Hs. 1st Year Chemistry 2019
Hs. 1st Year Chemistry 2019
Hs. 1st Year Chemistry 2019
CHEMISTRY
(Theory)
Full Marks: 70
Time: Three hours
The figures in the margin indicate full marks for the questions.
General Instructions:
1) Question No. 1 is compulsory.
2) From Question No. 2, answer any ten.
3) From Question No. 3, answer any nine.
4) From Question No. 4, answer any three.
5) Answer should be specific and to the point.
1. Answer the following questions: 1x8=8
a) Atomic number of Mg is 12 and its mass number is 24. How many protons and electrons does a Mg 2+
ion have?
b) Calculate the number of moles in 10 g of CH4 .
c) Give two examples of state function.
d) Write down the formula of Baking Soda.
e) Why liquid drops are spherical?
f) Arrange the following in ascending order of their stabilities:
(CH 3 )3 C, C H 3 , CH 3 C H 2 , (CH 3 )2 C H
g) What is the Oxidation number of Mn in KMnO 4 ?
h) Mention the shape of PCl5 molecule.
a) Draw the molecular energy level diagram for O +2 molecule and find the bond order of the species.
b) 250cm3 of nitrogen at 720mm pressure is mixed with 380cm3 of oxide at 650mm pressure in
1dm 3 vessel at constant temperature. What be the total pressure of the gas mixture?
c) Write short notes on:
1) Photoelectric effect.
2) Black-body radiation.
d) State and explain Hess’s law of constant heat formation.
e) What are hydrides? Give one example of each of the following:
1) Covalent hydride.
2) Metallic hydride.
f) Write a short note on silicones and silicates. 3
g) Write short notes on global warming. Name one greenhouse gas. 2+1=3
h) Explain the variation of first ionization energy in F, O, N and C. 3
i) The enthalpy of combustion of C, H2 and C2 H4 are given below: 3
1) C(s ) + O2 (g ) → CO2 (g ); ΔH 0C = −393.5 kJ
2) H 2 (g ) + 1 O 2 (g ) → H 2O(l); ΔH 0C = −285.9 kJ
2
3) C2 H 4 (g ) + 3O2 (g ) → 2CO2 (g ) + 2H 2O(l); ΔH 0C = −1430.9 kJ
Calculate the enthalpy of change of the following reaction 2C(s) + 2H2 (g ) → C2 H4 (g ) .
j) What happens when?
1) Doran is heated strongly?
2) Aluminium is treated with dilute NaOH?
3) CO is heated with ZnO?
4. Answer any three questions: 3x5=15
a) State and explain: 2x1=2
1) Pauli’s Exclusion Principle.
2) Aufbau Principle.
b) What do you mean pH of a solution? Find out the relation between K C and K P . What will be the
Bronsted base of HF and H 2 SO4 . 1+1=2
c) What happens when –
1) HBr is added to CH3CH = CH 2 in presence of peroxide.
d) Ethyne is passed through red-hot iron tube?
2) Whether the following compounds are aromatic or not: 2
e) (1) Write the IUPAC names of the following: (any two) 1x2=2
2) CH C − CH = CH − CH = CH2
CH3
OH
f)