BATTERIES

– Material Safety Data Sheet –

Valve Regulated Lead Acid Battery
SECTION I
Manufacturer’s Name: USA Contact Information: Date: Feb 2007
HAZE Battery Company Ltd Ph: 952-746-7528 Range Name: GEL Bloc & Monobloc
Xiangshuihe, Dayawan Economy Shakopee, MN
& Technology Development Zone
Huizhou, Guangdong
China. 516085

SECTION II
HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous Components Range

Specific Chemical Identity CAS Percent
(Common Name (s)) Number OSHA PEL ACGIH TLV By Weight Average
Lead 7439-92-1 50 µg/m3 50 µg/m3 45-55% 50%
Sulfuric Acid 7664-93-9 100 µg/m3 1.00 mg/m3 19-25% 22%
3 3
Amorphous Silica 7631-86-9 5 µg/m 10 µg/m 8-10% of Acid Wt 9%
3 3
Lead Oxide 1309-60-0 50 µg/m 500 µg/m 19-23% 21%
Lead Sulfate 7446-14-2 50 µg/m3 10 µg/m3 <1 % <1%
3 3
Calcium 7440-70-2 100 µg/m 1.0 mg/m 0-0.1% <0.1%
3 3
Tin 7440-31-5 20 µg/m 2.0 mg/m 0-0.1% <0.1%

SECTION III
PHYSICAL/CHEMICAL CHARACTERISTICS
Electrolyte (Sulfuric Acid):
Appearance and Odor: Clear, Odorless, colorless liquid Solubility in Water: 100%
Boiling Point: 112 – 115o C (235 -240 o F) Specific Gravity (H20=1): 1.270 – 1.330
Evaporation Rate (Butyl Acetate=1): less than 1.0 Vapor Density (AIR=1): Greater than 1
Melting Point: N/A Vapor Pressure (mm Hg): 10
SECTION IV
FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method Used): Non-Flammable Flammable Limits: *Hydrogen Gas
Extinguishing Media: Class ABC extinguisher, LEL: 4% UEL 74%
NOTE: CO2 may be used, but not directly on the cell. The thermal shock may cause cracking of the battery case
and/or cases.
* Hydrogen gas may be generated during battery charging.
SECTION V
REACTIVITY DATA
Stability: Stable Condition to Avoid: Prolonged overcharging, sources of ignition

Incompatibility (Materials to Avoid): Sulfuric Acid: Contact with combustibles and organic materials may cause fire
and explosion. Also reacts violently with strong reducing agents, metals, strong oxidizers and water. Contact with
metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas.

Hazardous Decomposition of By-Products: Sulfuric Acid: Excessive overcharging or fire may create Sulfur trioxide,
carbon monoxide, sulfuric acid mist, sulfur dioxide, and hydrogen.
Lead Compounds: Contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine
gas.
MSDS: Valve Regulated Lead Acid Battery; Page 2 of 3

SECTION VI
HEALTH HAZARD DATA
Route(s) of Entry: Not Applicable under normal use.

Carcinogenicity:
Sulfuric Acid: The International Agency for Research on Cancer (IARC) has classified “strong inorganic acid mist containing sulfuric
acid” as a Category 1 carcinogen, a substance that is carcinogenic to humans. This classification does not apply to liquid forms of
sulfuric acid contained within a battery. Inorganic acid mist (sulfuric acid mist) is not generated under normal use of this product.
Misuse of the product such as overcharging, may result in the generation of sulfuric acid mist.
Lead Compounds: Lead is listed as a 2B carcinogen, likely in animals at extreme doses. Proof of carcinogenicity in humans is lacking
at present.
Arsenic: Listed by National Toxicology Program (NTP), IARC, OSHA and NIOSH as a carcinogen only after prolonged exposure at high
levels.

Signs and Symptoms of Exposure: Avoid contact, with absorbed electrolyte (sulfuric acid) may cause irritation of eyes, nose and
throat. Contact with eyes and skin causes irritation and skin burns. Absorbed electrolyte is corrosive.

Medical Conditions Generally Aggravated by Exposure: Pregnant women and children must be protected from lead exposure.

Health Hazards (Acute and Chronic): Do not open the battery. Avoid any contact with internal components. Internal components
include lead and absorbed electrolyte. Electrolyte is corrosive and contact may cause skin irritation and chemical burns.

Emergency and First Aid Procedures: (contact with electrolyte)

1) Flush contacted area with large amounts of water for at least 15 minutes. Remove contaminated clothing and obtain
medical attention if necessary. Eye wash and/or emergency shower should be readily available.
2) If swallowed, give large volumes of water. DO NOT induce vomiting, obtain medical treatment.
SECTION VII
PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to be Taken in Case Material is Released or Spilled: Electrolyte material is corrosive. Contains sulfuric acid. Neutralize
any spilled material. Reference 1996 North American Emergency Response Guidebook, #154.

Waste Disposal Method: Lead-acid batteries are completely recyclable. For information on returning batteries to Haze for recycling,
contact your Haze Representative. Dispose of any collected material in accordance with local, state or applicable federal regulations.

Precautions to be Taken in Handling and Storing: Store away from reactive material as defined in Section V, Reactivity Data.
Place cardboard between layers of stacked batteries to avoid damage and short circuit. Do not allow metallic materials to
simultaneously contact both terminals.

Other Precautions: If battery case is broken, avoid direct contact with internal components. Keep away from ignition sources during
charging.
SECTION VIII
CONTROL MEASURES
Respiratory Protection (Specific Type): N/A

Ventilation: Must be provided when charging in an enclosed area.

Protective Gloves: Recommended

Eye Protection: Recommended

Other Protective Clothing or Equipment: N/A

Work Hygienic Practices: Good Personal hygiene and work practices are recommended.
MSDS: Valve Regulated Lead Acid Battery; Page 3 of 3

SECTION IX
OTHER REGULATORY INFORMATION
NFPA Hazard Rating Sulfuric Acid Lead
Health (Blue) 3 3
Flammability (Red) 0 0
Reactivity (Yellow) 2 0
Note: Sulfuric acid is water-reactive if concentrated.

U.S. DOT: The Non-Spillable lead acid battery complies with the provisions listed in 49CFR173.159(d) therefore must not be marked
with an identification number.

RCRA: Spent lead-acid batteries are not regulated as hazardous waste when recycled. Spilled sulfuric acid is a characteristic
hazardous waste, EPA hazardous waste number D002 (corrosivity).

CERCLA (Superfund) and EPCRA (Emergency Planning and Community Right to Know ACT)
a) Reportable Quantity (RQ) for spilled 100% sulfuric acid is 1000 lbs.
b) Sulfuric acid is a listed “Extremely Hazardous Substance” under EPCRA with a Threshold Planning Quantity (TPQ) of 1000 lbs.
c) EPCRA Section 312 Tier II reporting required for batteries if sulfuric acid is present in quantities of 500 lbs or more and/or
lead is present in quantities of 10,000 lbs or more.

California Prop 65: This product contains chemicals known to the State of California to cause cancer, birth defects and other
reproductive harm.
For additional information concerning Haze Battery Company Ltd. products or questions concerning the content of this MSDS please
contact your Haze agent.

This information is accurate to the best of Haze battery Co.’s knowledge or obtained from sources believed by Haze to be accurate.
Before using any product, read all warnings and directions on the label.