Chap 1 Periodic Table Exercise
Chap 1 Periodic Table Exercise
Chap 1 Periodic Table Exercise
CHEMISTRY
ALLEN
Study Package
For – JEE (Advanced)
JEE-Chemistry
EXERCISE-01 CHECK YOUR GRASP
SELECT THE CORRECT ALTERNATIVE (ONLY ONE CORRECT ANSWER)
1. The atom having the valence shell electronic configuration 4s 2 4p 2 would be in:-
(A) Group II A and period 3 (B) Group II B and period 4
(C) Group IV A and period 4 (D) Group IV A and period 3
2. An element with atomic number 106 has been discovered recently. Which of the following electronic
configuration will it posses :-
(A) [Rn] 5f 14 6d 5 7s 1 (B) [Rn] 5f 14 6d 5 7s 2 (C) [Rn] 5f 14 6d 6 7s 0 (D) [Rn] 5f 14 6d 1 7s 2 7p 3
3. The electronic configuration of transition elements is exhibited by :-
(A) ns 1-2(n-1)d 1-10 (B) ns 2 (n - 1) d 10 (C) (n - 1)d 10s 2 (D) ns 2np 5
4. Which of the following electronic configurations in the outermost shell is characteristic of alkali metals :-
(A) (n–1) s 2p 6 ns 2p 1 (B) (n–1) s 2p 6d 10 ns 1 (C) (n–1) s 2p 6 ns 1 (D) ns 2np 6 (n–1)d 10
5. The chemistry of lithium is very similar to that of magnesium even though they are placed in different groups.
Its reason is :-
(A) Both are found together in nature (B) Both have nearly the same size
(C) Both have similar electronic configurations (D) The ratio of their charge to size is nearly the same
6. Configuration of Br– is : [Ar] 3d10 4s24p 6. The electronic configuration of Br+2 would be identical with the
element :-
(A) Se (B) As (C) Ga (D) Ge
7. 4d 35s 2 configuration belongs to which group :-
(A) IIA (B) IIB (C) V B (D) III B
3– 2– –
8. The ionic radii of N , O and F are respectively given by :-
(A) 1.36, 1.40, 1.71 (B) 1.36, 1.71, 1.40 (C) 1.71, 1.40, 1.36 (D) 1.71, 1.36, 1.40
9. From the given set of species, point out the species from each set having least atomic radius:-
(a) O –2 , F – , Na + (b) Ni, Cu, Zn (c) Li, Be, Mg (d) He, Li + , H –
correct answer is -
(A) O–2,Cu, Li, H – (B) Na + Ni, Be, Li + (C) F –, Zn, Mg, He (D) Na + , Cu, Be, He
10. K +, Ar, Ca 2+ and S 2– contains _
(A) Same electronic configuration and atomic volume
(B) Different electronic configuration but same IP.
(C) Same electronic configuration but different atomic volume
E:\Data\2014\Kota\JEE-Advanced\SMP\Che\Unit-02\Part (I)\Eng\01-Periodic Table\Exercise.p65
(D) None
11. Which of the following is not isoelectronic series :-
(A) Cl- , P3-, Ar (B) N 3-, Ne, Mg +2 (C) B +3, He, Li + (D) N 3-, S 2-, Cl -
12. Atomic radii of Fluorine and Neon in Angstrom units are given by :-
(A) 0.72, 1.60 (B) 1.60, 1.60
(C) 0.72, 0.72 (D) None of these
13. In the isoelectronic species the ionic radii (Å) of N 3–, Ne and Al +3 are respectively given by:-
(A) 1.36, 1.40, 1.71 (B) 1.36, 1.71, 1.40
(C) 1.71, 1.40, 1.36 (D) 1.71, 1.36, 1.40
–2
14. S is not isoelectronic with :-
(A) Ar (B) Cl– (C) HS– (D) Ti +3
15. The IP1, IP2, IP3, IP4 and IP5 of an element are 7.1, 14.3, 34.5, 46.8, 162.2 eV respectively. The element
is likely to be:-
(A) Na (B) Si (C) F (D) Ca
34
E
E 35
40. The covalent and vander Waal's radii of hydrogen respectively are :-
(A) 0.37 Å, 0.8 Å (B) 0.37 Å, 0.37 Å (C) 0.8 Å, 0.8 Å (D) 0.8 Å, 0.37 Å
41. The electronic configuration of two neutral elements A and B are
A = 1s 2 2s 2 2p 6 3s 1 and B = 1s 2 2s 2 2p 5
(A) A + B – (B) A – B + (C) A – B (D) A 2+ (B –) 2
42. If the ionic radii of K and F are nearly the same (i.e. 1.34 Å) then the atomic radii of K and F respectively
are :–
(A) 1.34 Å, 1.34 Å (B) 0.72 Å, 1.96 Å (C) 1.96 Å, 0.72 Å (D) 1.96 Å, 1.34 Å
43. The electronegativites of the following elements H, O, F, S and Cl increase in the order:–
(A) H < O < F < S < Cl (B) S < H < Cl < O < F
(C) H < S < O < Cl < F (D) H < S < Cl < O < F
44. The correct order of size for iodine, species I, I , I + is :
—
(A) I > I — > I + (B) I > I + > I — (C) I + > I — > I (D) I — > I > I +
36
E
SELECT THE CORRECT ALTERNATIVES (ONE OR MORE THEN ONE CORRECT ANSWERS)
1. If the difference in atomic size of :
Na – Li = x Rb – K = y Fr – Cs = z
Then correct order will be:-
(A) x = y = z (B) x > y > z (C) x < y < z (D) x < y << z
2. 3- 2- –
In the ions P , S and Cl the increasing order of size is:-
(A) Cl– , S2- , P3- (B) P3- , S2- ,Cl– (C) S2-, Cl– , P3- (D) S2-, P3—, Cl–
3. Which of the following order of atomic/ionic radius is not correct :–
(A) I– > I > I+ (B) Mg+2 > Na+ > F– (C) P+5 < P+3 (D) Li > Be > B
4. Ionic radii of :-
(A) Ti4+ < Mn7+ (B) 37Cl– < 35Cl– (C) K+ > Cl– (D) P3+ > P5+
5. The best reason to account for the general tendency of atomic diameters to decrease as the atomic numbers
increase within a period of the periodic table is the fact that
(A) Outer electrons repel inner electrons
(B) Closer packing among the nuclear particles is achieved
(C) The number of neutrons increases
(D) The increasing nuclear charge exerts a greater attractive force on the electrons
6. Correct orders of Ist Ionisation Potential are :-
(a) Li < B < Be < C (b) O < N < F (c) Be < N < Ne
(A) a, b (B) b, c (C) a, c (D) a, b, c
7. The second ionisation potentials in electron volts of oxygen and fluorine atoms are respectively given by
:-
(A) 35.1, 38.3 (B) 38.3, 38.3 (C) 38.3, 35.1 (D) 35.1, 35.1
8. In which of the following pairs, the ionisation energy of the first species is less than that of the second :-
(A) O-, O2- (B) S, P (C) N, P (D) Be+, Be
9. The correct order of stability of Al+, Al+2, Al+3 is :-
(A) Al+3 > Al+2 > Al+ (B) Al+2 > Al+3 > Al+ (C) Al+2 < Al+ > Al+3 (D) Al+3 > Al+ > Al+2
10. Mg forms Mg(II) because of :-
(A) The oxidation state of Mg is + 2
(B) Difference between I.P1 and I.P2 is greater than 16.0 eV
(C) There are only two electrons in the outermost energy level of Mg E:\Data\2014\Kota\JEE-Advanced\SMP\Che\Unit-02\Part (I)\Eng\01-Periodic Table\Exercise.p65
(D) Difference between I.P1 and I.P2 is less than 11 eV
11. IP1 and IP2 of Mg are 178 and 348 K. cal mol-1. The enthalpy required for the reaction
Mg Mg2+ + 2e– is :-
(A) + 170 K.cal (B) + 526 K.cal (C) - 170 K.cal (D) - 526 K.cal
12. Which of the following decreases in going down the halogen group :-
(A) Ionic radius (B) Atomic radius (C) Ionisation potential (D) Boiling point
13. Sucessive ionisation energies of an element 'X' are given below (in K. Cal)
IP1 IP2 IP3 IP4
165 195 556 595
Electronic configuration of the element 'X' is:-
(A) 1s 2 , 2s 22p 6 , 3s 2 3p 2 (B) 1s2 , 2s 1
(C) 1s 2 , 2s 22p 2 (D) 1s 2 , 2s 22p 6 , 3s 2
14. The energy needed to remove one electron from unipositive ion is abbreviated as :-
(A) Ist I.P. (B) 3 rd I.P. (C) 2 nd I.P. (D) 1 st E.A.
38
E
E 39
40
E
3 4 5 6 7 8 9 1 01 1
Z
51. M(g) M+ (g) + e–, H = 100 eV, M(g) M2+(g) + 2e–, H = 250 eV which is/are incorrect statement(s) :-
(A) IP 1 of M(g) is 100 eV (B) IP 1 of M+ (g) is 150 eV
(C) IP 2 of M(g) is 250 eV (D) IP 2 of M(g) is 150 eV
52. AB is predominantly ionic as A + B – if :-
(A) (IP)A < (IP)B (B) (EA) A < (EA) B (C) (EN) A < (EN) B (D) Size of A < size of B
53. Which is correct order of size of O, O 2–, F – and F :-
(A) O 2– > O > F – > F (B) O > O 2– > F > F –
(C) O 2– > F – > F > O (D) O 2– > F – > O > F
54. Both metals and non-metals are found among......elements in the periodic table :-
(A) p-block (B) d-block (C) Transition (D) Inner transition
E 41
66. The correct order of ionization energies of F—, Cl—, F and Cl is:
(A) Cl < F < Cl— < F— (B) Cl— < F— < Cl < F
(C) F— < Cl— < Cl < F (D) Cl— < Cl < F— < F
67. Atomic radii of alkali metals (M) follow the order Li < Na < K < Rb but ionic radii in aqueous solution follow
the reverse order Li+ > Na+ > K + > Rb+ . The reason of the reverse order is :
(A) Increase in the ionisation energy (B) Decrease in the metallic bond character
(C) Increase in the electropositive character (D) Decrease in the amount of hydration
68. The first ionization potentials (eV) of Be and B respectively are :
(A) 8.29eV, 9.32 eV (B) 9.32 eV, 9.32 eV
(C) 8.29 eV, 8.29 eV (D) 9.32 eV, 8.29 eV
69. The decreasing order of the ionization potential of the following elements is :
(A) Ne > Cl > P > S > Al > Mg (B) Ne > Cl > P > S > Mg > Al
(C) Ne > Cl > S > P > Mg > Al (D) Ne > Cl > S > P > Al > Mg
42
E
44
E
E 45
Column-I C o lu mn - I I
(A) 19 (p) p-block
(B) 22 (q) f-block
(C) 32 (r) d-block
(D) 64 (s) s-block
2. Match Column–I (Elements) withColumn–II (configuration of elements) and select the correct answer using
the codes given below :
Column-I C o lu mn - I I
(A) The third alkali metal (p) 1s 2s 2p6 3s2 3p5
2 2
(B) The second transition element (q) 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6
(C) The fourth noble gas element (r) 1s2 2s2 2p6 3s2 3p6 3d2 4s2
(D) The second helogen element (s) 1s2 2s2 2p6 3s2 3p6 4s1
46
E
4. Column-I C o lu mn - I I
(A) Metalloid (p) Selenium
(B) Radioactive (q) Silver
(C) Transition (r) Arsenic
(D) Chalcogen (s) Uranium
5. Column-I C o lu mn - I I
(A) Increasing atomic size (p) Cl < O < F
(B) Decreasing atomic radius (q) Li < Be < B
(C) Increasing electronegativity (r) Si < Al < Mg
(D) Increasing effective (s) N > O > F
nuclear charge
because
Statement -2 : Zeff of anion is greater than that of their parent atom.
4. Statement -1 : Atomic radius of inert gases is largest in the period
because
Statement -2 : Effective nuclear charge of inert gases is minimum
5. Statement -1 : 2 nd IP of alkali metals is maximum in the period.
because
Statement -2 : Alkali metals has smallest atomic size in the period.
6. Statement -1 : First ionization energy of nitrogen is lower than oxygen.
because
Statement -2 : Across the period effective nuclear charge decreases.
7. Statement -1 : The third period contains only 8 elements and not 18 like 4th period.
because
Statement -2 : In III period filling starts from 3s1 and complete at 3p 6 whereas in IV period it starts
from 4s 1 and complete after 3d 10 and 4s 2 .
E 47
Tr u e / Fals e
1. T 2. T 3. T 4. T 5. F 6. F 7. T 8. F 9. T
F i ll i n t h e B lank s
1. IA group /1 2. VIIA/17 3. Variable 4. higher, first
5. Si, P, C, N 6. 28 7. (non polar) covalent 8. Mg
9. IA 10. Lithium 11. Higher effective nuclear charge 12. Iner pair effect
Matc h th e C o lu m n
1. (A)-s (B)-r (C)-p (D)-q 2. (A)-s (B)-r (C)-q (d)-p 3. (A)-r (B)-q (C)-p (D)-s
4. (A)-r (B)-s (C)-q (D)-p 5. (A)-r (B)-s (C)-p (D)-q
A s s er ti o n - R eas o n Q u es ti o ns
1. D 2. D 3. C 4. C 5. C 6. D 7. A
C o m p r eh ens i o n B as ed Q u es i o ns
Comprehension #1 : 1. B 2. B,C 3. C 4.A 5.B 6.A
Comprehension #2 : 1. B 2. A
48
E
J
B F I
K H L G
E
E:\Data\2014\Kota\JEE-Advanced\SMP\Che\Unit-02\Part (I)\Eng\01-Periodic Table\Exercise.p65
A
D
E 49
Q
H L R
J T
Answer the following on the basis of modern periodic table
(I) Element havinhg greatest ionic character in its compound with non-metals
(II) Metal cation which is coloured in its aqueous solution
(III) Element (s) of which carbonate salt is/are water soluble
(IV) Which element is monoatomic gas at room temperature
9. Electronegativity of F on Pauling scale is 4.0. Calculate its value on Mulliken scale :
10. Calculate the electronegativity of fluorine from the following data :
E H–H = 104.2 kcal mol –1 ;
E F–F = 36.6 kcal mol –1 ;
E H–F = 134.6 kcal mol –1 ;
Electronegativity of hydrogen = 2.1
11. Ionisation potential and electron affinity of fluorine are 17.42 and 3.45 eV respectively. Calculate the
electronegativity of fluorine on Mulliken scale and Pauling scale :
12. Addition of an electron to Na(g) is slightly exothermic process, whereas addition of electron to Mg(g) is strongly
endothermic. Explain.
1. No. because there no provision for filling of g-block element in periodic table.
E:\Data\2014\Kota\JEE-Advanced\SMP\Che\Unit-02\Part (I)\Eng\01-Periodic Table\Exercise.p65
3. 14th group, carbon family
4. (i) Most reactive metal will be an alkali metal of 1st group with its IE2 > > IE1. Thus most reactive metal is (a).
(ii) Most reactive non-metal will be a halogen of 17th group. Its IE1 will be quite high. Thus most reactive non
metal is (b).
(iii) A noble gas will have very, very high IE1. Thus (c) is a noble gas.
(iv) A metal that forms a stable binary halide will be an alkaline earth metal of 2nd group. Its IE2 will not be much
higher than IE1. Thus (d) is such a metal that forms a stable binary halide of formula AX2.
5. (a) C (b) Si (c) Al (d) Al
6. Na, becuase during IP2 electron is removed from stable octet configuration (ns np6). 2
7. (i) B, (ii) H, (iii) A, (iv) B, C, F, J, I, (v) A, (vi) I (vii) B, J (viii) E, H, K (ix) G (x) L
8. (i) H, (ii) J2+, (iii) H (iv) T
9. 11.2 10. 3.87 11. 10.435, 3.726
50
E
electronegativity.
12. (a) If internuclear distance between Cl atoms in Cl2 is 10 Å & between H atoms in H2 is 2 Å, then calculate
internuclear distance between H & Cl (Electronegativity of H = 2.1 & Cl = 3.0)
(b) Compare the following giving reasons
Acidic nature of oxides : CaO, CO, CO2, N2O 5, SO 3
13. With the help of EN values [ENA = 1.8, ENB = 2.6, ENC = 1.6, END = 2.8] answer the following questions
for the compounds
HAO, HBO, HCO, HDO
(a) Compounds whose aqueous solution is acidic and order of their acidic strength
(b) Compounds whose aqueous solution is basic and order of their basic strength
(c) Comment on the chances of being coloured on the basis of percent ionic character for the compounds
CD & AB.
E 51
1. Mn+7 < V+5 < Ca+2 < K+ < Cl– < S2– < P3–
2. Ionic radius of Se2– is expected to be in between the ionic radii of S2– and Te2–. Thus
1.84 2.21
Ionic radius of Se2– = = 2.025 A0
2
52
E
4. The atomic numbers of vanadium, (V), chromium (Cr), manganese (Mn) and iron (Fe) are respectively 23,
24, 25 and 26. Which one of these may be expected to have the highest second ionization enthalpy ?
(1) Cr (2) Mn (3) Fe (4) V [AIEEE-2003]
5. Which one of the following sets of ions represents the collection of isoelectronic species ?
[AIEEE-2004]
+ – 2+ 3+ + 2+ 3+ – + 2+ 3+ –
(1) K , Cl , Mg , Sc (2) Na , Ca , Sc , F (3) K , Ca , Sc , Cl (4) Na , Mg 2+ , Al 3+ , Cl –
+
6. Which of the following ions has the highest value of ionic radius ? [AIEEE-2004]
2– 3+ + –
(1) O (2) B (3) Li (4) F
7. Among Al 2O 3, SiO 2, P 2O 3 and SO 2, the correct order of acid strength is :- [AIEEE-2004]
(1) Al 2O 3 < SiO 2 < SO 2 < P 2 O 3 (2) SiO 2 < SO 2 < Al 2 O 3 < P 2 O 3
(3) SO 2 < P 2 O 3 < SiO 2 < Al 2 O 3 (4) Al 2O 3 < SiO 2 < P 2 O 3 < SO 2
2–
8. The formation of the oxide ion O (g) requires first an exothermic and then an endothermic step as shown
below :- [AIEEE-2004]
O(g) + e – = O –(g), H° = – 142 kJ mol –1
O –(g) + e – = O 2– (g), H° = 844 kJ mol –1
This is because :-
(1) O – ion will tend to resist the addition of another electron
(2) Oxygen has high electron affinity
(3) Oxygen is more electronegative
E:\Data\2014\Kota\JEE-Advanced\SMP\Che\Unit-02\Part (I)\Eng\01-Periodic Table\Exercise.p65
E 53
20. The outer electron configuration of Gd (Atomic No. : 64) is :- [AIEEE- 2011]
4 4 2 7 1 2 3 5 2 8 0 2
(1) 4f 5d 6s (2) 4f 5d 6s (3) 4f 5d 6s (4) 4f 5d 6s
21. The correct order of electron gain enthalpy with negative sign of F, Cl, Br and I, having atomic number 9, 17,
35 and 53 respectively, is :- [AIEEE- 2011]
(1) I > Br > Cl > F (2) F > Cl > Br > I (3) Cl > F > Br > I (4) Br > Cl > I > F
22. The increasing order of the ionic radii of the given isoelectronic species is :- [AIEEE- 2012]
+ 2– 2+ – – 2+ + 2– 2– – 2+ +
(1) K , S , Ca , Cl (2) Cl , Ca , K , S (3) S , Cl , Ca , K (4) Ca 2+ , K +, Cl –, S 2–
54
E
1. Moving from right to left in a periodic table, the atomic size is: [JEE 1995]
(A) increased (B) decreased (C) remains constant (D) none of these
2. The increasing order of electronegativity in the following elements: [JEE 1995]
(A) C, N, Si, P (B) N, Si, C, P (C) Si, P, C, N (D) P, Si, N, C
3. One element has atomic weight 39. Its electronic configuration is 1s2, 2s2 2p6, 3s2 3p6 4s1. The true statement
for that element is: [JEE 1995]
(A) High value of IE (B) Transition element
(C) Isotone with 18Ar38 (D) None
4. The number of paired electrons in oxygen atom is: [JEE 1995]
(A) 6 (B) 16 (C) 8 (D) 32
5. The decreasing size of K+, Ca2+, Cl– & S2– follows the order: [REE 1995]
(A) K+ > Ca +2 > S–2 > Cl– (B) K+ > Ca +2 > Cl– > S–2
(C) Ca +2 >K+ > Cl– > S–2 (D) S–2 > Cl– > K+ > Ca+2
6. Which of the following has the maximum number of unpaired electrons [JEE 1996]
(A) Mg2+ (B) Ti3+ (C) V 3+ (D) Fe 2+
7. The incorrect statement among the following is: [JEE 1997]
(A) the first ionisation potential of Al is less then the first ionisation potential of Mg
(B) the second ionisation potential of Mg is greater then the second ionisation potential of Na
(C) the first ionisation potential of Na is less then the first ionisation potential of Mg
(D) the third ionisation potential of Mg is greater then the third ionisation potential of Al
8. Li+, Mg2+, K+,Al3+ (Arrange in increasing order of radii) [JEE 1997]
9. Which one of the following statement (s) is (are) correct? [JEE 1998]
(A) The electronic configuration of Cr is [Ar] 3d5 4s1.(Atomic No. of Cr = 24)
(B) The magnetic quantum number may have a negative value
E:\Data\2014\Kota\JEE-Advanced\SMP\Che\Unit-02\Part (I)\Eng\01-Periodic Table\Exercise.p65
(C) In silver atom, 23 electrons have a spin of one type and 24 of the opposite type. ( Atomic No. of Ag = 47)
(D) The oxidation state of nitrogen in HN3 is –3.
10. The electrons, identified by n & l ; [JEE 1999]
(i) n = 4 , l = 1 (ii) n = 4 , l = 0 (iii) n = 3 , l = 2
(iv) n = 3 , l = 1 can be placed in order of increasing energy, from the lowest to highest as :
(A) (iv) < (ii) < (iii) < (i) (B) (iii) < (ii) < (iv) < (i)
(C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
11. Gaseous state electronic configuration of nitrogen atom can be represented as : [JEE 1999]
(A) (B) (C) (D)
12. The electronic configuration of an element is 1s2 2s2 2p6 3s2 3p6 3d5 4s1. This represents its :
(A) excited state (B) ground state (C) cationic form (D) none [JEE 2000]
E 55
15. The IE1 of Be is greater than that of B. [T/F] [JEE 2001]
16. The set representing correct order of IP1 is [JEE 2001]
(A) K > Na > Li (B) Be > Mg > Ca (C) B > C > N (D) Fe > Si > C
17. Identify the least stable ion amongst the following: [JEE 2002]
– – – –
(A) Li (B) Be (C) B (D) C
18. The maximum number of electrons that can have principal quantum number n=3, and spin quantum number,
m s = – 1/2, is [JEE 2011]
1. A 2. C 3. C 4. A 5. D
6. D 7. B
17. B 18. 9
56
E
------------------------------------------------------------------------------------------------------------------------------------------------
Thank you for your love and support, we hope you are always being happy and get success in your life, we
are happy to see you again.