TMS: Thermal Metal Spray Coatings: Corrosion Engineering Division

CORROSION ENGINEERING DIVISION
TMS: Thermal metal spray coatings
Prepared for Institute of Corrosion
Prepared by Coatings Work Group
ICorr Reference ICorr/CED/CT05 Issue 1
Date of issue December 2017

Title TMS: Thermal metal spray coatings
Prepared for Institute of Corrosion
Our Reference ICorr/CED/CT05
Confidentiality, This report was prepared by members of the Institute of

copyright and Corrosion. © Institute of Corrosion 2017. It should not be
reproduction copied without the permission of the Institute of Corrosion.
The Institute of Corrosion accepts no responsibility for any loss

of information, materials or equipment arising from actions
taken as a result of any of the information provided in this
report either by the Customer or by any third party who has
obtained any of the said information directly or indirectly from
the Customer. Neither party shall be liable to the other for any
indirect consequential or special loss whatsoever including but
not limited to loss of revenue or profit.
Contact Details Institute of Corrosion
ICorr Head Office

Barratt House
Kingsthorpe Road
Northampton
NN2 6EZ
Tel 01604 438222
E: [email protected]
http://www.icorr.org
Name Signature Date
Author(s) Ray Peters 23 June 2017
David Horrocks MICorr

(Chairman CED 26
Reviewed by Coatings group) and September
Working Group 2017
members
Nick Smart, Chair of

19 December
Approved by Corrosion Engineering
2017
Division
2
Executive summary
This report has been prepared as an outcome of discussions within the Institute of Corrosion’s
Corrosion Engineering Division (CED) Coatings Working Group where it was agreed to produce a
number of technical guidance documents and make them available through the members’ area of
the Institute of Corrosion website. This document is intended to give a brief insight into Thermal
Metal Spray coatings. The document seeks to address the basic questions regarding the nature of
thermal metal spraying, the surface preparation required, the types of metal spray available, spray
application methodologies, specific characteristics of thermal metal spray (including water
permeability), when, where and why thermal metal spraying might be used, whether it can be used
without the addition of organic coatings, where thermal metal spray might not be recommended
and where the user can obtain further advice regarding thermal metal spraying.
3
Contents
1 Introduction 5
1.1 Context and definition 5
1.2 Process of thermal metal spraying 5
1.3 Surface preparation standards 5
2 Methods for applying thermal metal spray coatings 5
2.1 Flame spray 5
2.2 Arc spray 6
3 Properties 6
3.1 Permeability of thermal metal spray to water 6
3.2 Abrasion resistance 6
3.3 Galvanic protection 6
3.4 Longevity 6
4 Use of thermal spray coatings 6
4.1 Without the addition of organic coatings 6
4.2 Situations where metal spray systems are not recommended 6
4.3 Duplex system 7
5 References 7
5.1 Standards 7
5.2 Further information 7
6 Acknowledgements 7
4
1 Introduction
1.1 Context and definition
Thermal metal spraying is a process in which coiled metal wire is melted and, by various methods,
fired onto a suitably prepared substrate surface according to the standard EN/ISO 2063. Most
commonly the metals sprayed are zinc and aluminium. The types of metal spray can be quite
extensive but can be broken down into two main categories:
 Protective coatings used for their anti-corrosive properties
 Engineering coatings such as wear resistant and thermal barrier coatings.
Thermal spraying is carried out in a wide range of anti-corrosion and engineering markets, which
include oil and gas, construction, petrochemical and marine, and rail infrastructure. The benefits of
thermal spraying are the lack of heat input to the steel, thereby minimising potential distortion, and
the fact that products of any size can be coated.
1.2 Process of thermal metal spraying
Thermal spraying involves the projection of small molten particles onto a prepared surface where
they adhere and form a continuous coating. To create the molten particles, a heat source, a spray
material and an atomisation/projection method are required. Upon contact, the particles flatten onto
the surface, freeze and mechanically bond, firstly onto the roughened substrate and then onto each
other as the coating thickness is increased.
As the heat energy in the molten particles is small relative to the size of the sprayed component,
the process imparts very little heat to the substrate.
As the temperature increase of the coated parts is minimal, heat distortion of the steel is not
normally experienced.
1.3 Surface preparation standards
A suitably prepared substrate surface is one that has been blast cleaned to enable the thermally
sprayed metal to satisfactorily bond to the substrate. BS EN ISO 8501.1 - SA 2.5 and SA3 provide
acceptable standards for thermally sprayed zinc and aluminium; however SA 3 will give the best
adhesion, especially with flame-sprayed aluminium.
2 Methods for applying thermal metal spray

coatings
For normal corrosion protection purposes, coatings are applied by flame spray or arc spray. These
processes are detailed below.
2.1 Flame spray
In the flame spray process a wire (e.g. aluminium or zinc) is fed by a driven roller system through
the centre of an oxy-fuel gas flame where it is melted. An annular air nozzle then applies a jet of
high-pressure air, which atomises and projects the molten material on to the steel surface. The
aluminium coating acts as a corrosion protection barrier coating. Flame-sprayed zinc, which is
predominantly used on new steel structures, provides both barrier and sacrificial protection. Zn/Al
and Al coatings can be used; Zn or Zn/Al is typically used for urban areas, whereas Al is often
specified for saline/coastal areas and splash zones. The flame spray process is generally agreed to
be slower to apply than the arc spray method but it is still a common method used for application to
steelwork.
5
2.2 Arc spray
In the arc spray process, two electrically charged wires are driven and guided so that they
converge at a point and form an arc. An air nozzle atomises the molten metal produced and
projects it towards the work piece. The driving of the wires typically employs either an air motor or
electric motor and gearbox arrangement. Typically defined as a corrosion protection barrier
coating, arc sprayed Zn/Al has a bond strength that is approximately 2.5 times higher than flame
sprayed aluminium. As with flame spray Zn, Zn/Al and Al can be used. This application process is
predominantly used on new steel structures and it is generally agreed that it is quicker to apply
than the flame spray method.
3 Properties
3.1 Permeability of thermal metal spray coatings to water
There is a general perception that a thermal metal spray (TMS) coating is permeable. This is in fact
the case because when it has been applied the coating is not homogenous and there are a
considerable number of vacuoles in the coating. To overcome this, the metal spray is often used as
part of a duplex system (see Section 4.1).
3.2 Abrasion resistance
Thermal metal spray coatings are relatively hard with a degree of malleability. Therefore they have
good abrasion resistance.
3.3 Galvanic protection
Zinc and aluminium thermal spray coatings are anodic to steel (albeit to different degrees) and
therefore they offer cathodic protection to the underlying metal. Zinc is normally more effective in
this respect than aluminium.
3.4 Longevity
When combined with organic paints the resultant system has been proven to provide excellent
longevity properties, exceeding those of paint systems alone, although there is no real data to
indicate the level of improvement. The life of thermal metal spray coatings has in some cases been
extended by fixing suitable sacrificial anodes to the thermally metal sprayed structure. Specialist
advice is recommended with respect to this approach.
4 Use of thermal spray coatings

4.1 Without the addition of organic coatings
Unsealed thermal metal spray coatings have been used where there is no requirement to provide a
colour coating on the structure. In these circumstances the thickness of the thermal metal spray
has been increased. Exposure to the atmosphere causes the voids in the coating to close up
because of the formation of zinc or aluminium oxides.
4.2 Situations where metal spray systems are not recommended
Applications of TMS coatings are varied but they tend to be used for large solid objects, including
wind turbine towers, bridges and boats. It has been found that on bridges where road salting for de-
icing is frequently carried out in the winter months, the salt can permeate its way through any
breaches in the coating system. These breaches can be chips in the paintwork caused by road-
stones from passing cars, joints in the deck, and/or holidays within the coating system. Where the
system is breached considerable coating breakdown can occur. This could also occur where there
is a possibility of tidal sea water splashes at coastal locations. In general, metal spray systems
should not be used on open or lattice-like structures.
6
4.3 Duplex system
The general view is now that thermally sprayed coatings should not be used as part of a duplex
system. Rather, a thermally sprayed coating with a thin organic sealant is the generally preferred
option with a life to first maintenance of 20 years being achievable.
5 References
5.1 Standards
EN/ISO 2063: 2005 - Thermal spraying -- Metallic and other inorganic coatings -- Zinc, aluminium
and their alloys https://www.iso.org/standard/37440.html
EN ISO 8501.1: 2007: Preparation of steel substrates before application of paints and related
products -- Visual assessment of surface cleanliness -- Part 1: Rust grades and preparation grades
of uncoated steel substrates and of steel substrates after overall removal of previous coatings
https://www.iso.org/standard/43426.html
5.2 Further information

For further information the Thermal Spraying and Surface Engineering Association can be
contacted at http://www.tssea.co.uk/
6 Acknowledgements
The original version of this document was authored by Ray Peters. The present version contains
further contributions from Desmond Makepeace (Elcometer Ltd), Martin Hilliard, Stuart Milton
(Association of Metallisation) and Colin Arrow (Association of Metallisation).

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CORROSION ENGINEERING DIVISION

TMS: Thermal metal spray coatings

Prepared for Institute of Corrosion

Prepared by Coatings Work Group

ICorr Reference ICorr/CED/CT05 Issue 1

Date of issue December 2017

Prepared for Institute of Corrosion

Our Reference ICorr/CED/CT05

Confidentiality, This report was prepared by members of the Institute of

The Institute of Corrosion accepts no responsibility for any loss

Contact Details Institute of Corrosion

ICorr Head Office

Name Signature Date

Author(s) Ray Peters 23 June 2017

David Horrocks MICorr

Nick Smart, Chair of

2 Methods for applying thermal metal spray

4 Use of thermal spray coatings

5.2 Further information

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