Gs Battery (U.S.A.) Inc.: Material Safety Data Sheet

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GS BATTERY (U.S.A.) INC.

1000 Mansell Exchange W., Suite 350


Alpharetta, GA 30022
Tel.(800) 472-2679 (678) 762-4818 Fax: (678) 739-2132

MATERIAL SAFETY DATA SHEET

DATE 2002 April ISSUED BY Toshio Ohara, CEO & President Phone# 1-800-424-9300
PRODUCT NAME VALVE REGULATED LEAD-ACID BATTERIES

HAZARDOUS COMPONENT
COMPONENT %WEIGHT TLV LD 50 LD 50 LD 50
ORAL INHALATION CONTACT
Lead(Pb, PbO2, PbSO4) about 70% (500) mg/kg
Sulfuric Acid about 20% 1mg/m3 (2,140) mg/kg

PHYSICAL DATA
COMPONENT DENSITY MELTING POINT SOLUBILITY ORDER APPEARANCE
(Boiling) IN WATER
Lead 11.34 327.4 degrees C None None Silver-Gray Metal
Lead Sulfate 6.2 1070 degrees C 40 mg/l (15 C) None White Powder
Lead Dioxide 9.4 290 degrees C None None Brown Powder
Sulfuric Acid about 1.3 about 114 degrees C 100% Acidic Clear Colorless Liquid

FLAMMABILITY DATA
COMPONENT FLASHPOINT EXPLOSIVE LIMIT COMMENTS
Lead None None
Sulfuric Acid None None
Hydrogen 4% - 74.2% Sealed batteries can emit
hydrogen only if over charged.
(float voltage > 2.40 VPC)

REACTIVITY DATA
COMPONENT STABILITY DECOMPOSITION PRODUCTS
Sulfuric Acid Stable at all temperatures Sulfuric dioxide, trioxide, hydrogen sulfide, hydrogen
INCOMPATIBILITY POLYMERIZATION
Reactive metals, strong bases, most organic compounds Will not polymerize
CONDITIONS Prohibit smoking, sparks, flames, etc. from battery charging area. Avoid mixing acid with
TO AVOID: other chemicals.

HEALTH HAZARD DATA


LEAD
The toxic effects of lead are cumulative and slow to appear. It affects the kidneys, reproductive organs and central
nervous system. The symptoms of lead overexposure are anemia, vomiting, headaches, stomach pains (lead colic),
dizziness, loss of appetite, muscle and joint pain. Exposure to lead from a battery most often occurs during lead
reclamation operations through the breathing or ingestion of lead dust and/or fumes.
***This sheet must be passed to any scrap dealer or smelter when the battery is resold.
SULFURIC ACID
Sulfuric acid is highly corrosive. Contact can cause severe burns in the skin and eyes. Ingestion of sulfuric acid will
cause GI track burns. Exposure to sulfuric acid may occur if the battery case has been damaged or the vents have
been tampered with.
***See other side for first aid information.
GS BATTERY (U.S.A.) INC.
1000 Mansell Exchange W., Suite 350
Alpharetta, GA 30022
Tel.(800) 472-2679 (678) 762-4818 Fax: (678) 739-2132

SPILL OR LEAK PROCEDURES


STEPS TO TAKE IN CASE OF LEAK OR SPILL
If sulfuric acid is spilled from a battery, neutralize the acid with sodium bicarbonate (baking soda), sodium bicarbonate
(soda ash), or calcium oxide (lime). Flush the area with water and it is acceptable to discard the neutralized acid in
the sewage system.
***Do not allow unneutralized acid in to the sewage system.
WASTE DISPOSAL METHOD
Neutralized acid may be discarded in the sewage system. Spent batteries must be treated as hazardous waste and
disposed of in accordance with Local, State, and Federal regulations.
***A copy of this Material Safety Data Sheet must be supplied to any scrap dealer or secondary
lead smelter.

SAFETY DATA
ELECTRICAL
Due to the battery's low internal resistance and high power density, high levels of short circuit current can develop
across the battery terminals. Do not rest tools or cables on the battery. Use insulated tools only. Follow all
installation instructions and diagrams when installing or maintaining a battery system.
CONDITION TO AVOID
Prohibit smoking, sparks, flames, etc., from battery charging area. Avoid mixing acid with other chemicals.
PROTECTION
EXPOSURE SITE PROTECTION COMMENTS
Skin Rubber gloves, Apron Protective equipment must be worn if the battery
Respiratory Respirator (for lead) is cracked or otherwise damaged. A respirator
Eyes Safety goggles, Face shield should be worn during lead reclamation
operations if the TLV is exceeded.

FIRST AID
SULFURIC ACID
SKIN CONTACT Flush with water. See a physician if the contact area is large or if blister occur.
EYE CONTACT Call a physician immediately. Flush with water until medical help arrives.
INGESTION Call a physician immediately. If patient is conscious, flush mouth with water, have the patient
drink milk or sodium bicarbonate solution.
***Do not give anything to an unconscious person.

REGULATORY INFORMATION
SCHEDULE: II LIST: II CLASS: 8 PACKING GROUP: IIIII
DESCRIPTION: BATTERIES, WET, NON-SPILLABLE

DOT REGULATION: Class 60


DESCRIPTION: BATTERIES, NON-HAZARDOUS, NON-SPILLABLE

COMMENTS
As a result of test performed in accordance with D.O.T. Title 49 CFR Part 173.159 (d). As a result of
tests performed, verification was made that "GS Portalac" or "GS Superlac" batteries meet the requirements of the
above subchapters of D.O.T. regulations for vibration and pressure differential. Accordingly, "GS Portalac" and "GS
Superlac" batteries qualify to be listed and categorized as electric storage batteries wet, non-spillable and therefore as
of September 30, 1995 excepted from the D.O.T. requirements set forth in 49 CFR Part 173.159. The regulation
change effective September, 1995 was to clarify and distinguish to shippers and transporters, all batteries that have
been tested and determined to be in compliance with D.O.T. Hazardous Material Regulations, the International Civil
Aeronautics organization (ICAO), and the International Air Transport Association (IATA) Packing Instruction 806 and
Special Provision A67, and therefore excepted from all other requirements of the regulations and classified as a
non-spillable battery.

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