) Methyl
bromide to
Rate of (a)
60 x10 mol L min k(0.1)(0.1 (b) Acetaldehyde to
acetone.

benzophenone.
(c) Benzaldehyde to
5x220 the
structures of A and B in
D (i) Write the
Rate of formation of
x20
6x =
10 mol L min following:
= 0.12 mol L-" min
(3)
+NH,OH A
(a)
(i) For reaction,
3H2 (b) (CH) C=0-
LiA B
2NH Na +

molecular
Reaction rate =k[NH3]' =k Or An organic compound
with

Rate of production of N2 formula C,H100, forms 2,4-DNP

and
aNek =25 x10 Ms derivative, reduces Tollen's reagent
undergoes Cannizzaro reaction.
On vigorous oxidation, it gives
Rate of production of H2
1,2-benzene dicarboxylic acid. Identify
O2=3k=3 x25 x10 Ms the compound. Also, give the
appropriate reactions.
=7.5x104 Ms1 (2)
Ans. () (a) Methyl bromide to ethanoic acid
Or

9a)Decomposition of PH is a
first order reaction
CH-Br
Alc KCN ACHC =N
xt -KBr Acetonitrile
lonPHalo 0.693 xt 0.3010 Methyl bromide
H HOCH COOH
_

PH 2.303 xt/2 ty2

0.3010 xt Hydrolysis Ethanoic acid (1)
PH3lo
For t=t3/4 PH3o/4 (b) Acetaldehyde to acetone
37.9s
CHCHO KCr07/HO CH COOH
31.98 0g 4=758s Acetaldehyde Oxidation Acetic acid
0.3010
 CHOO COOH
a0rp (CH%COO)%Ca-
Dydistilation
OL 1,2-benzene
COOH
-CaCOs
dicarboxylic acid
8 C a l c u ma c e l a l e

-H0 CHy-C-CH
NO2
Acetone

(1) HNNH NO2

(c)Benzaldehydetobenzophenone CHO 2,4-DNP

COOH

CHO
OpN
calO2,
0 Heat CH=NNH-
HONo+
KMnO4
B e n z o i ca C i d
2,4-DNP derivative

Benzaldehya0e

Oxidation state
stable
be the electronic
What may
33. (i) elements
havingouter 3d"and3d
of 3d,
Benzophenone
(1) configuration
a s 3d",
N-OH

following:
Describe
the atomisation
of
(i) of
enthalpies
high.
+NH,OH
(a) The elements
are

of
Cyclopentane

OXIime
(1) transition
metals
and many
yclopentanone

transition
A
(b) The act a s good
compounds
their
LACHa-CH-CH
exhibit
p) (CHa C=0 catalyst. does not
(Z=21)
Propanone
OH Scandium
and yetit is
Propan-2-0 (c) oxidation
states
variable
B (1) transition
element.

as
regarded are
formula electrons
molecular

compound
with unpaired number
of
Or a)As the given derivative and
Or i) How many
ion (atomic
forms a 2,4-DNP Mn*"
CgH150, thus it must
be an present in it influence
reduces Tollen's
reagent, How does ions?
Mn= 25)?
aldehyde hence magnetic
behaviour ofMns*
Cannizzaro reaction,
(b)As it undergoes attached to the Describe the
following:
-CHO group is directly (ii) bonding is
more
ot
Metal-metal
benzene rin. (a) 4dand
5d-series

e x t e n s i v e in the
vigoroUs Oxidation, gives
it
C)On
1,2-benzenedicarboxylicacid. Therefore,it elements than the
transition
ortho-substituted benzaldehyde
must be an 3d-series. disproportionato

and the only o-substituted aromatic aldehyde

formula is o-ethyl (0) Mn(1) undergoes
which have CH10 molecular
(2) reaction easily, the
benzaldehyde. oxidised in
Reactions involved (c) Co(11) is easily
ligands.
presence of strong
CHO
AgNH*OHT
O CH5
Tollen's reagent Ans.)
Electronic configuration
Stable
oxidation

+3 +5
states

si
0-ethyl benzaldehyde
3d4s2
CO0 +2,+7

3d 4s2
OL CoH
2-ethylbenzoate
+Ag
Silver
mirror
3d As
-2
+3+6
 Question Paper 2 59
sample

elements have high enthalpies of It has five unpaired electrons. Therefore, it is

(a)Transition
() atomisation due to strong metallic bonding and paramagnetic in nature. Its magnetic moment is
covalent onding. Metallicbonding is calculated as,
additional
smaller size, while covalent
due to their Hspin only =yn (n + 2) =V5(5+2)
bonding is due to d-d overlapping. (1) =35 5.92 BM (2)
(b) The catalytic
activity of the transition elements Because, less energy is required for more
i) (a)
by two basic facts. Firstly,
can be explained because number of electrons to take part in metal-metal
metals, of their variable
transition bonding, as there is smaller difference in the
form unstable intermediate and ns-orbital of 4d and
Oxidation state, energies (n -1)d
of
a new path by (1)
compounds and provide 5d-series.
lowering the
activation energy (E)for the intermediate
transition metals also
(6) In +3state, Mn is unstable. It is
reaction and secondly Oxidation state, so it gets reduced to
more

surface for the reactions to

orovide a suitable stable Mn-t and oxidised to another
more

OcCur.
(1) stable higher oxidation state like Mn'* (1)
elements are those elements that have electronic configuration being 3d
(c)Transition
d-subshell in their elementary form or
(c) In Co, electron even after
nartialy filled there is one unpaired
oCCurring oxidation state. field
in their commonly pairing in the presence of a strong
21SC [Ar4s3d1
ligand.
more stable Co*.
has partially filled d-subshell in its Hence, Co is oxidised to
As, scandium considered as a transition
it is 3d7
elementary form,
(1)
Co?-1 1 1 11
element.
Or

0 25Mn: [Ar 4s 3d5 In the presence of strong

field ligand

Mn2:[Ar]83d54s0 3do

Mn-1111111 Co3t-1 1 1 (1)

3d