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    Chemistry Sample Paper 1

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    Himanshi Prajapati
    This document contains the details of an engineering chemistry exam including 7 sections with multiple choice and long answer questions. Some of the key topics covered include: impurity defects, selection rules, phase diagrams, Grignard reagents, polymers, liquid crystals, calorimetry, and water treatment processes. The exam is out of a total of 100 marks and tests knowledge across different areas of chemistry.

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    Chemistry Sample Paper 1

    Uploaded by

    Himanshi Prajapati
    29 views4 pages
    This document contains the details of an engineering chemistry exam including 7 sections with multiple choice and long answer questions. Some of the key topics covered include: impurity defects, selection rules, phase diagrams, Grignard reagents, polymers, liquid crystals, calorimetry, and water treatment processes. The exam is out of a total of 100 marks and tests knowledge across different areas of chemistry.

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    This document contains the details of an engineering chemistry exam including 7 sections with multiple choice and long answer questions. Some of the key topics covered include: impurity defects, selection rules, phase diagrams, Grignard reagents, polymers, liquid crystals, calorimetry, and water treatment processes. The exam is out of a total of 100 marks and tests knowledge across different areas of chemistry.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    29 views4 pages

    Chemistry Sample Paper 1

    Uploaded by

    Himanshi Prajapati
    This document contains the details of an engineering chemistry exam including 7 sections with multiple choice and long answer questions. Some of the key topics covered include: impurity defects, selection rules, phase diagrams, Grignard reagents, polymers, liquid crystals, calorimetry, and water treatment processes. The exam is out of a total of 100 marks and tests knowledge across different areas of chemistry.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 4

    Subject Code: KAS102T

    Roll No:
    B.TECH. (SEM I) THEORY EXAMINATION 2021-22

    ENGINEERING CHEMISTRY
    Time: 3 Hours Total Marks: 100
    Note: 1. Attempt all Sections. If require any missing data; then choose
    suitably.
    SECTION A

    1. Attempt all questions in brief. 2 x 10 = 20

    Qno. Question MarksCO


    a. Explain impurity defects. 2 1
    b. Why Teflon is highly chemically resistant? 2 1
    c. What is selection rule? 2 2
    d. On the basis of IR spectra, distinguish between 2 2
    intermolecular and intramolecular hydrogen bonding.
    e. Calculate Phase, Component and Degree of freedom in 2 3
    the given system;
    C(s)+ ½ O2 ← → CO(g)
    C(s)+ O2 ← → CO2(g)
    f. Why calgon is better than other internal process for water 2 3
    treatment?
    g. Give the preparations of Grignard reagent. 2 4
    h. Why O2 is paramagnetic and N2 is diamagnetic? 2 4
    i. How can sulfur be estimated by ultimate method? 2 5
    j. How much rust (Fe2O3.3H2O) can be produced by 3g of 2 5
    iron?

    SECTION B

    2. Attempt any three of the following: 3x10=30


    Qno. Question MarksCO
    a. With the help of Molecular orbital theory how Metallic 10 1
    bonding in metals can be explained?
    b. Write the criteria for a molecule to show Raman, IR, 10 2
    Rotational and UV Spectra. Give the possible electronic
    transitions (UV spectra) inCH3CH2CH3, CH3CH=CH2,
    CH3CH=O and CH3-CH=CH-CH=CH-CH3. How many
    fundamental Vibrational degrees of freedom are expected.
    for the following molecules: CO2, H2O and C2H?
    c. The percentage composition of coal sample is: C = 70 %, 10 3
    H2 = 10 %, O21%,S= 5%,ash = 0.5 %and N = 0.3 %.
    i. Calculate the quantity of air needed for complete
    combustion of 1kg of coal, if 60% excess of air is
    supplied.
    ii. Calculate the gross and net calorific value of the coal
    using dulong’s formula
    d. Give significance of Nernst equation. Consider a cell 10 4
    reaction: Zn / Zn 2+ [0.1M] || Cu 2+[0.2M] / Cu Standard
    reduction potential of Zn2+ and Cu2+ are -0.76V and
    0.34V respectively. Write half-cell reactions, complete
    cell reaction and calculate EMF of the cell.
    e. Distinguish between addition and condensation 10 5
    polymerization. Give monomers and one use each of
    PMMA, Polyethylene, Bakelite, PVC, nylon6,6.,Buna S.

    SECTION C

    3. Attempt any one part of the following: 1x10=10


    Qno. Question MarksCO
    a. i. Explain types of Non stoichiometric defects with 10 1
    examples.
    ii. Calculate bond order, magnetic behavior and order of
    stability of NO, NO - , NO+
    b. Write a note on liquid crystal describing classifications 10 1
    and applications of liquid crystals.
    4. Attempt any one part of the following:
    1x10=10

    Qno. Question MarksCO


    a. The e.m.f. of the cell cd | cdcl2, 2.5 H2O (Saturated) || 10 2
    AgCl(s) | Ag involving following reaction Cd(s)
    +2AgCl(s)aqcdcl2 2.5H2O(Saturated)+2Ag(s) is
    0.6753V and 0.6915V at 250 C and 00C. Calculate  H,
    G and S at 250 C.
    b. Draw the Phase diagram of water and explain triple point 10 2
    and metastable state

    5. Attempt any one part of the following: 1x10=10

    Qno. Question MarksCO


    a. Write Notes on chromophores and Auxochrome. Explain 10 3
    Transitions in UV spectra.
    b. Explain the Microwave (Rotational) spectra of diatomic 10 3
    molecule and write their applications.

    6. Attempt any one part of the following: 1x10=10

    Qno. Question MarksCO


    a. Draw diagram of Bomb calorimeter. Explain proximate 10 4
    analysis of coal.

    b. Explain Ion exchange process of water softening. Zeolite 10 4


    softener was 90% exhausted, when 10,000 hard water was
    passed through it. The softener required 200 L of NaCL
    solution of strengths 50 gm/L. Calculates the hardners of
    water.

    7. Attempt any one part of the following: 1x10=10


    Qno. Question MarksCO
    a. Explain with equations preparations of acid, ketone, 10 5
    alcohol, alkanes and Organometallic compound from
    Grignard reagent.
    b. What are composite materials? Give the classifications of 10 5
    composite materials?

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