HYTORC Oil MSDS - NEW

Download as pdf or txt
Download as pdf or txt
You are on page 1of 10

Safety Data Sheet

Material Name: HYTORC HYDRAULIC OILS

Section 1 - PRODUCT AND COMPANY IDENTIFICATION


Material Name: HYTORC AW Hydraulic Oils, ISO 22, 32, 46, 68, 100, 150, 220

Product Code: Prefix 31

Synonyms: Petroleum oil, Petroleum hydrocarbon, lube oil, lubricant.

Product Use: Hydraulic oil. If this product is used in combination with other products, refer to the Safety
Data Sheet for those products.

Restrictions on Use: None known.

SUPPLIER
HYTORC
333 Route 17 N. Mahwah, NJ 07430, USA
www.hytorc.com
Phone: 201-512-9500

Issue Date: December 2, 2019


Supersedes Issue Date: July 18, 2018
Original Issue Date: April 22, 1993

Section 2 - HAZARDS IDENTIFICATION

Classification in accordance with Schedule 1 of Canada’s Hazardous Products Regulations (HPR) (SOR/2015-
17) and paragraph (d) of 29 CFR 1910.1200 in the United States
None needed according to classification criteria.
GHS Label Elements Symbol(s)
None needed according to classification criteria.
Signal Word
None needed according to classification criteria.
Hazard Statement(s)
None needed according to classification criteria.
Precautionary Statement(s) Prevention
None needed according to classification criteria.
Response
None needed according to classification criteria.
Storage
None needed according to classification criteria.
Disposal
Dispose of in accordance with all applicable federal, state and local regulations.

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

CAS Component Name Percent

64742-58-1 Lubricating oils, petroleum, hydrotreated spent 9-99

64742-62-7 Residual oils (petroleum), solvent dewaxed 0-71

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters,


68649-42-3 0.2-0.55
zinc salts

128-39-2 2,6-Di-tert-butylphenol 0.085-0.17

Lubricating oils, petroleum, C20-50, hydrotreated


72623-85-9 0.085-0.17
neutral oil-based, high-viscosity

Concentration ranges are used to express batch-to-batch variability in the production of the mixture.

Section 4 - FIRST AID MEASURES

Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get medical attention if
needed.
Skin
IF ON SKIN: Wash with plenty of soap and water. Get medical attention if needed.
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy
to do. Continue rinsing. Get medical attention if needed.
Ingestion
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.
Most Important Symptoms/Effects
Acute
No information on significant adverse effects.
Delayed
Repeated exposure may cause skin dryness or cracking.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically and supportively. Treatment may vary with condition of victim and specifics of
incident.

Section 5 - FIRE FIGHTING MEASURES


Extinguishing Media
Suitable Extinguishing Media
Carbon dioxide, dry chemical, regular foam, water spray, water fog. Water or foam may cause frothing.
Unsuitable Extinguishing Media
Do not use high pressure water streams.

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

Special Hazards Arising from the Chemical


Negligible fire hazard.
Hazardous Combustion Products
Decomposition and combustion materials may be toxic. Burning may produce aldehydes, hydrogen sulfide,
alkyl mercaptans, sulfides, nitrogen oxides, phosphorus oxide, sulfur oxides, carbon monoxide, unidentified
organic compounds.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. Keep unnecessary people away, isolate hazard area
and deny entry.
Special Protective Equipment and Precautions for Firefighters
A positive-pressure, self-contained breathing apparatus (SCBA) and full-body protective equipment are
required for fire emergencies.

Section 6 - ACCIDENTAL RELEASE MEASURES


Personal Precautions, Protective Equipment and Emergency Procedures
Wear personal protective clothing and equipment, see Section 8.
Methods and Materials for Containment and Cleaning Up
Remove all ignition sources. Do not touch or walk through spilled products. Stop leak if you can do it
without risk. Wear protective equipment and provide engineering controls as specified in SECTION 8:
EXPOSURE CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and
unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist. Contain spill away
from surface water and sewers. Contain spill as a liquid for possible recovery, or absorb with compatible
sorbent material and shovel with a clean, sparkproof tool into a sealable container for disposal. Additionally,
for large spills: Dike far ahead of liquid spill for collection and later disposal.

Section 7 - HANDLING AND STORAGE

Precautions for Safe Handling


Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe for such
locations should be used. Use clean tools and explosion-proof equipment. When transferring large volumes
of product, metal containers, including trucks and tank cars, should be grounded and bonded. These products
have a low vapor pressure and are not expected to present an inhalation hazard under normal temperatures
and pressures. However, when aerosolizing, misting, or heating these products, do not breathe vapor or mist.
Use in a well ventilated area. Avoid contact with eyes, skin, clothing, shoes.
Conditions for Safe Storage, Including any Incompatibilities
None needed according to classification criteria.
Keep container tightly closed when not in use and during transport. Store containers in a cool, dry place. Do
not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away from heat, flame,
sparks, static electricity, or other sources of ignition. Empty product containers may retain product residue
and can be dangerous.
Incompatible Materials
Acids, oxidizing agents, reducing agents.

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


Component Exposure Limits
Canada, ACGIH, OSHA, and NIOSH have not developed exposure limits for any of this product's
components.
ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI)
There are no biological limit values for any of this product's components.
Engineering Controls
Provide general ventilation. Where adequate general ventilation is unavailable, use process enclosures,
local exhaust ventilation, or other engineering controls.
Individual Protection Measures, such as Personal Protective Equipment
Eye/face protection
Wear safety glasses. Additional protection like goggles, face shields, or respirators may be needed
dependent upon anticipated use and concentrations of mists or vapors. Eye wash fountain and emergency
showers are recommended. Contact lens use is not recommended.
Respiratory Protection
A respiratory protection program which meets USA's OSHA General Industry Standard 29 CFR 1910.134
or Canada's CSA Standard Z94.4-M1982 requirements must be followed whenever workplace conditions
warrant a respirator's use. Consult a qualified Industrial Hygienist or Safety Professional for respirator
selection guidance.
Glove Recommendations
Where skin contact is likely, wear neoprene, nitrile, or equivalent protective gloves; use of natural rubber or
equivalent gloves is not recommended. To avoid prolonged or repeated contact where spills and splashes are
likely, wear appropriate chemical-resistant faceshield, boots, apron, coveralls, long sleeve shirts, or other
protective clothing. When product is heated and skin contact is likely, wear heat-resistant gloves, boots, and
other protective clothing.
Protective Materials
Personal protective equipment should be selected based upon the conditions under which this material is
used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified
professional pursuant to regulatory requirements. The following PPE should be considered the minimum
required: Safety glasses, Gloves, and Lab coat or apron.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


Amber, red, blue
Appearance Physical State Liquid
to green liquid.

Odor petroleum Color Amber, red, blue to green

Odor Threshold Not available pH Not available

Melting Point Not available Boiling Point 246 °C (475 °F Minimum )

Boiling Point Range Not available Freezing point Not available

Evaporation Rate Not available Flammability (solid, gas) Not available

Autoignition
Not available Flash Point 165 °C (329 °F Minimum )
Temperature
Decomposition
Lower Explosive Limit Not available Not available
temperature

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

Upper Explosive Limit Not available Vapor Pressure <0.1 mmHg @ 68 °F (20º C )

Specific Gravity
Vapor Density (air=1) Not available 0.88 (Approximate Water = 1 )
(water=1)
Partition coefficient: n-
Water Solubility (Insoluble ) Not available
octanol/water
>20.5 mm2/s 40
Viscosity Kinematic viscosity Not available
ºC (104 °F )

Solubility (Other) Not available Density 7.3 lb/gal (US Approximate )

Volatile Organic
-6 °C (21 °F
Pour Point Compounds (As Negligible, as per 40 CFR 51.100(s)
Maximum )
Regulated)
Molecular Weight Not available

Section 10 - STABILITY AND REACTIVITY


Chemical Stability
Stable under normal temperatures and pressures.
Possibility of Hazardous Reactions
Polymerization is not known to occur under normal temperature and pressures. Not reactive with water.
Conditions to Avoid
Avoid sparks or flame.
Incompatible Materials
Acids, oxidizing agents, reducing agents.
Hazardous decomposition products
None under normal temperatures and pressures. See also SECTION 5: HAZARDOUS COMBUSTION
PRODUCTS.

Section 11 - TOXICOLOGICAL INFORMATION


Information on Likely Routes of Exposure
Inhalation
No information on significant adverse effects.
Skin Contact
Prolonged or repeated skin contact may cause skin dryness or cracking.
Eye Contact
No information on significant adverse effects.
Ingestion
May be harmful if swallowed.
Acute and Chronic Toxicity
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected
endpoints are published:
Lubricating oils, petroleum, hydrotreated spent (64742-58-1)
Oral LD50 Rat >2000 mg/kg; Dermal LD50 Rabbit >4480 mg/kg
Residual oils (petroleum), solvent dewaxed (64742-62-7)
Oral LD50 Rat >5000 mg/kg; Dermal LD50 Rabbit >2000 mg/kg; Inhalation LC50 Rat 2.18 mg/L 4 h

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS
2,6-Di-tert-butylphenol (128-39-2)
Oral LD50 Rat >5000 mg/kg; Dermal LD50 Rabbit >10 g/kg
Lubricating oils, petroleum, C20-50, hydrotreated neutral oil-based, high-viscosity (72623-85-9)
Oral LD50 Rat >5000 mg/kg; Dermal LD50 Rabbit >2000 mg/kg; Inhalation LC50 Rat 2.18 mg/L 4 h
Product Toxicity Data
Acute Toxicity Estimate

Oral > 2000 mg/kg

Immediate Effects
No information on significant adverse effects.
Delayed Effects
No information on significant adverse effects.
Irritation/Corrosivity Data
May cause slight skin or respiratory irritation.
Respiratory Sensitization
Based on best current information, there is no known human sensitization associated with these products.
Dermal Sensitization
Based on best current information, there is no known human sensitization associated with this product.
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA.
Germ Cell Mutagenicity
Based on best current information, there is no known mutagenicity associated with this product.
Tumorigenic Data
No information is available for the product.
Reproductive Toxicity
Based on best current information, there is no known reproductive toxicity associated with this product.
Specific Target Organ Toxicity - Single Exposure
No target organs identified.
Specific Target Organ Toxicity - Repeated Exposure
No target organs identified.
Aspiration hazard
No information available for the product.
Medical Conditions Aggravated by Exposure
Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin disorders may have
increased susceptibility to the effects of exposure.

Section 12 - ECOLOGICAL INFORMATION


Ecotoxicity
Harmful to aquatic life with long lasting effects.
Component Analysis - Aquatic Toxicity

Residual oils (petroleum), solvent dewaxed 64742-62-7

Fish: LC50 96 h Oncorhynchus mykiss >5000 mg/L

Invertebrate: EC50 48 h Daphnia magna >1000 mg/L IUCLID

Phosphorodithioic acid, O,O-di-C1-14-


68649-42-3
alkyl esters, zinc salts

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

LC50 96 h Pimephales promelas 1 - 5 mg/L [static ]; LC50


Fish:
96 h Pimephales promelas 10 - 35 mg/L [semi-static ]

Invertebrate: EC50 48 h Daphnia magna 1 - 1.5 mg/L IUCLID

2,6-Di-tert-butylphenol 128-39-2

Invertebrate: EC50 48 h Daphnia magna 0.45 mg/L IUCLID

Lubricating oils, petroleum, C20-50,


hydrotreated neutral oil-based, high- 72623-85-9
viscosity

Fish: LC50 96 h Oncorhynchus mykiss >5000 mg/L

Invertebrate: EC50 48 h Daphnia magna >1000 mg/L IUCLID

Persistence and Degradability


No information available for the product.
Bioaccumulative Potential
No information available for the product.
Mobility
No information available for the product.
Other Toxicity
No additional information is available.

Section 13 - DISPOSAL CONSIDERATIONS


Disposal Methods
Dispose in accordance with federal, state, provincial, and local regulations. The responsibility for proper
waste disposal lies with the owner of the waste. Processing, use, or contamination by the user may change
the waste code applicable to the disposal of this product. Regulations may also apply to empty containers.
Contact HYTORC regarding proper recycling or disposal.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.

Section 14 - TRANSPORT INFORMATION


US DOT Information: Not regulated for transport.
IATA Information: Not regulated for transport.
IMDG Information: Not regulated for transport.
TDG Information: Not regulated for transport.
International Bulk Chemical Code
This material does not contain any chemicals required by the IBC Code to be identified as dangerous
chemicals in bulk.

Section 15 - REGULATORY INFORMATION


Canada Regulations
CEPA - Priority Substances List
None of this product's components are on the list.

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

Ozone Depleting Substances


None of this product's components are on the list.
Council of Ministers of the Environment - Soil Quality Guidelines
None of this product's components are on the list.
Council of Ministers of the Environment - Water Quality Guidelines
None of this product's components are on the list.
U.S. Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or
require an OSHA process safety plan.

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters,


68649-42-3
zinc salts

1 % de minimis concentration (related to Zinc


SARA 313:
compounds)

SARA Section 311/312 (40 CFR 370 Subparts B and C) reporting categories
No hazard categories applicable.
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 68649-42-3 Yes No No Yes Yes

California Safe Drinking Water and Toxic Enforcement Act (Proposition 65)
Not listed under California Proposition 65.
Component Analysis - Inventory
Lubricating oils, petroleum, hydrotreated spent (64742-58-1)

US CA AU CN EU JP - ENCS JP - ISHL KR KECI - Annex 1 KR KECI - Annex 2

Yes DSL Yes Yes EIN No No Yes No

KR - REACH CCA MX NZ PH TW VN (Draft)


TH-TECI
No Yes Yes Yes No Yes Yes

Residual oils (petroleum), solvent dewaxed (64742-62-7)

US CA AU CN EU JP - ENCS JP - ISHL KR KECI - Annex 1 KR KECI - Annex 2

Yes DSL Yes Yes EIN No No Yes No

KR - REACH CCA MX NZ PH TH-TECI TW VN (Draft)

No Yes Yes Yes Yes Yes Yes

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3)

US CA AU CN EU JP - ENCS JP - ISHL KR KECI - Annex 1 KR KECI - Annex 2

Yes DSL Yes Yes EIN No No Yes No

KR - REACH CCA MX NZ PH TH-TECI TW VN (Draft)

No Yes Yes Yes No Yes Yes

2,6-Di-tert-butylphenol (128-39-2)

US CA AU CN EU JP - ENCS JP - ISHL KR KECI - Annex 1 KR KECI - Annex 2

Yes DSL Yes Yes EIN Yes Yes Yes No

KR - REACH CCA MX NZ PH TH-TECI TW VN (Draft)

No Yes Yes Yes Yes Yes Yes

Lubricating oils, petroleum, C20-50, hydrotreated neutral oil-based, high-viscosity (72623-85-9)

US CA AU CN EU JP - ENCS JP - ISHL KR KECI - Annex 1 KR KECI - Annex 2

Yes DSL Yes Yes EIN No No Yes No

KR - REACH CCA MX NZ PH TH-TECI TW VN (Draft)

No No Yes Yes No Yes Yes

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com
Safety Data Sheet
Material Name: HYTORC HYDRAULIC OILS

Section 16 - OTHER INFORMATION

NFPA Ratings
Health: 1 Fire: 1 Instability: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Summary of Changes
Update to composition and resultant changes.
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport;
AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CA/MA/MN/NJ/PA -
California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS - Chemical Abstracts Service;
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CFR - Code of
Federal Regulations (US); CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled
Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD
- Dangerous Substance Directive; DSL - Domestic Substances List; EC – European Commission; EEC -
European Economic Community; EIN - European Inventory of (Existing Commercial Chemical Substances);
EINECS - European Inventory of Existing Commercial Chemical Substances; ENCS - Japan Existing and
New Chemical Substance Inventory; EPA - Environmental Protection Agency; EU - European Union; F -
Fahrenheit; F - Background (for Venezuela Biological Exposure Indices); IARC - International Agency for
Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation
Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG -
International Maritime Dangerous Goods; ISHL - Japan Industrial Safety and Health Law; IUCLID -
International Uniform Chemical Information Database; JP - Japan; Kow - Octanol/water partition
coefficient; KR KECI Annex 1 - Korea Existing Chemicals Inventory (KECI) / Korea Existing Chemicals
List (KECL); KR KECI Annex 2 - Korea Existing Chemicals Inventory (KECI) / Korea Existing Chemicals
List (KECL) , KR - Korea; LD50/LC50 - Lethal Dose/ Lethal Concentration; LEL - Lower Explosive Limit;
LLV - Level Limit Value; LOLI - List Of Lists™ - ChemADVISOR’s Regulatory Database; MAK -
Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; MX – Mexico; Ne-
Non-specific; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety
and Health; NJTSR - New Jersey Trade Secret Registry; Nq - Non-quantitative; NSL – Non-Domestic
Substance List (Canada); NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational
Safety and Health Administration; PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource
Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of
Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; Sc -
Semi-quantitative; STEL - Short-term Exposure Limit; TCCA – Korea Toxic Chemicals Control Act; TDG -
Transportation of Dangerous Goods; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act;
TW – Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit; UN/NA - United Nations
/North American; US - United States; VLE - Exposure Limit Value (Mexico); VN (Draft) - Vietnam (Draft);
WHMIS - Workplace Hazardous Materials Information System (Canada).
Other Information
Disclaimer:
User assumes all risks incident to the use of this product. To the best of our knowledge, the information
contained herein is accurate. However, HYTORC assumes no liability whatsoever for the accuracy or
completeness of the information contained herein. No representations or warranties, either expressed or
implied, of merchantability, fitness for a particular purpose or of any other nature are made hereunder with
respect to the information or the product to which the information refers. The data contained on this sheet
apply to the product as supplied to the user.

HYTORC, Division UNEX Corporation Phone: Email: Online:


333 Route 17N, Mahwah, NJ 07430, USA 201-512-9500 [email protected] www.hytorc.com

You might also like