11.

Alcohols,
Phenols
ImportantFormulae and Ethers
and Shortcut
Methods
Alcohols: cohols are organic compounds
a saturated carbon atom. whose molecules
attacheed to

n
contain hydroxyl
***
group (-OH)

o
OH
enols: These
are aromatic hydroxyl
compounds is
s
attached to the benzene ring. in which hydroxyl
oxyl group (-OH)
example, is directly

e
For
OH

t s
Ethers
Phenol

are organic compounds having

u b
o
Fthers
C 0 -
C- linkage where two alkyl or

D
pwoaryl or one alkyl and one aryl groups are linked through
oxygen.

Preparation of alcohols
1. Hydroboration Oxidation

-c-6-BH,), 2(-c-tps
ofalkenes
1
2 006- NaOH6-f-f-OH 2B(OH),
Alkene

2 0
reduction of aldehydes and ketones
Trialkyl borane Primary alcohol

T
2. By
secondary alcohol
alcohol while ketone gives
On reduction, aldehyde gives primary

R- CHO

CE OLAR,
R-CH, -OH
P'alcobol

H T
R--R-
HNi or Pd

LiAIE
RCH-OH
R
20 alcohol my channe

M By reduction of carboxylic acids

R-C-OH- iii.LiAlHR-CH,OH
-

H,O alcohol
Primary
Carboxylic acid
(274)MHT-CET Exam Questions
reagent. Therefore, commercially acids are
ar rsttransformed
LiAIH, is as an expensive alcohols.
hydrogenation give primary C
esters which on catalytic

R-COOH+R'OH R-COOR'+ H,0

-OH+ R'-OHI
R-COOR+2H2 Ni/PdR-CH,

4. From Grignard reagents

o n
H
-
H-C-0MgDiy ether H--0-Mg XH.0R-CH,OH+
H

HO-Mg-x is
s
HC pri-alcohol
9 ser
R-C=0R-Mg-NR-C-0-Mg
H
-X
H0R-C-OH+HO
H

s
-Mg-x e
t
Dry ether
aldehyde R

b
sec-alcohol

u
R R R
R-C=0R-Mg-X R--0-Mg -X
R-C-OH+ HO-Mg-X
o
Dry
ketone ether
R R
tert-alcohol

D
9aizeba 91 20
Preparation of Phenols

2 1 oieale20lea

0
nlorobenzene
(Dow's
ONa ei OH
oilsiodoakt

2
process
NeOH, 150
73-623
m
K HC
Sodium pbenonsde

T
Phenol

E
SOH SOJNa
con.H,904

C Bensene
NaOH
Sodlum benzene

T
ulplhonle acdd
sulpbonate
H,C CH, H,C CH

H 523 K
Propene calalyst
Co Bapbthenate
0-0-H4

M
423K

Camene Cubene
hydrujperoxdde
NH2
OH
NaNO,+HC1
HO J+Na1+HCI
de
Msoulom chloride
Fbenol
 Chemical properties of Alcoh and Phenols: Alcohols,Phenols
tests & Ethers (275)2
edinto Laborato of alcohols and phenols
Characteristic A
Char acts test for phenols:
Phenol with neutral ferric
chloride solution
colouration of ferric phenoxide

n
to give deep (purple/violet/
3Ar-OH+FeCl (Ar-O)y-Fe+3HCI green)

o
(Neutral) (Deep Colour)

Distinguishing test for alcohols

Primary, secondary and teruary
(Lucas test)
is
s
aratory using Lucas alcohols can be distinguished
reagent (conc. HCl from each other in the
and ZnCl,). The

e
reaction involved is
R-OH R-CI
ZnCl2

s
Alcohols are soluble in Lucas
reagent but
elear solution becomes turbid when productthe product alkyl chloride is not. Hence, the

t
starts forming. Tertiary alcohol
and the reagent turms turbid instantaneously. Secondary
alcohols
reacts fast
slowly.Primary alcohols turn the reagent turbid only on turn the reagent turbid

b
heating.
.
u
Reactions due to breaking of 0-H bond
Esterification

o
Fsterification of alcohol or phenol is carried out in the presence of concentrated sulphuric

D
acid. The reaction is reversible and can be shifted in the forward direction by removing
water as soon as it is formed.

1
gsno3 2b1D0-91yodhao to
R-OH
+ HO--R ROdR+H.O

2
(olcohol) (acid) ester)
muoge mod
lo 2sqt aiaruy io Qcis
Ar:-OH+HO--RAr0-R'+H,o
0
bavsie 1e Bprito

2
phenol) (acid) (cster)
fom ester.
anhydrides in presence of acid catalyst
to
Alcohols and phenols react with acid

E T
R-OH+R--0-R ROR+R-COOH
(cster) (acid)oe

C
(adcohol) (auhydride)

ArOH-R0-RA-OdR»R:cOOH

T
(ocid)
(ester) presence of
phenol) (anlydride) in the
chloride is carried out

H alcohol and phenols with acid

Reaction of HCL
Pyrdine (base), which neutralizes

M R-OH+C-R
(aloobol) (acid chloride)
Rt-OR +HCI
(ester)

Ar:-OH+ CHC-R oridinR-0-Ar+ HCI

(cster)
phenol) (aoid chloride)
 Questions
(276) MHT-CET Exam alcohols
bond in
II.Reactionsdue to breaking C-O
of

hydrogen halides
alcohol < 2° alcohol < 3° alcohol

n
i. Reaction with HBr < HI and 1°
The reactivity is HCl<

o
R-OH+HX R-X+H,0 quired
required
anhydrous ZnCh. No catalyst is

is
in the case
HCl reacts only in presence of ot
HBr and H.

ii. Oxidation of alcohols

R-CH- R' R--R'
e s
ots10oal
s
OH
Ketone

t
(2° alcohol)
3.
R-CHO

b
2. R-CH, -OH no
(1 alcohol)
() (Aldehyde) bu ened uiesr1
3. In presence of common oxidizing agentaloieals

R-CH, -OHKMOGC,NO[R-CHO]
o u woa
R-COHtotaal

D
(O)

1 alcohol) Aldehyde Carboxylic he

Acid oidre

1
Tertiary alcohols are difficult to oxidise. On oxidation with strong oxidising agents a
high temperature tertiary alcohol undergoes breaking of C-C bonds and gives

3° alcohol.
4. Heating with Cu

0 2
mixture of carboxylic acids containing less number of carbon atoms than the starting

2
When vapours of various types of alcohols are passed over hot copper the followng
reactions are observed.
R-CH-OH R-CHO

E T
(1alcohol)

R-CH-RCus75K
R-CR
(aldehyde)
3ps7 alonaig-au 2loiool
5.

C
OH
(2 alcohol) (ketone)
co

T
HC-(OH)-CH,
CH dution HC-C= CH,
CH,

H
(3 alcohol)
(alkene)
6.
IV.Reactions of Phenol:

M OH

+3Br H
OH
Br
+3HBr
oeaid abte

Br
2,4,6-tribromo
phenol
 OH Alcohols,
Phenols &
H OH
Ethers(277)D
2B Br
in the case
of o-bromophenol
+2HBr

o n
p-bromophenol
is
OH
OH

e s
s
+H,SO, conc. 293 ,SO,H
3 K
OJ
t
+HO
QH

b
QH

O) +H,SO,conc. 373 K

u
i1) +H,O

ng agents at
and gives a
OH

D o OH
SoH

No
OH

1
the starting
+2HNO, dil
+ 2H,0

e following

0 2 NO

2
OH QH
oN NO,
+3HNO, conc. HSO4 conc.

T
snli +3 H,0

CE A5
acal
NO

picric acid
g aort os abiienn

T
0.
Reimer -
Tiemann reaction :

H
OH ONa CHO
CHO
CHC, NoOH H
CHC

M
(Salioyaldebyde)

(Phenol) Intermediate
 (278)MHT-CET Exam Questions Re
2.
7. Kolbe reaction :

i.
ONa OH OH
COONa COOH
co, CO, HO

n
(Sodhm (Sodium (Salicylic acid)
salioylote)
Phenoxide)

8. Oxidation

OH
of Phenol
O iso ii.

(Phenol) (p-Benzoquinone)

e s iii.

s
9. Catalytic Hydrogenation of Phenol
OH QH

(Phenol)
+3H,33
(Cyolobexanol)

b t
10. Reduction
OH
of Phenol

o u
D
+Zn +ZnO
(Phenol) (Benzenc)

Preparation
1.
of Ethers

Dehydration of Alcohols
2 1 3. El

2R-OH
Alcohol
2. Williamson Synthesis
concHS
413K R-0-R +HO
Ether

2 0 ou0HE

T
R-X+ Na-0-R R-0-R + Na -X

E
R-X +Na -0-Ar
(1 alkyl halide) R-0- Ar +Na -X

C
(Note: Aryl halides do not give
Williamson's synthesis.)
Chemical Properties of Ethers:

T
ott ansmu/t19rmts
1. Reaction involving
alkyl
Formation of Peroxide group of ether

H
Ethers combine
with atmospheric
oxygen to form peroxide.
CH,CH0CH,+0,L 0-OH

M
CH CH-O-CH,
(diethyl ethe)
da atr
(oxygen) peroxide of
diethyl ethe)
All ethers
which have been veg
undesirable exposed to the
reaction. Peroxides atmosphere peroxide. This is
temperature. are hazardous contain peroiolently hig
because they
decompos at
 action olving C-0 bond Alcohols,Phenols &
Ethers (279)
Reaction with hot dil.H,SO,
i. (Hydroly

n
R-0-R+H-0-H 2R-OH
R-0-R'+H-0-H
Ar-0-R+H-0-H-
R-OH+R'-OH
Ar-OH +R-OH
is o
i. Reaction with
R-0-R'+PCls
PCl
R-Cl+R'-Cl+POC
e s
Reaction with hot concentrated
a. R-0-R + HX R-X+R-OH
acide ve

t s
b
ee umdes
R-OH+HX R-X+H,0

u
b. In alkyl aryl ethers.

o
CH OH

D
|+ HI 398K +CHI
(Anisole) (Phenol) (Methyl iodido)-H o smen
3.

2 1
Electrophilic substitution in aromatic ethers

OCH OCH

0
Br
Br
Acctis ecid

2 Br
OCH

T
jonehrd
CHCUCS

E OCH3
Anhyd. A1Clh lA)

C
Ug CH
OCHs OCH

T
Anisole
CH,COC
Anhyd. A1Cl

H
cOCH
OCHs
OCH TRUs T3H

M
NO
conc. HNO
cooc. HSO4
ve
This is hgo
peroxide.
violently at ew NO2od (87
pose
 (280) MHT-CET Exam Questions
MHT-C
Multiple Choice Questions
Whi
h0e b
lo 11.
MHT-CET 2004
1. Tertiary alcohols (3°) having at least four
i.
carbon atoms upon drastic oxidation yieldcarbensyie 12. The
acid with (A)

n
(B) two carbon atoms less MHT-C
(A)one carbon atom less
(C) three carbon atoms less (D)all of these

o
Wha

is
13.
MHT-CET 2005 carb
2. 2,4,6-trinitrophenol is (A)
(C)chloropicrin (D) all of these

s
(B)picric acid
(A)tear gas 14. Whi
(A)

e
3. Which of the following compound is optically active?
(A)1-Butanol (B) Isopropyl alcohol (C) Acetaldehyde (D)2-Butanol

s
MHT-
MHT-CET 2007 -0 Nan

t
15.
4. Phenols are more acidic than alcohols because (A)

b
(A)phenoxide ion is stabilised by resonance (C)
(B) phenols are more soluble in polar solvents
16. Whi

u
(C)phenoxide ion do not exhibit resonance
(A)
D)alcohols do not lose H atoms at all

MHT-CET 2008
5. The IUPAC name of H,C-CH-C,H, is on
D o MHT-CI
*17. Wh
(Gi

1
OC,H (A)
(A)4-Propoxy pentane (B) Pentyl propyl ether suf 18. tert

2
(C)2-Propoxy pentane (D)2-Pentoxy propane (A)

0
MHT-CET 2009 (C)

2
6. Which alcohol of molecular formula CaHoOH 19. Wh
cannot be obtained by the reduction of carbony
compound? (A)
(A)2-Methylpropan-1-ol
B)2-Methylpropan-2-ol

T
(C)Butanol MHT-
(D)Butan-2-ol

E
7. Which of the following compounds 20. Wh
is optically active?
(A)Butanal
A (A)

C
(C)Butan-2-ol (B) Butanol
(D)2-Methylpropan-2-ol
MHT-CET 2010
C)

HT
8. The corect order of dehydration
(A)1°>2>3°
*9.1 mol alcohol reacts
(A)1g
(B)3°>2°>1
of alcohols is

with Na to give
(C)2°>1°>3
what weight of hydrogen?
(D)1°>3°>2°
21.Phe
reac

M
(B) 2 g
C)3 g
(A)
MHT-CET 2011
(D)3.5 g (C)
10. Phenol gives
characteristic
(A)iodine solution colouration
are MHT-C
with 22.Acti
(C) aqueous
FeCl3 solution (B) bromine water
(D) ammonium (A)I
hydroxide
C
 IHT-CET2012 Alcohols, Phenols
& Ethers (281)
following ssolves
which of the in ionic solvents?
CH (B)CH,OH
(A) (C)cCL
iation

n
yield nature
ature of
of 2,
2, 4,
4, 6-trinitrophenol
is (D)CcH2
carboxyie The
12. (A)neutral (B) basic

o
ic MHT-CET2015
(C) acidic

is
(D)weak basic
the possible inumber of monohydroxy
is he
hat atoms with nethyl group as derivatives
carbon a branch? of a hydrocarbon consisting

s
(B)3 of five
of these (A)2 (C)4
following compounds (D)5

e
14.Which ofthe has highest boiling
(A)Propan-1-ol (B)n-Butane point?
(C)Chloroethane

s
Butanol (D)Propanal
MHT-CET 2016

t
Namet catalyst used in commercial method
I5(A) Silica of preparation of phenol
B) Calcium phosphate

b
C) Anhydrous aluminium chloride
(D) Cobalt naphthenate

u
Which among the following phenolic compounds is
most acidic in nature?
(A) p-aminophenol (B) phenol (C) m-nitrophenol D) p-nitrophenol

o
MHT-CET 2017

is the quantity of hydrogen gas liberated when 46 g sodium reacts with excess ethanol?

D
7 What
(Given At. mass of Na = 23)
(A) 2.4 10 kg x (B) 2.0 x 10 kg (C)4.0x 10 kg (D) 2.4 x 10 kg

1
18. tert-butyl methyl ether on treatment with hydrogen iodide in cold gives
(A) tert-butyl iodide and methyl dide (B) tert-butyl alcohol and methyl alcohol

2
C) tert-butyl alcohol and methyl iodide (D) tert-butyl iodide and methyl alcohol

0
19. Which of the following compounds has lowest boiling point?
alcohol
eduction of carbonyl A)n-butyl alcohol (B) isobutyl alcohol (C) tert-butyl alcohol (D)sec-butyl
MHT-CET

0. Which of
2018

2
the following compounds reacts
immediately with Lucas reagent?

T (A)CH,CH-OH (B) CH;CH;CH;OH

CH,

C
1
E (C) CH-CH-CH3

npresence of
OH
sodium hydroxide reacts
(D) CH,-C-CH
d ÖH
with chloroform to
form salicylaldehyde. The

T Reimer-Tiemann reaction
a
Teaction is known as
3°2 (A)Kolbe's reaction
(B)
(D)Etard reaction

H
C) Stephen reaction
MHT-CET
2019

M
gives methanol
ofhydrogen iodide on anisole
Action
(B)
Iodobenzene and
iodomethane
A)Phenol and iodomehane D)Iodobenzene and
g
Phenol and methanol
 (282)MHT-CET Exam Questions
represented by the molecular formula CaHoO
Identif
23. How many metameric ethers are (D)4 36. Butan
(B) 3 (C)2
(A)5
forms a compound which on heat.
*24. Propene when treated with cold conc. HSO4 ating
with (A)2-

n
gives (C)propan-2-o (D)ethanol
We Methe
(A)propan-1-ol (B) butan-1-ol 37.

o
(A)m
hydrogen peroxide in presen

is
25. Isobutylene on hydroboration followed by oxidation wth ce (C)m
ofb
yields
alcohol (D) isobutyl alcoki
(A)n-butyl alcohol (B) tert-butyl alcohol (C) sec-butyl hol 38. How
26. Carbolic acid is oxidised by acidified sodium dichromate to give
(A) Ethyl methyl ketone (B) Anthraquinone

e s (A) 1
39. Ident

s
(C)Benzoquinone (D) Acetone

27. The conversion of 2- methylpropan-1-ol to 2- methylpropan-2-ol is CH

(A)rearrangement reaction
(C) addition reaction
(B) substitution reaction

b
(D) elimination reaction
28. Anisole when treated with cold and concentrated hydroiodic acid gives
t (A)E
40. Whi
(A)Iodobenzene and methanol
(C)Phenol and methanol D)Phenol
29. Which of the following compounds is dihydric phenol?
o u
(B)lodobenzene and iodomethane
andiodomethanem
oar
(A)
(C)

(A) m-Cresol (B) Pyrogallol

D
(C)Phloroglucinol
30. Which of the following compounds does not have a carboxyl group?
(D) Resorcinol 41. The
(A)
(A) Picric acid (B) Malic acid
31. TUPAC name of Catechol is

2 1
(C) Acrylic acid (D) Glutaric acid C)
42. Whi

0
(A) Benzene-1,3-diol (B)4-Methylphenol (A)
(C)4-Hydroxy benzaldehyde (D) Benzene 1,2-diol

2
43. Wh
32. In a given reaction, 1-Chloro-2-methylpropane KOHp HBr0 CaigONaR. (A)
alco
(C)

T
The compound R is
(A)(CH)2C= CH2 44. Wh

E
B) (CH)C-OC,Hs
C)(CH:)>CH-CH-OCaHs
D(CHs)3C- CH, -coOH A)

C
33. Which of the following alcohols is
(A) Butan-1-ol
least acidic?
(C)
45. Wh

T
(C)3-Methylbutan-1-ol (B) 2-Methylbutan-2-ol
(D) 3-Methylbutan-2-ol (A)

H
34. The IUPAC name
of neopentyl alcohol is C
(A)2-Methylpropan-1ol 46. A r
(C)2,2-Dimethylpropan-1-ol (B) Butan-2-ol

M
kno
(D)2-Methylpropan-2-ol
MHT-CET 2020 (A)
35.When carbolic acid
C)
acid it forms
is heated with concentrated noyleat2(e
ilrated
suphu 47.Wh
nitric acid in presence otC
(A)benzoic acid (A)
(C)benzene sulphonic
acid
(B) phthalic acid Ogoll ao To

48.Wh
C
picric acid oboi bsalt
(A)
1o0?
Identify '2' in the llowing series
16. x_ale of reaction: Alcohols, Phenols
heating Butan-2o & Ethers (283)
Y)Hs0,

n
with hlorobutane i) H-OH/heatZ
ol was (B) Butan-1
(C)Butan-2-o1

o
Methoxy ethane on reaction with
in presence 37 hot concentrated (D)But-2-ene

is
(A)methanol and ethanol HI gives
ofba (C)methanol and iodoethane (B) iodomethane
tyl alcohol (D)iodomethane and iodoethane

s
8. How many hydroxyl groups are present
in hydroxyquinol?
and ethanol
(A)I (B)2

e
(C)3
39, Identify product "C in following reaction (D)4

s
SOcl
CH,OH asONa dil H,504

t
Pyridine B C
A, Pressure
(A)Ethanol (B) Ethanoic acid

b
(C)But-2-ene
(D)Ethyl ethanoate
Which of the following compounds does NOT

u
ne react with sodium metal?
(A)CH-O-CH, (B) CH,OH

o
(C) CH-CH, -OH D) CH-CcoOH
cinol 41. The IUPAC name of

D
M CH-CH2 -0-CH,-CH(CH,), is
(A) 1-Ethoxyisobutane (B)3-Ethoxy-2-methylpropane
(C)1-Ethoxy butane

1
ic acid D)1-Ethoxy-2-methylpropane
42. Which among the following is a dihydric phenol?

2
(A)p-cresol (B)Pyrogallol (C)Catechol D)Phloroglucinol

0
43. What is of 3-chloropropyl ethyl ether?
TUPAC name
(A)3-chloro-1-ethoxypropane (B)1-chloro-3-propoxyethane

2
R. (C)1-chloro-3-ethoxypropane D)3-chloro--1-propoxyethane
catalyzed hydration of alkenes?
44. Which of the following alcohols is NOT prepared by acid

T
(B)2-Methylpropan-2-ol
T30-T14 (A)Ethanol
de-1 (D)Propan-2-ol

E
(C)Propan-1-ol
noide0 5. Which among the following is allylic secondary
alcohol?

C
(B) But-3-en-2-ol
(A)But-2-en-1-ol (D)2-Methylbut-3-en-2-ol
(C)Prop-2-en-1-ol salicyladehyde is

T
sodium hydroxide to form
46. A 1
phenol with chloroform in presence of
dction of Reimer-Tiemann reaction

H
known as
(A) Stephen reaction
diyite (B)
reaction
(D) Kolbe's
C)Friedel craft's reaction product obtained is
temperature, the major

M
Centrated
sulphun
47.When
phenol reacts with dilute nitric
(A) p-nitrophenol
(C)2,4,6-trinitrophenol
48.When
methoxy benzene reacts with HI
acid at room0-nitrophenol
(B) m-nitrophenol
(D) products formed are
temperature the lodobenzene
at room lodomethane and Benzene
(B) lodomethane and
A) Methanol and Iodobenzene (D)
lodomethane and Phenol
 (284) MHT-CET Exam Questions Which
49. Which of the following alcohol is more acidic? 62.
(B) (CH)»CH-OH
Zn
(A)
(A) CH-CH-OH
(D) (CH)»C-OH Which
C) CH,OH 63. A)CH
50. Which of the following is dihydric phenol?
(A) Resorcinol (B) Phloroglucinol
(D) Pyrogallol

o n (C)CH
Which

is
(C) m-Cresol
64. (A)Ca
51. Identify Z in the following sequence of reactions.
Identif
nlco KOHY- conc.H2S04Z

s
CH,-CH, -CH, -OH PChx H-OH/heat 65. (A)2-1
(C) Pr

e
(B) CHÇH-CH,
(A) CH-CH, -CH, -OH

s
OH 66.
Whic
CH2 (A) R
(D) CH -CH

t
=
(C) (CH),CH-CH-OH
67. Identi

b
52. Which among the following is an example of allylic alcohol? (CH
(A) 2-Methylbut-3-en-2-ol (B) 2-Phenylpropane-2-o1
(A) B

u
(C)Propane-1,3-diol (D) Propane-1,2,3-triol
68. Whic

o
53. Which of the following is NOT dihydric phenol?
(A) N
(A) Catechol (B) Hydroquinone (C)Resorcinol (D)a- naphthol (C) 2
54. Which of the following compounds does NOT contain
(A)Ester (B) Amide (C) Ether
D c =o group?
D)Acyl halide
69. Ident

1
Phen
55. Number of oxygen atoms present in salicyladehyde are (A) S

2
(A)3 (B)1 (C)4 gal D)2
70.Whic

0
56. What is IUPAC name of hydroquinone?
(A)Benzene -1, 3, 5-triol (B) Benzene -1,2-diol acetc

2
(C)Benzene -1,4-diol (D) Benzene -1, 2, 4-triol (A)
57. Which of the following benzylic alcohol is tertiary alcohol?

T
(A)2-phenylpropan-2-ol (8)1-phenylpropan-2-ol oagi
(C)Phenyl methanol C)

E
(D)1-phenyl ethanol
58. The number of a bonds in carbolic acid are

C
71. The
(A)8 (B) 13 C)12 (D)6 e
59. Which of the following is reacted with

T
benzaldehyde to obtain 1-phenylethanol?
(A)CHMgBr (B) CH MgBr
C)CHCHMgBr (D)CHCH,MgBr

H
60. Which of the following alcohols is
least soluble in water?
(A)Pentan-1-ol
C)2,2-Dimethylpropan-1-ol (B) 2-methylbutan-2-ol (A)

M
(D) Pentan-2-ol
61. Which of the following (C)
reactions yields propan-2-ol? 72. Whi
(A) H-CHO CHMgBr/ether
Hy0 (B) CH-CH = ) BaH (A)
(C) CH,-CH =CH,Ocold.comc
CH2) H202 73.Whi
H,S04 (A)
(i)H20 (D) CH-co-CH,C B)
C
(D)
 follow
e following reagents
the
of
Whrch(dust) is used
to convert Alcohols, Phenols &
(B) KMnO4(acidified) phenol to Ethers (285)
A)Zn

n
benzene?
(C) Na
obtai
Acfs are obtained
.Which products C>HsOOH when methoxy ethane (D)LiAIH

o
(A)CH;OH and is heated with
(B)CHsl and HI?

is
C)CHsl and CH:OH CH,OH
(D)CHl and
af the following is NOT a dihydric CHsl
64. Catechol (B)Resorcinol phenol?

s
(A) (C)Hydroxyquinol
& Identify the
alcohol that reacts immediately (D)Quinol
with Lucas reagent?

e
(A)2-Methylpropan-2-ol
(C)Propan-2-ol (B) Butan-2-ol

s
(D)Ethano
Which of the following is NOT dihydric phenol?
66.

t
(A) Resorcinol (B) Phloroglucinol
(C)Catechol
product A in the following (D) Quinol
loadi ldentify the

b
67. reaction.
(CH,), C-OH7KA

u
(A) Butanone (B) Butanal BeC)2-Methylpropanal (D)2-Methylpropene
58. which among the following compounds is used to

o
prepare solid fuel using calcium acetate?
(A) Methanal
naphthol rB) Ethanol
(C)2-Methylpropanol
s (D) Methanol ptar db ayer

D
69. Identify X
the product in the following reaction.
l halide Phenol 2O, xx

1
HSO4
(A) Salicylic acid (B) Benzoquinone (C)Benzoic acid (D) Benzaldehyde

2
70.Which of the following Grignard reagents, is used to prepare 2-methylpentan-2-ol from
acetone?

0
(A) CH-CH - Mg-I (B) CH,-CH -Mg-Idhe de73
ali-
C)CH-CH-
2
CH2- Mg-I (D) CH-
CH
Mg -I
tir aotnet
bon ort hiobt
l

nadt
T
lyproog(

E
71. The
reaction stated below is named as
OH
OH
HGHD

C
COOH HO-H-
nol? () NaOH
MgBr
CH

T
(2)cO,,H ogod
(A) Kolbe's reaction (B) Sandmeyers reactionr
reaction
(D) Stephen

H arftedoil.
(C)Reimer-Tiemann reaction
from alcohol?ol LiAlH4
72.Which
following is used to obtain alkene (D)
Ne Wing 1reagent (C)P:Os

M
(A)
(A) KMnO4 product acetone?
Na-Hg/HO (B) Acidic yields valuable by
phenol aW.Ta
73. Which preparation of
of the 1Olowing process of further acid hydrolysis 21d
rag.-l
A) From
Frompropyl benzene using air and
(8) From
aniline bydiazotization treating with NaOH, H Sigo
h C) From benzene sulphonic acid by
rom chlorobenzene by Rasching proOc
 (286) MHT-CET Exam Questions Identitythe
88. Phenol
74. Identify the product B in the following conversion?
PhenolNaOHACHlB Na2C
(A)
(A) Iodobenzene (B) Anisole (C) Toluene (D) Phenetole (CHCI

n
75. Which of the following alcohols has tertiary allylic carbon? Which of
(A) But-3-en-2-ol (B) Prop-2-en-l-ol 89. Benzer

o
(C) 2-Methylbut-3-en-2-ol (D)1-Phenyl ethanol (A)
(C)4-Met
76. Identify the role of PDC from following
(A)It carries dehydration of alcohols.
is Which of
90. CaHsC

s
(B) It helps to prepare carboxylic acids from alcohols. (A)
stage.
()It helps to stop oxidation of primary alcohols at aldehydic (B) CaHs

e
D)It carries hydration of alkenes.
77. What are the products of the following C)CHs

s
reaction?tto oito
(CH3)C-0-CH,+ HIod? D) 2 CaF
(A) (CH,),C-I+ CH,OH
(C) (CH,),C-OH +CH,I
(B) (CH,),C-OH+CH,OH
(D) (CH,),C-I+ CH,I

b
78. Carbolic acid when reacted with concentrated sulphuric acid at 373 K forms dA t 91.
Which an
(A) Propa
(C) Butar

79.
(A) salicyclic acid
(C) benzoic acid
Which of the following on oxidation yields

o
ethyl methyl ketone? u
(B) 2-hydroxy benzene sulphonic acid
(D) 4-hydroxy benzene sulphonic acid 92. Which of
(A)Phen

D
B) Butan-1-ol D)2-Methylpropan-2-o
igl

(A) Propan-2-ol C) Butan-2-ol (C)Viny

80. Which isomer of CaH100 is optically active ? Identify
93.
(B) 2-methylpropan-l-ol

1
(A) 2-methylpropan-2-ol
(C) Butan--ol (D) Butan-2-ol biouailaiise ( Chlc

2
81. Identify product B in following reaction, PhenoloA B to dede

0
(A)Toluene (B)Anisole C)Phenetole (D)lodobenzene (A) Ben2
82. Which of the following reactions of alcohols involves breaking of O-H bond? C)3-H

2
(A) Reaction with Lucas reagent (B) Reaction with acid anhydride 94. Which c
(C)Reaction with thionyl chloride (D)Reaction with phosphorus halides
(A)Con
83. Identify the product obtained when phenol is treated with bromine water?

T
(B) Con
(A)p-bromophenol B)m-bromophenol C)Con

E
C)2,4,6-tribromophenol (D)o-bromophenold
84. Which of the following is a vinylic alcohol? boe nonoasela D)Con

C
(A) CH2= CH- CH2-OH 95. Identify
(B) CHs-CH = CH- CH - CH-OH
C) CH-CH = CH-CH,OH D) CH,- CH-CH=CH-OH (A) Met
(C)Pro

T
85. Common name of ethoxybenzene is

H (A) anisole (B) phenetole

86. Which of the following alcohols
(C)catechol
CH,

D)
bpay 'sdlotA
quinolt
96. Identify
potassit
(A)Ethi
C)Eth

M
is NOT prepared by nds?
(A)2-methylpentan-2-ol reduction of carbonyl compoun
(B) Pentan-1-ol
97.1dentify
(C)3-methylpentan-2-ol
87. What is IUPAC
D)Pentan-2-ol
name of phenetole?
(A)1-phenoxy propane Srad lysppni11
(C)2-phenoxy propane (B) Methoxy benzened
HCmr (A) A
(D)Ethoxybenzenee 903 ot C)A
 Alcohols, Phenols & Ethers (287)
in
dentify the reagent A used following conversion.
Phenol Benzoquinone

n
tole + H,SO,
(A)Na;Cr0;aq. NaOH (B) conc. H,S0

o
(C)CHC (D) NaOH, CO

is
following compounds is also called
9.Which of the p-cresol?
Benzene 2, 4-triol
(A) (B) Benzene-1,3-diol
()4-Methyl phenol (D) Benzene -1-4-diol

s
which of the following conversion explains the acidic
90. nature of alcohols?

e
A)GH,OH CH,Cl+HCI+ POC

s
(B) CH-OH H CH-Br+H;0
95t%H,S04
C)CHOH CHA+ HO

t
443 K

D)2 CH-OH 2C.Hy-ONa+ H

acid
81. Which
among the following is a first oxidation product of butan-2-ol
(A)Propanoic acid and CO
(C) Butanoic acid
(B) Butanal
(D)Butan-2-one
?

u b
92.Which of the following alcohols is NOT having C-OH
o
acid bond?
(B)Methylpropan-2-ol

D
(A)Phenyl methanol
yipropan-2-4 (D)Propan-2-ol
C)Vinyl alcohol
product B in following conversion.

1
93. Jdentify the
COn. SO4 B
Chlorobenzene + H,O A 373K

2
Pressure

(B) 2-Hydroxybenzene sulphonic acid

sulphonic acid

0
nzene
(A) Benzene (D)4-Hydroxybenzene sulphonic acid
(C)3-Hydroxybenzene sulphonic acid
reagent?

2
is called as Lucas
94. Which of the following solution
zinc sulphate.
(A)Concentrated sulphuric acid with chloride.
lides with zinc
(B)Concentrated carbolic acid

T
nitrate.
(C)Concentrated nitric acid with zinc zinc chloride.
acid with
(D)Concentrated hydrochloric

E
from following?
having highest boiling pointPropan-l-ol
3 Identify the compound (B)

C
(A)Methoxy ethane (D)Propanal
H-OH treated with acidified
(C)Propane when 9.2 g ethanol is
quantity obtained
H
the product and it's

T
ucDty
oassium dichromate
under ideal
conditionsS Ethanoic acid, 3.2 g
(B)
4.6 g
(A)Ethanal, 3.2 g (D) Ethanal,

H
(C)Ethanoic acid, 12.0 g reaction.
following
nol
Compounas 97. Identify roducts A and B in
the

M
)LiAlH4 A+B
Ethylpropanoate-
(i) Ho Propanoic acid, B
-Ethanal
(B) A = Ethanol
Methanoic acid Propan-I-ol, B-
(D)A
(CADtanoic acid, B = acid
9A-Propanal, B Ethanoic
 o n
is
e s
t s
u b
D o
2 1
2 0
E T
C
HT
M
 (B) Alcohols, Phenols &
6.The structures of possible alcohols having formula Ethers (289)
CaHsOH
are as follows:
() OH
( OH (il) OH
ration butanol OH (v)

n
butan-2-ol 2-methyl propan-1-o
ofphens 2-motry
2-mer
these, 2-methylpropan-2-ol

o
Among these, propan-2-ot
-ol (tertiary alcohol)

is
carbonyl compounds. cannot be prepared
by the reduction of
7. (C)

ketone CH-CH--CH
e s
s
andthen OH
butan-2-ol
(Cchiral carbon atom)

ns. 8.
So,

(B)
butan-2-ol is optically active. a

b t
u
Dehydration of alcohols involves the formation carbocation
of intermediates. More the stability
of carbocation, more will be the ease of alcohol towards dehydration.

9.
The order ofstability of carbocation is 3>2°> 1

(A)
D o
The order of ease of dehydration of alcohols is 3°> 2> 1

1
2 R-OH+ 2Na > 2 R-ONa+ H2
21mol 1 mol

mol

The weight of
mol g-1g
0 2 mol

Thus, 1

2
g H2 is produced when
1
mole of alcohol reacts with
Na.

10. (C)

E T
Ienols give blue or violet colouration
with FeCl solution.

2ance.
11.(B)

C
Iethanol (CHOH) is soluble
in water due to CH

HT mation of H-bond between

methanol.

12.(C)
water molecule and

is acidic in nature.
O-H---0-H
H-bond

M
-trinitrophenol is picric acid. It
2,4,6-tri

OH
ON NO

NO
 Exam Questions
(290)MHT-CET 19. (C)
13. (C) CH H,
CH CH3-CH- ÇH-CH
-CH CH-CH-CH2 -CH,OH 20. (D)
CH--CH, OH Re
3-Methyl butan-2-o1

n21. (B
OH
3-Methyl butan-1-ol
2-Methyl butan-2 ol

HOCH-CH-CH-CH
CH

iso
s
2-Methyl butan-1-ol

e
14. (A) are
Boiling points of the given compounds

s
Chloroethane n-Butane 22.
Propan-1-ol> Propanal> 285.3 K 272.5 K
322 K

t
370.4 K
15. (D) phenol.
in commercial production of
Cobalt naphthenate is used as catalyst

CH-H
CH
CH
CH-C-0-0-H
u b
o
23
Cobalt naphthenate
+
0,(air)423 K/alkaline medium

D
1
24.
CH-C-0-0-H OH

2
26
dil

0
HSO4 +CH--CH3

16. (D)

2
The order for acidity in phenols depends upon the electron withdrawing groups
position.

T
p-nitro phenol > m-nitro phenol> phenol.

E
OH OH
2

C NO

T
NO
17. (B) 3

H 2Na+2CH,OH+2C H,0°Na" +H2)

2238 I mole

M
1 mole of H, -2 g of H2 =2 x 10 kg

18. (D)
boe snoig a
lod -0.
CH
cold
CH-C-O-CH, + HI
CH
CH-C-I +CH,OH
CH,
 9. () ic alcohols, as
Alcohols, Phenols&
Forisomeric branching
imcreases
Ethers (291)
boiling point
20.(D) decreases.
Reactivity of alcohols towards Lucas reagent
is 3°>2°>1°.
21 (B)
OH
OH

o n
+CHCl O NaOH
(i) H/HO
CHO

is
22.(A)
Reimer -Tiemann reaction

e s
ol. CH,

+HI398K
OH

+CH,
t s
23.(B)
(Anisole) (Phenol) (Methyl iodide)

u b
24. (C) 25. (D)
D o
1
26. (C)

2
Carbolic acid = Phenol

groups position.
(Phenol)

2 0
-OH orCKO
Nacr,o/i,50,
(p-Benzoquinone)

T
27.(A) is changed. Such
only position of functional group
There is no change in molecular formulae,

E
reaction is called rearangement reaction.
32.(B) 33.(B) 34.(

C
28. (D) 30. (A) 31. (D)
29. D)
35.(D) acid (a nitrating
acid and conc. sulphuric
of conc. nitric

T
wnen phenol is warmed with a mixture picric acid, is formed.
6-trinitrophenol, commonly called
DTUre or the mixed acid), 2, 4, OH

H
NO
OH ON +3H,0
HONO,
onc H,So4

M
+3
itric acid
NO
Phenol Pioric acid
 (292)MHT-CET Exam Questions
42.
(C)
36. (C)
3CH, - CH, -CH-CH, H,PO.
+ P-
) 3CH,-CH, -ÇH- CH, + PCI, Py
C
OH
2-Chlorobutane
Butan -2- ol

n
(X)

() 2CH, -CH, -ÇH-CH, +2KOHACH,-CH = CH-CH, +CH, -CH, -CH=CH

(alc.) But-2-ene
(Major)
,+2K.Cl+2HO
But-1-ene
(Minor)
is o 43. (A

s
2-Chlorobutane
Y) C

e
i) H-OH/heat
- CH, -CH-CH,)HOH/heatCH
(ii) CH,-CH- CH-CH,0HSOCH, ,CH,-CH,-CH-CH, +H50,
But-2-ene
(Y)
OSO,H

t s OH
Butan-2-ol

(2)
44. (C
Pr
re
37. (B)

CH,-0-CH, +2HI 4 CH,I +C.HI +H,O

u b 45. (B
A

o
Methoxy ethane Iodomethane Iodoethane

D
38. (C)
OH

1
OH 46. (F
O

OH
3- hydroxy groups)

0 2 ipredbiop alad

Hydroxyquinol

2
T
39.(A)

E
CH,OHSOCh C,HC CHONa C,Hs -0-C2HsA,Pressure
PyridineChloroethane
dil.H,SO42C,Hs -0H
Ethanol a Ethano

C
Diethyl ether

40.(A)
47.
(et

T
Due to absence of acidic proton.

H
41. (D)
1

M
CH-CH2-0-CH, -CH-CH
OA CH
1-Ethoxy-2- methylpropane
 Alcohols, Phenols& Ethers (293)
42.(C)
Cresol>Phenol, Catecho Dihydric -

gallol ,
Pyroga oglucinol -Trihydric phenol
phenol
CH OH
OH
OH OH

n
28.R HO OH
OH

o
HO
OH

is
p-Cresol Catechol
4-Methylpbehol Benzene-1,2-dtol Phloroglucinol
Pyrogallol
Benzene-1,3,5-triol
43.(A) Benzene-1, 2,3-triol
-C8,-R CH,-CH,-0-CH, -CH, -CH, -C

2- 4.(
3-Chloro-1-ethoxypropane
O
e s
s
Propan-1ol cannot be prepared by acid
catalyzed hydration of alkenes
reaction follows Markownikoff's rule: because the addition

45.(B)
Allylic secondary alcoholgonsl

CHCH- CH,
b t
u
H,C
OH

46. (B)
But -3-en 2- ol1

D o
On treating phenol with chloroform in the presence of sodium hydroxide, a -CHO group is
introduced at ortho postion of benzene ring. This reaction is known as Reimer-Tiemann reaction.
9H
CHC, aq NeOH

2 1 2NaOH
-2NaCl
Na'CH(OB

0
(unstable)
Tntemediate

2
OH
ONa CHO
CHO dilH
H,-OH -NaCl

T
Saleylaldehyde
thano 2-Hydroxybenzaldehyde)

E
47.(B)
OH
OH

C
NO
room +2H,0
+2[HO- NO,]emn
temp 22

T
dil O-nitrophenol NO
Phenol p-nitrophenol

H intra-molecuar H-bonding
ortho product

M
Due to para product
S
more stable than
 Exam Questions
(294)MHT-CET
55. (D
48. (C) QH
-CH,

n
+HI- +CH,-I

Methoxy benzene
49. (C)
the number of alkyl
Phenol lodomethane

groups increases, acidic strength of

alcohols deçreases,
iso
s
As
56.
50. (A)
H
e
Resorcinol Dihydric phenol
QH OH

s
ÇH OH
HO OH

C OH OH
HO

b
OH
t
u
Phloroglucinol Pyrogallol
m - Cresol Resorcinol
51
51. (B)
3CH,-CH, -CH, -0H
Propan l-ol
PC
3CH,
(X)
D o
-CH, -CH2 -Cl + HPO
1-Chloropropane
ns--10

1
- Cl alc.KOH CH,-CH = CH, + KCl +H0
CH,-CH- CH,
Propene

2
1-Chloropropane
(Y)
rt

0
conc.
H,SOCH, -CH-CH,
CH-CH=CH,- H-OH/A + H,SO4

Propene

2 OH
Propan-2-0l

52. (A)

E T CH,
()

C
CH,-C-CH=CH,

T
OH
2-Methylbut -3 en -2-ol

H 53. (D)
QH

M
a-naphthol
54. (C)
 (D) Alcohols,Phenols &
Ethors
5 (295)

-H

OH
OH
Salicylaldehyde

o n
(No.of oxygen atoms = 2)
is
s
6.(C)
OH

OH IUPAC name Benzene - 1, 4-

diol

s e
8
gallo
OH
Hydroquinone

b t
57.(A)
OH

CH,--CH,
o u
D
2-phenyl propan - 2-ol

2 1
0
(tertiary) ydlsM gbiboljedle
58.(B) bibot

2
Phenol is known as carbolic acid.

H
E T
C H
HT
59.(B)
H

OMgBr
OH OH

M HC =oCH-Mg-Br, H/H,OH,c, -H-CH, + M8R

CH f-1-phenylethanol
H
Product oloe t vrnt
Addition s
Benzaldehyde
The number = 13 u rkgeile
of aG bonds
Or
 MHT-CET Exam
Questions
(296) 66.
(B)
60.(A)
61. (C) C.H, MgBr/ether,CH,-CH,-CH,-OH
H-CHO H,O Propan-1-ol

n
Fomaldehyde
CH,-CH,-CH, -OH
2. CH,-CH-CH,
Propene
Propan-1
i.cold,cone. H,SO, CH,-ÇH-CH,
iso ph

s
CH,-CH- CH H, OH

e
Propene 67.
Propan-2-ol

CH,-CO-CH, H,O
OH

CH, -Ç-CH,
t s
b
CH,
Acetone

u
2-Methylpropan -2- ol
68.

o
62. (A)
benzene is obtained.
When phenol is heated with zinc dust,

D
OH
69

1
Za +ZnO

2
Pheno Benzene
63.(D)

0 C,H,
CH -0-CH, +2HI +CH,I+ H,O
Ethyl lodide Methyl

2
Methoxy ethane lodide
64. (C)

T
OH

E
OH 70

C OH

HT 65. (A)
Hydroxyquinol

M CH,-C-CH,
OH
2-Methylpropan-2-ol
(tertiary alcohol)
Tertiary alcohol reacts immediately
with Lucas reagent.
d a
 Alcohols, Phenols&
(B) Ethers (297)
OH QH
QH
OH

n
OH
HO OH

o
OH

is
Resorcinol Phloroglucinol
etoo Catechol OH
Phloroglucinol i8 a trihydric phenol Quinol

67 (D)

e s
s
on reaction with Cu at 573 K gives alkene.
3 alcoho

t
CH
Cu
(CH,),C-OH73KH,C-C=CH,
2 methyl propene

u b
o
68.(B)
Ethanol is used to prepare solid fuel using calcium acetate.
69. B)
OH
D
Na,Cr,O,
H,SO
2 1
2 0 O
Cx)

T
Benzoquinone

E
70.(C) OMgI
akoein

C
cunCH-C-CH-CH -CH
-CH, -Mg-1
-C=0+CH,Propyl
-CH,
magnesium iodide CHs

HT CH
Acetone

CH-C-CH, -CH,
OH

-CH, +Mg
fo-

M CH3 OH-
2-Methylpentan-2-ol

E
 uueau
(298)MHT-CET Exam
71. (A)
OH
OH
COOH
() NaOH
(2)CO,,H
Phenol
Salicylic acid

It is Kolbe's reaction.

o n
72. (C)
is
s
Conversion of alcohol into alkene is a dehydration reaction.

e
PO, is a dehydrating agent.
76.

CH,OH H,C=CH,

t s
b
73. (A)

CH CH,

HC--H H,C-0-0-H
o H'
u QH 2u
17

O
D H,O
+CH,COCH,

1
Cumene Phenol Acetone

74. (B)

OH
0 2 8.

2
QNa OMe
NaOH

T
CH,I

75. (C)
CE (A)
Anisole
(B)

HT But-3-en-ol
H,C=CH-CH-CH
OH

M
2° alcohol

Prop-2-en-1-ol H,C-HC=CH, 79
OH tnalba-t
1° alcohol
 Alcohols, Phenols&
CH
H,C-CH-C-CH,
Ethers (299)
-Methyl but-3-en-2-ol

OH
3 allyl alcohol

1-phenyl ethanol
CHCH,OH

o n
is
s
1 alcohol

e
76.(C)
PDC Pyridinium dichromate: (Mild oxidizing

s
PDC agent)
Alcohols Aldehydes
1 CH,CL

17.(A)
Room temp

b t
u
(H,C),C-O-CH, cold
HI(CH,),C-I+CH,OH
COCH,

etone
When one
formed. Since

D o
of the alkyl group of ether is tertiary,
tertiary carbocation is more stable.
tertiary alkyl halide and
lower alcohol is

1
78.(D

OH OH

conc.H,S0, 15-20°C

0 2 -SO,H

2 2- hydroxy benzene
Sulphonic acid

T OH OH

CE +conc. H,SO,
100°C
(373K)
SOH

HT
h.C)
4-hydroxy benzene
Sulphonic acid

M
H,c-CH-CH, -CH, rOH,C-c-CH, -CH,
(0)
OH
Ethylmethylketone
Butan-2-ol
 (300) MHT-CET Exam
Questions

80. (D)

H,C-C-CH, -CH,
OH
it has chiral carbon at C- 2 position.
Butan-2-ol is optically active as
81. (B)
OH ONa OMe

o n
NaOH CH,I
is
s
-H,0 -Nal

e
Phenol Sodium phenoxide Anisole
'B

s
'A
82. (B)

R-OH R'--0-ë-R'=R'-Ë-OR
b t
+R°-COOH
ooe

u
Alcohol Acid anhydride Ester

83. (C)
OH

Br
QH
-Br
D o 3-0-00

1
Br,/H,O

Phenol

0 2 Br
2,4,6- tribromophenol
84. (D)
2
E T
Ci,CII-CH= CI-OH
CH,
unbgd

C Vinylic Carbon

T
85. (B)

Q-CHCH,

H
M Ethoxybenzene/
Ethyl phenyl ether/
(Phenetole)
HD-2
H
io--e
 (A) alcohols and 2° Alcohols,
Only1 alcohols
ols can be prepared Phenols & Ethers
(301)
CH by reduction
of carbonyl group.
H,C-C-CH,-CH,-CH,
OH

n
2-Methylpentan - 2-ol

o
(3 alcohol)
87.(D)

0-C,H, is
Ethoxybenzene

e s
88.(A)
(phenetole)

t s
OH
CrO
or Na,Cr,0,/H,SO,

u b
89.(C)
OH

D o p-Benzoquinone

1
-9-9,H

CH

0 2
2
p-Cresol
.(D)

T
it means H' is acidic.
Since H atom of CaH,OH is replaced by 'Na' atom,
91.(D)

CE
'alcohols- oxidationAldehydes
alcobolsoxidation
Ketones

HT H,C-CH-CH, -CH, CrO,H.Cc-Ç-CH,CH,

OH
Butan-2-ol
(0)
Butan-2-one
-0-

M
2(C)
sp
HC-CH

OH
Vinyl bond.
alcobol -OH
has 2
 (302)MHT-CET Exam Questions
98.
(C)
93. (D)
QH QH
H,C
HO-SO,H
HO-SO,H
O
n
673 K
O +H,O
Cu,
200-300atm 373 K
Eth

so,H
4-Hydroxysulphonicacid
is o
99.
(A)
HCC
Et

s
(p-Phenolsulphonicacid)

e
94. (D)
Lucas reagent is a solution of anhydrous zinc chloride in concentrated hydrochloric
H
s
aci
95. (B)

boiling point is more as compared to alkane, aldehyde and either of comparable

96. (C)
b t
In alcohols strong intermolecular forces i.e. hydrogen bonding is present because of wh.s
mass.
2-N

HC-CH,OH
Ethanol
gO, HNOHC-CH
(O)
Acetaldehyde
o u HO

M.W. 46 g
Mass-9.2g
D
2 1
H,C-C-OH M.W 60Dg

0
Ethanoic acid Mass = ?

2
46 g of Ethanol = 60 g of Ethanoic acid
100. (C)
9.2 gof Ethanol =
0x9.2 = 12.0 g of Bthanoic acid

T
46 fos13-

a
E
By using KCr:O7, primary alcohol
Oxidation
is first oxidised to aldehyde and then carboxylic H,C
does not stop at aldehyde stage.

97.(D)
C
T
sbyrsbia
oitabt0 elode

H
H,C-CH,-C-0-CH,-CH, +LiAlH, H,C-CH,CH,OH+

M
-

Ethypropanoate Ethanol
Propan-1-ol

HO
toaloole len
 (C) Alcohols,Phenols&
9 Ethers (303)
HC-CH,OHCu,S73 K
Oxidation 1,C-c-H
Ethanol Ethanol

n
(Acetaldehyde)
99.(A)

o
onic acidA
HCCH-0- CH,CH,
micacid) Ethoxy ethane
OH
HC-0-CHCHCH
1-Methoxypropane
is
s
ychloric
acid. H,C-C-CH,

e
H,C-CH-CH,
because

s
CH OCH
ofwhich
blemas. is 2-Methyl propan - 2- ol

t
2-Methoxypropane
ed

b
Molecular formula for all above
4 structures are same (CalHi«0)

OH

H,C-CH,-C-CH,
o u
CH
D
1
2-Methyl butan - 2- ol

2
M.F.- CH,0

- 0
100. (C)

2
CH, CH,

carboxylic acid HCCH HC--O-0-H onarq nbnd

T
en
+0Co-Iapthenate

E
423 K
Cumene hydroperoxide

C -a, [O
T
dil HC1
OH+CH,CHOH
Acetone

H
Phenol
(Propanone)
Ethanol

M
 H
14. Biomolecules
Important Formulae and Shortcut Methodss

o n
Carbohydrates
is
s
Theseare polyhydroxy aldehydes or ketones or the substances which give such compounds on
hvdrolysis and they contain elements C, H, O and have general formula C.(H,O).

e
e.g.Glucose (CoH1206), Sucrose (C12H011),
etc.

lectron
Classification:
Monosaccharides: They do not undergo hydrolysis. e.g. Glucose, fructose, ribose.
Oligosaccharides: On hydrolysis they give 2-10 monosaccharides. e.g Sucrose, raffinose,

t s
stachyose.

b
Polysaccharides: On hydrolysis they give a large number of monosaccharides. eg. Starch,
glycogen.

u
Preparation of Glucose
Glucose is prepared either from cane sugar or from starch.

C2HO+ H,O-HClor
H,So
C,H,0, +CH,
D o ebbos islb

1
cane sugar 4glucose fructose

1. HSO

2
(CH,0,)n+ nH, 393 K,2-3atm nCgAa°s
to
uhip6 odg

0
Reactions:

2
Hot HI
CH CH-CH-CH-CH CH
n-Hexane

A08S 73-THIH

T
HC-(CHOH)-CH,OH+ H,O
HON Glusoxime

E
HCN NC-CHOH-(CHOH)-CH;OH
yanobydrisP

C
CHIO
() HOOC-(CHOH)-CHOH
)
Bromine water onle
d HNG
ataib () obituioou

T
9 ug dil HNO HOOC(CHOH)O0
(O) Saccharic acid

H
s(CH-COOOHC--CH-O-coCH iling
+SCH,COOH
CH,0-COCH,

M Structure of
Glucose can be
projection formulae.
Carbohydrates:
represented by Fischer
Fructose is
and belongs to
projection
ketohexose and
D series.
laevo rotatory cyclic structure by
Fructose
formulae
made

Haworth projection
by
and cyclic

formulae.
formulae.
structure by Hau orth
1somerisation of glucose
by Fischer
can be representedDisaccharides
Te.
ose. It is

Haworth
formulae and represented by
can be
maltose, cellobiose
 201
UHT-CET
the
of
AVSacáyas
Which
Questions 201
(360)MHT-CET Exam MHT-CET
on

n
Proteins nitrogenous organic
compounds containino 16%
polymeric (nr 10% Aglucarc
CIcose
Proteins are naturally
occurring
classified into fibrous proteins keratin
(insulinn

o
linkages. Proteins are
nitrogen and peptide of muscles) and globular proteins

is
(protein
hair, wool, and nail),
myosin
legumelin). The structure of
protein can be studied at differ MHT-CET 20
albumin, serum albumin, on hydrolysis give
secondary, tertiary and quaternary. Proteins Ve
levels called primary, mole

s
R
One mole
(nH,N-CH-COOH). (4)Imole

e
mixture ofa-amino acids (B)2
mol

s
and neutral amino acids. (C)1
into three types-basic, acidic
Amino acids are classified and -NH2 group by D)2
mol
amide formed between -coOH

t
y
Peptide linkage (-CONH) in an
MAT-CET
elimination of water molecule.
Enzymes u
Enzymes are biological catalysts for various
are required in small quantities. They act
u b
chemical reactions in living organisms.
as catalyst and reduce the activation
Enzymes
energy for a
10.
Which
(A)Coll
o

particular reaction.
Nucleic acids
Nucleic acids are esters of phosphoric acid with
D o
sugar. They control the synthesis of proteins
and are also responsible for storing the genetic information of
living organism and passing the
11. During
giucose
(A)hyd
(C)prin

1
information from one generation to another.
Chromosomes contain two types of nucleic acids: Ribonucleic acid
ribonucleic acid (DNA).

2
(RNA) and deoxy
enolseiH
MHT-CE1

12. Glucos

0
(A) six
Multiple Choice Questions C)ald

MHT-CET 2004
2 13.Which
(A)VE

(A)2
MHT-CET 2005
E T
1. Glucose on oxidation gives the acid containing the C-chiral atoms equal to
(B)3 (C)4 (D)5 MIHT-CE

14.What

C
2. Raffionse is
(A)trisaccharide (B) disaccharide (C) monosaccharide (D) polysaccharide 15.The
(AJD

T
MHT-CET 2007 (A)H
3. Zwitter ion is formed by 16.

H (B) acetanilide
Am
(A) aniline (C) benzoic acid (D)glycine (A)6
4. Glucose gives silver mirror with ammoniacal silver nitrate because it has

M (A)aldehyde group (B) ester group

5. Sucrose on hydrolysis gives
()ketone group

(A)gucose and maltose trpa noiseti (B) glucose and lactose

C)ghucose and fructose
MHT-CET 2009
u saoyaD)only glucose
(D) alcoholic silver nitral

mui undaa
g
MHTC
1.whi

6. Stachyose is a
(A)monosaccharide (B) disaccharide tetrasaccharide
(C) trisaccharide (D)
 MHT-CET 2010 Blomolecules
(361)
7. Which of the following is a trisaccharide?
(A) Stachyose (B) Sucrose
C)Raffinose (D)Ribose

n
MHT-CET 2011
8. Glucose on reaction with Br2 water
gives

o
(A)glucaric acid (B) gluconic acid

is
(C) saccharic acid (D) citric acid
MHT-CET 2014

s
9. One mole of stachyose on hydrolysis yields
(A)I mole of glucose+ I mole of fructose + 2 mole

e
of galactose
(B) 2 mole of glucose+ 1 mole of fructose+ 1 mole
of galactose

s
(C)1 mole of glucose +2 mole of fructose+ 1 mole of galactose
(D)2 mole of glucose +2 mole of fructose

MHT-CET 2015
10. Which of the following proteins is globular?]
b t
u
(A)Collagen (B) Albumin (C)Myosin D)Fibroin

o
11. During conversion of glucose into glucose cyanohydrins, what functional group atom of
glucose is replaced?

D
(A)hydrogen (B) aldehydic group
(C)primary alcoholic group (D) secondary alcoholic group

MHT-CET 2016

2 1
12.Glucose on oxidation with bromine water yields gluconic acid. This reaction confirms
(A) six carbon atoms linked in straight chain (B) secondary alcoholic group
presence of
in glucose

0
(C) aldehyde group in glucose (D)primary alcoholic group in glucose

(A) Valine (B) Tyrosine

onitLas olom so aE 2
13. Which of the following amino acids is basic in nature?
(C)Arginine D)Leucine

MHT-CET 2017
.
E T
Wnat type of sugar molecule is present in DNA?n slom i 52060 D2 C18
(C)D-2-deoxyribose (D)D-Glucopyranose

C
(A)D-3-deoxyribose (B) D-ribose
15.The amino acid which is basic in nature is
C)Proline ureol(D) Valineuet

T
(A)Histidinen o(B) Tyrosine
carbon atoms?
A molecule of Stachyose contains how many
l6. (D)24i woll,06-

H
faa (A)6s oideoamgad B) 12 (C)18oe

MMHT-CET 2018 ooelg lo tiumul

atom deoxy Ribose sugar in DNA does NOT Contain -OH bondd?
17.Which carbon of
go
alesgnea yniwoliot arl
(D)C iCA
(A)Cs (B)Cse o8(0 (C)C
carbon atom in its molecule.
one asymmetric
y the monosaccharide containing only (C)Erythrose (D)Glyceraldeny de
jibulose (B)Riboseoo
 group

chan
ske
(362) MHT-CET Exam Questions
moles
MHT-CET 2019
na7yACetu
*19. B-pleated sheets of polypeptide chains are presentin

n
(A) Secondary structure (B) Tertiary Structure erces
Hio
(D) Quaternary structure
(C) Primary structure
t
o
qua

is
20. Which of the following molecules form a zwitter ion? Lheconc
(C)CHCOOCH (D)CH,CH,coOH
(A)HNCH:coOH (B)CH,COC;Hs WhatI8
ideal
under
21. The enzyme which converts maltose to glucose is

s
(A)maltase (B) lysine (C)insulin lid (D) zymase among

e
22. Which of the following is NOT present in DNA? Hbeh
Collagen
(A)Adenine (B) Uracil (C) Guanine (D) Thymine A) among
23. Glucose reacts with NH;OH to form
(A) Gluconic acid (B) Saccharic acid (C) Glucoxime
24. The compound containing two hetero cyclic rings is

t s
(D) n-Hexane
Whch
Arginine
(A)
among

b
Whicth
(A)Uracil
Al 4)16ß
(B) Thymine (C) Guanine (D) Cytosine
(C)14B

u
MHT-CET 2020 1
25. Identify the product Y in following reaction amo

o
Which
41.Yanide?
Maltose ra X excess) Y
(A)Gluconi

D
(A)n-Hexane (B) Saccharic acid (C) Gluconic acid (D)Glucoxime (C)Glucose
26. When one mole of lactose is hydrolysed, the hydrolysate
contains -T
pa(A) 1.0 mol Glucose +2.0 mole Galactose (B)1.0 mol

1
Galactose + 1.0 mol Glucose What is the
2.
(C)2.0 mol Glucose (D) 1.0 mol Glucose + 1.0 mol Fructose A)Glucon

2
27. Identify basic amino acid from following C) Saccha
(A)Phenylalanine (B)Serinen

0
(C)Alanine (D)HistidineA 43. Which am
28. Which among the following is product (A)Glycin
a of hydrolysis of one mole raffinose?

2
(A)2 moles of Glucose
(B)2 moles Glucose +1 mole Fructose+ 1
tor TaD-TRM 4.Which ree

(C)1 moles Fructose + 2 moles Glucose

mole Galactosese
e
losingt urlW glucose?

T
(D)I mole Glucose+ I mole Fructose+ 20dn- 8)erodmgb-0 (A)Dilute
I mole GalactOSe
-irir

E
29. Which among the following biauonie sd G 45.Which
reagents is used to obtain gluconic
(A)Acetic acid from glucose?
anhydride (B) Acetyl chloride together

C
(C) Bromine water (D)dil. Nitric acid
30. How many optical isomers (A)C-2
are possible for a compound
(A)9 having 3 asymmetric carbon atoms?
(B)3 (C)8 B)c-2

T
31. What is molecular formula (D)6
of glyceraldehyde? C)c-1
(A)C0,Hs B1O 790-1THM
aieto (B)C0H2 (DyC-
Aa C.0Heb o
H
(D)C.OHs
32. Which among the following
(A) Dilute Nitric acid
reagents is used for conversion
of glucose to glucoxime?
E 46.1f
nist
919(B)
M
(C)Hydroxylamineo Brz water
() byform
aitern esne
33. How many optical
(A)16
isomers are possible for a compound
having four asymmetric carbon&a ms?
A
(B)8 C)4 1,Which
(D)12
AJR
 sidechain
chain group-R for
for amino
ami Biomolecules (363)
4. If
(A)Arginine
acid is -CH,0H,
(B) Proline identify the amino acid from following?
(C) Serine
Identify the numbe
nber of oxygen atoms (D)Tyrosine
35. present in saccharic
(A)6 (B)8 acid?
many moles of acetic acid are (C)4 (D) 12
36. How obtained in the

n
with excess acetic anhydride? reaction when one mole gluco
glucose is treated
(A)3 moles (B)5 moles

o
(C)2 moles (D)4 moles

is
37. What is the quantity of glucose obtained when
68.4 g of sucrose is hydrolyzed in laboratory
under ideal ndition? (Molar mass of sucrose =
342 g mol")
(A) 68.4 g (B) 198.0 g8

s
(C) 36.0 g (D) 180 g
18. Which among the tollowing is a globular protein?

e
(A) Collagen (B) Fibroin (C) Insulin (D) Myosin
20, Which among the following amino acids has lowest molar mass?
(A) Arginine (B) Asparagine (C) Aspartic acid

40. Which among the following type of linkages is present in cellulose?

t s
(D) Alanine

(A)168 glycosidiclinkagesd (B)

C)14pglycosidic linkages (D)16a
14a
glycosidic
b
glycosidic linkages

u
linkages

o
41. Which among the following compounds is obtained when glucose react with hydrogen
cyanide?
se
(A) Gluconic acid (B) Saccharic acidoni to

D g h
o
(C) Glucose cyanohydrin (D)n- Hexane
the product obtained when Br2 water reacts with glucose?

1
42. What is
(A) Gluconic acid (B) 1,6-Dibromoglucose

2
D)Bromohexane
(C) Saccharic acid
43. Which among the following amino acids has
a lowest molecular mass?

0
(C)Proline (D)Serine
(A)Glycine (B) Aspartic acid
carbonyl group in

2
following is used to confirm presence of aldehydic
44. Which reagent among the
glucose? (D) Acetic anhydride
(C) Bromine water

T
(A)Dilute nitric acid (B) Hydroxylamine
respectively are linked
a-D-glucopyranose and B-D-fructofuranose

E
45. Which carbon atoms of sih
glycosidic linkage in sucrose? aotel
ogether to form

C
B-D-fructofuranose
and C-2 of
(A)C-2 of a-D-glucopyranose B-D-fructofuranose
a-D-glucopyranose and C-3 of B-D-fructofuranose
(6)C-2 of

T
and C-2 of
(C)C-1 of a-D-glucopyranose B-D-fructofuranose
a-D-glucopyranose and C-6 of is given

H
(D)C-1 of number of optical isomers possible
atoms, the
asymmetric carbon
0 lf n is the number of

M HD-F14
by formula (D)2
(B)n2ehy f0)(C)2 n
(A) reagent?otjodaa
reduce Tollen's
sugars does not D) Sucrose
among the following (C) Maltose
(A)Ribose (B) Lactose
 tollo
trom
Ghu-Acidic
(CLeu-NNeutral
aWhueh
(364)MHT-CET Exam Questions

n
48. Which among the following is a natural biopolymer of monosaccharides? A)
tta of
(A)Isoprene B)Neoprene Whenmoles

o
(C)Glycogen (D) Silk

is .
49. On hydrolysis sucrose gives b
(A)2 moles of galactose (B) 2 moles of fructose A)4 hydre
()2 moles of glucose
nll
oit(D) equimolar mixture of glucose and fructose any

s
HOw
50. Which among the following is basic amino acid?
A)3

e
andgli
(A)Cysteine (B) Glycine (C)Cystine (D) Lysine EL6) Gilucose
*51. Which among the following statements is true for amylose?

s
undicate?
(A) It is water soluble 2 sugge
(B) It has branching to large extent This
(A)Carbonylg
(C) It constitute about 80 % starch
(D) Glucopyranose are linked by 14 B glycosidic
bonds()

b t
52. Which among the following observations suggests that glucose also exists in cyclic form?
(C)Presenceo
(B)

(D)
Presence c

u
(A) Hydroxylamine reacts with glucose to form glucose oxime.
(B) Acetylation of glucose obtains glucose pentaacetate. Identity the si

o
63.
(C) Glucose does not undergo condensation with 2,4-dinitrophenylhydrazine. (A)CH;)4
(D) Prolong heating of glucose with Hl yields n-hexane. do 8 C)-CH:OH

D
53. Which of the following statements is NOT true about saccharic acid?
64.Identity the
PRgab (A) It can be obtained from gluconic acid
(B) It contains one carboxyl group and four hydroxyl groups
wollor gnod ar (A)6
(C) It can be obtained from glucose
(D) It contains two carboxyl groups a

2 1 65. Which amir

(A)Histidin

0
54. What is the number of groups present in nitrogen bases of nucleic acids, thymine and
S=0 6. What is the

2
uracil respectively? (A)Two
(A) 1 and 2 (B) 2 and 2 (C)1 and 1
D) 2 and 1 dad W
67.Which of

T
55. Which following reagent is used to detect presence of five hydroxyl groups in a glucose

E
molecule?
(A) Acetic anhydride a(B)
Dilute nitric acid ataliA
(A)It has
B)It is o
C)It is a

C
Losai () Br2 water sto)Hydroxyl amine D)It con
itctat b ths laut
56. Which among the following reagents is, used to confirm the presence of carbonyl group in 68.Prolong

T
glucose? uhotani,G-8to
A prest
(A) dilute HNO (B) hot HIu-q ()Bra water D) NHOHo B)pres

H 006Tgtoeaett C)pres
57. Identify group - R in isoleucine H,N-CH-COOH (Dpres

M
69.How
m
(A) CH3- CH- CH (B) CsHs- CH stachy
C) (CH);CH- CH (D) (CHs)%CH (A)I,)

58. Which of the following molecules reduces Fehling's solution?

(A) Erythrose (B) Acetone (C) Sucrose (D) Butan-2-one
 Which from follo
owing pairs of symbol
Biomolecules (365)
59. and nature
(A) Glu-Acidic of amino acids is
(B)Asp- Neutral NOT correct?
Y

(C)Leu -Neutral
(D)His
2,moles of stachyose Basic
an
Whe

n
60. is hydrolyzed,
(B) 2 the number
(A) 4 of moles of galactose obtained

o
(C)6 is
(D) 3

is
many hydroxyl groups are
61. aw present in Erythrulose?
(A) 3 (B) 4
(C)2 (D) 5
e Glucose and gluconic acid treated with dilute
indicate?
(A) This suggests that all
nitric acid forms saccharic acid. What

e sdoes this

s
six carbon atoms of glucose are
(B) Carbonyl group in glucose is aldehydic. in the form of straight chain.

t
(C)Presence of primary alcoholic group in glucose.
D) Presence of five hydroxyl grOups in glucose. oteit
63.Identify the side chain-R
(A)CH)4-NH2 io
present in amino acid lysine.
(B)-CH(CH3)2
u b
nb sobie

o
(C)-CH2OHoq bne B naoneono(D) CH-
64. Identify
(A)6 (B)4 (C)3
D
the number of secondary carbon atoms in glucose. 0 (D)2m
65.
(A)Histidine (B) Lysine

2 1
Which amino acid from following is neither acidic nor basic in nature?
(C) Leucine (D) Arginine

66. What
(A)Two (B) Zero

67. Which of the following statements 2 0

is the number of hydroxyl groups present
in lactic acid?
(C) Three

is NOT true for

ato(D)One
glyceraldehyde?

T
(A)It has carbonyl and hydroxyl

E
(B) It is optically active.
(C)It is a sugar molecule.
group.unomme i otim evie s

C
asymmetric carbon atoms.
D)lt contains two
n-Hexane, confims
with HI to form

T
0. FTolonged heating
68. of glucose chain.
six carbon atoms in a straight
Apresence of all

H
group.
B) presence of carbonylalcoholic group.
presence of primary carbonyl group. fo gonainnog sietaioosata rgabd
presence of aldehydic hydrolysis of l mole

M are obtained on
respectively
fructose and galactose
many moles of
stachyose? (B)3, 1
(A)1,1 u (D)2,2
ovr aig
* soot zsvig saenitun
 (B
Glucose
CH
366)MHT-CET Exam Questions (CH
SOLUTIONS

1 (C)
Write the oxidation reaction of
glucose and count number of
chiral carbon (having four dif..
iferent

o n
is
groups) in it. ÇHO çoOH
-c-OH m
H--OH

s
moles
HO- -H
HO--H (B)

e
H- OH H -OH 10. Albun

H-C-OH
CH,OH
a-glucose
CH,OHg l
gluconic acid
quo
ag
t s
9
l
trD3)
1
(03
1.(B)
Durin
group
CH

b
(4-chiral C-atoms)
(4-chiral C-atoms)

u
2 (A) (CH
Monosaccharides do not hydrolyse, disaccharides give two molecules of monosaccharides,

o
trisaccharides give three molecules of monosaccharides and polysaccharides give many CH
molecules of monosaccharides on hydrolysis.
gae to ori tduin lie

D
CsH32016 +H,0 glucose+ fructose+galactose
Raffinose G
Raffinose is trisaccharide.

1
12.(C)
3. (D) 9aibteli Glu

2
Zwitter ion is formed by amino acid. Glycine is amino acid. of

0
Zwitter ion of glycine is NH -CH-C00

2
4. (A)
Glucose gives silver mirror with ammoniacal silver nitrate because of presence of-CHO group
(aldehyde group) in the structure of glucose.
. (C)

E T afoglom 1guet

Sucrose gives glucose and fructose on hydrolysis with invertase enzyme.

t begnioti
13. (C

C
Ci2H2011 Invertase
C6Hi206+CgH,0,
Sucrose Glucose Fructose

T
6. (D) 14.
Stachyose is a tetrasaccharide consisting of two a-D-galactose units, one a-D-glucose unit andd
one p-D-fructose unit sequentially linked. It is naturally found in numerous vegetables 16.(

H plants.

7. (C)
17.

M On hydrolysis stachyose gives four, sucrose gives ves no

two, raffinose gives three and ribose g
molecules, of monosaccharides. Thus, only raffinose
is a trisaccharide.
CsH2016+ H,0 3CgH1,06
 . (B)
Glucose on oxidation with Br2
Biomolecules (367)
water gives
CHO gluconic acid.
ÇOOH
CHOH)4+[O]-
B/H (ÇHOH)4
H,OH

n
H,OH
Gluconic acid
9. (A)
One mole of stachyose on
bemoles of galactose.
hydrolysis yields one
mole of glucose, one mole of fructose
is
and two o
s
10. (B)
Albumin is globular protein

e
while collagen, myosin
11. (B) and fibroin are fibrous proteins.

s
During conversion of glucose to glucose
cyanohydrin hydrogen cyanide is added
group of glucose to carbonyl

V5acchari
CHO

(CHOH) HCN
CN

CHOH

b t
CH,OH

Glucose
(CHOH)

CH,OH 22
o u
12. (C)
Glucose Cyanohydrin

D
1
Glucose on oxidation with bromine water yields gluconic acid. This reaction confims presence
of aldehyde group because for formation of gluconic acid free aldehyde group must be present.
CHO

(CHOH) Br/HO
(0)
(HOH)
CoOH-G

0 2 phaiDf

,
HOp CH,OH
Glucose
2HOH
Gluconic A.cid 0-
13. (C)

E T
Arginine consists of amine group
functional group.
as HN=C-NHECH2 -CH-C-OH

obizeaosbiy J1 dirwa3 oeouig no

ne
bhelbizg eiNH lbibbla kint nl

C (biaoilzod
Hence is basic in nature.
HOC
14. (C) 15. (A)

HT 16. (D)

17.(C)
Stachyose is tetrasaccharide. HO HO

M
(6)
OH
HOH unamn louf0
(4)
(ettrots todJatsi1
H/H
H oGtoliMA)OO-shgilsbdioo
OH
 CHOH,
(368) MHT-CET Exam Questions

n
18. (D) COH
Or Giucose
ÇHO

H-OH
CHOH
is o
(A)
Possible
.:2=16
nu

s
Glyceraldehyde

e
19. (A) 4C)
20. (A) same molecule called as
negative ion shown with the

s
Zwitter ion: When both positive and
- COOH]
zwitter ion. e.g. NH-CH, -CO0° [NH CH2

21. (A)
22. (B)

b t Am

u
Uracil is not present in DNA. 35.(B)

o
23. (C) 24. (C)
25. (B)
H-

D
Hydrolysis dil.HNO, Saccharic acid
Maltose- Glucose excess
HO-

1
26. (B) one molecule each of
an acid or enzyme lactase gives
Lactose on hydrolysis in presence of
H
2
glucose and galactose.

0
or lactase D-(+)Glucose D-(+)-Galactose
Lactose

2
27. (D)
28. (D) S

T
CigH2O16+ 2H,0 CH120g + CHi206 +CHi206 36. (B
Fructose Galactose

E
Raffinose Glucose

C
29. (C) forming gluconic acid.
bromine water, it undergoes oxidation,
When glucose is treated with
group is oxidised to carboxylic acid).
(In this aldehydic

T
çOOH
CHO
(ÇHOH),
(CHOH),+[0]

H
37
CH,OH CH,OH

M
Gluconic acld
Glucose
30. (C) isomers 2
Possible number of optical
chiral carbon atoms)
(n- No. of asymmetric/
23 8
31. (D)
Glyceraldehyde CHs03 (Aldotriose)
 32.(C) Biomolecules (369)
CHO
ÇH-N-OH
(CHOH) NH,OH(CHOH)

CH,OH
Glucose
CH,OH
Glucoxime

o n
33. (A)
Possible number of optical
isomers
is
s
2
(n No. of asymmetric carbon
2-16 atoms)

e
34. (C)

NH,
HO-CH+CH
NH,

t s
b
COOH
cOOH
Amino acid

u
Serine
35. (B)

H-C-OH
HO-C-H
ÇOOH

D o
H-C-OH
9mOt (No. of oxygen atoms

2 1 8)

HOD
H-C-OH
COOH
Saccharic acid
2 0 IHOHO

HO HO
ulos noouli

36. (B)

ÇHO
E T OHO

C -CH,5H
CH-C an. ZnC2
(CHOH)+ 5 A

T
CHS- -CH,nt goog lond
CHOH CH-Opentaacetate
Glucose

H 37. (C)

H C,H,0, +C,H,0,

M CHO+H,O(Invertase)
Sucrose
(342 g)
cose Fructose

342 g of sucrose gives 180

g of
Glu

glucose
(180 g) (180 g)

180x68.4 -36 g of glucose

68.4 g of sucrose gives 342
 1sa7
surse
370)MHT-CET Exam Questions
38. (C)
Globular protein - Insulin
Gbogen
Fibrous protein -Collagen, Fibroin, Myosin

n O
39. (D)
SUCrose

o
40. (C) gl
acthot
HO1

is Su

OR

e s IA)

s
Amylo
p-1,4-9lycosidic link

41. (C)
Glucose reacts with hydrogen cyanide to form glucose cyanohydrin.
CN

b t 2(C)
Gluco
also e
CHO
CHOD
a,OH
CHOH

HOHD
CH,OH

o u HO-2-H
(8),2
3.B)
Sacc

D
Glacose Gtucose cyanohydrin

42. (A) HO
When glucose is treated with bromine water, it undergoes oxidation, forming gluconic acid.

1
(In

this aldehydic group is oxidized to carboxylic acid). HO-0-8

2 It
CHO çoOH
HO--

0
(CHOH), [O] B0 (ÇHOH), 4.(B
HOOD

2
1 CH,OH CH,OH
bioe armisae
Glucose Gluconic acid

T
43. (A)
44. (C) CHO cOOH

CE
When glucose is treated with bromine water,
it undergoes oxidation, forming gluconic acid.
(In this aldehydic group is oxidized to
carboxylic acid), which shows that the
(CHOH),

CH,OH
+[0] S/O (CHOH),

CH,OH

T
carbonyl group in glucose is aldehyde group. Gluconic acid 55
Glucose
t).TE

H 45. (C) CH,OH

O. -0H0. H,2
M
HOH,C

HO -o -

Glycostdic
H HO CH,OH

OH Inkage OH
a-D-Gluco pyranose topPbFructo Furanose
38
)Sucrose
 46. (D) Biomolecules (371)

47.(D)
Sucrose is a non-reducing
sugar (free aldehydic
group cannot be produced in solution).
4s.(C)

n
Glycogen is a branched biopolymer
consisting of linear chains
of glucose residues.

o
49.0

is
Sucrose on hydrolySis in the presence
each of glucose and fructose. of dil. acid or the enzyme invertase gives one molecule

s
C2H2O1u +H20or
Sucrose invertase CgHi20, + CHi20%

e
D)Glucose D()Fructose
50. (D)

51. (A)

52.
Amylose is a linear polymer of glucose and it is water soluble.
(C)

t s
Amylose has a- linkages.

b
Glucose does not undergo condensation with 2, 4-dinitro-phenylhydrazine which shows that it
also exists in cyclic form.

53. (B)
Saccharic acid also called Glucaric acid.
OH
o u
TOlo agde

D
-

OH
HO

1
OH OH
HO,B
Ithas 2 carboxy and 4-OH groups.
54. (B)

0 2 -00

2
H,C NH NH -2-VE
=o

E T
Thyminetan ti nibia ai h ot a0U
Uracil
iead Ibns oibton S and gef
3uuqu
AT02

55.(A)
C
se0oul o
ano 3209
um ano slo ano kory
11 b92 loubyti zi 80edate
to of
980alsg to 8slou us
&,ok
slom seo

T
gd zo seo qtoetn 1o calot
CHO
ÇHO vig irelonbCH,COOH (A)
(CH,CO), 0, (CH-O-t-CH,), +
HO

H (ÇHOH)
CH,OH
CH,-0-G-CH,

M Glucose

t 1s observed that,
there is
Glucose
formation
pentacetate
of
pentacetate so there must be five
hydroxyl groups

present in glucose.
 MHT-CET Exam Questions
(372)
56.(D)
(C0
HO
CHO N-OH
H= H
(CHOH), NHOH(CHOH)
CH,OH CHOH

o n H-

Glucose Glucoxime
lucose reacts with NH,OH to form an oxime which confirms the
is
presence of a carbonyl groun

s
in glucose.
57. (A)
Isoleucine: H,N-CH-COOH
HC-C,H,
s eE HO
H

R CH-CH
CH,
CH
H
ndh.k
b
iw msasb/it. 3 oa1sbry to
tyt paeire
t
danu da0sig
ele
H

58. (A)

o u
Erythrose is a reducing sugar, i.e. it has free aldehyde group which can reduce Tollen's reagent
and Fehling's solution.
H-

D
Bof

H- -OH Erythrose 63.(A

1
OH
H,OH H
59. (B)
çoo
0 2
2
HN-C-H
CH 64.(E

E T
COO
Aspartate -Asp has 2 acidic and 1 basic groups. So it is acidic in nature.
60. (A)

C
When one mole of stachyose is hydrolysed it gives one mole of glucose, one mole of fructose
and 2 moles of galactose.

T
So, 2 moles of stachyose on hydrolysis gives 4 moles of galactose.
61. (A)
0-E

H
CH
OH )-0-HD 0,89
Erythrulose has in total 3 -OH and one C= O groups

M
993010
gor
H--OH
o CH,OH
 62. (C) Biomolecules (373)
ÇHO
COOH
H--OH H--OH
HO-C-H HNO,

n
HO-C-H
H-C-OH
H--OH
H--OH
CH,OH
H--OH
COOH
is o
Glucose
COOH
Saccharic acid
ÇOOH

e s
H--OH
HO-C-H
HNO
H-C-OOH
HO-CH
t s
H--OH
H-C-OH neee
H--OH
H-C-OH
u b
CH,OH

Gluconic acid
CoOH

D o
Saccharic acid

Both give saccharic acid due to the presence of

1° alcoholic group in glucose.

63.(A)

2 1
0
HN OH

Side Chain
NH
2
T
Lysine amino acid

2 E
64.(B)

C
CHO
H-C-OH

HT2
2°
HO-C-H
H-C-OH
HC-OH
number of 2° 'C'atoms
ta lsC
4
obruilaoneononm u
abteieaboain

M CH,OH

Glucose
 p (374) MHT-CET Exam Questions
Classifi7
65. (C)

CH
OH -OH

o n Nat
Sen

is
CH, NH, SyT
EX
Leucine

s
group, it 1s neutral. Classi
and one -NH
Since leucine has one -COOH group

66. (D)
çoOH

s
HOU e
t
H-C-OH
CH,

b
Cla
Lactic acid

67. (D)
CHO CHO

o u HO

D
H
H- -OH HO
bre stmoault
C
i uub bior atlaasa ovet
CHOHngoa otoileCH,OH
D+Glyeerakdehryde

2 1
L-Glyceraldehs

Glyceraldehyde has only one asymmetric carbon atom.

68. (A)
HO
(CHOH),
2 0
H,C-(CH,), - CH,
rtisr sbi

CHOH
gucose
E T n - Hexane OP

C
It confirms that, glucose has 6 'C' atoms in a straight chain. HO-H

HT 69. (C)
Stachyose is tetrasaccharides, yields four monosacharide units on hydrolysis.
Stachyose>1 Glucose+ Fructose+2 Galactose.
1
EHO--H

M
 15. Introduction
to Polymer Chemistry
ImportantFormulae and
Shortcut Methods
Classification on the basis of source

n
or origin
Natural Polymers: Examples

o
-Silk,
Semi-synthetic polymers: Exampleswool, cotton, linen, natural rubber, etc.

is
Svnthetic Polymers: These are Cellulose acetate rayon, cellulose
nitrate, etc.
man-made polymers.
Examples-Nylon, terylene, neoprene,
etc.

s
Classification on the basis structure:
.
e
Linear or straight chain polymers Examples- PVC,
high density polythene, etc.

s
Branched chain polymers: Examples- Low density polythene, polypropylene, etc.
.Cross-linked polymers: Examples Bakelite,melamine, etc.
Classification on the basis of mode of polymerization:
Addition polymerization: Example- Poly vinyl chloride
b t
Condensation polymerization : Example- Terylene/Dacron
Ring opening polymerization: Example Nylon-6

o u
D
Classification on the basis of intermolecular forces:
intermolecular forces of attraction
Elastomers: These are the polymers having very weak

1
rubber, buna-S, buna-N, neoprene,
between the polymer chains. Examples Vulcanised
-

2
etc. are long and thread
for making fibers as their molecules
Fibres: These polymers can be used

0
like. polystyrene (terylene), etc
Examples- Polyamide (Nylon-6,6),

2
heating.
be easily moulded by
Thermoplastic polymers: These can polyvinyls, etc.
Polystyrene,
Examples- Polyethylene, thermosetting polymer becomes hard on heating.

T
Thermosetting polymers: A
formaldehyde resin, etc.
Examples- Bakelite, Urea

E
monomers:
the basis of type of different
Classification of polymers on repeating unit
only one type of

C
Homopolymers: which have Polyacrylonitrile, etc.
Polypropene, Nylon-6,
Examples- Polythene, more types of
repeating unit

T
two or
:
Copolymers which have
etc.
Examples- Buna-S, Buna-N, biodegradability:

H
basis of
Cassification of polymers on - PHBV, Nylon-2-nylon-6, ete.
the
Biodegradable : Examples
Examples-Bakelite, Nylon-6,6,
etc.

M Non-biodegradable:

Some Important polymers

1. Natural rubber It is
linear polymer
of isoprene
(2-methy1-1,3-butadiene), cis-isomer,

exhibits elastic property

 Po
(376) MHT-CET Exam Questions
2.

Polythene p
o9ot nolb30071
i. Low density polyethylene (LDP)

CH-CH
Traces of O2
peroxide at 350-370 K,
LDP ad s0bsoha
o n
1000-2000atm
ii. High density polyethylene (HDP)
is
CH- CH2
333K-343K
6-7 atm,catalyst
HDP

e s
3. Teflon

nCF =CR
(Tetrafluoroethene)
Polymerization CE,
Peroxide
-

(Teflon)
CF ntahsniog

t s
hoini 7

4. Polyacrylonitrile
oieurvlog
o osolga
anbesdetlug irobk
doishearlog aniteusbro
u b
ke nboano ieud pilt n ueiteofivan

o
Polymerization
nCH=CHCN- Peroxide
fCH2- CHnitsissn doyariosgo gni
(Acrylonitrile)

D
CN
(Polyacrylonitrile) ta ateed ons no nohaoiiel

5. Polyamide polymerse
1
grgnieai drutrylg sit it sypit moiltu

2
i. Nylon-6,6

0
HOOc(CH) coOH+nHN{CH),NH, a,myint edT sidi
(adipic acid) ghexametbylene

2
diamine) ai0yg-29lgn
TO4CH-OHNACH, NH,]

T
eloq
(aylon salt) uitotoa

E
| 553K high iteLS1gilenft-ga
tototol pressuree a zALd adt ao m9Rreloq lo nordas@lia)

C +CH),&NH(CH),N
u g(aylon 6,6)
H
o-q

HT ii. Nylon--6

HN
-si 2-uf-1l.

M fNECH co
S35343K
dsbryyabolt-nof
(Nylon 6)
910ce Auns(- caprolaotam)
 Polyesters Introductionto Polymer
6 Chemistry (377)
Example: Terylene or Dacron

aHO-CH-CH,- OH+nH-o-
(ethyleneglyeol)
O0.H
o n
is
(terephthalic acid)
420 460 K zno aoetote-amtimony
triexide catalyet

s
aHO

e
to-CH-CH-O-

(terylene or dacron)

t s
b
7. Buna-S rubber

CH,- CH

u
CH CH+ CHCH CH,

o
ysiraln 1.3 butodiene styrene
(75 %) (25 %)

mCH, CH CH CH -
-
CH,- CH- CH CH,
(SBR)
D
- CH, -
H -CH, CH, - CH - CH

8. Neoprene

2 1
Pohymardrtan CH,- -
0
nCH--CH CH CH- CH
(Neoprene)lg d
ta (chloroprene)

9. Biodegradable polymers
2
1.

E T
PHBV

nHO-CH-CH-coOF)+
aHO -CH-CEH-coOH) 10 abio belleyr

C
CH CH, CH, armgetot

HT f:0--a,
,
(-hydroxybutyric acid) (B-
hydroxy valeric acid)

M 3tobentedy
2. Nylon-2-nylon-6
el

Glycine+8-amino caproic acid>

PHBV

Nylon-2-nylon-6
afoltone
80RL TD-THI
 2010
MHT-CET pe
Isa
A)ethylenegl
Terylene
(Cethylene g
(378)MHT-CET Exam Questions 2012
polymers
Some Commercially important Applications MHT-CET

n
Monomer
Polymer structure naturalrv
Trade name lenses, paint, security 3-buta

o
methyl The
Perspex/acrylic barrier, LCD screen,

is
CH, 4 (A)1,
Nylon-ó,61s
Glass methacrylate
f cOOMe shatter resistant glass (A)polyster
coOM 5
adhesives, rubber belts,
Buna N Butadiene and
Acrylonitrile
fH,0-CH-CH-CH CH,-CH
N
shoe soles,
gaskets

e s MHT-CET

Whichis
20
th

s 6. (A)CH;
=
water pipes, rain coats,

t
PVC (polyvinyl vinyl chloride
CH, CH flooring

b
chloride)
Polyacrylamide gel (C)CH
Polyacrylamide Acrylamide CH, CH

u
cONH used in electrophoresis
CONH,
Nylon 1s

o
unbreakable dinner 7.
(A)polys
Ureaformaldehyde a. urea
- CO - NH - CH, ware, decorative

D
resin b. formaldehyde NH MHT-CET
laminates
Identify

1
8.
a. ethyleneglycol| paints and lacquers (A)Pol
Glyptal
CH- 0OC co

2
b. phthalic acid 0-CH-
9. Which
a. bisphenol electrical and (A)Bal

0
Polycarbonate
b. phosgene telecommunication

2
MHT-CE
hardware, food grade
CH 10. Corre
plastic containers

T
(A)It
Thermocol (made Styrene non-biodegradable (B)It
CH,-H L

E
from airfilled thin styrene can leach when (C)I
walled beads of heated. Therefore, it is (D)I

C
polystyrene banned.
MHT-C

11. The

T
Multiple Choice Questions
(A)

H
MHT-CET 2005 MHT4
1. Name the compound/compounds used in preparation of nylon-6,6. 12.

M
(A)e-caprolactum (B) hexamethylene diamine and adipic acid
(A
(C) dimethyl terephthalate (D)hexamethylene diamine
MHT-CET 2008
C
13.W
*2. Rayon is fe--0oh bi iggssnisr a A
(A)natural silk (B) artificial silk (C)regenerated fibre D) synthetic fibre 14.W
 MHT-CET 2010 Introductionto Polymer
Chemistry (379)
3.
Terylene is a polymer obtained from
(A)ethylene glycol and glycerol
C) ethylene glycol and terephthalic acid (B) ethylene glycol
and glyceradehyde
(D)none of these
MHT-CET 2012

4 The
natural rubber is the polymer of
3-butadiene

o n
is
(A)1, (B)polyamide
(C)isoprene
(D)none of these
5. Nylon-6,6 is a
(A)polyster (B)polyamide

s
(C)polyacrylate (D)none of these

e
MHT-CET 2013

s
6. Which is the monomer of neoprene in the following?
(A)CH CH- C= CH (B) CH, =Ç-CH=CH,

(OCH, -f-CH - CH, (D)CH

H,
CH - CH

b CH t
u
CI
Nylon is an example of

o
7.
(A)polyster (B) polysaccharide C)polyamide (D)polythene

MHT-CET 2015
8.
D
Identify the heteropolymer from the list given below.

1
(D)Nylon-6,6
(A)Polythene (B)Nylon-6 (C)Teflon
does NOT soften on heating?

2
*9. Which polymer among the following polymers
(C)Polystyrene D)PVC
(A)Bakelite (B) Polythene

MHT-CET 2016
10.

2 0
ebe oliravi 1(C

Correct statement for thermoplastic

(A)It does not become soft on
polymer is
heating under pressuree

T (B) It cannot be remoulded

(C)It is either linear or
branched chain polymer

. CE
(D)It is cross-linked polymer
MHT-CET 2017Oo-
making handles of
is
cookers and frying pans (D)polyvinyl chloride
The polymer used in (B)nylon-2-nylon-6 (C) orlon

T
(A) bakelite
MHT-CET 2019 semi-synthetic polymer?

H Which among the following

(A) Cupra-ammonium silk
is NOT a
(B) Terylene
(D) Viscose
Rayon

M (C) Acetate Rayon

13. Which of the following
(A)Buna-S
14. Which of the
polymer
(B) Gutta
is used in
percha

lowing is a natural
polymer?
paints?
(C) Melamine

(C) Nylon
(D) Novolac

(D)Linen

(B) Teflon
(A)Orlon
 Which
ar
17
CH
(380)MHT-CET Exam Questions to class of (A)
on cooling, belongs
which becomes soft on heating and hard
15. A polymer (B) fibers
(A) thermoplastic polymer thermosetting polymer Whicha
(D)

n
(C) elastomer (A)PVC
show cross linking it?
in 28.
among the following polymer does not Nylon-6 (D) Vulcanized Rubber Orlo
ch

o
*

(B) Melamine (C)

(A) Bakelite

is
Zieglar-Natta catalyst? Which
is prepared by using
17. Which of the following polymers (B) High density polythene 29.(A)HD
(A)Low density polythene (D)Poly tetrafluoro ethylene
(C)Polyacrylonitrile Which
18. Natural rubber
(A) isoprene
is a linear polymer of
(B) 1,3-butadiene (C)vinylchloride (D) styrene

e s 30.
(A)
(C)PH
Ure

s
19. Novolac is obtained from
(A) Phenol (B) Tetrafluroethylene Which
D) Phenol and formaldehyde 31.
(C) Melamine and formaldehyde 80 (A)H
20. Which of the following polymer has ester linkage?
(A) Bakelite (B) Nylon (C) Terylene

b t
(D) PVC C)D
Whic
32.

u
MHT-CET 2020 (A)T
21. Which of the following monomers is used in manufacture of Neoprene rubber (B) T

o
(A)Styrene (B)2-Chlorobuta-1,3-diene (C)T
(C)1,3-Butadiene (D)Isobutylene (D)1
22. Identify addition polymer from following.
(A)Orlon
D
(B)Nylon-6,6loor3 rsbt
33. Whi
(A)
t
1
(C)Polyester (D)Urea formaldehyde polymerio
34. Ider

2
23. Which among the following is a linear polymer? (A)
(A) Vulcanised rubber (B) Polypropylene (B)

0
(C) Melamine (D)Polyvinylchloride (C)
24. Which among the following formula represents the s-amino caproic acid? D)

H,N-(CH2)s - COOH 2 s toe o

hihoim
NH2 35. W
(A

T
(A) (B)H,N-CO-CH2-CH C
ero
E
COOH 36. Id
C) HO-CH, CH- CoOH (D) H,N-CH, - COOH (A

C NH2 C

T
*25. Which of the following polymers is prepared by using phenol? 37. W
(A) Bakelite (B) Neoprene (C)Teflon (D)Melamine

H
26. Which polymer is obtained from monomers 3-Hydroxybutanoic 38. T
acid and 3-Hydroxypentauo
acid?

M
(A)PHBV (B) Nylon-2-nylon-6 (C) HDPE (D)Dextron

39.
 among the following
among Introduction to Polymer
27. Which monomers
is used to prepare Chemistry (381)
CH3 Teflon?
(A)
CH CH (B)CF CF2
(C)CH CH-CI (D)CH
CH -CH CH

28. Which among the

(A)PVC
following is a cross-linked
polymer?

o n
is
(B) Vulcanized rubber
(C)OrlonotC a (D)Polypropylene
oWhich among the following polymer is
used

s
(A) HDPEltg
to make crockeries?
(B) Buna-N
(C)Buna-S (D)Melamine

e
40. Whichamong the following is an
example of addition polymer?
(A)Urea formaldehyde

s
(C)PHBV (B) Teflon
cbreina rit D)Nylon-6,6

t
Trc
31. Which of the following compounds contain-co-NH- linkage?

b
(A)Hexamethylene diamine (B) Vinyl cyanide
(C) Dimethylterephthalate
olep
(D)e-Caprolactum
32. Which of thefollowing properties is of thermoplastic polymer?
(A) These can't be remoulded.
(B) These are either linear or branched chain polymers.

o u bo retgd one

D
(C) These can't be recycled.
D)These do not become soft on heating.

1
33. Which among the following polymers belongs to the class elastomers?
(A) Nylon (B) Polystyrene (C) Neoprene ( D) Bakelite

0 2
34. Identify the monomers used in preparation of PHBV polymer.
(A) 3-Hydroxybutanoic acid and 3-hydroxypentanoic acid
(B) Lactic acid and glycolic acidA0)

2
(C) Styrene and glycolic acid
(D) Glycine and o amino caproic acid olrA

T
rubber as a monomer?
35. Which of the following compounds is present in natural
(A) 2-Methyl-1,3-butadiene (B) Styrene

E
(D) 1,3-Butadiene
(C) 2-Chloro-1,3-butadiene
36. Identify the catalyst used in the manufacture of high
density polythene td

C HHo (B) V20s

(A) Co-Th alloy A(C>Hs)»
T1CL along with
iCD)
T
(C) MnO
ester linkage in it?
following does NOT contain ()D)Nylon-2-nylon-6
7. Which polymer among the

H
C) PHBV
(A) Dextron (B) Dacron
polymers?
properties is of the thermosetting
8. Which of the following

M (A) These are cross linked polymers. bu af lo

dd nov
(B) On heating these become soft,
(C) These can be remoulded.
(D)These can be recycled.
used as synthetic leather? (D)Polystyrene
polymer from following is (C)Polythene
hich
(A)PVC (B) BakeliteA()
 Which

56.
A)Te
(ON
(rs (382) MHT-CET Exam Questions Guodgo fs
in preparation
of Novolac, Methanal Whic/
40. Identify the monomers used (B) Phenol and
(A)Phenol and Ethanol D)Urea and
Phenol 57.(A)O
()N
n
C)Urea and Methanal polymers?
belongs to class thermoplastic
among the following polymers D)Polythene Whi
Which R

o
(C)Terylene
(A) Bakelite (B) Neoprene 58.(A)

is
used for making
handles of cooker? 1(1
among the following polymers is (D)Novolac
2. Which
(B) Acrilan (O(C)Melamine
(A) Bekelite Wh

s
59.
43. Identify thermoplastic polymer from following. D)Nylon-6 A)
C) Bakelite

e
(A) Neoprene (B) Polystyrene u
preparation dacron?
0

W7
following catalysts is used in the

s
**which among the antimony trioxide 60.
(B) Zinc acetate and (A
(A)Oxygen
olte t D)Titanium chloride and triethyl aluminium

t
(C)Peroxide
neoprene?
as monomer for the preparation of 61.

b
among following is used a
45. Which the
(C) Chloroprene (D)Glycine A
(A) Styrene (B) Isoprene
46. Which among the following is biodegradable polymer?
(A)PHBV (B) PTFE
47. Identify the use of Buna-N.
(C) Buna-N

giog sifo hsi

o u (D)PVCunoi.2E

shoes
92011 (8)
oarT (
62. I

D
(B) In making soles of
(A) For making inner tubes of tyres chemical containers
(C) To prepare bubble gums (D) To manufacture 63.
48. Which among the following polymers is a copolymer? givoliot.at
atormis tlai tt
(A) Polystyrene (B) Nylon-6)(C)

2 1 Polythene (D)
49. Which among the following polymers is obtained first by formation of
ABS plastic
salt by neutralization and
bior iormindyzobyh-E (0

0
then by step growth polymerization?atgyx
(A) Nylon-6 (B) Nylon-6,6 (C) Novolac ilosis (D) Polyester8 64

2
polymerisation?
50. Which among the following polymers is obtained from CH; CH-CN by
=

(A)Teflon (B) Neoprene (C)Orlon D)PVC

T
catalyst? 6
51. Which among the following polymers is prepared by using Zeigler Natta
(A) LDPE (B) HDPE (C) Orlon (D) Dacron

CE
52. Which of the following compounds is used to prepare orlon?a
(A) CH2 C(CH)2
O
(B) CH CH- CN
egis0 pis giaRBl
golle -o3t4)
0

T
(C) HOOC-(CHa)4- COOH D) H;C= CH CH CH2

53. Which of the following polymers is obtained from chloroprene? oe 19nnoq o

H (A) Butyl rubber (B) Neoprene rubber (C) Buna-S Buna-N
(D)

M 54. Which of the following polymers is used to obtain adhesives?l et 9d

gr

(A) Buna-N (B) Neoprene rubber (C) Melamine slo D) Buna-S

sbioog

55. Which among the following catalysts is used in preparation of terylene?

(A) Benzoyl peroxide (B) Oxygenrollste.t onho
(C) Zinc acetate and antimony trioxide1 (D)Alkali
 Which from following
foll polymers is used Introduction to Polymer
56. Chemistry (383)
to make
(A) Terylene blankets?
(C)Nylon-2-nylon-6 (B) PAN
(D)Nylon-6,6
57.
which among the folowing polymers
does NOT contain
(A)Orlon amide linkage

n
in it?
(B) Urea formaldehyde polymer
(C) Nylon-6,6
(D) Nylon-2-nylon-6
Which amongthe following polymers can NOT be remoulded?
(A) PVC (B) Polystyrene (C) Polythene (D) Bakelite
is o
s
cO Which among the following polymers
is obtained from styrene and 1-3-Butadiene?
(A) PHBV (B) SBR

e
(C) Buna-N (D) Butyl rubber
inirum

s
60. Which of the following polymers contain ester linkage
(A) Neoprene (B)PHBV (C) Orlon (D)Buna-S

61. Which of the following polymers is used as insulation for cables?

(A) Teflon (B) LDPE

b t
(C) Neoprene rubber (D) HDPE

62. Identify the natural polymer from following.

(A)Bakelite
(C) Linen
o
(B) Cuprammonium silk
(D)Acetate rayon u
63. Which of the following pair of compounds
(A)(CH3)2 C = CH2 and CH2 = CH CN
D
is used as monomers for bakelite?

ralization and
(B) HCHO and CsH OH
(C)HCHO and HNCONH2
(D)CsHCH= CH2 and CH2 =

2
CH1 - CH = CHog etym ena loputoure lin

nenisanon (A) 4

2 0
64. The number of-NH2 groups present
(B) 1
in a molecule of melamine is
C)3
polymerisation of n moles of areylonitrile.
D) 2

T
65. Identify the ploymer obtained by (C) PVC (D) Teflon
(B) SBR
(A) Orlon abinsa fo ounoetng h los

E
log ol zgjpolsd nollU gal linkage.
polymer from following that contains amide D)PHBV
b6. Identify the C)Nylon-6,6

C
(A)Dextron 30
(B) Terylenent
addition polymer?
polymers is an example of

T
07. Which among the following (B) Nylon
(A) Ureaformaldehyde polymer D)Dacron puoe
ob ametoglog

H balaai bia babla

C)Polythene
heteropolymer ?
polymers is a D)Polystyrene
68. among the following C)Polythene

M ich
(A) Buna-N (B) Nylon-6

among the following

(A)Neoprene rubber
() Styrene butadiene rubber
polymers is used to manufacture chemical
(B) Buna-N
(D) Butyl
rubber
containers?

shri grrubud
nn itoe
 natural
po
Linen15

n
whic
(384) MHT-CET Exam Question polymer
SOLUTIONS 1B(A) becomes

o
The not

is
does
1. (B)
ypec
2. (C) 15
Rayon is a regenerated fibre. (Nylon-6

s
18.
3. (C) known as
acid forms the polymer terylene (also

e
Ethylene glycol on reaction with terephthalic 17.(B)
dacron) which is used as synthetic fibre. 21.(B) monomer u
4 (C)
Natural rubber is a polymer of isoprene

nCH,-CH-Ç= CH mraODfCH2- CH== Ç-CH2

t s The

CH, =C

b
n
CH, iatiyCH, 2-Chlorobut
n

u
Natural rubber

5. (B)
hexamethylene diamine. It is a polyamide. 22.(A)

o
Nylon-6, 6 is a condensation polymer of adipic acid & addit
Orlon is
6. C) of chloroprene which is chemically

D
Neoprene is synthetic rubber and is a polymer 3. (D)
2-Chlorobuta-1,3-diene. i. Linear pe
ii. Branche

1
= CH
nCH=C-CH CH,-¢=CH-CH ii. Network

2
CI
Neoprene 24. (A)
Chloroprene

0
7. (C) 26. (A)
The general structure of any nylon polymer is HDn gHO-H 20 PHBV is ol

2
acid.

R--N-R OH

T
CH-CH-

E
Amide linkage (a
3-Hydrox
Because of the presence of amide linkage, nylon belongs to polyamides.

C
aplog sdiftrsb1.oa 27.(B)
D)
Heteropolymers are composed by joining of more than one kind of monomers. Nylon 6, 615
formed by combination of adipic acid HOOC-(CH)4-C0OH and hexamethylene diamine n

T HN-(CH)6-NH2 Tetra
28.B)
9. (A)

H
relof( e
Thermosetting polymers do not become soft on heating under pressure, hence canno0 30.(B)
remoulded and recycled.
e.g.Bakelite

M
nCF
While polythene, polystyerene and PvC are thermoplastic polymers. Tetrafll
10. (C) comes 1.(D)
Thermoplastic polymer is a linear or branched polymer which can be remouldea an
soft on heating under pressure.uE 4.(A)
h
11.(A) 12. (B) 13. (D)
O
C
3-Hyda
 Introduction to Polymer Chemistry
14.(D) (385)
nen is natural polymer while Orlon,
Teflon and Nylon
are synthetic polymers
15.(A)

n
The polymer which
ne
also not become softbecomes soft on heating is thermoplastic
on heating is called polymer while the polymer which
thermosetting polymer

o
kam

is
(C)
10-lon-6 is type of fiber polymer.
All other are examples
of cross linking polymer
17.(B) 18. (A)

s
19. (D) 20.((C)
21.(B)

e
The monomer used is chloroprene
(2-chlorobuta-1,3-diene)

e.Itisaplya
n CH,-C-cH=CH2
naoylpeoideFCH,-C=CH-CH,t

t s
b
2-Chiorobuta-1,3-diene
Neoprene
22. (A)

u
hich
is chemialy Orlon is addition polymer and others are condensation
polymers.

o
23.(D)
i. Linear polymer - Polyvinylchloride

D
ii. Branched chain polymer Polypropylene
ii. Network or cross linked polymer Vulcanised rubber, Melamine.

1
24.(A) 25. (A)

2
26. (A) fanliero/)
PHBV is obtained by the copolymerisation of 3-hydroxybutanoic acid &3- hydroxypentanoic

0
acid.
OH

2
OH
CHCH-CHcoOHCH,-CH CH-CH-coOH fo-cH-CH--oCH-CH-
CH, CHCH,

T
3-Hydroaybutanoic acid 3-Hydroxypentanolc acid
lbPHBV

E
gonli
27.(B)

66s Catalyst
-CE n (A)

C
n CE = C Pressure fCRTeflon
Nyilar
Tetrafluoroethene High
mers. diame
Anetayiene
28.(B) 29. (D)
penos e al-enu
T
iiinolgs bob aosiheg-30
30.(B)

H
Polymerization
nCE=
CF Peroxide
f CE-CFf.
Tetrafluoroethene Teflon

M
31.(D) 33. (C)
32.(B)
baaa 34.(A)
and
ulded OH ogo0g
CH-CH,-coOH CH CH-CH-CH-COOH {cH-CH-; -0-CH-CH
CH, CH,CH,
3-Hydroxypentanolc acdd PHBV
3-Hydroaybutanolc actd
 (B)
386)MHT-CET Exam Questione
35. (A) aH,N-
H,

n
CH,
n CH,-C-CH-CH,Polymerizaio CH,-C-CH-CHt g

36. (D)
2-Methyl-1,3-butadiene
(lsoprene)
Natural rubber

iso
37.(
Nylon-2-nylon-6 has polyamide linkage init.

e s step

s
38. (A) First
39.(A)
40. (B)

t
50. (C)
OH OH OH Orlon 1s

b
CHOH CHOH HOH,C CHOH
cRo
O OY =(

u
n CH,
Phenol) Formaldehyde)miabit eif 0CHOH bcH Ou

OH
CHOH
O
d

D
O
o CH, 51. (B)
The cat

1
polyethe
(Novolac)

2
41. (D) 42. (A)lbide 43. (B) tr44. (B) bon nudo et VRH 52.(B)

0
45. (C)
nCH,
C

2
CHO Acryl
n CH C-CH=CH, benzoyl peroside CH-C-CH-CH,f.HO07183R39
2-Chlombuta-1,3-diene

T
Neoprene
(Chloroprene)

E
46. (A)
olta 53.(B)

C
47. (B)

Buna-N is a copolymer of 1,3-butadiene and acrylonitrile.

nH,C

T
It is used in making soles of shoes.

H
48. (D) abion9 sulooula C
Polystyrene is a homopolymer of styrene.
Nylon-6 is a homopolymer of caprolactum.. 54.(A)

M Polythene is a homopolymer of ethene

ABS plastic is a copolymer of acrylonitrile,
butadiene and styrene
Buna-1
 Introductionto Polymer Chemistry (387)
49. (B)

nH,N-(CH,), NH, - + nHO-C-(CH,), --OH

-H,O

o n
(CH,)-C- NH(CH,), - NH-
is
n
First step by neutralization and then by step growth polymerisation.

e s
HOH
50. (C)

Orlon is a commercial name of PAN Polyacrylonitrile whose monomer is Acrylonitrile.

t s
n CH, = CHCN CH,-

u b bolt

51.(B)
The catalyst in Zeigler Natta
polyethene (HDPE).
PAN

D omncgoog01
(C;Hs)3Al + TiCl4 which is used to prepare high density

1
(82
52.(B)ommo od giog siedlmdoq gnitseumo/i r ilelea
nCH, = CHCN-
Polymerization

Acrylonitrile
sn51
Peroxide
To

0
190loqo3 2CH, - CH

al :(9N Jadiy ansibetud sasngie to 2-tu

83-13 0-8- 2 Orlon/Polyacrylonitrile

53. (B)

E T Polymerisation
-1
-CH

C
CH,
nH,C=C-f=CH,-
CI H n (Et) 0

T
Neoprene
Chloroprene Synthetic rubber

H 54. (A)

Buna-N is used in the preparation of

adhesives or as a pigment binder. H

M (/EH
 (388) MHT-CET Exam Questions
55. (C)
(CH,COO),Zn
n[HO-CH, - CH, -OH]+n HO

n
Sb,o,

o
500 K

is
Fo CH,-CH, -0-C

e s
s
Terylene
Catalyst used is zinc acetate and antimony trioxide.
56. (B)

b
PAN Polyacrylonitrile is used in making blankets (artificial wool).
57. (A) t amo

u
Orlon:

o
2CH,=CHCN-
N

It has -CN linkage only.

Polyacryonire

dai T D
H:27- e5
8)12

1
glens
58. (D) 0H)sorog
Bakelite is thermosetting polymer. These

59. (B)

0 2
polymers are rigid and cannot be remoulded.

2
Buna-S or styrene butadiene rubber (SBR):
It is a copolymer of styrene & 1,3-butadiene.

T
egirrklanodnd
CH-CH,
CH-CH CH-CH-CH-CH

CE Syrene
n CH
CH-CH=CH50
-13-Butadiene
SBR
(Buna-5

T
-9,H
60. (B)

H
M 0-CH-CH, -C-0-CH-CH,-C
CH O

(PHBV)
CH,-CH,
 Introductionto Polymer Chemistry
(B) (389)
61DPE
LDP is most commonly used in the insulation of cables
flexible and poor conductor of electricity. because it is chemically inert, tough,

62. (C)
Linen is natural polymer obtained from

n
flax plant.
63. (B)
OH OH

CH,OH HOH,C
OH
CH,OH
OH
is o
s
or base CH,OH

e
Phenol Formaldehyde
H,OH

s
CH,OH
Structure of Bakelite

t
OH OH QH
www.-H,CC

b
CH CH CHww

CH CH,
o CH, u E83-R

QH
D
w-H,C CH
2 1
OH
CH
OH
CH

CH
2 0
64. (C)

E T
C S2oagt3eug baiu oluse a ad

T
H,N N NH,e 9d oei

H
Melamine
Number of-NH2 groups3

M
65. (A)
Polymerization CH,-CH
nCH,= CHCN- Peroxide CN
Polyacrylonitrile
(Orlon)
 (390)MHT-CET Exam Questions
66. (C)
NH2

n
nHooC-(CHa)- CoOH+nHaN-(CH2)%-
hexamethylene diamine
adipic acid

-(CH,).Fë-NHCH), -N
Amide linkage
H

is o
e s
s
nylon 6,6
67. (C)

nCH, =
CH,Folymerisation

Ethene
CH,-CH
Polythene

b t
68. (A)
nCH, = CH-CH CH,
Buta
=
+ nCH=CH,

o u
D
1,3- diene CN
Acrylonitrile

-CH=CH -CH, -CH-CH,-

2 1
Polymerisation

0
CH,

2
CN

Buna -N

69. (A)

E T
Buna-N is formed by two different types of monomer, so it is an example of heteropolymer.

Neoprene's chemical inertness helps it resist impacts from weather, ozone and other outdoor

C
variables as well as withstand petroleum - based mixtures such as
Because it is stable and unreactive, neoprene can also be used to make
solvents, oils and greases.
corrosion resistance

T
coatings and as a base for adhesiVes. It 1s also used to manufacture
chemical containers.

H to dini

M
 16.Green Chemistry and Nanochemistry
Important Formulae and Shortcut Methods
Green chemistry : Green chemistry is the use of chemistry for pollution prevention and it
designs the use of chemical products and processes that reduce or eliminate the use or

o n
generation of hazardous substances.

is
s
Principles of Green Chemistry:

Prevention of waste or by-products

Atom economy
s e
t
Less hazardous chemical synthesis

b
Designing safer chemicals
Use safer solvent and auxiliaries
12 Principles of
Green Chemistry
Design for energy efficiency

o
Use of renewable feedstocks u
Reduce derivatives (Minimization of steps)
-
D
Use of catalysis

1
Design for degradation
prevention
Real-time analysis for pollution

0 2
Safer chemistry for accident prevention

2
the following formula:
The atom economy of
a process can be calculated using
product
Formula weight of the desired x100

T reactants used in the reaction

% atom economy Sum of formula weight of all the

CE
Consider the conversion of

CH-CH2-CH2 -CH,OH +
Butan-1-ol to

NaBr+ H,SO4
1-bromobutane.

CH-CH,-CH2 -CH -Br+

NaHSO +H,O

ep
HT
% atom
20912G
economy
bE aim
sum of mass of 1-
mass of 1-bromo
butanol + sodium
butane
bromide +
tzlhis
sulphuric acid
-x100

M
+1 Br) atoms x100
mass of (4C +9H +1S) atoms
+50+1Br +1 Na
mass of (4C+12H

137u 100 49.81 % 10 902ue

275 u
 (392)MHT-CET
Exam Questions
Material in Daily Life:b Fs
Sort Plastie
Chart to

HDPE
Mumber 21 HDPE hg

n
Nember 1 1 PTKOr PET devasypo)hyene
rethakntetrayw houschold cleaner and
(nwhyee

o
mierowavable food Uend In
Ueeel e t

not drink, water

and shanpoo bottles ne known chemicnls

is
alnl dressing, Stnten iransnite
1

beer bottle abeorbs haoterie food detergen

Stetee: hard to elean; Recyeled To Mahe pem
avwid resng Hoor tiles,
and flavor
Recyeled Te Mahe
carpet. hottles, femcing,
e
1

s
larmifere, new continers, |
polar
tleece

Other
wmber 7: Other

s e
Number 3 : Vor PVC
(viny

t
S- gellon waiegg bottles, dear
Deed In: -and coetainers Used In 1 cooking oil
yien sane fond
which HOUSEHOLD food packagng, mouthwanh bottla
Contains biapbenol A, fo contain

b
has been limked to beart disease
and PLASTICS Statas isbelived
phalases that snlerere with hocmonal
obesily; avoid development, avoid
la Recycled T Make
: custom

u
Recycded To Make cable
b
nade prodUcs
uditlaps paneling rOdhway

o
guttcrs

Namber 8: PS
(Podysorene)
D LDPE
Number 4: LDPE (Low

1
aed In disposablc cups and plales, Number 5: PP densigy polyethylene)
Qgg cartons, take-out containc (Poypropylene)
Used In:brend and shopping begs
Statas; is belived lo kach stynene, Ueed In: ketchup bottles, medicine,

2
carpet, clothing, fumiture
passible hurnan carcinogen into and syrup bottle, drinking struws Transmits nowa
Status
food: avod Status: transmits no known chemicals

0
b Recyced To Male : foam chemicals into food
packaging.insulation, light intofood To Malke batery Is Reeycled To Malke emvelopes
1

bRecyeled
awichplates, rulens ioe scrapers, rakes foor tiles, Jumber, trasi-can liners

2
Cables, broons,

E T
Nanochemistry: It is the combination of chemistry and nanoscience. It deals with
designing

C
composition
and synthesis of materials of nanoscale with different size and shape, structure and
and their organization into functional architecture.

HT Characteristic features of nanoparticles:

1. Colour
2. Surface area R0 001
tobeb

ent

M 3. Catalytic activity
 (393)
Green Chemistry and Nanochemistry
tools used for characterization of nanoparticles are:
The analytical
Information
Name of Technique Instrument used
UV-visible spectroscopy UV-visible Preliminary confirmation
spectrophotometer of formation of
nanoparticles

n
X-ray Diffraction (XRD) | X-ray diffractometer particle size, crystal
structure, geometry

o
Structure of surface of

is
Scanning electron Scanning electron
microscopy microscope (SEM) material that is morphology
Transmission electron Transmission electron particle size

s
microscopy microscope (TEM)
Absorption of functional
FTIR (Fourier transform Fourier transform

e
groups, binding nature
infrared spectroscopy) infrared

s
spectrophotometer

t
Applications of Nanoparticles: and systems.
1. Nanoparticles contribute to
stronger, lighter, cleaner and smarter surfaces
sunscreen, crack
scratchproof eyeglasses, transport,

b
They are used in the manufacture of
resistant paints, etc. (MRAM).

u
Magnetoresistive Random Access Memory
2. Used in electronic devices like techniques. Silver
role in water purification

o
3. Nanotechnology plays an important
get safe drinking water.
nanoparticles are used in water purification system to
: Lotus is an example of self
cleansing. Nanostructures on

D
4. Self cleansing materials self
dirt as it rolls off. Lotus effect is the basis of
lotus leaves repel water which carries
cleaning windows.

Advantages and disadvantages

Advantages:

2 1
of nanoparticles

Revolution in electronics and computing

and nanotecnno108

0
1. efficient.
2. Nanotechnology makes solar power
more economical and energy storage more
manufacture of smart drugs which cure life threatening

2
3. Nanotechnology is used in the
diseases.

T
Disadvantages: which is dangerous for living organisms
1. Nanotechnology causes environmental pollution
known as nano pollution. tahio un-oreto f9

E
2. Nanoparticles

C
can cause lung damage.

Multiple Choice Questions

T This topic has been included in the CET syllabus for the first time for CET 2021. Find sample
questions below:

H In green technology developed by Drath and Frost

is enzymatically synthesized from

M
glucose.
(A) adipic acid (B) benzene (C) lindane (D) sucrose
(A)
used for water purification?
4Which highly effective and cost effective nanoparticles arenanoparticles
(A)gold nanoparticles (B) copper
(C) silver nanoparticles ODD (D)silica nanoparticles
 morphologu
MHT-CET Exam Questions nanoparticle 1.e.
(394) surface of
the structure of
3. The analytical tool used to study
(A)Absorption spectroscopy

n
(B) Scanning electron microscopy
(C)Emission spectroscopy

o
spectroscopy
(D)Nuclear magnetic resonance drinks bottles
made from polyethyler

is
trays and soft ar
food
* 1he plastic microwavable
terephthalate (PET) can be recycled to make
(A) carpets, fumiture, new containers

s
scrapers
(8) battery cables, brooms, ice
(C) custom made products

e
gurters
(O) cables, mudflaps, panelling, roadway are present in the useft
starting materials that ful

s
measure of the amount of atoms from the
he as
product at the end of chemical process is known economy

t
(A) catalyst (B) atom energy
(C) design of safer chemicals (D) design for efficient

b
principles of green chemistry?
Which of the following is not one of the twelve

u
(A)using renewable feedstocks
(B) designing safer chemicals and products

o
(C)maximizing atom economytta8apgeliput
(D)avoiding the use of catalysts
nanomaterials?
7. What is the information obtained from UV-visible spectroscopy when used for
no sa
Tloe a
A)morphology of structure
e (B)preliminary conformation of formation of nanoparticle
D 22/6 lol

1
(C)particle size
D)functional group present

number of reaction sites?

(A) Electrical conductivity 2
8. Which of the following property of nanomaterials play significant role in providing more

0 (B) Thermal property ey2

2
(C) High surface area to volume ratio (D) Colour
9. The plastic ketch-up bottles and syrup bottles made from polypropylene (pp) can be recycled to

T
make
(A) battery cables, brooms, ice scrapers, rakes gatn

E
(B) envelopes, floor tiles, lumber
(C) custom-made products

C
(D)carpet, furniture, new containers
10. The material synthesized on the nanometer scale possess
(A) same bulk properties

HT B) different bulk properties

C) unique optical, magnetic, electrical properties
D)no change in properties Fofgd inoop

M
SOLUTIONS
1. (A) 2. (C) 3. (B)
oheofidg7. (B) osu 4. (A) 5. (B)
6. D)
8. C) 9. (A)
0,(C)blog
 Electrophilic

13. Amines

ImportantFormulae and Shortcut

Methods

o n
is
in which one or more hydrogen
atoms of ammoni
Amines: The derivatives of ammonia are
replaced by alkyl or aryl groups are called amines. NH

s
Classification of amines: Amines are classified into primary, secondary and tertiary amis.
or aryl groune
depending upon the number of hydrogen atoms in ammonia replaced by alkyl
shownbelow:

NH R-NHRNH RN
s e
t
ammonia primary
tertiary
amine secondary amine
aminei oa b go3

>Methods of preparation and the reactions of primary amines:

u b
o
R-X Exces NH R-NH,X
aloahol
Allyt mlide Ammonbu salts

D NoNO, +HC
Preparat
NH cOM R-OH
co (2)R-X
DETAEE
olcobnls

1
Title
Fathamide CHOOCI ur
R-NHCOCH,

2
KCH,CONO
R-CN ~R-NHa Nacetyl ambes

0
ydes Sandme
R-X R-NH-R, (good y

2
R-CONH, econdsy aine

T
R-NO S0+HC RNX
or H,/
tronlae Tete allyl mon

E
R-CO-NH Br+OW Gatten
CHCL,+KO
R-N C

C
Hoctn
broeaido
lodoar

T
CRS0NH-R forma

H Mild

M Phen
 Amines (337)
Substitution:
etrophilic Aromatic atnislul
Electr
NH
Br
Br 246 tribromoaniline

n
Br

o
NHCOCH,
a are

is
(CH, CU,OD
Acetanilide
NH

s
ines NH NH NH
8 as NO

e
Conc. HNO,/H,SO,

s
NO
NO

t
p-Nitroaniline m-Nitroaniline o-Nitroaniline

NH
Conc.HSOo
HO H2

u b
o
SO H
Sulpbanilic acid

Preparation and reactions of arene diazonium salts:

D Products

1
Substrate Reagent
Title of reaction

2
CuCl/ HCl Ar Cl
+NaDu
Ar-N,X

0 CuBr/HBr Ar Br+N2 h oll

Sandmeyer reaction Ar-N

2
(good yield)
CuCN/KCN Ar CN +N2
Ar-NX

T Ar-Ng Cupowder Ar - Cl+N

HCl
DA

CE
Gatterman reaction

p
Ar-Na

Ar-N,CI
Cu powaer
HBr

KI
Ar- Br + N

Ar-I+Na0 /0

T
Iodoarene
formation
Ar-Na
H,PO2 Ar -H+Na + H3POs +HCI

H
H0
HCI
Mild Reduction N,aCH-CH2-0HAr-H+N +CH,CHO+

M Phenol
formation
Ar-,C H0
283 K
Ar- OH+Na +HC1
 ay
Apaimar
Questions conppounc
(338)MHT-CET Exam
Multiple Choice Questions AL-methyl
The
MHT-CET 2004 tollowii
NH

1. The IUPAC
name of H,C-CH-CH is

(A)dimethyl amine (B)

2-aminopropane (C)isopropylamine
(D)2-propanamine

o n theamune-
lia
AEtby/
ANCHNH

2. Primary amine (R NH;) reacts

(A)R NHNO, (B) ROH
with nitrous acid to give
(C)ROR (D)None of these
is MET-CET
201/

s
N-ethy-NV
MHT-CET 2005

e 8(4)1°amine
H2SO4
3. Complete the following reaction. R NH2+

s
(A)R NH1 HSO (B)|[R
NH, ], SO (C)R NH2. H,SO (D) No reaction
MHT-CET201

t
4. Acetonitrile on reduction gives
(A)propanamine (B) methanamine (C) ethanamine (D)none of these
follo

b
the
Reduction T6In
5. CH,Br+ KCN (alc) x Y CH,-CH

u
Na/C,H,OH
What is Y in the series?

o
(A)CHCN (B)CaH,CN (C)CaHNH (D) CH NH2 NH
MHT-CET 2006

D
The compc
6. An organic compound "A' having molecular formula CaHN on reduction gave another A) butanc
compound B, upon treatment with nitrous acid B gave ethyl alcohol. On warming with

1
C)2-met
chloroform and alcoholic KOH, it formed an offensive smelling compound 'C. The compound
C' is

2
MHT-CET 2
(A) CHCH
NH2 (B) CH,CH,N=C (C) CHC= N (D)CH,CHOH 17.Which
of

0
of the three amines and ammonia isstbs
7. The decreasing order of basic characters A)CHs

2
(A)NH>CH,NH2> CHsNH2>CoHNH2 (B) C.HsNH2> CH3NH2> NH> CsHsNH2 MHT-CET
(C)CHNH;> C,HsNH> CH3NH2> NH; (D)CHNH> CHsNH;> CsHsNH;> NH 2
18.An
organ
MHT-CET 2007

T
chloride
8. Isopropyl amine with excess
t
of acetyl chloride will give andreacts

CE
(A)(CH,CO)hN- CH--CHh

(C)(CHs)CHN(COCH1);
A (B) (CH,),CH-N-COCH,
H
D) CH,CH,CH,-N-cOCH
(A)CH

HT
9. A mixture of ethyl amine,
(A) alkyl cyanide
MHT-CET 2008
chloroform and alcoholic KOH
(B) ethyl cyanate (C) ethyl
H
on heating gives
isocyanide (D) ethyl isocyanate
totope 19.
CCH

dentify

M
10. On heating benzyl
amine with chloroform and
(A) benzyl alcohol ethanolic KOH, product obtained 1s
(B) benzaldehyde (C) benzonitrile
11. When acetamide is (D) benzyl isocyanide
treated with Brz and
(A)N-bromamide caustic soda, lanart9
the product formedis
(B)bromoacetic acid (C)methanamine (D)ethanamine

A)
 n
Amines (339)
MHT-CET 2009

o
12. Iso-propyl amine is a

is
(A)primary amine (B) secondary amine (C) tertiary
amine (D)quarternary amine
13. The compound that forms a yellow oily liquid with nitrous acid is

s
amine (A)2-methyl aniline (B) methyl amine (C) benzyl amine (D)diethyl amine

e
14. In the following reaction sequence, anlgtsol

s
hese Ethyl amine A BNHC
(A)CHNH2 e(B) C.H$NH2ob fo(C) CH,CH NH (D)(CHs)»NH

t
=

MHT-CET 2010

b
n 15. N-ethyl-N-methylpropan-1-amine is
(A)1° amine (B) 2° amine

u
(C)3 amine (D)4° amine
ese

o
MHT-CET 2011
16. In the following sequence of reactions:
rigireualo-gtiir atotit anime n
CH,-CH-CH,NO2 A

D 32 oba
Oxidation B0CMgCda
(i)H20:2)
NH

gave another
warming with
The compound C formed will be
(A) butanol-1
C)2-methylpropanol-1

2 1 nona (B) butanol-2

D)2-methylpropan-2-ol tu

0
The compound
MHT-CET 2012
17. Which of the following is the strongest
base?

2
H (A)CHSNH2 (B) CHNH (C)NH (D)CHCONH2
MHT-CET 2014
sHsNH2 molecular formula CaHiN reacts with p-toluene sulphonvl

T
18. An organic compound X having active
Y is soluble in aqueous KOH. Compound X is optically
>NHs chloride to form a compound that compound Z. Identity the compound Z.
to form
and reacts with acetyl chloride

E
SH,

C
NHCOCH, (B) CH,CH,CHNHCOCH,
(A) CH,CH,CH,CH,
CH
CH,-C-NHCOCH, off 9

T (C) CH, HCH,

NHCOCH, OD)
odanifeandu CH, sd yoonun
eicR

H
following series of reactie
reactions.
is produced in the following series of
19. Identify the alkene that
yanate

M Moist, x
> Alkene + tert. amine +
H0
(CHa)s
AgpO a
s
DCyanide
(C) (D)
(B)
(A)
 NNAZnethyy
prop
TeN d
(340)MHT-CET Exam Questions
of
nnent
Teact
e9 13-TRH

n
MHT-CET 2015
20. Which of the following is the
most stable diazonium salt7
Ai
IReumer-Iie
ASnais
(D) CH,N;XA

o
(C)CH,CH,N;X"
(A) CH,CH, N;X (B) CH,N;X 2020
MHT-CET 2016
21. Select the compound which on treatment
with nitrous acid liberates nitrogen.
is TCET
alky/hal
Asecondayp
HRen

s
(C) Diethylamine (D)Ethylamine L
(A) Nitroethane (B) Triethylamine
Wprinaya7

e
MHT-CET 2017
basic strength is
otthef
s
22. In case of substituted aniline the group which decreases the &Which
(C)-NH2 (D)-CaHs
(A)-OCH (B)-CH TO-B1 (A)R-CN+

t
23. Which of the following statements is incorrect in case of Hofmann bromamide degradation?
(A) Reaction is useful for decreasing length of carbon chain by one carbon atom
(B) It gives tertiary amine
(C)It gives primary amine
b
OR-CH=

u
BE T3D-THIM KJUPAC
nam
(D) Aqueous KOH is used with bromine
1,5t ai ar (A)benzenar

o
24. The amine which reacts with p-toluenesulphonyl chloride to give a clear solution which
on Phenylet
acidification gives insoluble compound is (C)
(A)C.HNH

D
(B) (CaHs)>NH (C)(CHs)NN (D)CHNHCH,
T. Which of t
MHT-CET 2018 strongly he

1
25. Identify the product 'C' in the following reaction. (A)Alkyne
(CH,CO)%0
-loneld (A

2
Aniline
Pyridine
Br
A CHCOOH BHor OH>c 1onoxqyrforn-( Which of t
(A)Acetanilide 220 Ta3-THM (A) AnN$

0
(B)p-Bromoacetanilidejloi
(C)p-Bromoaniline (D)o-Bromoaniline h 10
tid.(A
HM B) AN
MHT-CET 2019
26. Identify the amine formed when
2 ethyltrimethyl ammonium iodide is
EOS T0-TE
C) ArN

T
hydroxide and further heated strongly. treated with silver
D) ANG
(A) CH NH, (B) CaHs(CH:)2 ly
o
E
(C)(CH)N (D)CaHsNH 19.Which
27. Hinsberg's reagent is an

C
(A) sodium benzene sulphonate (A)n-Bul
(B) benzene sulphonic acid
(C) benezene sulphonyl chloride HO(A) B)n-Bu
(D) benzene sulphonamide
28. How many primary C Diet

T
amines are possible for molecular
(A)4 formula CH,N?
(B)2 D)Ethy
29. Which among the following
(C)1 (D)3 D(O)

H
A0.In
amines has highest boiling aquer
(A)C,HshNH point?
ito aro awol (B) CH3-CH-CH:-CH NH2 ACH
C)CH) C NH2
iebl.
M
30. The reduction
D)CHsN(CHs)h ByCH
of alkylcyanide with sodium
(A) Stephen reduction and ethanol to give primary
amines 1s, OCH
(C) Clemmensen
reduction B) Rosenmund reduction DCH
31. Aniline when (D)Mendius reduction gh
4Ldentif
heated with chloroform
(A) Benzyl alcohol and alcoholic potassium
hydroxide form
(C) Phenol (B) Phenyl isocyanide
(D) Chlorobenzene

C
 Amines (341)
butyl1
butyl bromide on reaction with alcoholic ammonia
32. Tertiary
tiary

(A)N,N-dimethylethanamine m(B)
giveso
tert-butylamine
ou

n
C)2-methylpropan-1-amine (D) 2-methylprop-1-ene
13. Replacement of diazo group by CI using cuprous chloride is known as

o
(A)Swarts reaction
noE
v
is
(B) Sandmeyer's reaction
(C)Reimer -Tiemann reactiondnd (D)Wurtz reaction
MHT-CET 2020
34. When alkyl halide is boiled with large excess of alcoholic ammonia it forms
(A) secondary amine (B) tertiary amine

e s
s
(C)primary amine (D)quaternary ammonium salt
Which of the following reactions does NOT yield an amine?

t
dation? 35.

(A) R-CN+ H,0 h peolle ( (B)R-X+NH (ako)

b
= NOH
R-NO2 Sn/conc.HC um a
(C)R-CH CaHOH ssedD)

n which on
36. IUPAC name of benzylamine isl)
(A)benzenamine be oilidigslouri
(C)Phenylethanamine
(B)phenylmethanamine
laindbitage(D)N-methylbenzenamine
o u
D
is obtained when quaternary
ammonium hydroxide is
37. Which of the following compounds
strongly heated? (C)Alkene D)Alkane

1
(B) Amide
d

(A)Alkyne
is a Gattermann reaction?
38. Which of the following

Arl+N2
ArN;XCuCVHCArCI+N,T
THIM (A)

0
t+KX
w.T (B) ArNX
T BR
HSEArNŠBF ArF+N,

2
(C) ArNX
T
ArNX Cu/HBrArBr+ N2
(D)
silver points is correct for amines?
decreasing order of boiling

T
with 39. Which among the
following
dimethylamine> Diethylamine
(A)n-Butylamine> Ethyl > Ethyl dimethy
lamine

E
(B)n-Butylamine> Diethylamine
dimethylamine> n-Butylamine
Diethylamine> Ethyl Diethylamine > n-Butylamine

C
C) go
(D)Ethyl
dimenthylamine>
strength of
alkylamine is n ele
basic
phase the order of
CHNH> NH
40. In aqueous

T
(A)(CH:);NH> (CH)N> (CH)JN> NH
(CH,),NH> CHNH;> CH,NH> NH
(B) (CH);NH> greotofa

H
()(CH),N> (CH)>NH> (CH)JN> NH
(D)CHNH> following reaction
in

M
41. Identify product B
conc.HNOAH
HSO
OH
Acetanilide-conc.H,SO4 oror O et(B)p-Nitroaniline
B)p-Nitroanilineutiroioa(y
(A)o-Nitroacetaniliderote (D)Aniline

()Nitrobenzene
 Benzene
dia
Apheno
Questions
6 of th
shWhich

n
(342)MHT-CET Exam boiling point? A)-OCH
compounds has highest apub-
of the following
42. Which (B)CaHCH(CH)2

o
many
(A)CH(CH:);CH;OH (D)(C;H)»NH

is
(C)CH(CH:);CH;NH How
having highest boiling point isgf. 57.(A)3
isomeric amines, an amine tert-butylamine endpr
43. Among the following (B)
(A) ethyldimethylamine 1io/9 The

s
(D)n-butylamine 58. CHNH
(C) diethylamine
replacement of diazonium group?

e
does NOT involve
*44. Which of the following reaction (A)Chlorc
HCI
(A)Reaction with cuprous chloride in
(B) Reaction with aniline
C)Reaction with potassium iodide
(D)Reaction with hypophosphorus acid
45. Benzene diazonium chloride on reaction with
t s
aniline in mild alkaline medium forms
59.
Which
(A)
Trime
of

What is

b
(C)yellow dye D) blue dye 60.
(A) orange dye (B) red dye cuprous

u
diazonium chloride and phenol in mild
46. Formation of p-hydroxyazobenzene from benzene (A) Wolf
alkaline medium is a
C) Balz

o
(A) nucleophilic substitution (B) electrophilic addition mee DAO.0t
() electrophilic substitution D) nucleophilic addition
nsned 61. Which o0

D
47. Which of the following amines cannot be prepared by Gabriel phthalimide syndhesis? (A)Na/(
(A) Isopropylamine (B) Ethylamine (C) sec-Butylamine (P) Aniline TE
62. The rea

1
48. Which of the following reagents is used in Hoffimann elimination reaction of amines?
(A) CHCl+KOH (B) CHCOCI (A)Gat

2
(C)Ag:OH,0,A (D) NaNO2+ HCI (C) San
slol alt to fau3E
49. Which of the following does NOT give carbylamine test?

0
63. Which
(A) Ethylamine (B) Isopropylamine chlorid
(C) sec-butylamine

2
(D) Dimethylamine
(A) CF
50. Identify the product obtained when benzamide is treated with
bromine and aqueous sodium
hydroxide? 64. Which

T
(A) Aniline (B) Phenol (C) Benzyl alcohol (D) Bromobenzene (A)R

E
51. Identify the product 'A' in the following reaction.
65. TUPA
(CHCO),
Aniline A atsthiyab shie o8-70/3 (A)N

C
pynidine
(A) Acentanilide
edstibJad oniotlydrsid
C)N
(C) Benzenediazonium alzo (B) Sulphanilic acid
chlorideu (D) p-nitroacentanilide
66.Inthe
ab v(C

T
52. Alkyl cyanides on reduction
by sodium and ethanol give primary amines.
as The reaction is cal Ar-

H
(A) Wolff-Kishner reduction
B) Hell-Vohlard-Zelinsky reaction i6A)
(C) Clemmensen reduction
D) Mendius reduction
A)t
53. Identify compound 67.Incas

M
'B' in following series of reactions.
AcetonitrileNa/alcoholANaNO, /dil. HC1R (A)
(A)Nitroethane (B) Ethyl chloride
(C)Ethyl amine
68.Iden
*54. Which of the following (D)Ethyl alcohol
(A)Reaction with dilute
reaction of diazonium
salt involves retention diazonium N.N
(B) Reaction with phosphinic acid g
(C)Reaction with phenol
sulphuric acid of
(D)Reaction with HCl and Cu powder
(A
69.Wh
(A
 Amines (343)
Benzene diazonium chloride on reaction with ethanol
(A)phenol (B) benzene formsllel
(C)nitrobenzene (D) aniline bu A)

n
Which of the following groups increases the basic strength of substituted aniline?
(A)-OCH (B)-NO (C)-SO (D)-CN
How
(A)3

58. The
many primary amines are possible for the formula CaH,N?
(B)2 (C)4
end product C of the following reaction is
(D)1

is o
C.H,NH,NACBNHc
(A)Chloroethane (B) Ethanamine
alcohol

(C)Nitroethane (D)Ethanol

e s
59. Which of the following amines is most basic in nature in aqueous phase?
(A)

60. What is
Trimethylamine (B) Dimethylamine (C) Ammonia

t s
(D)Methylamine
the name of reaction involving replacement of diazonium group by chloride using

b
ol in mild cuprous () salt?
(A) Wolf-Kishner reduction

u
(B) Friedel Craft's reaction
(C) Balz Schiemann reaction (D) Sandmeyer's reaction

o
61. Which of the following reagents is used in Mendius reduction reaction of alkyl cyanide?
(A)Na/CaH,OH (B) Sn/HCI (C) Na-Hg/H;O (D)LiAIH;/Ether

D
in diazonium salt is called,
62. The reaction in which copper (T) salt is used to replace nitrogen
(B)Hoffmann elimination
(A) Gattermann reaction -ngoC

1
(C) Sandmeyer reaction D)Balz- Schiemann reaction
a clear solution when treated with benzene sulphonyl

2
63. Which of the following amines forms
chloride and excess of potassium hydroxide?
D)(CH,)N

0
NH
(A) CH,NH2 (B) (CH,)> NC Hs C)(CH,),
phthalimide?
amines is obtained by alkylation of

2
Pous sodium 64. Which of the following type of (D)R)»N
(A)R - NH-R (B)R - NH2 (C)Ar- NH2
ne name of CHN(C;Hs)2
is

T
65. IUPAC
(B) N-methyldiethanaminea-M
(A) N, N-diethylmethanamine
(C)N-ethyl-N-methylethanamine (D) N- methylethanaminet a

Ftion is
called
66.

CEIn the following reaction the

Ar-N,'XA>Ar-N,"BE
(A) borontrifluoride
reagent A is,

(B) fluoroboric
Ar-F+BF +N, t
acid (C) hydrofluoric acid
(D) boric acid
issdi fafU

T
which decreases the basic strength
aniline the group (C)- NO (D)- CH3
07. In case of substituted OCHs
(B)-

H
(A)- NH2 conversion?
following
aniline7-278K4+nitroso-N-N-dimethylaniline
in
08. Identify reagent 'A'
Nitric acid (D) Sulphuric acid
N-NDimethyl

M
Hydrochloric acid (C)
(B) substituted
(A) Nitrous acid strength in bstituted aniline?
ol increases the basic (D)-CN
from following ()-SO
group? 09, Which group ouB)-OCHsT
(A)-NO2o
 Whicho
A24
(O24
Questions point ?
(344) MHT-CET
Exam lowest boiling
compounds has ((CH)CNH; (D) CH, CH(CH;)»
following Which

n
among the (C;Hs)»NH CusO A/see
70. Which (B) with ammonia and
(A) nCHoNH chlorobenzene is heated (ON
when
product obtained

o
71. Identify the Benzenediazonium chloride

is
(B) BAHhich
under pressure. (D)Benzaldehyde
(A) Aniline (A)n-
()Benzene aniline in strongly
acidic medium.
by nitration of and o-nitroaniline
C)D

s
72. Identifjy the
products obtained (B) p-nitroaniline
m-nitroaniline m-nitroaniline and p-nitroanilins Whict
(A) o-nitroaniline and
andp-nitroaniline (D) o-nitroaniline,

e
(C) m-nitroaniline
amine with chloroform andan 4 carby
compounds is obtained on heating primary
(A)P

s
73. Which of the following
alooholic potassium hydroxiue
n (B) Alkyl isocyanide t fdod
nliheesTOR
(C)N

t
(A) Amide w D) Alkene Nitr
() Alkyl cyanide 86.
(A) s

b
B in following reaction.
74. Identify product
C.HN X- A B 87. Whe

u
(C)CcHSF (D) CHNH
(A) CHNO (B) CsH COONa form
bromine and alcoholic NaOH, it gives (A)

o
75. When propanamide treated with
is
(A) Propan-2-amine (B) Ethanamine (C) Propan-1-amine D) Methanamine
88. Ani
76. Which among the following cannot be prepared by
ammonolysis of alkyl halide?

D
(A)
(A)Propan-1-amine (B) Ethanamine (C)
()2-methylpropan-2-amine oHi D)Propan-2-amine

1
89 Wh
77. Which among the following is a Gatterman reaction?
CH,N,CICCH,CI+N, T

2
(A)
(B)C.H,N,CI CH,OH+N, 1+HCI (A

0
(C)C.H,N,CI CH,-I+N, T+KCI 90. M
(D) C.H,N,C1HCCH,CI+ N,

2
A
78. Which among the following compounds is obtained when diethyl amine reacts with benzene C
sulphonyl chloride? 91. Id

E T
(A)N-Ethyl benzene sulphonyl chloride
(B)N-Nitroso N-methylaniline
-

(C)Phenyl isocyanide
(D)N, N- Diethyl benzene sulphonyl amide
ninedisynlurloit-

C
79. Which of the following amines liberates
(A) (CH;)%NH B)(CHs)%CHNH2
nitrogen gas when treated with nitrous acid?
(C) CoHNH2

T
80. What is the product obtained
D) CHsNH1 92.I
in the following reaction?
N sil botome n tu

H
NaNO,/HCI
273-278K
93.

M
(A) Benzene diazonium
chloride (B) Sodium phenoxide
(C) Nitrobenzene
(D) Chlorobenzene
81. What is the product
obtained 94.1
when ethylamine
(A)Diethyl amine is heated with large excess ofetny iodide?
(C)Ethyl methyl amine (B)Tetraethyl ammonium iodide
D)Triethyl amine
 Amines (345)

Whichof the
following
ing amine is most basic in nature?
)2,4-Dimethylaniline
Ealun0
(B)2,4-Dinitroaniline
t e
2 Dichloroaniline (D)2,4-Dibromoaniline

n
(C)2,4-
O at 473 of the followi
wing amines cannot be prepared by Gabriel phthalimide synthesis?
K hich

o
83.
sec-propyl amine (B) tert-butyl amine

is
(A) amine (D)2-phenyl ethyl amine
(C)N-methylbenzyl A
su Which of the following compound
does NOT give Hoffmann's carbylamine test?

s
(A)n-
Propylamine switege8) Ethylamine
nitroaniline (C) Dimethyl
amine D) sec-Butyl amine

e
hydroxide yields
roform s5. Which of the following on heating with chloroform and alcoholic potassium

s
and
carbylamine?
Phenylmethanamine (B) N-Methylethanamine -y

t
(A)
(D) N-Phenylanilinell-gisnotup
(C)N,N-Dimethylbenzenamine

b
Nitrogen atom in amines is (D)sp' hybridised
(C) sp hybridised
86.
sp hybridised (B) dsp hybridised
(A)

u
the compound
propanamide is treated with bromine and aqueous sodium hydroxide,
87.When

o
formed is (D)propene
ethanamine (C) bromopropane
nine (A) 1-propanamine (B)
water at room temperature to give

D -13-
88. Aniline reacts with bromine (B)2-Bromoaniline
(A)2,4,6-Tribromoaniline (D)3-Bromoaniline
(C)4-Bromoaniline

1
reaction?
obtained in the following
89. What is the product X +NaBFo
X+N2

2
CHN,CIOHBP,DNaNO2 (D)CcHSNH2
(C)CcHN0;
(B) CHsF

0
(A)CHC1
represents
90. Molecular formula CaHN (B) only 2 amine

2
(A)only 1° amine (D)2° amine and 3° amine
(C)1° amine and 2° amine
following reaction.
compound 'A' in the

T
ith benzene .Identify
pH

E 273K
+Nat +HCI
OHNO2 +HCI
A

C
H2S04 (D)Chlorobenzene
(i)H20, dil. (C) Cumene
(B) Benzene
(A)Aniline
following reaction.
.
T
Identify product B in
AnilineNaNOA B
Benzyl iodide
(C)lodobenzene (D)Benzenediazonium iodide
(B)

H.
in substituted aniline?
(A)
Nitrobenzene decreases th basic strength
following (C)-CH (D)-CcHs
from (B)-OCH
93. Which group
reaction.

M
(A)-NH2 following
compound A in
Identify (CH,), N+ H,o
N(CH,), OH AA+
CH,CH
(C) CH,CHOH (D) CH CH
C,H, (B)
/odide?
(A) CHsNH
 am
Exam Questions
(346)MHT-CET reaction.
B in following NANO2BB
the product ay

n
95. Identify
AcetonitrileNa-ethanolnol A HCI ethanoate CH
(B) Sodium
(D) Ethanol

o
methanoate
(A) Sodium poalA
temperature gives

is
(C) Ethanamine water at room
with Bromine 6-Tribromoaniline
96, Aniline on
reaction (B)2, 4,
(A) m-
Bromoaniline (D)o-Bromoaniline ful (0
Ele

s
(p-Bromoaniline respectively. Ele
in following
reaction (i)
97. Identify A' and 'B'
Br
Acetanilide ROetic acid

(A) 4-Bromoaniline and

A
4-Bromoacetanilide
(B)p-Bromoacetanilide and p-Bromoaniline
B i

s e (i)E

(C) Aniline and

p-Bromoacetanilide
(D)Aniline and p-Bromoaniline
SOLUTIONS

b t &)

u
(CH
1. (D)

o
3tqugoionid(
NH,
9. (D)

D
CH,-CH-CH, irsova 2eTrondr-3,62u
2-propanamine lsoroner

1
2. (B)
10.(D
amines on reaction with HNO2, form alcohol and evolve Nz.
1 aliphatic

2
Iti
R NH, +HONONaOHCROH+N, +HCI

0
3. (B)

Bases react with acid to form salt.

c
2
Amines are basic in nature
It forms salt on reaction with H,SO4

E T
4.(C)
2R NH, +HsO,[RNH,} SO 11.

C
Cyanides on reduction give 1° amine.

CH,CN Reduction
»CH,CH,NH2

T
Acetonitrile LiAIH
amine
or ethanamine
horist 12
5. (C) 9Tssruei

H CH,Br KCN(ale) quo iloi

CH,CN Na-CH,OHCH,CHNH2 mo
Methyl bromide
Methyl cyanide

M
X Ethyl amine

6. (B)
) Proceed back with
known compound
CaHsOH.
 1° amine on reaction with HNO gives 1° alcohol. Amines (347)
ii)
ReductionCH,CH,NH2

n
CH-C
cyanide
HONOCH,CH,OH
Methyl Ethanamine

o
(A) (B) Ethenol

(B)
CHCh,KOH
CH,CH,N C
Ethyl isocynnide
HMHD
is
s
(C)
. (B)

)Electron donors are bases.

) Electron withdrawing groups (e,g. benzyl)olloy
decrease the basicity of amines.
s e
) Electron donating groups (e.g. alkyl) increases the acidity amines.
The correct order of basicity of amines is

b
of
t
u
CaHNH,>CHNH>NH> CH,NH HOHO

o
8. (C)

(CH3)CH

D
NH2 +2CHJcOCI (CH,),
Is0-Propyl amine
(pr amine)
-HCI
CH- N(COCH,)2
Tert. amine
a-to onuroo

1
9. (D)

2
CH amine
NH,+CHCl+ 3KOH
Ethyl (Alcoholic)
CHNC+3KCI+2H,0. It is carbylamine reaction.

0
10.(D)
It is carbylamine reaction.

2 CH,NH,
CHCh
CHNC

T
KOHA
CaHsOH

E
Benzyl isocyanide
Benzyl amine
o noosCarbylamine reaction (test for 1° amine)

C
11. (C) d ta os te soda to give thei
heir corresponding primary amines.
and caustic Thu
des react with bromine This reacton
reaction is bromamide degradati
AnOWn as Hofmann's bromamide degradation reaction
13 known
cetamide gives methanamine.

HT 12.(A)
0
H,C-C-NH, + Bry +4KOH
Acetamide
2KBr+ KaCOs
+H,C-NH,+2H,o
Methananmine

M
18
iso-propylamine
ne structure of
CH,-CH-CH
ecoo
NH,
t is a primary amine.
 Ouartermary

(348)MHT-CET
Exam QuestionsS 1s/
nitrous acid
reacts with nitrous acid (HNO), action
amines) when a Bcartbonha
13.0 (-NH group containing
Secondary amines

n
is formed. CH,NH,
nitroso compound
yellow oily CH-CH
NH

o
(D) (C2H,)2 NH
CH,

is
(B) CHNH Diethyl amine

(O methyl amine
(Amine) (benzyl amine) 1° amine
(2 amine)

CH;
-CH

s
2-methyl aniline
(1 amine)
forms a yellow oily
liquid with HNO2.
CH-CH

e
Hence, only diethyl amine
CHs), N-N==O
(CHs) NH+ HNO, iN-nitosodiethylamine

s
Diethyi amine
95)2q0 grttsol tiotool G
(yellow oily liquid)
CH-CH

t
14.( (B)
FHNO2CH,OH CH,Cl NHC,H<NH2,H
-HCI
CHNH

b
chloride
Ethyl Ethyl amine
Ethyl amine Ethanol -HCI B
20.(D)

u
15. (C)
Compou
The structure of N-ethyl-N-methyl propan-1-amine
isS

o
CH R-NaX
CH,CH,CH, N
Temperal

D
CH
Since, in this compound, the three valencies of nitrogen are satisfied by three different alkyl 1.(D)
groups, it is a 3° amine.

1
1/prim
CH,CH
16. D)

2
Ethyl am

CH-CH-CH CH, -ÇH-CH,-CH-c-CH CHMgL, (CH,),COH

2.(D)

0
(i)H
NH2 H20 2-methylpropan-2-ol
OH CsHs

2
A
23.(B)
17.(B)
It is us
Basic nature of amine is due to the presence of lone
pair of electrons on nitrogen atom which is

T
available for the bond formation with Lewis acid. Due 24.(A)
the strongest base
to+I effect of-CHs group, CHsNH; 5
1 ami

CE
18. (B)
ont2itof gvoit Rnodnst eoT seinnntrg vovig slbtmiti0
Since, X (CaH11N) reacts with p-toluene
compound which is soluble in KOH,
sulphonyl chloride (Hinsberg reagent) to tou
therefore X must be a primary amine.
15.(C)

NH

HT CHSO, CI+H-N-¢-CH,-CH
CH,SO -N-Ç-CH2-CH3

M
(Souble in KOH)
16.
CH-CH-CH-N-H+CICOCH- C)
X -HCT CH-CH -CH-NHCOCH
H
 43Amines (349)
(HNO),
19.(B)

monium
ammonium salts of alkyl amines, when
ry
reacts with silver oxide yield quarternary
hydroxide. On strong heating, it decomposes

o n
is
a into alkene, tert. amine and water. This
tion is known as Hofmann elimination reaction. Here, elimination
of H takes place from
B-carbonhaving more hydrogen atoms. n

s
CH,
2CH-CH,-CH -CH-CH2 - N(CH,)yl +Ag,O + H,0
H,
2CH-CH,-CH -CH-CH,- N(CH,),OH +2Agl
s e
CH
CH-CH-CH -CH-CH, -N(CH,),OH A
CH
CH,-CH-CH, -=CH +N-CH+H,o - ub a) 1 X-5
t
20. (D)
CH

D o (eaxaybilsd iellA

Compounds containing -N2 X group are called diazonium salts. Aliphatic diazonium salts
4)2

ferent alkyl
R-N2 X are very unstable and not isolated whereas
temperature.

2 1
aromatic diazonium salts are stable at low

0
21. (D)
Nitrous acid Nitrogen T. Only Ethylamine is primary amine here.
1/primary amines

2
01 CHCHNH2 + HNO2 CHCH,OH +H20+ Na T
Ethanol
Ethyl amine

3 COH

T
22. (D)
group.
opan-2-ol
-CHs is electron withdrawing

E
23.(
amine.
lt used to obtain primary

C
1s

om
whichis
aciditication gives insoluble
compoundns
(A) which on
CH NH; is Tamine gives clear solution

)to
form

HT25. (C)

NH, saimilo-4 n NH-

(CH,CO,O,
B
CH,COOHH
H

OH
or

M
Pyridine
DEk insnb Br
B
C
P-Bromoaniline

26.(C)
AON-CH,
ÇH3
+ H,C=CH, +H,O fod te a
(a)4
H,C-CH1.. CH
CHs
 VHCOCH,

cOnc
Questions cOnc
(350) MHT-CET Exam
27. (C)
28.(B)

n
CaH N
CH-CH-CH- NH amine
Primary

o
CH,-CH -CH,

is
NH,
30. (D)
29..(B) pountof

s
(B) Bouling
Carbylamine reaction

e
32.( 33. (B) orderof bo

s
The amine
34.( Praimary
R-X+NH,(alc.)>R- NH, + HX basedoni

t
Primary amine (itis
Alkyl halide (excess)

b
35. (A) 4(B)
OH

R-C N+H-OH
Aly cyanide
(NH,+HCINH,CI)
Acid aunde
R-c-OH

o
bs
u
Carboxylic acd
+NH,oqo
6 - Be1zendiazonium
chioride

D
Or the final equation becomes
oget -
5.(C)

1
R-C N+ 2H,0+HCI R-C-OH + NH,CI .HO
Alkyl cyenide Carboxylie acid -H 2 46.(C)

2
36. (B) This is an exa
CH-NH,

0
7.(D)
Aromatic
pri

2
8.C)
When
Common name Benzylamine tetraa

T
TUPAC name Phenylmethanamine
- ammoniumt
reaction
alkene. is c

E
37.(
Quaternary ammonium hydroxides on strong heating undergo B-elimination e.g
to give an alkcu CH,

C
the reaction is called Hoffmann elimination.
CH-N-CH
38.(D)
HOG,H

T
CH%
In Gattermann reaction, chlorine or
bromine can be introduced in the arene ring by
u
g the mh ammcnm
arene diazonium salt solution opper
with corresponding halogen acid in the presence o CH

H
powder.
Ar-N$X Ar-X+N2
C-C
M
39. (B) 9.D
The order of boiling point
of amines is as follows: Primary> Secondary> This
40. (B) Teruay reactio
 Amines (351)

41.(B)
NHCOCH,
NHCOCH, NH
conc.HNO
conc.H,SO
H
or OH

o n
Acetanilide
p-
NO, NO,
is
s
Nitroacetanilide p-nitroaniline
(B)

e
(A)
0,(09,HO

s
42.(A)
alkane and amines of comparable mass.
Boiling point of alcohol is higher than

43.(D)
The order of boiling point of
Primary amine> Secondary
isomeric amines is
amine> Tertiary amine
shilig

b t
u
them)
(It based on intermolecular forces in
is

44. (B)

NNCr
Benzendiazonium
Aniline
-NH

D o
NN-
p-Aminoazobezene
(yellow dye)
NH HCI A

1
chloride
H
45. (C)
46. (C)
example of
0
electrophilic 2
substitution reaction.

2
This is an
method.
cannot be prepared by this
47. (D)
Aromatic primary amines

T
it gives quaternary
heated with moist silver oxide, alkenes; the
is
48. (C) tetraalkylammonium halide heating undergoes B-elimination to give substituted

E
strong
ng
Who
Vhen on
hydroxide which elimination. the major product is least
on. In this reaction
ammonium Hoffmann

C
is called
ction
reacti
+Agl
alkene. e.8
C lr+AsOH 902

T
CH-N-CH,H,
alkene, Bayl trnatl ammoniun
Byoro
o fo 2135
n H, R 3

H
ammonis o CH,-CH,+(H)N+H,OO
inethyl
CH OH
CH,-CH eriyf amine

the CH,-N-CH-CH,OH Btylene

eating

M
copper
H amines, h g0aan lot omo
of only primary amines.
v ony
shoWn oy
49. (D) reaction is
This
 Questions
MHT-CET Exam
352)
50. (A) +Na,CO +2H,0
N2NaBr

n
+4NaOH
-NH, +B

o
Aniline

is
Benzemioe

51. (A)

s
H -CH,
NH,

CHCOO
Pyridine
+CH,COOH aoolar los p

s e
t
Acetanilide
Aniline

b
cyanide with sodium and ethanol. This
52. (D)
amines can be obtained by the reduction of alkyl
Primary

u
is known as Mendius reduction.
58.
Na/ethanolR-CH, - NH,

o
R-C=N +4[H] Primary amine
Alkyl cyanide

D
53. (D)
- CH, - NH,
CH, -C=N+4[H] AOCH,

1
Acetonitirile Ethyl amine 59.

2 T
nE
NaNO, /dilHCI u0 60

54. (C)
2 0 boibom CH,-CH,-OH+ H,O+N, T
Ethyl alcohol
iap

E T N NCr+ H
Benzendiazonium Phenol
OH NN- OH+

p-Hydroxyazobenzene (orange dye)

HCI

C
chloride
55. (B)
Replacement of diazonium group by hydrogen.

HT 56. (A)
CH, N,CI
Benzene diazonuium
Chloride
+CH,CH,OH

-OCH is electron releasing group and hence increases

CH, +CH,CHO+HCl+N
Benzene

the basic strength of subsututed

aniline.

M
 Amines (353)
57.(C) -
CH,-CH,-CH, -CH, NH,
Butan 1- amine

n
NH,

o
CH,-CH-CH, -CH,
Butan 2- amine
CH,- CH-CH, - NH, is
s
ii.
CH
-
2-Methylpropan 1- amine
NH
s
ina arnoionen-E-A e
t
(33.Te
CH-C-CH,

b
1V.

CH,

u
ol. This aodilb doge qdeg gaboufto aH
2- Methylpropan - 2-amineq-goo ug ghinioni sit
58. (B)
4 primary amines are possible for formula CH11N.

CH,NH, HNO,,c.H,OH
D o
SRltDE
NH,CH,NH,
C.H,CI- alcohol A

1
Ethanol Chloroethane Ethanamine
Ethanamine (C)
(B)

2
(A)
59. (B)

0
in aqueous solution.
Secondary amine is most basic

2
60. (D)
Sandmeyer's reaction anilins oiisnib-
CuCl/ HCAr-Cl+N, T

T
ArN, X-
61.(A) nilinu be reduction wit
with Na in ethanol gives primary amines.
on

E
Nitriles - NH, tatosis
Mendius reaction- Na/ethanol
R-C=N +4[H]-

C
1° amine

HCI Alkyl cyanide

62. (C)

T
Sandmeyer's reactior CuCl/HCI

H
Chlorobenzene

CuBr/HBr
Br+ N,t

M
i=NCI Bromobenzene

Benzenediazonium CuCN/KCN
ride -CN Nt
aniline Benzonitrie
 Questions
(354)MHT-CET Exam

n
excess of potassium
63. (A) with benzene sulphonyl chloride and
Primary amine when treated

64.(B)
hydroxide forms a clear solution.

Only aliphatic primary amine

is obtained by alkylation of phthalimide.

is o
s
65. (C)
CHN(CHs)2
N-ethyl-N-methylethanamine CH,NH+
66. (B)

ArNX SArN;BF; ArF+ BF + N,

T

s e tis
carbylar

t
A HBF- Fluoroboric acid.
4.(A)
67.(C) NCI
NH

-NH, is +R effecting group which directs

u bniguichgis24-

o
the incoming group to o & p- position
ig k
-NO; 1s deactivating group with -I effect.
a t1 8

D
So it decreases the basic nature of aniline.
15.(
68.( CH,CON

1
NCH NCH)
uits Propanar

2
HNO, (E2 Hoffmann
273-278 K

0
76.(C)

2
NO Ammonoly
A HNO, p-Nitroso-N, N-dimethyl aniline NH
69. (B)

T
+I effecting group increases the basic strength in substituted aniline.
H.C-C
-OCHs is electron releasing group. ttiie
toaiat ao elinid- o

E
All other groups are electron withdrawing groups.
atibral CH
a-5 7.(A)

C
70. (D)
biega fvlk Gatterman
Alkanes have lowest boiling point compared to
amines of similar masses, as amines rorm
H-bonding which increases the boiling point.

HT 71. (A)

+ NH, Cu,0
NH

+2CuC1+H,O T%.(D)

M Aniline
of potassium
72. (D)
NH,

+HNO, -
conc.H,S0,
.
NH,

.
NH,
a T0T Amines (355)
NH,

is
NO,
o n
s
NO,
NO, (47 %) 2%

(B)
(51 %)

s e
t
CH,NH2+ CHCl +3KOH-
(alc.)
CHNC +3KCI+3H,0
(foul smelling)

b
It is carbylamine test given only by 1° amines but not by 2 and 3° amines.

u
74. (A)
NCI NBF
NaNO
-o NO,

D
+HBF- +N, + NaBBF
Cu, A
Fluoroboric
(A) B)i

1
asacid
75. (B)
C,H,NH, +2H,0 + Na,CO, +2NaBr

2
C,H,CONH, + Br, + 4NaOH
Ethanamine

0
Propanamide
1° amine with one carbon less is formed.
Hoffmann bromamide reaction:

2
(8).02
76. (C) 3° amine is difficult.
produces 1, 2,3° amines but
Ammonolysis of alkyl halide
(d).00

T
NH propan -2 amine 1S not easy
H,C-C-CH, 2- methyl ammonolysis

E
to be made by
CH

C
onqee bU aniee gabimilech londa
77. (A) simn yuutsg
Gatterman reaction

HT
amines form
NCI
Cu/HC I+N, T
H-9

onia

M
$o,N(C,HJ
78. (D) so,C

C,H,), NH+L
- diethyl benzene
N,N-
Sulphonyl amide
 (356) MHT-CET Exam Questions -H group
79. (B)

n
Amine N'H
Primary amines
HNO,N, T amune

o
Secondary amine
HNO Nitrosoamine ln

is
(yellow oil)
(B)
Tertiary amine
HNOColourlesssolution
HC-CH,
(CH,), CHOH + H,O+ Na)

s
(CH,),CHNH, +HNO,
1° amine
Propanami

e
s0. (A)
NC h
s
NH 88(4)
NH

t
NaNO, /HC
273-278K
Aniline

81. (B)
Benzene diazonium
Chloride

u b Aniline

o
CH,CH NH, CH,CH,),NH (CH,CH,),N (CH,CH,),NT
-HI Tetraethylammonium
Ethylamine Diethylamine Triethyl amine

D
iodide 89.(C)
82. (A)
Electron donating group increases the basicity of amine.
-F1OAaH0D CH
Phenyl di

1
Methyl group is electron donating group
sbioanegur chlori
sil axuue otusT obimarmod anaeftot

2
90.(C)

CH
piloto aiviomA

0
uEodoian 1borg aile
CH,CH

2
CH,
HO-2- Ethana
2, 4- Dimethylaniline (1-ar

T
83. (C) 91.(A)
Gabriel phthalimide synthesis is used to prepare primary amine.

E
84. (C) NE
Hoffimann's carbylamines test is for primary amines.

C H,C-NH
CH,

HT 85. (A)
Dimethyl amine
(Secondary amine)

CHNH CHCL CHNC

Anil

M KOH, CHOH
Benzyl isooyanide
(Carbylam ine) ah
irma frepclinlie
 Amines (357)

n
86.(D)

o
N-H
Amine group
In amine N' has three sigma bonds and one lone pair. is
87.(B)
sfrold

e s
H,C-CH,-
Propanamide
NH, +Br + 4NaOH
anl 10 dgstp EthananiDe

t s
CH,CH,NH, +2NaBr +Na,CO, +2H,0
iwbe p1

b
88.(A)
NH, NH,

+3Br,
Bromine Br
Water

o
Br
u
D
Hona
,NT Aniline
MBr
monium 2,4,6- tribromoaniline
89. (C)

CsHN,C
Phenyl diazonium
HBF4

2 1
CHF
Fluorobenzene
NaNO,.Cu,A+ C^H, NO, + NaBF
Nitrobenzene
+ N2

0
chloride O MHO-9,F-
90. (C)
ierb
CHnu
CH,CH,NH
2 H,C-NH (olest)

T
Ethanamine N- Methyl methanamine
(1°-amine) (2-amine)

E
91. (A)

C H
HNO, +HCI, 273-278
K
NICI

HT Aniline

NC
P
aniliuotrun

QH
Diazonium salt Eye

M
bi
+N, T+HC
LSO
H,SO
dil Phenol
 Exam Questions Carbohydrates
(358) MHT-CET
92.( polyhyd
NCI they

n
NH2 are
These and
+N, T tydrolysis (CH2

o
NaNO
Glucose

is
HCI
Benzene Iodobenzene eg
zClassification
Anine diazonam
Monosaccharid
[B

s
chloride Oligosaccharid
[A)
O-33-

e
group is electron stachyose.
93. (D) basic strength of anilineCHs Polysaccharide

s
withdrawing group decrease
Electron group.
groups are electron donating
withdrawing group, where as other giycogen.

t
94. (D)
+ (CH,),N +H,O Preparation

b
C,H, N(CH,),
OH H,C= CH, +
Trimethylamine
Glucose is pre
Ethene
95. (D)
H,C-C=N Na-EthanolHC-CH- NH
Acetonitrile Ethanamine

o u cane sugar

D
NaNO,, HCI
CH,0,n n
273 -278 K
tatesit
1
sbroid Reactions
H,C-CH,OH + N, 1+ HCI0H,C-CH, N, CP
09
Ethanol

0 2
Ethyl diazonium
Chloride
(unstable) -3.H

2 rimoed>/ beaisM-M
96.((B)
NH, NH

T
Br Br
+3Br,-Br,/HO +3HBr H
CHO

Aniline

97. (B)
CE Br
2, 4,6-Tribromoaniline

3ti

T
NHCOCH, NHCOCH,
NH, 13M

H B
Acetic acid
Solvent
H*
or OH
O2Hb
Structure

M
Acetanilide
Br
Br Glucose
P-Bromoacetanilide P-Bromoaniline ca
projection
laevo
rotatu
iormulae
maltose,
ce
 Carboxylic a.
cids
Preparatio
Aldehydes, Ketones &
12. ShortcutMethods Methods
Formulae and
Important Benzoylc

n
R-C-H called Alkanal.
Aldehydes:
Benz

Ketones: R-C-R called Alkanone.

is o CHs
Benzo

s
acid.
called Alkanoic
Carboxylic acid: R-C-OH

e
of aldehydes: Preparat
Methods of preparation reduction)

s
1. From Acyl chloride (Rosenmund Etard
1.

R
Acyl chlonide
R-C-H+HICI
Pa/Bas04 Aldehyde

From nitriles (Stephen reaction)

b t
u
2.
Tol

o
n = NH- HCI R-C-H+ NH.C
HC
R-C=N+ 2[H]nh, R-CH
Aldehyde
Alkane nitrile Imine hydrochloride 2. By o

D
(Alkyl cyanide)
3. From Esters

R-C-0-R'AH-Bu
H,O,195 K
R

2 1-C-H
Tol

0
Ester Aldehyde

2
Methods of preparation of ketones: 3. By s
1. From Acyl Chloride

T
2R-Mg-X +CdCl RCd +2Mg(X)CI
Grignard reagent Dialkyl
cadmiumn

2R'--Cl+R,Cd
CE
Acyl chlodie
2R'--R+CdCl,
Ketone O
To

HT 2. From nitriles

R-C NR-Mg-X
R-Mg-XR-C=NMaX H,0R-C-R'+NH, +Mg
dry ether
4. Gatt

M
Akane nitrile
R"
Ketone
Be
 preparation of Aromatic Ketones: Aldehydes,
Is Ketoner
&Carboxylle
Acids(305)
S-coCi +R,Cd RMgX
CAClh
Benzoyl chloride

n
RCOCI
Anhyd.AIC

o
A
Benzene

gK/dy ether is
s
CHCN
Benzonitrile H,O

aration of Aromatic ldehydes from

hydrocarbons:

s e
1. Etard Reaction
CH ÇHO

b t
u
+ CrO,Cl, i.CS
HO
o
Chromylocp
Toluene Chloride Benzaldehyde

D
LCI
By oxidation of methyl arene using CrOs

1
CH ÇHO

2
CrO, +(CH,CO), O/273-283 K
A,H,0

3.
Toluene

By side chain
2 0
chlorination of toluene (commercial method)
Benzaldehyde

E T
CH3 CHCh CHO

C C-C1
hv
H,0
4,373 K

T
Toluene Benzal Benzakdehyde
chloride

H 4. Gatterman
- Koch formylation of
arene
CHO

M Anhy. AlCI,, high

v
Co, HCI
pressure
Benzaldehyde s 0o
Benzene 7 90
 Questions
(306)MHT-CET Exam
5. From ester

Al HG-Bu),_ -H +R'-OH
C-Ö-R H,O
Benzaldehyde
Ester

Preparation of Carboxylic acids:

o n
is
R-CN HO
dil HCI H,CHO
HO (ana)
R-COCI dil NCI

s
C-C0-CH
R-CO),0 HO Pranone

RCOOR

RCOOR
HO
dil H,SO4
NaOH
-
coOH

s e
t
conc HC

R-Mg-X

b
i) dil HCT

KMnO. coOHiot
u
KOH
H,O
CH
KMnO4. KOH
H,OA

D o Nucl

1
CH=CH KMa0. dil B,So
deri

KMaO dil H,SO,

0 2 coOH
coOH
Laboratory
. 2
tests for aldehydes and ketones:

T
Fehling solution test

E
R-CHO+2Cu +50H
Aldehyde
Fehling solution
R-COO +Cu,0 +3H,0

C
red p

Tollen's test or silver mirror test

HT R-CHO+2 Ag(NH3),+30H
Aldehyde

Schiffs reagent
Tolen's reagent
R-CO0 +2Ag+4NH, +2H,O
Silver
miror

M Aldehyde+ Schiff's reagent >magenta

Only aldehydes give Fehling
ketones, hence can be used to
orpink or red colour
solution test, Tollen's
distinguish between them.
test or Schiff's reagent tests and ot
sega ral reaction of aldehydes Aldehydes,
and ketor Ketones
&Carboxylic
Products Aclds(307)
from acetaldebyde
H (ethanal)

n
Products
from acetone
(propanone)

o
CN OH

is
ibe CH-C-CN OH
CH,-C-CH,
etaldehyue CN

s
cyanuhydrin
acetone

e
yenohydri
NaHSO, OH

s
CH,CHO
CH,-C-SO,Na OH
(ethanal) le CH,-C-CH,

t
CH-CO-CH,J acetaldehyde
sodium
so,Na
popanne)

b
acesone sodium
bisulpbite
bisuiphite
CH,Mg!

u
CH,
CH-CH-CH
CH,-c-OH

o
OH
CH,
CH,O OCH,

D
CM,OH CH,0 OCH,
HCI
H,C

1
H,C CH

2
Nucleophilic addition elimination reactions of aldehydes and ketones with ammonia
derivatives

0
Sr. Aldehyde(R'=H} +NH,-Z imine (a erystalline
No. Ketone(R'+H)

2
derivative)
NH-OH
-O Hydraxyl amine
C=N-OH

T
ONne
NH-NH

E
=0 Hydrozine =N-NH,
hydrazone

C
NH-NH CH
Phenyi hydrazine R-C-N-NH-CH
phenythydrazoae

T
NH-NH-CONH,
Semicarbaride R-C N-NH-CONH,
BemicarbazoDe

H
NO
R

tHN¥- NO N-N NO

ent M
tests and
no
24-Dinitropheny
haydrazine
2.4
Dialuophenylhydrazone
 Oxid
Aldeh
MHT-CET Exam
Questionss KMn
(308)
Haloform reaction all methyl ketones (CH- CO- R) and ou
cohols
is given by acetaldehyde,
This reaction (CHOH) - group.
-
containing CH

CH,-C-CH, + 3NaO
NaOH, , CHI, +CH, --ONa +2NaOH

o n
is
A
Sodium Iodoform Sodium
Acetone
hypoiodite acetate

Aldol condensation
Aldehvdes containing at least one a-hydrogen atom undergo a reaction in presence of dilute

e s
s
alkali (dil. NaOH, KOH or Na2CO3) as catalyst to form
- hydroxyl aldehydes (aldol). This

reaction is known as aldol reaction.

2R-C-C=0dq.NaOH R-¢-¢-¢-C=o
b t
Aldehyde
H OHR
Aldol

o u
warm

D
-H,O

2 1
R-CH,-CH=CR -C=o
a, B-unsaturated aldehyde
Cross aldol condensation

2 0
It refers to the aldol condensation that takes place in between two different aldehydes or
ketones. If both aldehydes or ketones contain two a--hydrogen atoms each, then a mixture of
four oducts is formed.

E T
Cannizzaro reaction
In the presence of
aldehydes undergo
a strong base, aldehydes without a hydrogens,
self-oxidation reduction, i.e., disproportions reaction.
i.e. nonaldolizable

e.g.

C
2CH,CHO
2HCHO+ NaOH
+ NaOH CH,CH,OH + C,H,COONa
CH,OH+HCOONa

HT Cross cannizzaro reaction

When a mixture of formaldehyde and non-enolisable aldehyde (aldehyde
a hydrogen) is treated with a strong base, formaldehyde oxidized to
-

the other non-enolisable is reduced to alcohol. Formic

is formic acid while
acid forms sodium formate with
with no

M
formic acid. For example:
NaOH. On acidification sodium formate is converted into

CH-OH
H-- o Leana NoOH
L.HO
(Pheayimethanol)
+H-C-OH
(formic ocid
CFormaldehyde) (Benzaldehyde)
 . Oxidation of aldehydes by dilute
ies are oxidized to the
Aldehydes HNOs,
Aldehydes, Ketones & Carboxylic
KMnO4 and K,Cr;O
Acids (309)
corresponding
KMnO4 and K2Cr20; in acidic medium. carboxylic acids
by oxidant such as dil.HNO3,
K,CrO
R-CHO- R-COOH
dil. H,SO
Aldehyde

n
Carboxylic acid

o
Oxidation of Ketones

ofdilute
Ketones resist oxidation due to strong
Oxidizing agents such as CrO3, CO C bond, but they are oxidized by strong
alkaline KMnO4 or hot concentrated
is
s
carboxylic acids having less HNO; to a mixture or
dol).This number of carbon atoms than
the starting
Oxidation of ketones 18 accompanied ketone. Inus,

e
by breaking C- C bond.

R-C-R R-cOOH+R-cOOH
t s
b
(Ketone) (Carboxylie acide)

u
.Clemmenson reduction

C = O+
(Carbonyl group
in akdehydes and
4[H] Zn-Hg, conc. HCI

D o
CH, +H,O
Methylene
group

1
ketones)
rupe
lehydes or
mixture of
.Wolf-Kishner reduction
H,N- NH,
0c 2N-NH,KOH,HO-CHCH-OH CH,+N,

2
C-0 -H,O
Hydrazone (Methylene
aldolizable (Carbonyl group group)

T
in akdehydes and
ketones)

no
CE
Electrophilic substitution reaction
Aromatic aldehydes and ketones
nitration, sulphonation and
are electron-withdrawing by
undergo electrophilic substitution
halogenation.
inductive
The aldehydic
as
(-CHO) and
well as resonance effects.
reactions such as
ketonic (PC-0) groups
They deactivate the
formation of meta-product.

T
ewith
wthile para-positions. This results in the
acid with Denzene ring at ortho- and
mate

H
For example:
le CHO
+H,O edtA

M
CHO
+HO-NO,
(conc. HNO,
NO,
(Benzaldehyde) (m-Nitrobenzaldehyde)
 MHT
Structu
Exam Questions ethy
(310)MHT-CET
Carboxylic acids
Reactions of
sOChROCI+ 80, +HCI
(A))=
Acil chorikde
NH RCOONH, A R-cONH,
HO Amide
o
n
Sat The
POs (RCO%O
7

o
A Ackd anhydride

SOch RCOCI A (RCO),0+ NaCl

Acikd anhydride
is cHa

s
RCOOH NaOH RCoONa
Carboxylic Ack

i NaOH
e
Na,CO, CHs
R-H+

s
CaO, Alkane

t
LiAIH (A)I
R-CH,-OH

b
dry ether Akohol MHT-C

u
Multiple Choice Questions 8.
Writ

MHT-CET 2004
1. Which of the acids cannot be prepared by Grignard
(A)Acetic acid (B) Succinic acid
reagent?
(C) Formic acid

D o (D)All of these

1
MHT-CET 2006
2. Compound A (molecular formula C3Hs0) is treated with
acidified potassium dichromate to

0 2
form a product B (molecular formula C3H,O). B forms a shining silver mirror
ammoniacal silver nitrate. B when treated with an aqueous solution of
sodium acetate gives a product C. Identify the structure of C.
on warming with
HaNCONHNH2. HCl and
(A)
C)

2
(B)(CHs)2C = NNHCONH2 MHT
(A) CH,CH,CH= NNHCONH2
(C)(CHs)2C = NCONHNH2 (D)CHCH,CH = NCONHNH2 9.
R-
MHT-CET 2007

(A) CH,CHO
E T
3. Which does not react with Fehling's
(B) CcHCHO
solution?
(C)CsHi20% (D) HCOOH
(A
C
MHT-CET 2009
C 10.Th

(A

T
crotonaldehyde is
4. The IUPAC name of
(B)butanal--1tmatear sa e C
aho (A)butenaldehyde
H
(C) but-2-en-1-al (D)prop-2-en-1-ol 11.A
(A

M
MHT-CET 2011 C
acetone on dehydration gives
5. Aldol condensation product 2.w
(B)2-methylpent-3-en-4-one
(A) but-2enal
(C)4-hydroxy-4-methylpentan-2-one (D)4-methylpent-3-en-2-one A
olyilst o
 Aldehydes, Ketones &
MHT-CET 2013 Carboxylic Acids (311)

nictuire of the compound

Structur whose IUPAC.
name i
3-ethyl-2-hydroxy-4-mehtvlhe
tylhex-3-en-5-ynoic

n
acid is
OH
QH

o
coOH (C)
0OH ()
is
CoOH
OH
The orde of stability of the following tautomeric compound

s
7. is
OH

e
CH,=C-CH2-C-CH, CH-C-CH,-C-CH,
OH

CH-C=CH-CCH
t s
(A)I>II> II
MHT-CET 2014
(B)II >II>I (C)II>I> III

u b (D)II>III>I

l of these
& Write the IUPAC
OH
name of following compound.

D o
1
HaN

2
CoOH
tassium dichromate to (B)6-amino-4-hydroxybenzoic acid
(A)2-amino-4-hydroxybenzoic acid
irror on warming wi

0
(D)2-carboxy-4-hydroxyaniline
NCONHNH2. HClad (C)3-amino-4-carboxyphenol

2
MHT-CET 2015
is known as
H RCHO + NH4CI this reaction
NH2 9. R-C=N+2 (H) -OSnCydil
(i) Ho

T
(B) Stephen reaction
(A)Etard reaction (D)Balz-Schiemann reaction
(C) Hell-Vohlard-Zelinsky reaction

E
hydrogen cyanide is
and ketones towards
ICOOH correct order of reactivity of aldehydes HCHO> CHCHO

C
he (A)CH COCH> CH,CHO> HCHO
(B)CH COCH> > CHCOCH
(D)HCHO> CH,CHO
CH,CHO> CH,COCH> HCHO
50 % NaOH yields

T
formaldehyde when treated with
benzyl alcohol
of benzaldehyde and formate (B) Sodium formate andmethyl alcohol
Aire
Sodium benzoate and sodium (D)Benzyl alcohol and

H
alcohol
C Sodium benzoate and methyl
acidic in nature?
2.Which compounds is most 3-Chlorobutanoic acid

M
of th wing B)
acid
A)4-Chlorobutanoic aciu (D) Butanoic
Fone )2-Chlorobutanoic acid uty s
2-one
 Exam Questions Wh
(312)MHT-CET 26.
(A)
dibenzyl cadmium
MHT-CET 2016 when treated with dsbenzyl (
compounds n
following
13. Which of the (D)Acetyl The
ketone? Acetaldehyde (C) Acetic acid chloride 27.
(A)Acetone
(B) (A)
reduction is andIKOH in ethylene
reagent used in Wolf-Kishner (B) NH- NH2 gycol 28.
The
14. The
(A)Zn-Hg/conc. HCl (D) Na -Hg/H,0 (A)
(C) NaBH
15. What is the reagent used
in Etard reaction?
Ethanoyl chloride (C)
SnClh and HCI (D) Cadmium chloride

o n (C)

is
(A) Chromyl chloride (B) 29. In t
acid?
following carboxylic acids is a tricarboxylic (A)
16. Which of the (C) Succinic acid (D) Adipic acid

s
(A) Oxalic acid (B) Citric acid
30. In s

e
MHT-CET 2017 (A)

s
17. The acid which contains both -OH
and-COOH groups is (C)
(B) adipic acid (C)glutaric acid (D)salicylic acid
(A)phthalic acid

t
MHT
18. Aldehydes or ketones when treated with CoHs-NH-NH2, the product
formed is

b
31. Wh
(A) semicarbazone (B) phenylhydrazone (C) hydrazone (D) oxime
(A)
19. Which of the following compound will give positive iodoform test?
(A)Isopropyl alcohol
(C) Ethylphenyl ketone
(B) Propionaldehyde

o
D)Benzyl alcohol u D490 9 32. Wh
(A)

MHT-CET 2018

D (B)

1
20. Which of the following is a tricarboxylic acid?
(A)Citric acid (B) Malonic acid (C) Succinic acid D)Malic acid C)

corresponding cyanohydrin?
(A)Acetone (B) Formaldehyde
2
21. Which of the followings is most reactive towards addition reaction of hydrogen cyanide

0
n fim
33.
D)

Wh

2
(C) Acetaldehyde D)Diethylketone
(A)
22. Which of the following compounds does NOT undergo
haloform reaction? D 34. Whi

T
(A) CH-ÇH-CH (B) CH-
-CH3 sulp

E
OH (A)
C)CHs-CH-CHs 35. Whi

C
(D) CH -C,Hs carb
(A).

HT
MHT-CET 2019
23. Which among the following
(A) Acetic acid
compounds is obtained
(B) Formamide
24. Which of the following does
when ethanenitrile isacidhyai
(C)Acetamide acid
(D)Formic
36. Whi
BaS
(A)E
37.1dent

M
not give yellow solid iodite?
(A)Pentan-2-one on treatment with sodium
" CH
(C) Acetophenone ht B) Pentan-3-one
too
(D) Ethanal (A)A
25. The order of reactivity
for addition hydrogen B)A
(A)propanone> methanal of cyanide to carbonyl comphanal
> ethanal
(C)methanal> ethanal>
8) ethanal> propanone> methana (C)A
propanone (D)A
(D) methanal> propanone> ethana
 following compounds
the fol
Vhich of the
Aldehydes, Ketones & Carboxylic
26. Benzophe undergoes aldol Acids (313)
(A) condensation reaction?
methoy 22-Din
Dimethylpropanal (B) Benzaldehyde
) (D) Propanone
reducing agent preferred to convert carboxylic
27. The
(A)H/Ni (B) Na-Hg/H;O acids and esters
(C) NaBH4 to primary alcohols is
correct PAC name of Glyceraldehyde (D) LiAIH
28. The

n
is
(A)2,3-Dihydroxypropanal
(C)3-Hydroxypropanal (B)2,3-Dihydroxybutanal

o
(D)Hydroxy ethanal

is
de 19, In the reaction, CoH,COCH [H
Zn -Hg/conc.HCI,Xis
(A) benzylalcohol (B) methylbenzene

s
(C)toluene
(D) ethylbenzene
ln salicylaldehyde benzene ring is attached with

e
30.
(A)one-OH group and one-CHO group (B) two-OH groups and two-CH0 groups

s
Ctwo-OH groups and one -CHO group (D)one OH group and two-CHO group
-

t
MHT-CET 2020

1.Which of the following carbonyl compounds does NOT

b
undergo aldol condensation?
(A) Benzophenone (B) Acetone (C)Acetaldehyde (D)Acetophenone
32 Which

(A)
of the following is Rosenmund reduction?
Ar-CO-ClPd-Bo,Ar-CHO+HCI
o u
D
B) R-CO-R+ [H]a R-CH, -R+H,Odbrhleadey
(C)R-C=N+2[H] R-CH
R-CHO+NH,CI
= NH-HC1

ide to form -H20

1
D) R-CHOHN-NHR-CH = N-NH,KOHens RroRCH, +N

2
of the following is a solid trimer of formaldehyde?

0
35. Which
(A)Paraformaldehyde (B) Metaldehyde (C)Paraldehyde (D) Trioxane

2
potassium permanganate and dilute
4. Which of the following compounds on heating with
sulphuric acid forms adipic acid? (D)n-Butylbenzene
(C) Methylbenzene

T
(A)Cyclohexene (B) Phenylethene
35. Which among the following substituent group decreases the acidic strength of aromatic

(A)-CI

ich
BaSO4?
CE
carboxylic acid?
(B)-NH2
of the following is obtained by
(C)-CN (D)-NO
hydrogenation of benzoyl chloride
in presence of Pd on

(D)Benzyl alcohol

T
(C) Benzaldehyde
ysed? (A) Benzoic
acid B) Benzene
37. ldentify following reaction

H
the npound A and B in
Daite? CH,CI KCNG
2H;0 >B+NH,CI
HCI
acid

M
AJA =Methylcyanide, B = Methanoic
B)A Ethanenit B= Ethanoic acid
acid
A= ylisocyanide, B Methanoic
(D)ABthanenitrile, B = Methanoic acid
 Identify
to obtain ophenone 48.
Exam Questions with benzonitrile
(314)MHT-CET compounds is treated

n
the following
in
38. Which among hydrolysis? (C)CHsMgBr (D)CH,MgBr 2A + (C

o
acid
dry ether and then
(B) CH,COCH

is
(A)CHONa
reaction. (A)
CH3-
in following
39. Identify the product C
NaOHANOHBHNOC Which am
CH,CH,COOH A
49.

s
(A) CH3-
CaO.A
= CH2 (D)CH,CH,NO,
(B)CH,CH;CH,OH (C)CH;
(A)CHCHCH (C)CH

e
the following
reaction.
40. Identify product 'A' in Which of

s
50.
R-C N DIBA-HA (A) Carbc

t-
i) HO
(C)R-CHNH2 (D)R-CHO0
(B)R-COOH
(A)R-CONH (B) C-C

b
mesityl oxide?
41. What is IUPAC name of (B)4-Methylpent-3-en-2-one (C) Carbe

u
(A)1-Phenylbutan-2-one
()4-Methylbenzaldehyde
(D)2-Bromohexan-3-one D) The c
42. What is IUPAC name of acrolein?
(A)3-methylbut-2-enal
C)Prop-2-enal
43. Identify 'A' and 'B' respectively in following reaction
D o
(B)2-methybut-2-enal
(D)But-2-cnal spomadosre
51.

52. A
What is
(A) sp
reactio
t

1
aldehydic
Toluene
hv A HOB (A) Steph

2
(A) Benzyl chloride and benzaldehyde (B) Benzyl chloride and benzoic acid C) Roser
(C) Benzoyl chloride and benzoic acid (D)Benzoyl chloride and benzaldehyde

0
53. An acylc
44. Chromyl chloride converts methyl group to a chromium complex, which on acid hydrolysis
aldehyde.

2
gives corresponding aldehyde. This reaction is called (A) Wolfi
(A)Etard reaction (B) Wolf-Kishner reaction (C) Etard

T
(C) Stephen reaction (D)Rosenmund reaction 54. Propane
45. Which of the following is NOT dicarboxylic acid?

E
complex.
(A) Succinic acid (B) Acrylic acid (C) Malonic acid (D) Phthalic acid (A)3-Pen

C
46. Identify 'A' in the following reaction, APM 5. Which
d-E CHCHO + HCIcla of
iae (A) Benzoic acid puuy (A)Capro
(B) Chlorobenzene

T
(C) Benzyl chloride 56.Which
(D)Benzoyl chloride lgxnt of
47. Identify product A in the following reaction.
CH-CH

H CH,-C-NH, +H,O+HCI A (A)H,O

S7.ldentify

M
O
A
(A) CH-C-H A+CH,M
ab
(B)CsHs-NH2
O A (A)Acety
(C)CH-C-CI S8.Which
(D)CHs-C-OHti da
oft
(A)2-Brot
C24,6-
 Aldehydes,Kotones&

n
A' the followin reaction Carboxylic Acids (315)
nitrile to obtain ldentify in
i
benzophenone 48

o
in
(D)CHMgBr

is
(CH,CH,), Cd 2CH,-C-CH,-C,H, +cacl,
CH-CO-CI B) CH-Mg-Cl
(A) C)CH-Co-CI D) CcH-CH,-CI

s
(D)CHCH,NO among the following
49.
oh compounds has highest boiling point?
(A) CH-CH2-COCH3

e
CHs-CH-COOH -B (B) CH-CH-CH-CHO
(C) (D) CH-CH-CH:-CH;-OH

D)R-CHo
50
which of

(A) Carbon atom

the

(B) C-C-O bond angle is 90°

following statements is true for carbonyl group?
is sp hybridised

t s
b
en-2-one
(C)Carbonatom forms three sigma bonds
-one

nal
51. What
)sp
is

(B) sp (C) sp
u
(D) The carbonyl bond is weaker as compared to double bond in alkene.

o
the type of hybridization of carbon atom in carbonyl group?
(e) (D)sp'd
os
52. A
reaction
aldehydic group on acid hydrolysis is called

D
in which chromyl chloride in presence of CS2 converts methyl group of toluene to

1
(A) Stephen reaction (B) Etard reaction
nd benzoic acid (D) Gatterman Koch formylation
C)Rosenmund reduction
and benzaldehyde

2
acylchloride is hydrogenated over catalyst palladium on barium sulphate to form an

-
53. An
ex, which on acid hydrolysis aldehyde. This reaction is called as

0
(A) Wolff-Kishner reduction (B) Rosenmund reduction
tion (C)Etardreaction (D) Stephen reaction

2
on S4. Propane nitrile on reaction with ethyl magnesium iodide in
presence of dry ether gives
complex. This imine complex on acid hydrolysis forms.
(C) Butanone (D)2-Pentanone
(A)3-Pentanone (B) Propanone

T
(D) Phthalic acid
Which of the following is a tricarboxylic acid?
S5.
(C)Citric acid (D)Oxalic acid
HCI oby

E
(A)Caproic acid (B) Valeric acid
0.Which of the following reagents is used for the following
conversion?oloted

C
CH-CH CH-CHO CH-CH= CH-CHOH (D)Zn-Hg/HCI
(A)H0 (B) H/Ni a (LiAIH,

T
S7. Identify A in the following reaction

A+CH,MgBr Dcomplex (CH,),C-OH

H
(C)Propionaldehyde (D) Acetaldehyde
4)Acetyl chloride (B)Acetone
bromine water?
when phenol react with
Which of the following compounds is obtained

M A)2-Bromophenol )-bbT((B)3-Bromphenola bas

92,4,6-TribromphenolaatoDK (D)4-Bromophenole lue
 HCN? Which ofth
Questions towards 66. (A)Pd-Ba
MHT-CET Exam highly reactive
(C)CH-CO-CH (D)CH-CHO
(316) compound is
following
59. Which of
the
(B) CH-CHO Which ofth
(A)H-CHo 67.

n
Stephen reaction?
the following
is a
-C=
60. Which of SoR-CHO+HCI (A)

o
KOH/ethylene
(A) R-COCl gycoR-CH,+N, (B)-COC

is D)C
R-CH= N- NH2
(B) R-CH= 0HN -Ha0 +H,O (C)-CO
4[H]n-Hg/conc. HCR-CH,-R

s
(C)R-C-R+

e
H

R-C =0+ NHC

s
NH.HCI-
(D)
R-C=N+2[H]CR-CH dil. H
=
Identify B

t
68.
reaction
'B in the following
61. Identify
R-C
Benzonitrile
CHMgBr
ether
A H B+Mg

u b (A) R-G

o
(C) Diphenyl e(D)Benzophenone
(A) Benzaldehyde (B) Aniline
Identify

D
reduction? 69.
62. Which of the following is Clemmensen CH,COC
H

1
(A) Etha
(A)-C=N+2[H] CH=NHHCI -=0 + NH,CI (C) Etha

(B)-CH 0NN
(C)-CO-+ 4[H]a-Hconc.
R-CH =N-NH,

0 -CH,
2 -CH, +N 70. Which c
presence
(A) Ace

2
- + H,O

H2 + HCI 71.Which
(D)-CO-CI- Pd-BaSO4-CHO

T
dry ethe
te aaid (A) But
63. 1dentify the product Y in the following series of reactions.23uwal2
o

E
C) Pro

C
4-Nitrotoluene hOCo
273-278K HoY 72.Which
(B)4-Nitrobenzoic acid H3HO-80
(A) Benzaldehyde (A) Eth

T
(C)Acetophenone (D)4-Nitrobenzaldehyde 73. Identif6
64. What is the final product obtained when benzonitrile
niden (A) Ac

H
react with phenyl magnesiu
equimolar proportion?
(A) Dicyclohexane
74. Which
(B) Diphenyl magnesium bromide

M
(C)Benzene mixture
D)Benzophenone called (A) Ac
65. The reaction in which methyl
group on benzene ring is converted
(A) Etard reaction to aldehyaic 75. Which
(C)Rosenmund reaction
5B) Fridel - Craft reaction (A) CH
dC DGatterman Koch reaction (C)CH
 Aldehydes, Ketones & Carboxylic
Acids (317)
following catalysti used in Rosenmund reaction?
Hhic of the
06(A)Pd-BaSO (B) CS2

n
C)CuClh (D)V,0s
hich of the following is a Wolf - Kishner reduction?

o
67.Which

A)-CN+2[H]-dil HC-CH=
HCI
NH.HCI -CHO + NH,CI
is
s
(B)-COClpd-Baso, -CHO+ HCI

e
Zn-Hg/conc.HC-CH,-+
(C)-CO-+4 A H,O

(D)-0
KN-Ne
-H,0
xOH/ ethylene gyeol
-N-NH CH,+N

t s
b
68.Identify B in the following reaction

u
R-C=N-SC/HCLdiA B+NH,CI

o
=
(A)R-C=0 (B) R-C- OH (C) RCH2-NH D) R- C 0
NH

D
H

Identify the product B in the following reaction.

1
69.

CH,COOH+C,H,OH A>B (B)Ethanol and propionic acid

2
(A) Ethanol
(D) Ethanol and ethanoic acid
(C) Ethanol and propanol

0
reacts with benzoyl chloride in
is obtained when benzene
*70. Which of the following compounds

2
presence of anhydrous AlCly? (D) Chlorobenzene
Benzophenone
(B) C) Benzaldehyde
(A) Acetophenone
Butan-2-one is treated with CH,Mgl in

T
compounds is obtained when
71. Which of the following
dry ether and then acid
hydrolysed?
(B) 2-Methylbutan-2-ol
-
(A) Butan-1-ol

E
(C) Propan-1-ol

C
72. Which of following
acid (B)
u
Ethanal (C) Ethanol
(D) 2-Methylpropan-2-ol

ethanoic anhydride is treated

compounds is obtained when Ethyl ethanoate
(D)
with water?

T
(A) Ethanoic hydrolysed further.
chain chlorination of toluene and
obtained by side D) Benzaldehyde
73. Identify the compound alcohol (C) Benzophenone
Benzyl

H
Acetophenone (B)
(NaOH +I)
de 1 (A)
NOT give yellow precipitate when reacted with
following does
74.Which the of

M
(C) Acetophenone (D) Acetone
mixture? Benzaldehyde
(B)
(A) Acetaldehyde treatment with DIBAL-H yields dodecanal at
195 K?
compound on
following (B) CaHCN
75. Which amomong the
CH,CH = CH CH, CN
pe
g (D) C6 HsCN
(A)
(C)CH(CH2)1oCOOCH
 thi
Whatis
(A)ketone
s9. formal

318)
MHT-CET Exam
Questions

following
compounds is
obtained on
ozonolysisofof = followed
by reduction (B)othera
(C)tormal
76. Which of the
(D) Propanal
(D)
Aldehyyde
water? C)Propanone
with Zn dust and (B) Butanone 1-dichlorocyclohev. 90.
concentrat
hydrolysis of 1, exane?

n
(A) Butanal alkaline Clemr
following is obtained on Benzaldehyde (A)
77. Which ofthe
(B)
Cyclohexanone (C)Wolf

o
Cyelohexane carbaldehyde (D)
(A)

is
(C)Cyclohexanol property of carboxylic acid? Which
explain the acidic
78. Which among the
following reactions
R-C-CI+SO,t +HCIT
91. iodide fo
(A)R-C-OH+SOCl (A)Propa

s
+
R-C-OH +R-
(B)
OHCHS R-C-OR HO + H;T Which of

e
2R-C-ONa 92.
C)R-C-OH +2 Na (A)
Chloi

s
POs(R-CO),0 + Ho
(D) 2 R-C-OH mar
93. How
A
Ten

t
79. What is the molecular
formula of glyceraldehyde? (D) C HO (A)
(B) CH,O4 C) CH,O
CH:O Which of

b
(A)
94.
succinic acid ?
80. What is IUPAC name of
Propanedioic acid (C) Butanedioic acid (D)
Pentanedioic acid (A) CH3

u
(A) Ethanedioic acid (B)
dryice HOH
B in following reaction C,H,MgBr- dry ether A dil HCIB.

o
81. Identify the product o
95. Which
(B) CH,COOH (C)CH,OH D) CcH CH (A)KCr
(A) CH COC
82. Which among the following compounds does
(A) Formaldehyde (B) Butyraldehyde (C)Acetaldehyde
D
NOT undergo aldol condensation?
(D)Propionaldehyde
(C) dil. F
96. Whicha

(A) o-nitrobenzoic acid

(p-nitrobenzoic acid
2 1
83. Which among the following aromatic acids is a strongest acid?
ento (B) m-nitrobenzoic acid
(D) p-methoxybenzoic acidoeoto
in preser
(A) Acet

0
97. Which
84. Which of the following functional groups is reduced
by diborane? a
carboxy

2
(A)Carboxyl group (B) Halo group
Nitro group
pp D) Ester group
(A)-OH
98. Which
a
85. Which of the following compounds is not isomeric with diethyl ether? o-1-ta (

T
(A) But
(A) n-Propyl methyl ether (B) Butanone

E
C)Butan-1-ol (D) 2-Methylpropan-2-ol 99. Identify
suW bentatdo er dbiioginoo grniwrolloi 1o toid
86. Identify A in the following reaction. Acetyl c

C
8) biat oionndA (
dry etherR HOH (A)Acet
Dry ice+ Isobutyric acid+ Mg(CI)OH
o ioH C)Ben

T
(A) Isobutyl magnesium chloride (B) Isopropyl magnesium chlorideAA 100.
Which
(C)n-Propyl magnesium chloride (D) n-Butyl magnesium chloride reaction

H 87. Aspirin is an acetylation product of

(A) 2-hydroxy benzoic acid
0)
(B)1,4-dihydroxy benzene
(A)
C)
101. SnC
Cl

M
(C)3-hydroxy benzoic acid (D) 1,2-dihydroxy benzene Which
88. Which of the following carboxylic acids has
highest acidic strength? gnom
(A)o-
(A)Chloroacetic acid
5631 (B)Trichloroacetic acid B
C)m-
(C) Dichloroacetic acid 102.
tU (D)Acetic acidrD002HD) Tdentif
(A)
3,5-
C3,5
 Aldehydes,Ketones
he correct order of reactivity of HCN & Carboxylic Acids
is th (319)
Vhat towards aldehydes
owed by o.etones< other aldehydes < formaldehyde and ketones?
reducti

n
ction formaldehyde < ketones other aldehydes
ther aldehydes < formaldehyde < ketones

o
panal D)formaldehyde < other aldehydes
<ketones

is
hexane? dahvdes and ketones those are not
90.A sensitive to acids when heated
entrated hydrochloric acid give alkane.
concent with zinc amalgam and
This reaction is known as
reduction

s
(A) Clemmensen (B) Rosenmund reduction
acid? (C)Wolf- Kishner reduction (D) Stephen reaction
hich the following compounds yields 3-Ethylpentan-3-ol

e
Oof
by using ethyl magnesium

s
iodide followed by acid hydrolysis?
(A) Propanone (B) Pentan-2-one (C) Butanone (D) Pentan-3-one
92.Which of the following compounds does NOT undergo Friedel-Crafts reaction?
(A) Chlorobenzene (B) Benzoic acid
93.
(D) Benzene

b
(D) Toluene
many carbon atoms are present in a molecule of benzylmethyl ketone? t
u
How

(A) Ten (B) Seven (C) Nine (D) Eight

A

o
94. Which of the following has highest boiling point?
dioic acid (D) CH-CH-CH-OH
(A) CHy-CH-0-CH (B) CH3-CH2-CHO (C) CH, -C-CH,

D
B.
95. following reagents is used to avoid further oxidation of aldehydes?
Which of

1
(A)KCrO7/ dil. HaSO4 B) CsHsNHCrO,CI
(C) dil. HNO3 D)CrO
aldehyde

2
with CO and HC1
following compounds is obtained when benzene treated
is
96. Which among the
in presence of catalyst anhydrous
AIClh and Cu2Clh under high pressure?

0
D)Benzaldehyde
(A)Acetophenone (B) Toluene (C) Benzoic acid
aromatic
increases the acidic strength of

2
7. Which among the following substituent groups
carboxylic acids? (D)-CH
(A)-OH (B)-NH2 (C)-NO

T
highest boiling point'?
8. Which among the following compounds has (D)2-Methylbut-1-ene
(B) Butan-2-one (C) Propanoic acid

E
(A) Butan2-ol
99. Identify the product A in following reaction:

C
Acetyl chloride + Dibenzylcadmium A
(B) Benzyl methyl ketone
(A)Acetophenone (D) Benzoic acid
(C) Benzophenone Stephen
from alkyl cyanides by

T from following is used to prepare aldehydes

00. Which reagent
reaction? (B) DIBAI-H, HO"

H
(A) Clh/hv, H20 (D) CO, HCI (anhydrous AlCl)
SnCl/dil. HC1, H,O benzoic acid?
(C) following aromanc acids nas less acidic strength than
101. Which of the (B)o-nitrobenzoic acid

M
o-chlorobenzoic acid methoxy benzoic acid
(D)p-
(A) nitrobenzoic acid chloride ?
(C) m- ) dinitrobenzoic acid heated with thionyl
is
obtained when 3, (B)3-Chloro-5-nitrobenzoic acid
102. Identify the product chloride
3,5-Dinitrobenzoyl (D)3,5-Dinitrobenzyl chloride
(A) 3,5-Dichlorobenzyl chloride
(C)
 compound? (B)
Questions
a carbonyl 7.
MHT-CET Exam
The ro
(D)Ethoxy
(320) compounds is NOT(C) Acetamide ethane
following
(B)Propanamide H-bon
the
103. Which of chloride
(A) Acetyl

n
SOLUTIONS
H,C

o
(Stabili
reagent with CO
and H

is
(C) of Grignard
by reactioncarbon
prepared atom.
Carboxylic acids are one
(HCOOH) has only reagent,
*Fomic acid cannot be prepared from Grignard
8. (A)

s
Formic acid
HOHRCOOH

e
RMgX+CO,
R-C-OMgX- Acid

s
Grignard
reagent HN
2. (A)

() Aldehydes reduce
i) 1 alcohol
ammoniacal

aldehyde.
AgNO, to silver mirror.

with ammonia derivative

b t Priori
There

u
Aldehydes give addition product
(1i)
(C3H,O) is aldehyde.

o
A (CH,0) is 1° alcohol; B
CHCH,CH=NNH H
CH,CH,CHO NHCONH
CH,CH,CH,OH

D
2-amind
Propanal
Propanol
9. (B)
3. (B)

1
Aromatic aldehyde i.e. CsH CHO are not able to reduce Fehling's solution. bo
R-
2
4. (C)
The structural formula of Crotonaldehyde is ad osdulbo This 1

0
CH-CH-HCHO
But-2-en-1-al 10. (D)

2
H0- Cyan
5. (D)
C C=0+HCH,coCH, e CH F

T
c-CH,COCH H,0,CH-Ç-CHCOCH
CH CH OH 11. (B)

E e bc
Acetone CH
A mi
Di-acetone alcohol de 4-methylpent-3-en-2-40t

C
& alcoh
or mesityl oxide
It is c

T
NH
6. (B)

H CoOH
H0N

M
12. (C)
Chain of 6C-atoms The a
This is the structure 2-Ch
of given compound.
osudinit
 Aldehydes,
(B) 8-dicarbonyl Ketones
7 rolls of B-dicarbonyl compounds
con & Carboxylic
Acids (321)
ethane nding. Thus,
H-bond the order of stabilityare more stable
is because
OH of conjugation
and intramolecular
H,C-C --CH>CH-C-CH,--CH>
Stabilised by conjugation
OH
CH,=C-CH,--CH

o n
is
and H-bonding) Less stable
as () bond
1s not
in conjugation with
carbonyl group

OH

e s
HN COOH
Priority order of functional groups
There fore, IUPAC name is -coOH>-OH> -NH

t s
b
of the compound is as
QH follows

CONH2
HN
COOH
2-amino-4-hydroxybenzoic acid

o u
9 (B)

D
1
H
20H)SnCh/dnl. HCR-CH = NHHCI
R-C0+NH,CI
This

10.(D)
reaction is called Stephen reaction.

0 2
2
Cyanohydrin formation is reversible. The order of reactivity is
Formaldehyde> other aldehyde> ketones
The correct order is HCHO > CH,CHO> CH,COCH

T
cCoCH
11.(B)
50 % NaOH gives benzyl

E
when treated with
A mixture of benzaldehyde and formaldehyde
en-2-one alcohol and sodium formate.

C
It
is cross Cannizzaro's reaction

H CHOH
H-C-ONa

T
NH + NaOH
=0 + H-C=O (50%)
Sodium formate

H
Benzyl alcohol
Benzaldehyde Formaldehyde
12.(C)

M e 4-chlorobutanoic acid > Butanoic acid

acid strength of the given acids 1s pKa=4.8
3-chlorobutanoic acid>
hloro butanoic Cid > pKa =4.5
acid
pKa=4.0 trt
pKa =2.9
oole
 MHT-CET Exam
Questions 20. (A)
(322)
cadmium >
ketone
Benzyl methyl1 ketone 1e e
13. (D)
Acetyl chloride
+ Dibenzyl HO-

n
+CdCl2 C
-C-CH, CHs
CH-C-Cl+(CH,CH,), Cd2CH
Benzylmethyl ketone

o
2 Dibenyl
cadmium 21. (B)

is
Acetyl chloride ethylene Formald
and KOH in
and ethylene glycol.
14. (B) Wolf-Kishner reduction is NH;-NH2 Reactivi
The reagent used
in
glyeol CH,+ N, In aldeh
c=N-NH,KOH/ethylene
=0-aNH0 N2 Hydrazone

in Etard reaction.

e s 22. (C)
Only m
reaction

s
15. (A) used
Chromyl chloride is the reagent CH (OCrOHC1) CHO 23. (A)

t
CH
H,0
+CrO,Cl 24. (B)

b
Oxidati
Toluene Chromium Complex oa Benzaldehyde carbon
16.((B)
Citric acid is a tricarboxylic acid.

o u 25. (C)
29. (D)

D
CH2 -C-OH

1
HO-C-C-OH

2
CH-C-OH AD(0-Ma0- Ace
Citric Acid (Tricarboxylic acid)

17. (D)
COOH

OH
2 0 30. (A)
31. (A)
Absen

T
32. (A)

E
34. (A)
Salicylic acid
tot sit cof

C
18. (B)
R noxtaes
HN-NH-CH,
H c=N-NH-CH,

T
H
Aldebyde Cyclo

H
35. (B)
R
c=0+ HN-NH-CH c=N-NH-CHsbabla -NH2

M
R
Ketone
Phenyl hydrazone make
19. (A)
withd
Alcohols having biu aineltidalh
R-C-CH, structure give positive iodoform
test.
OH
 Aldehydes, Ketones & Carboxylic
Acids (323)
20.(A) CH,-COOH

n
HO--COOH Citric acid

o
CH-COOH

O1.
21.(3)
Formaldehyde
Deactivity towards nucleophilic addition: Aldehyde > Ketone. is
s
aldehydes HCHO > CH;CHO > CH,CHCHO
n

e
.(C)
ketones, acetaldehyde and 2° alcohol with

s
Only CH,-ÇH-R group gives iodoform
reaction. OH

23.(4)
24.(B)
Oxridation

b t
of methyl ketones by aldehyde and ketones having at least one methyl group linked to
carbonyl carbon oxidized by sodium hypohalide solution.
15.(C)

29.(D)
26. (D) 27. (D) 28. (A)

o u
CH H
D CHCH

Acetpphenone
Zn/Hg/Conc.HCI

2 1 Ethyl benezene

0
30.(A)

2
31.(A) 43
Absence of a-Hydrogen atom.

33. (D)

T
32. (A)
34.(A)

E KMnO,/dil H,SO,
coOH
coOH

C
+4(0)-
Adipic acid 3)
Cyclohexane

HT 35. (B)

NH2 is electron
make aromatic
activate the benzene ring to
donating group which acidic. While -cl, -CN and
carboxylic acids less acidity of aromatic carboxylic
withdrawing groups
which increases the
electrophilic attack and
-NO2 are electron
acids.

H-3-H3

M ias--qo
 (A)
Side c
43.
Exam
Questions
MHT-CET
(324)
36. (C)
Rosenmund reduction
Tol

n
-H
-CI
44. (A)
H
Pd/BaSO,
+HCI
Benzaldehyde
iso Whe
com
Etar

s
Benzoyl chloride

37. (B)
2H,0CH, --OH+
KCNa) CH, -C=N- HCI Ethanoic acid
NH,CI

s e
A

t
CH,CI
A Ethanenitrile
Chloromethane -KC sldsbin (B)

b
(A) 45. (B)
O)2

u
38. (C) NMg Br
Mg Br
H

o
OH+NH
(U

D
tmneconpiex Bantophcnone
Pheayl magoesium
Beseonitnik*
46. (D)

1
Wh
39. (D) pal

CH,-CH, --OH-
Propanoic acid
NaOH

0 2 NaOH
CH, -CH, -C-ONa- CaO,A CH,-CH
Sodium propionate -Na,CO,
Ethane
is c
47. (D)
W

2
(B)
(A)
HNO,

T
(On

CE 2. ibl,Onkd
CH, -CH, - NO, +H,0
Nitroethane
(C)
48. (A
Bea

T
40. (D)
2
41. (B)

H (CH)-C=CH--CH, vb uio ou al 49. (C

M 42. (C)

CH,=CH-C-H
Prop 2- enal
Ca
hy
 Aldehydes, Kotones
& Carboxylic
Aclds (325)
chlori
lorination of toluene gives benzal
chain chloride which
Side on hydrolysis gives benzaldehyde.
CH,C CHC
CR CH(O)

n
CHO
Sunlight Sunllght

o
HC)
-HC Benzs
Benznl

is
chloiode chloride (unetabie) Benaaldehyde

A(4)
is treated with solution of chromyl
obtained, which on acid hydrolysis chloride (CrO,Clh) in CS2, brown chrominum

s
When
complex gives benzaldehyde. This
reaction is called
Etard reaction.
CH

+2C10C S
CHCCLoOH
oCc,oH Ho
CHO

s e
t
oysls
A E Toloeos
droly
Benzaldehyde

b
Brown chromium
compier

u
56)

NH
HC=CH-OH
Acrylic acid
(Unsaturated carboxylic acid)
mumu

D o
holdFciozt9

1
46. D)
COCI CHO
When benzoyl chloride is hydrogenated in the presence

2 HC
paladium on barium sulphate (Pd/BaSO), benzaldehyde H, -8aSo
is obtained. This reaction is called Rosenmund reduction. Bauy etine

0
Benzaldehyde

41.(D)

2
benzamide is heated with dil. HCl, benzoic acid is obtained.
1 When

T
NH OH
H20+HC1- +NH,CI

H,O Benzaemride

4(A)

CE Benzoic acid

HT
C)
C-CI+
Acetyl
chloride
(C,H,CH,), Cd 2CH, -C-CH, -CH,
Benzyl methyl ketone
+ Cacl

M
ether,
alcohols, aldehydes, ketones,
points than those of
ydrocarhds possess higher boiling
aDons of comparable molecular masses.
 Exam Questions
(326) MHT-CET
50. (C)

56.

Orbital diagram for the

formation of carbonyl

o n
is
51.( 51
Structure of Carbonyl group

C' atom forms three 'o' bonds, it

is sps - hybridized.

e s
52. (B)

ocrOH)C,
t s CHO 58.
H
CrO,Cl, OCrOH)C,

u b HO 2

o
Chromyl Chloride
Toluene (Chromium Complex) Benzaladehyde

D
This is known as Etard reaction.
(bi3 or0 bolmutean)
53. (B)

1
54.(A)

CH, -CH,-C=N
Propane nitrile
nDuouber

0
C.H, Mg-I
-

2 CH, -CH,
--C,H,
59.

60. (D
Di

2
Bss bro gre D6 iComplexi ahresrnd saf
61. (D
H,O

E T
C
NH, + Mg +CH,-CH, -C-CH, -CH, Benz
OH A
55. (C) Pentan 3-one 62. (C)

HT CH-C-OH
sbldn
63.(D)

M ots HO0-C. C-OH

pts
tatii aiog goiod NO
CH-C-OH
ted eSryg als eipur 4-N
Citric acid (Tricarboxylic
acid)
 Aldehydes,
CH, CH, CH, -CH, -COOH - Valeric
- Ketones8& Carboxylic
-

CH, CH,,-CH,-CH, -CH, -COOH-Caproic

acid Aclds(327
C-CoOH Oxalic acid - acid(Monocarboxylic
(Dicarboxylic acid)
acid)

n
56%.(C
LiAIH doe not reduces isolated olefin
bond and hence

o
etones to unsaturated alcohols. it can reduce

is
unsaturated aldehyde
and
57.(B)

ioOMgBr
C-O+CH,MgBrCther
HC
H,C
HoH,C-C-OH+Mg
e s Br

s
CH
Acetone CH OH

t
(A) Complex
tert-butyl alcohol

b
58%.(C)
HO When phenol 1s treated
With bromine water, a

u
2,4,6-tribromophenol is formed. yellowish white
precipitate of

adehyde
QH

+3Br, T.
OH

D
Br
o ehiold lyrsA

+3HBr

1
Phenol

2
2,4,6-tribromophenot
59.(A)

0
Due to less steric hinderance.
0.(D)

61.(D)

2 oHOB.doo-namTm

T
N Mg Br
Mg-Br
Br+NH

E
OH +NH,
*

C
enaonitrile imine complex Benzophenone
Phenyi magnesium
bromide
2C)

HT
3.D)

CH
+(CH,CO),0 273-278K
CH
OCOCHylbal
OCoCH,
brokls ioxad

HO
an
mdl
CHO

M
NO CrO NO
Norololucne NO
Diacetate derivative
+-Nitrobenzaldehyde

-
 (A)
68.
Exam Questions
(328)
MHT-CET R-
N Mg Br
64. (D)
Mg-B Dy ther MeN,
Benzophenone 69. (A)
lmine conprek

n
Benaonierie
henyl ma nesiu CH

o
65. (A)
CHO

is
(A) Etard
reaction
OCICI,OH For
CH Este
cocCLOH bydrolysis

s
Benzaidehyde
70. (B)

e
ouene Brown chromium
contplex

(B)Fridel-Craft reaction
CH
CH,

t s
b
AICI, HCI cdottt-2
+CH, -C-CI

u
Acetyl Chloride Frie
COCH

o
Toluene
71.
4-methyl acetophenone
(C) Rosenmund reaction
cOCi CHO
D CH

|+H,
Benzoyl chloride
P-Bas50

2 1
Benzaldehyde
+HC1

(D)Gatterman Koch reaction

CH

2 0 CH

T
Co HCI
AICl

E
Toluene
CHO

C
4-Methylbenzaldehyde
66. (A)
COCi
CHO 2.(A)
When benzoyl chloride is hydrogenated in the

T
presence palladium on barium sulphate +HC
Pa-BaSO
(Pd/BaSO4), benzaldehyde is obtained.
This
+H,

H
reaction is called Rosenmund CE
reduction. Benzoyl chloride
Benzaldehyde
67. D)
Carbonyl group is converted followed
Et

M N2 H
to corresponding alkane group in presence
KOH and ethylene glycol. of
anh
HN-NH
KOR/ ethylene glycol
N-NH
-H0 Ha+N
 Aldehydes, Ketones & Carboxylic Acids
(329)

AA) SnCl,/dil.HCI R-CH=NH

R-C=N Stephen's reduction R-C= 0+NH,CI

n
Br H
OHNH,

o
9%.(A)

"N
is
H H,/Ni
CH,COOH+C,H,OH LoH-C-0C,H, 2CH CH,OHH
(A) (B)
Formation of A
Ester on catalytic
- Esterification.
reduction gives alcohol.

e s
70..(B)
R

t s
b
C-CI
ot(eD)3polo

Friedel Craft acylation

AICL

o
Benzophenone u
HOOO3EO),R0
a eVIH-JAIC
71. (B)

D QMg

CH,--CH,CH, +CH,Mgl
Butan-2-0ne

2 1
dry ether,CH, -¢-CH_CH,
CH,

2 0 HoOH
H' HO
OH
CH,-C-CH,CH,

E T aitonsasd
2-
CH,
Methyl butan-2-ol
olioib-1
d olsg

(A)
C aMO-2

T
CHO
+HCI H,O2CH,COOH

H
CH
Ethanoic
tnldehyde
Ethanoic acid

M
followedby anhydride
2
Bslurmot nlaooioly
 Questions 80.
MHT-CETExam S
(330) OH
73. (D)
ba
H--OH
ÇHC%

C/hv
HCI

o n81.

is
H-=o

74. (B) methyl ketones having s

haloform

e
CH3CO-group undergo oformreaction

s
Acetaldehyde, acetone and CH;CO-group)
(Benzaladehyde > Absence of

75. (C)
Dodecanal= CH(CH3)1oCHO
CH,(CH, COOCH,
DIAL-HCH,(CH,), CHO
b t 82.

u
Do decanal
converts esters into aldehyde.

o
DIBAL H
76. (C)

H ,CH
()0,
D
2H,C-C-CH HD H3-0- 83.

1
(2) Zn dust H,O
Propanone atro--a1chsie
CH

2
H,C

0
77. (D)

HOOH

2
C
C
NaOH -H,O

T
H,O

1,1- dichloro Cyclo hexanone

78. (C)

CE
cyclo hexane
tslud erlisM
Acid is a substance which gives out H' ion.
2R-f-OH 2Na
T
R--ONa +H, T
O

H
The above reaction shows the acidic 84.
nature.
79. (C)

M
ÇHO

ÇHOH

CH,OH
Glyceraldehyde: Molecularformula
C.HO
 Aldehydes,
Kotones&
(C)
Succinicacid COOH
CarboxylleAclids
(331)

3utan-1,4-dioic acid CH

n
CH,
or Butanedioic acid

o
COOH
MO
s1.(8)
is
s
R
A-ceo + PhMgBr Ph-C-0MgBr
haloform
reaction.
(Dry ice CO (A)
HOH

s e
t
| dil. HCI

b
Br
PhCOOH+ Mg

u
(B) OH
82(A)
eoOE D M

o
2or at alummo!
3lebe luoim irfib anunlad
Presence of a-Hydrogen is required for aldol condensation.

Formaldehyde H-C-H has no a

D
- Hydrogen in it.
83.(A)

2 1
The presence of electron withdrawing groups increases
whereas electron donating group decreases the acidic nature.
the acidic nature of benzoic acid

COOH

NO

2 0 ÇOOH

O
çoOH çoOH

E T
(1-R
Orthoeffect)
NO, abnbyilk
NO
OMe

hra oalsilol)

C O
uilriÇOOH
NO,
Strongest

T
acid:

aii quots ureebudh

natalt

H
A.(A) iy to giblos oR6o

M
RCOOH B,H, /etherR.CH,OH
H
h-he HO0-HOHO09
acid
Reduction Alcono -
 shelayVdes
Lo
(332)MHT-CET Exam
Questions
a
C'atom e
athydogen
85.((B)
H,C-CH, -0-CH,CH,

n
H,C-CH,-CH, -0-CH,
Diethylether
n-Propyl methyl ether

o
(M.F.C,H,0)

is
H,C-CH,CH,CH, -OH Carbony
Butan-1-ol

H,C-C-CH,
OH

e s
s
CH,
H,C-CH,

t
2-Methyl propan-2-ol
H,C--CH,CH,

b
Pentan

u
Butanone
(M.F.C,H,O)

o
Since, butanone has different molecular formula; it is not isomeric with diethyl ether.
H,C-CH
86. (B) ho sottues
rotaaniatea lobili aolbonipn aiatehgit-o
CH
Ji reyoihg
D CH 3-Ethy

1
O-C-O + H,C-CH-MgC H
Dry ice
0-C-CH-CH,
Isopr opyt magnesinm ch oride
H,C-CH-C=0 Ma
HOH

2
92.(B)
OMgCtigo0 Tsobutyric
OH
Deactivated
acia

0
87.(A)

2
COOH
coOH
+H,C-C-0-c-CH, CH, -OH

T
OH Acetic Anhydride
oçCH,
2-hydroxy benzoic avid

E
Since
(Salicylic acid) -CO
Friedel-Cra

C
Acetyisalicylie acid
Os(Aspirin)
88. (B)

HT Electron withdrawing
trichloroacetic acid is
Order of increasing
group like -Cl, increases
very low so stronger
acidity
is the
acidity of carboxylic acid and
acid.

HHO ÇI
pk, vaucof
HC-

Benzyl

M
CH,COOH<
CH, -C0OH <CI-CH-COOH<CI-C-COOH Numbermett

DSoling of
Alcohols
poin
nadcohols
>\
 Aldehydes,Ketones
& Carboxylic
Acids (333)
S(A) ndketones, +I effect of alkyl groups
ldehy
er
atom. Lower the
is t electrophilic character; lower
decrease electrophilic
is
(E) 2e
character of carbonyl
the reactivity towards
hydrogen cyanide to form corresponding cyanohydrin.
C

addition reaction
of

n
90.(A)
Zn-Hg, conc.HCI olhinodocolifD nuwioibiry

o
C- 0 +4[H]
-CH, +H,0

is
A
(9
Carbonyl group Methylene
group
o roialyrol
s
oD14 du tnotta
91.(D)

H,C-CH,-f-CH,CH,+C,H,Mgl- Dry
H,C-CH¢-CH,CH,
s e
Hydrolysis

t
ether
OMg

b
Pentan-3-One
sgasmad o1 bpeug 916 10FComplex to uga as

u
H, onisdoai obvris blasn9dOu9O1A
er.x ().re

o
H,C-CH, -C-CH,CH3 + Mgnote ibtas stor3i quong gnivathiwT n0dosl3
OH 3l O -OHD-quo8 0-83

D
OH
3-Ethylpentan-3-ol O1.8
o
OH
1
gniliod rodgii svnil abioe ilyzodeOp
92.( 1/e csnn to seodi nritFriedel
ztioq
23o2 D
Crafts conditions.

2
Deactivated benzene are not reactive to
CoOH

,.C-0 HO-
2 0Benzoic acid

T
group it deactivates the benzene towards
electron withdrawing
Since COOH group is

E
Friedel-Crafts reaction.
DQ0--16q01qisl-

C
93. (C)

H,C--CH, MD-

T
1OP-H-OH-9+ H
valueof O
obinolitoonberl aniou
sbinsg lelA
pK,

H
Benzyl methyl ketone (CIh.01
A Number of'C' atoms=
tO0a18 go (t0-) xodiom 30ai
uatt ganot
following order sood bubinalks
1oit i toagujoo

M
follov
4.(D)ri sey8 in
decreases in the onutauz ssilidaa quo briiw
Boiling point aldehyde >e ether ub
therefore
rli boiling point.
higher
>ketone > fore it has
Alcohols present,
bonding is
ln alcohols 'H'
 Exam Questions 102. (A)
(334) MHT-CET
95. (B)

r-Cl
NH
Pyridinium Chlorochromate

o n 0,N

96.0(D)
(PCC)

is
s
Koch formylation of
arene:
Gatterman -
ÇHO 103. (D)

CO+HCI
Anhyd.AICl,/CuCl

s e Comp

t
Benzaldehyde
benzene in the presence of anhes

b
When vapours of C0 and HCl are passed into ahydroua
H
AICl/CuCI, benzaldehyde is obtained.
97. (C)

e.g,-NO group, -CH0, -C=0 etc.

o u
Electron withdrawing group increases acidic strength of aromatic carboxylic acid
HO H
98. (C)

D
Carboxylic acids have higher boiling points than those of alkanes, ethers, alcohols, aldehyda

1
and ketones. In liquid phase carboxylic acid forms dimer, double the size the moleule
of
resulting in increase in intermolecular van der Waals forces.

99. (B)

0 2
2
2H,C-C-Cl+(C,H,CH,),cd
CH,-C-CH, + CáCl,
2
Acetyl chloride Dibenzyl
cadmium
ether
l equo 009-302

T
Qsatasbon
1- Phenylpropan - 2- one

E
(Benzyl methyl ketone)
100.(C)

C
10-9-2
R-C=N + 2H] SnCl,, HCI
R HC = NH- HCI 0NH,CI+R-CHO
Alkyl cyanides

T
imine hydrochloride
101.(D) snos hgisn Aldehyoe
Since, methoxy-OCH3)

H conjugation is not group is electron

donating ring, d
but
withdrawing group
extended because
of which structure itactivates
AS
electu
stabilize the structure is not much stao
due to resonance.abi

M
a
 Aldehydes, Ketones & Carboxylic Acids (335)

102. (A)

ÇOOH
sMotsodeaus eslug Cg

o n
1ba+
is
SOCl, ainon
NO, Thionyliefsl NO
0,N

s
Chloride

e olap90 em3, 5-Dintrobenzoyl Chloride urp

103. (D)

s e
Compounds containing C-groups are called carbonyl compounds.

b t
u
nce of anhydrous
H,C-C-CI
H,C-CH,OCH,CH,
Acetyl Chloride

o
K
Ethoxy ethane

acid.

D
H,C-CH,-C-NH, H,C-C-NH,
Propanamide Acetamide

alcohols, aldehydes
ze of the molecule

2 1
CdClh
2 0 H00-

(128
E T 9-
-03-

C
1+R-CHO
a Aldehyde
HT
but the
ring electro

M
the
S
le.
Whereas

oiooia