Cocamide Dea Msds

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Safety Data Sheet

(Cocamide DEA)
DATE PREPARED: 5/3/2016

Section 1. Product and Company Identification

Product Name Cocamide DEA


CAS Number 68603-42-9

Parchem - fine & specialty chemicals EMERGENCY RESPONSE NUMBER


415 Huguenot Street CHEMTEL
New Rochelle, NY 10801 Toll Free US & Canada: 1 (800) 255-3924
(914) 654-6800 (914) 654-6899 All other Origins: 1 (813) 248-0585
parchem.com [email protected] Collect Calls Accepted

Section 2. Hazards Identification

Classification of the substance or mixture


GHS Classification
Skin Irritation: Category 2
Eye Irritation: Category 2A
Carcinogenicity: Category 2

GHS Label Elements


Pictograms:

Signal word: WARNING

Hazard and precautionary statements


Hazard Statements
H315: Causes skin irritation
H319: Causes serious eye irritation
H351: Suspected of causing cancer

Precautionary Statements
Prevention
P201: Obtain special instructions before use
P202: Do not handle until all safety precautions have been read and understood
P260: Do not breathe dust/fume/gas/mist/vapors/spray
P264: Wash thoroughly after handling
P280: Wear eye protection/ face protection/ protective gloves
Response
P302+P352: IF ON SKIN: Wash with plenty of soap and water

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Safety Data Sheet
(Cocamide DEA)
DATE PREPARED: 5/3/2016

P305+P351+P338: IF IN EYES: Rinse cautiously with water for 20 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313: If exposed or concerned: Get medical advice/attention
P332+P313: If skin irritation occurs: Get medical advice/attention
P337+P313: If eye irritation persists: Get medical advice/attention
P362: Take off contaminated clothing and wash before reuse
Storage
P405: Store locked up
Disposal
P501: Dispose of content/container in accordance with local regulation

WHMIS Class
Carcinogen: D2A
Eye Irritant: D2B

Section 3. Composition / Information on Ingredients

Common Name Cocamide DEA


CAS Number 68603-42-9

COMPONENT CAS NUMBER CONCENTRATION


Cocamide DEA 68603-42-9 85 – 90%
Glycerin 56-81-5 ~ 8%
Diethanolamine 111-42-2 1 – 5%

Section 4. First Aid Measures

General Advice: No hazards which require special first aid measures.


Inhalation: If respiratory irritation develops, remove to fresh air. If difficulty breathing, give oxygen
and get medical attention. If not breathing, apply artificial respiration and get medical attention.
Skin Contact: Flush with plenty of water. Obtain medical attention if irritation develops. Remove
contaminated clothing and wash separately before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids open
to ensure adequate flushing. Remove contact lenses if present and easy to do. Continue flushing. Get
medical attention.
Ingestion: Do NOT induce vomiting. Do not give anything to an unconscious person. If conscious
wash mouth out and give 1 - 2 glasses of water to drink. Get medical attention. Vomiting may occur
spontaneously - lay victim on side to avoid aspiration of swallowed product.

Section 5. Firefighting Measures

Flash Point: > 93.3°C (> 199°F)


Flammable Limits: Not established.
Auto-ignition Temperature: Not established.
Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide.

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Safety Data Sheet
(Cocamide DEA)
DATE PREPARED: 5/3/2016

Special Procedures: Do not use a solid water stream as it may scatter and spread fire. Do not
allow run-off from firefighting to enter drains or water courses. Use water spray to cool unopened
containers.
Special Equipment: Firefighters should use self-contained breathing apparatus to avoid exposure
to smoke and vapor.
Hazards from Chemical: During combustion, oxides of carbon and oxides of nitrogen may be
produced.

Section 6. Accidental Release Measures

Personal Precautions: Wear personal protective equipment as defined in Section 8. Ventilate


enclosed spaces and monitor oxygen levels.
Environmental Precautions: Prevent product from entering drains and water courses. Prevent
release to the environment.
Spill Clean-Up: Dike and contain spills to prevent further leakage. Absorb with inert materials.
Shovel into recovery drums for disposal. Dispose of product in accordance with local, state, federal
and international regulations.

Section 7. Handling and Storage

Handling: Wear personal protective equipment as defined in Section 8. Avoid contact with skin,
eyes and clothing. Handle in accordance with good industrial hygiene and safety practices.
Storage: Store in a cool, dry, well-ventilated place in original closed containers away from heat,
open flame and out of direct sunlight.

Section 8. Exposure Controls / Personal Protection

Exposure Limits
Ingredients CAS No. Form of Permissible Basis
Exposure Concentration
Diethanolamine 111-42-2 TLV-TWA 1mg/m3 ACGIH
Glycerin 56-81-5 PEL-TWA 10 mg/m 3
OSHA
Cocamide DEA 68603-42-9 No Data Found N/A N/A

Engineering Controls: Use general ventilation. Local exhaust suggested for enclosed spaces.
Respiratory Protection: The use of a NIOSH approved respiratory protection device may be
needed if working in a poorly ventilated area.
Protective Gloves: Chemical resistant gloves.
Eye Protection: Chemical goggles or safety glasses.
Body Protection: Impervious clothing
Work/Hygienic Practices: Avoid contact with eyes, skin and clothing. Wash thoroughly after
handling.
Other Equipment: Eyewash station and safety shower in work area.

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Safety Data Sheet
(Cocamide DEA)
DATE PREPARED: 5/3/2016

Section 9. Physical and Chemical Properties

Physical State: Liquid


Specific Gravity: 1.004
Color: Light Yellow
Evaporation Rate: Not Available
Odor: Characteristic
Vapor Pressure: Not Available
pH (1% Aqueous Solution): ~ 10
Vapor Density: Not Available
Melting Point: Not Available
Solubility in Water: Dispersible
Boiling Point: ~ 150°C %
Volatile (by weight): Negligible
Flash Point: > 100°C
Auto Ignition Temp.: Not Available
Flammability: Not flammable, but will burn
Decomposition Temp.: Not Available
Explosive Limits: Not Available
Relative Density: Not Available

Section 10. Stability and Reactivity

Stability: Stable under normal conditions.


Incompatibility: Strong oxidizing agents and reducing agents
Conditions to Avoid: Heat, open flame, sparks, sources of ignition, direct sunlight
Hazardous Decomposition: Combustion products: carbon oxides, nitrogen oxides
Hazardous Polymerization: Will not occur.

Section 11. Toxicological Information

Acute Toxicity
Component Test Test Type Species Results
Cocamide DEA Oral LD50 Rat 12,200 mg/kg
Cocamide DEA Dermal LD50 Rabbit > 2 g/kg
Diethanolamine Oral LD50 Rat 1600 mg/kg
Diethanolamine Dermal LD50 Rabbit > 8200 mg/kg
Glycerin Oral LD50 Rat 12,600 mg/kg
Glycerin Dermal LD50 Rabbit > 10 g/kg
Skin Irritation: Moderately irritating
Eye Irritation: Moderately irritating

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Safety Data Sheet
(Cocamide DEA)
DATE PREPARED: 5/3/2016

Chronic Data
Carcinogenicity: This product contains Cocamide DEA (68603-42-9) an IARC Group 2B
Carcinogen.
This product contains Diethanolamine (111-42-2) an IARC Group 2B Carcinogen.
Mutagenicity: No evidence found of mutagenicity.
Reproductive Effects: No evidence found of reproductive toxicity.
Sensitization: No evidence found of respiratory or skin sensitization.

Section 12. Ecological Information

Ecotoxicity
Test Type Species Results Time Comments
LC50 Brachydanio rerio (zebra 6.7 mg/l 96h Static-renewal
fish)
EC50 Daphnia magna (water flea) 3.3 mg/l 24 h Loss of ability to swim

Biodegradability: This product is readily biodegradable.

Section 13. Disposal Considerations

Waste Treatment Methods: Dispose of product and contaminated packaging in accordance


with all local, state, and federal environmental control regulations.

Section 14. Transport Information

Department of Transportation: Regulated only when the RQ is met or exceeded


Proper Shipping Name: Environmentally Hazardous Substance, Liquid N.O.S. (Contains
Diethanolamine)
Hazard Class: 9
UN Number: UN3082
UN Packaging Group: PG III
Diethanolamine: 100 lb RQ; 45.4 kg RQ

TDG: Not regulated


ICAO/IATA: Not restricted
IMDG: Not regulated

Section 15. Regulatory Information

SARA 311/312 Hazards: Acute Health Hazard; Chronic Health Hazard


SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
SARA 313: The following components are subject to the reporting levels established by
SARA Title III, Section 313: Diethanolamine (CAS# 111-42-2): 1 - 5%

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Safety Data Sheet
(Cocamide DEA)
DATE PREPARED: 5/3/2016

US State Regulations
Pennsylvania Right To Know, New Jersey Right To Know:
Cocamide DEA 68603-42-9 85 - 90%
Glycerin 56-81-5 ~ 8%
Diethanolamine 111-42-2 1 - 5%

California Proposition 65: Warning: This product contains a chemical known to the State of
California to cause cancer:
Cocamide DEA 68603-42-9
Diethanolamine 111-42-2

Chemical Inventories
USA (TSCA): Listed
Europe (REACH): Listed
Australia (AICS): Listed
Philippines (PICCS): Listed
Canada (DSL): Listed
Korea (ECL): Listed
Japan (ENCS): Listed
China (IECSC): Listed
New Zealand (NZIoC): Listed

HMIS Rating
Health: 2
Flammability: 1
Reactivity: 0
Personal Protection: C

Section 16. Other Information

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. The information in this document is based on the present state of
our knowledge and is applicable to the product with regard to appropriate safety precautions. It
does not represent any guarantee of the properties of the product.

REVISION DATE: 5/3/2016

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