General Instructions

1. The test is of 3 hours duration and the maximum marks is 300.

2. The question paper consists of 3 Parts (Part I: Physics, Part II: Chemistry, Part III: Mathematics). Each Part
has two sections (Section 1 & Section 2).

3. Section 1 contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.

4. Section 2 contains 5 Numerical Value Type Questions. The answer to each question is an integer ranging
from 0 to 9 (both inclusive).

5. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc. inside the examination room/hall.

6. Rough work is to be done on the space provided for this purpose in the Test Booklet only.

7. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.

8. Do not fold or make any stray mark on the Answer Sheet (OMR).

Marking Scheme
1. Section – 1: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.

2. Section – 2: +4 for correct answer, 0 for all other cases. There is no negative marking.

Name of the Candidate (In CAPITALS) :

Roll Number :

OMR Bar Code Number :

Candidate's Signature : Invigilator's Signature

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PART - I : PHYSICS 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. A man places a chain (of mass 'm' and length ‘  ’) on a table slowly. Initially the lower end of the chain
just touches the table. The man drops the chain when half of the chain is in vertical position. Then work
done by the man in this process is:
 mg mg mg
(A)  mg (B) – (C) –3 (D) –
2 4 8 8
 2ˆ
2. A body is displaced from (0, 0) to (1m, 1m) by a force F  ( x i  yjˆ) N . The work done by this force
will be:
4 5 3 7
(A) J (B) J (C) J (D) J
3 6 2 5
3. A block of mass 2 kg is kept at origin at t = 0 and is having velocity 4 5 m/s in positive x-direction.
The only force acting on it is a conservative and its potential energy is defined as U  – x3  6 x 2  15 (SI
units). Its velocity when its acceleration is minimum after t = 0 is:
(A) 8 m/s (B) 4 m/s (C) 10 24 m/s (D) 20 m/s

4. A particle moves in a straight line with its retardation proportional to its displacement 'x'. Change in
kinetic energy is proportional to:
(A) x2 (B) ex (C) x (D) log e x

5. A ball of mass 1 kg strikes a wedge of mass 4 kg horizontally with a velocity of 10 m/s. Just after
collision, velocity of wedge becomes 4 m/s. Friction is absent everywhere and collision is elastic. Select
the correct alternative:

(A) Speed of ball after collision is 12 m/s

(B) Speed of ball after collision is 8 m/s
(C) Impulse between ball and wedge during collision is 16 N-s
(D) Impulse between ball and wedge during collision is 32 N-s

6. A body is moving in vertical circle of radius r such that the string is just taut at its highest point.
The speed of the particle when the string is horizontal is:

(A) gr (B) 2gr (C) 3gr (D) 4gr

7. The ratio of work done by all the forces on a car in order to change its speed from 0 to V, from V to 2V
is (Assume that the car moves on a horizontal road):
(A) 1 (B) 1/2 (C) 1/3 (D) 1/4

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8. A particle is placed at the origin and a force F = kx is acting on it (where k is a positive constant). If U
(0) = 0, the graph of U (x) versus x will be: (where U is the potential energy function)

(A) (B) (C) (D)

9. In gravity-free space, a man of mass M standing at a height h above the floor throws a ball of mass m
straight down with a speed u. When the ball reaches the floor, the distance of the man above the floor
will be:
 m  m
(A) h 1   (B) h 2 – 
 M  M
(C) 2h (D) A function of m, M, h and u

10. Find the distance of center of mass of two square plates system as shown from point O. If masses of
plates are 2m and m is (their edges are 'a' and '2a' respectively):
a
(A)
2
(B) a
3a
(C)
2
2a
(D)
3

11. A 2 kg block is connected with two springs of force constants k1 = 100 N/m and k2 = 300 N/m as shown
in figure. The block is released from rest with the springs unstretched. The acceleration of the block in its
lowest position is : (g = 10 m/s2)
(A) Zero
(B) 10 m/s2 upwards
(C) 10 m/s2 downwards
(D) 5 m/s2 upwards

12. A body of mass m1 moving at a constant speed undergoes an elastic head on collision with a body of
mass m2 initially at rest. The ratio of the kinetic energy of mass m1 after the collision to that before the
collision is:
2 2 2 2
 m1 – m2   m1  m2   2m1   2m2 
(A)   (B)   (C)   (D)  
 m1  m2   m1 – m2   m1  m2   m1  m2 

13. A parabolic bowl with its bottom at origin has the shape y = x2/20.
Here x and y are in metres, the maximum height at which a small mass m
can be placed on the bowl without slipping (coefficient of static friction
is 0.5) is:
(A) 2.5 m (B) 1.25 m
(C) 1.0 m (D) 4.0 m

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14. A block of mass m slides in an inclined right angled trough as

shown in the figure (Trough is placed symmetrically). If the
coefficients of kinetic friction between block and material
composing the trough is  k , find the acceleration of the block:
(A) 
g sin   2 k cos   (B) g  sin   k cos  

(C) g  sin   2 k cos   (D) 

g sin    k cos  
15. Two blocks of masses m and 2m placed one over the other as
shown in figure. The coefficient of friction between m and 2m is
µ and between 2m and ground is µ/3. If a horizontal force F is
applied on upper block and T is tension developed in string then
choose the incorrect alternative.
µ
(A) If F = mg , T = 0 (B) If F = µ mg, T = 0
3
µmg
(C) If F = 2µmg, T = (D) If F = 3µmg, T = 0
3
16. A stream of water of density d, cross-section A and speed v strikes a wall that is perpendicular to the
stream as shown. The water then flows sideways along the wall. The force exerted by the stream on the
wall is:

(A) dv2A (B) dvA/2 (C) dghA (D) v2A/d

17. Two blocks are connected by a massless string through an ideal pulley as shown. A force of 22N is
applied on block B. Find acceleration of COM of system.

(A) 1.4 m/s2 (B) 1 m/s2 (C) 2 m/s2 (D) None of these

18. Two blocks A and B of masses m and 2m respectively are held at rest such that the string is in natural
length. Find out the accelerations of both the blocks just after release.

g g
(A) g ,g  (B) ,  (C) 0, 0 (D) g ,0
3 3

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19. Two blocks A and B of masses 2m and m, respectively are connected by a massless and inextensible
string. The whole system is suspended by a massless spring as shown in the figure. The magnitudes of
acceleration of A and B immediately after the string is cut, are respectively:

g g g g
(A) g, (B) ,g (C) g, g (D) ,
2 2 2 2
20. A block is dragged on a smooth plane with the help of a rope which moves with a velocity v as shown in
figure. The horizontal velocity of the block is:

v v
(A) v (B) (C) v sin  (D)
sin  cos 

SPACE FOR ROUGH WORK

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SECTION-2
This section contains Five (05) Numerical Value Type Questions. The answer to each question is an integer
ranging from 0 to 9 (both inclusive).

21. Each of the blocks shown in figure has mass 1 kg. The rear block moves with a speed of 2m/s towards
the front block kept at rest. The spring attached to the front block is light and has a spring constant 50
X
N/m. The maximum compression of the spring is given by m, then find X.
10
k= 50 N/m
1 kg 1 kg

22. A small ball is projected from point P towards a vertical wall as shown. It hits the wall when its velocity
is horizontal. Ball reaches point P after one bounce on the floor. The coefficient of restitution assuming it
to be same for two collisions is N/10. All surfaces are smooth. Find the value of N.

23. A single conservative force acts on a body of mass 1 kg that moves along the x-axis. The potential energy
U(x) is given by U (x) = 20 + (x – 2)2, where x is in meters. At x = 5.0 m the particle has a kinetic energy of 20
J. If the maximum kinetic energy of body is x joules, then find the value of  x  20  Joules .
10
24. A particle of mass Kg is moving in the positive direction of x. Its initial position is x = 0 & initial
7
velocity is 1 m/s. The velocity at x = 10 is:

1
25. If one end of the cord A is pulled down with 2 m/s, then calculate the velocity of block as . Find value
N
of N.

SPACE FOR ROUGH WORK

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PART - II : CHEMISTRY 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.

1. Z1 is the molar compressibility factor for a real gas obeying Vander Waal’s equation at its critical
conditions, and Z 2 is the molar compressibility factor of the real gas at its Boyle’s temperature (TB ) and
pressure P. The pressure P is neither very low, nor very high. Then-
8 3 8
(A) Z1  Z2 (B) Z1  Z2 (C) Z1  Z2 (D) Z1  Z2
3 8 27
2. Which of following relationship is NOT true for fixed quantity of a perfect gas?
(A) nP  nK  nV, at constant temperature
(B) nV  nK ' nT, at constant pressure
(C) nP  nK" nT, at constant volume
(D) nV  nK ' nT, at constant pressure

3. Select the pair in which both species are planar and non-polar:
(A) BF3 , NF3 (B) NH3 , XeF4 (C) BF3 ,SO3 (D) NF3 , NH3

4. Select the correct order of stability among given pairs of resonating structures.
1 1 1 1 1 1
(A) N  N  O  N  N O (B) O  C  O  O  CO
1 1
(C) CH 3  C  O   CH 3  C  O (D) N  C  O  N  CO
|| |
O 
O

5. Select the pair of electron deficient species:

(A) B2H 6 , AlCl3 (B) BH 4 , NH 4 (C) CCl4 , SiCl4 (D) NO 2 , NO3

6. Two vessels A and B having volume in ratio 1 : 2 are connected through a narrow tube of negligible
volume as shown in the figure. Both vessels were maintained at same temperature T and ratio of
pressure of the inert gases in the vessels i.e A and B is 2 : 1 before removing the stopper S. The ratio i.e.
final pressure : initial pressure for the vessel B after removing the stopper S will be:

(A) 4:3 (B) 3:4 (C) 2:1 (D) 2:3

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7. For three gases (a), (b) and (c) each having negligible size of particles as compared to volume of the
container, graphs have been constructed at a temperature T between their molar compressibility factor
 1 
(Zm ) and   ( Vm is molar volume) as shown in the figure. The correct alternatives for the gases
 Vm 
(a), (b) and (c) are.

(A) H2 , N2 , O2 (B) N 2 , CO, CO 2 (C) H 2 , CO 2 , N 2 (D) NH3 , CO 2 , H 2

8. Select correct order from the following.

(a) Bond angle: CH 4  NH3  H 2O
(b) Boiling point: CH 4  NH3  H 2O
(c) Bond order: B2  O 2  N 2
(A) a, b, c (B) a, b only (C) b, c only (D) a, c only

9. Select correct statement regarding SNF3 .

(a) Central S-atom is sp3 hybrid

(b) Central S-atom has 2 lonepairs in the valence shell
(c) Central S-atom forms 2 pie bonds using its valence d orbitals
(A) a and b only (B) a and c only (C) b and c only (D) a, b, c

10. Select the correct match of the molecules in List-I with properties in List-II.
List I (molecules) List II (properties)
(a) XeF6 (p) sp3d , polar
(b) XeF2 (q) sp3d 3 , polar
(c) SF6 (r) sp3d 2 , Non polar
(d) IF3 (s) sp3d , Non polar
(A) a  p, b  q, c  r, d  s (B) a  q, b  s, c  r, d  p
(C) a  q, b  p, c  r, d  s (D) a  p, b  r, c  s, d  q

11. 50ml of a gaseous hydrocarbon is burnt in presence of oxygen gas. The gaseous mixture obtained
undergo reduction in its volume by 100ml on cooling. The cooled gaseous mixture then passed through
an alkali solution and a further reduction of 100ml is observed. Vapour density of the hydrocarbon is:
(A) 28 (B) 26 (C) 13 (D) 14

12. Critical temperature of a real gas is 200K. Value of temperature at which the gas can behave ideally for a
certain range of pressure is:
(A) 402°C (B) 398°C (C) 675°C (D) 569°C

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13. From the given statements, incorrect statements are:

(a) HOMO of dioxygen is  *2p
(b) LUMO of dinitrogen is 2p

(c) Bond strength of B2  F2

(A) a, b and c (B) b only (C) b and c only (D) c only

14. Select correct statement from the following.

(A) According to K.T.G, average molar thermal kinetic energy of ideal gas particles depends upon
molar mass of the gas
(B) VRMS  Vavg. for both symmetrical and unsymmetrical distribution of molecular speeds
(C) Collisions between ideal gas particles are perfectly inelastic
(D) Potential energy of the ideal gas particles varies non linearly with separation between the
particles

15. Equal masses of H 2 , He and Ne were kept in a closed container. If total pressure of the gaseous mixture
is 5.6 atm then partial pressure of helium is: [Atomic masses H = 1, He = 4, Ne = 20]
(A) 2.85 atm (B) 3.45 atm (C) 1.75 atm (D) 1.95 atm

16. Which of following statement is NOT true for following species

ClO4 ClO3 ClO 2

(A) Central chlorine atoms are sp3 hybrid in all three species
(B) Central chlorine atoms are using one/more d-orbital for  -bond/s
(C) Average bond order of Cl–O bonds decreases with increase in number of oxygen atoms
(D) All three species are diamagnetic

17. Radii of a xenon atom is 4A°. Value of Vander Waal constant “b” for the gas is approximately-

[N A  6 1023 / mole,   3]
(A) 0.2 L/mole (B) 0.3 L/mole (C) 0.5 L/mole (D) 0.6 L/mole

18. The Maxwell-Boltzmann distribution of molecular speeds is given below for two different gases, X and
Y at 300K. Identify correct relationship. ( f (v) fraction of particles)

(A) Molar mass of X > Molar mass of Y (B) Vapour density of X < Vapour density of Y
(C) VMP of X > VMP of Y ; at 300 K (D) VRMS of X = VRMS of Y; at 300K

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19. Assertion: Bonding M.O formed by linear combination of two atomic orbitals is lower in energy as
compared to the antibonding M.O formed by combination of these atomic orbitals.
Reason: Square of wave function of the M.O formed by constructive interaction of two atomic
orbital wave functions is higher in magnitude as compared to its value obtained by
destructive interaction of the atomic orbital wave functions.
(A) Assertion and Reason both are incorrect statements
(B) Assertion is correct while Reason is incorrect
(C) Assertion and Reason are true and the reason is a correct explanation of the Assertion
(D) Assertion and Reason are true BUT the Reason is NOT a correct explanation of the Assertion

20. Select the correct relationship.

8a 2
(A) Critical temperature of a real gas, TC 
27Rb
2
(B) Critical volume of a real gas, VC  3b

a2
(C) Critical pressure of a real gas, PC 
27b3
a
(D) Boyle’s temperature of real gas, TB 
Rb
SPACE FOR ROUGH WORK

SECTION-2
This section contains Five (05) Numerical Value Type Questions. The answer to each question is an integer
ranging from 0 to 9 (both inclusive).

21. Maximum number of H-bonds in which a H 2O molecule can involve is x. Number of unpaired electrons
in an anion of KO 2 is y. then (x + y) is equal to:

22. 2 grams of H 2 gas diffuses through a small hole in 2 seconds. Time taken for diffusion of 16 grams of
O 2 gas under identical conditions of temperature and pressure is ________ (seconds). [Atomic masses:
H = 1, O = 16]
23. Average thermal kinetic energy of helium gas at S.T.P is x kJ/mole, value of 2x is (round off to nearest
integer) [R = 8.314 J/mole K]
o
24. In a diatomic molecule AB, bond distance is 1.25A and charge over an atom is 1.6  10 10 esu . Dipole
moment of the molecule is x Debye. Value of x is:

25. A container of capacity 10L having 0.5 moles of N 2 gas at 300K is at one of the end of a Hg-
manometer. Other end of the manometer is open and Pair  1.20atm. The magnitude of difference in
height of Hg-coloums is x cm when the gas is allowed to exert pressure over the liquid Hg, then value of
4x is [Take 1 atm  75 cm of Hg, R = 0.082 atm–L/mole–K]
SPACE FOR ROUGH WORK

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PART - III : MATHEMATICS 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY
ONE CHOICE is correct.

1. Number of 3 digit numbers containing the digit 7 exactly once :

(A) 225 (B) 220 (C) 200 (D) 180

2. All possible 720 permutations of MANDIR are arranged in dictionary order, what is the position (rank)
of MANDIR in that dictionary ?
(A) 372 (B) 373 (C) 374 (D) 375
3. Number of arrangements of letters of word MATHEMATICS such that no two vowels are together is :
(A) 210  7! (B) 420  7! (C) 210  8! (D) 840  7!

4. Number of integers greater than 5000, that can be formed using digits 3, 5, 6, 7 and 8 without repetition
is :
(A) 216 (B) 192 (C) 120 (D) 72
5. Highest power of 24 that divides 100! is :
(A) 4 (B) 48 (C) 32 (D) 13
6. In how many ways can 4 different prizes be distributed among 3 students, if each student can get all the
4 prizes?
(A) 4! (B) 34 (C) 34 – 1 (D) 33

7. If a polygon has 44 diagonals, then the number of its sides are:

(A) 11 (B) 7 (C) 8 (D) None of these

8. How many 10 digit numbers can be written by using the digits 1 and 2?
10
C1  9 C2 210 10
(A) (B) (C) C2 (D) 10!

9. In how many ways can 5 boys and 3 girls sit in a row so that no two girls are together ?
4 6 5
(A) 5 !  3! (B) P3  5! (C) P3  5! (D) P3  3!

10. The number of words which can be formed using all the letters of the word LUCKNOW when the
vowels always occupy even places is :
(A) 120 (B) 720 (C) 400 (D) 420
11. There are 12 volleyball players in all in a college, out of which a team of 9 players is to be formed. If the
captain always remains the same, then in how many ways can the team be formed ?
(A) 36 (B) 108 (C) 99 (D) 165
12. How many words can be made by using all letters of word 'BAHUBALI' if all words start and end with
vowels ?
(A) 2160 (B) 900 (C) 1560 (D) 780
1 1
13. Let x   2i, i  1 , then x 2187  2187

x x
1
(A) 2i (B)  2i (C) 2 (D) i
2

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2
14. If z 2  1  z  1 , then z lies on :
(A) real axis (B) imaginary axis (C) a circle (D) None of these

1  cos   i sin  7
15. Principal value of arg  z  and z , where z is : (  is acute)
 cos   i sin  3
     
(A)  , 27 cos 7   (B) , 27 cos 7  
2 2 2 2
  7    7 
(C) , 27 cos   (D)  , 27 cos  
2  2  2  2 

16. If a complex number z satisfies the equation z  2 z  1  i  0, then z is equal to :

(A) 2 (B) 3 (C) 5 (D) 1

17. If z is a complex number satisfying the relation z  1  z  2 1  i  then z is :

1 1 1 1
(A) 1  4 i  (B) 3  4 i  (C) 1  4 i  (D) 3  4 i 
2 2 2 2

7z
18. If f  z   , where z  1  2i , then f  z  is :
1  z2
z
(A) (B) z (C) 2 z (D) None of these
2

19. z1  z2  z1  z2 is possible, if :
1
(A) z2  z1 (B) z2 
z1
(C) arg  z1   arg  z2  (D) z1  z2

20. If x  a  b, y  a  b and z  a   b , where  and  are distinct imaginary cube roots of unity,
then xyz is equal to :
(A) a2  b2 (B) a3  b3 (C) a 3 b3 (D) a 3  b3

SPACE FOR ROUGH WORK

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SECTION-2
This section contains Five (05) Numerical Value Type Questions. The answer to each question is an integer
ranging from 0 to 9 (both inclusive).

21. If 8 Cr  7 C3  7 C2 , then minimum value of r is equal to :

3 3
22. If x3  1  0 has the non-real complex roots ,  then the value of 1  2      3  3  5  is :

23. The number of 4 letter words (with or without meaning) that can be formed from the 9 letters of the word
‘PRACTICAL’ is ‘abcd’ (a four digit number) then a  b  c  d is equal to _______.

24. There are 10 chairs in a row. If 3 persons wish to sit on these chairs such that there is no empty chair
between any of the three persons and total number of ways of doing this is equal to 2a  3b where a and
b are natural numbers, then ( a  b) is equal to ______.

1/ 2 1/ 2 
25. Im  3  2 54
  
 3  2 54   is equal to  2 a , then ‘a’ is equal to _______.


SPACE FOR ROUGH WORK

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