VISHRA JUNIOR KALASALA

TS-JUNIOR INTER
SUB: CHEMISTRY IMPORTANT QUESTIONS-2023

I VERY SHORT QUESTIONS:

QUESTION NO-1
1) What is Boltzmann’s constant? Give its value.

2) Which of the gases diffuses faster among N 2 , O2 and CH4 Why?

3) Calculate Kinetic energy of 5 moles of nitrogen at 270 C?
4) Why is pressure cooker used for cooking food on hills?
5) State Avogadro’s law
QUESTION NO-2
1) What are Lewis acid & base? Give suitable example.
2) What is homogeneous equilibrium? Write two homogeneous reactions.

3) Calculate the pH of 0.05M H 2 SO4 solution

4) What is the effect of pressure on a gaseous chemical equilibrium

5) What is Bronsted base? Give an example.
QUESTION NO-3
1) Which oxides cause acid rain ? and what is its value?
2) What is chemical oxygen demand (COD)?
3) Define the terms sink, TLV & Receptor?
4) a) What is Greenhouse effect? It is caused by ........and .... gases
b) Mention the harmful effects caused by Global warming
QUESTION NO-4

1) The empirical formula of compound is CH 2O . Its molecular weight is 90. Calculate the molecular
formula of the compound.
2) Assign oxidation number to the underlined elements in each of the following species.

a) H 2O2 b) O2 F2 c) H 2 S 2O2 d) KMnO4 e) MnO42 f) NaBH 4

3) What volume of CO2 is obtained at STP by heating 4g of CaCO3 ?

4) What is a redox concept? Give an example.

5) How many numbers of moles of glucose are present in 540 gms of glucose?
QUESTION NO-5
1) Name the common components of photo chemical smog?
 2) Mention the harmful effects caused due to depletion of ozone layer
3) Name two adverse effects caused by acid rains

4) What is Biochemical oxygen demand (BOD)?

b) Give the possiable BOD values for clean water and polluted water.
OR
1) Why H2O has higher BP than HF

2) What type of bonds are present in NH4Cl? Write its structure.

3) Which of the two ions ca 2  or Zn 2  = is more stable and why?

4) How many sigma and pi bonds are present in
a) C2 H 2 b) C2 H 4
QUESTION NO-6
. 1) How does graphite function as a lubricant
2) Diamond has high melting point – explain
3) Write the hybridisation of carbon in the following
(a) Diamond (b) Graphite
4) Graphite is a good conductor-explain
5) Name any two man made silicates.
OR
1) Give the formula of borazine. What is its common name?
2) Give two uses of Aluminium?
3) Explain why atomic radius of Ga is less than that of Al.
QUESTION NO-7
1) How is water gas or blue gas prepared?
2) Write the use of ZSM-5
3) What is allotropy? Give the crystalline allotropes of carbon.
4) Write the hybridisation of carbon in the following
(a) CO2 (b) Diamond (c) Graphite (d) Fullerene
5) Write any four uses of CO2 gas.?

OR
1) What happens when magnesium metal is burnt in air?
2) Why are alkali metals not found in the free state in nature
3) Why is gypsum added to cement?
4) Which is called milk of magnesia? Give its uses?
QUESTION NO-8
1) State the first law of thermodynamics. Explain its mathematical notation
 2) What are intensive and extensive properties
3) State the third law of thermodynamics.
4) What is entropy? Explain with examples.
QUESTION NO-9

1) Enthalpy of combustion of carbon to CO2 is –393.5 kJ mol–1. Calculate the heat released upon

formation of 35.2 g of CO2 from carbon and dioxygen gas.

2) What is the relationship between Cp and Cv ?

3) Define a system. Give an example.
QUESTION NO-10

1) Write the reagents required for conversion of benzene to methyl benzene.

2) Write a short note on a) Wurtz reaction b) Friedel craft alkylation

3) Write the structural formula of the given compounds -
(a) 3,4,4,5 - Tetramethyl heptane (b) 2-Methyl -1-butene
4) Write the IUPAC names of

0 CH 3  C H  CH 2  CH 2  CH 3
(a) CH3  CH 2  CH 2  CH  CH 2 (b)  (c) I
CH 3  C  CH 3 OH

5) Write the functional isomers of organic compound C3 H 6O.

II SHORT ANSWER QUESTIONS:

QUESTION NO-11
1) Deduce (a) Boyle’s law and (b) Charle’s law (c) Graham’s law
(d) Dalton’s law from Kinetic gas equation.
2) Write the postulates of Kinetic Molecular Theory of Gases.
3) State and explain Graham’s law of Diffusion?
4) State and explain Dalton’s law of partial pressures.? Problems
5) Derive Ideal gas equation.
QUESTION NO-12

1) Explain the hybridization involved in PCl5 molecule.

2) What is Hydrogen bond Explain the different types of Hydrogen bonds with examples.

3) Explain the hybridization involved in SF6 molecule

4) Predict the shape of the following molecules by using VSEPR theory

a) XeF4 b) BrF5 c) ClF3 d) lCl4

QUESTION NO-13
 1) Explain the formation of Coordinate covalent bond with one example
2) Explain Fajan’s rules and give suitable examples.
3) Define Dipole moment. Write its applications.
4) a) NH 3 has a higher dipole moment compared to NF3 . Why?
b) dipole moment observed for NF3 and not BF3 . why?
OR
1) State and explain the Hess’s law of constant Heat summation.
2) State the second law of thermodynamics and explain it.
3) Explain spontaneity of a process in terms of Gibbs energy
QUESTION NO-14
1) Balance the following redox equation by ion- electron method taking place in acidic medium.
 3 
a)
Cr2 O7
2
 NO2  Cr  NO3 b) 4 3 MnO 1  SO 2  Mn 2  SO 2
4

2) Determination of Empirical formula and molecular formula

A carbon compound contains 12.8%carbon, 2.1%hydrogen, 85.1% bromine. The molecular weight of
the compound is 187.9. Calculate the molecular formula.

3) Determination of Empirical formula and molecula formula A compound having 4.07% hydrogen,

24.27% carbon and 71.65 % chlorine its molecular weight is 98.96 what are its emperical formula.

and molecular formula

4) Balance the following redox equation by ion-electron method taking place in basic medium.

MnO4  I   MnO2  I 2

P4 
OH
 PH 3  H 2 PO2 b)
QUESTION NO-15
1) What is Lechatlier’s principle? Discuss briefly the factors which can influence the equilibrium.

2) Derive the relation between and for equilibrium reaction

a) N 2 g   3H 2 g   2 NH 3 g  b) 2 SO2 g   O2 g   2 SO3 g 

3) a) What is a conjugate acid-base pair? Illustrate with examples.

b) Write conjugated acid and bases for following species
i) H 2O ) ii) NH3 iii) HCO3 iv) HSO4 v) OH  vi) H 2O2
II SHORT ANSWER QUESTIONS:
QUESTION NO-16
1) Explain the terms hard water and soft water. Write a note on the
(i) ion - exchange method and
(ii) Calgon method for the removal of hardness of water.
2) Explain the following with suitable examples (a) electron-deficient hydrides
3) Discuss, with relevant chemical equations, various methods of preparing hydrogen peroxide, Which
of these methods is useful to prepare?
QUESTION NO-17
1) Explain the structure of diborane.

2) Explain borax bead test with a suitable example.

 3) What is lanthanide contraction? What are its consequences?
4) Lithium reacts with water less vigorously than sodium . Give your reasons.

5) What do you understand by (a) Allotropy (b) Inert pair effect (c) Catenation
QUESTION NO-18
. 1) What is Plaster of Paris? Write a short note on it.
2) What do you know about Castner-Kellner process? Write the principle involved in it
.3) Given an account of the biological importance of Na  and k  ions..

4) Give an account of the biological importance of Mg 2 and Ca 2 

OR
1) Explain the difference in properties of diamond and graphite on the basis of their structure.
2) Why is diamond hard?
3) Write a note on (a) silicates (b) zeolites (c) Fullerenes
LONG ANSWER QUESTION
QUESTION NO-19
1) What are the postulates of Bohr’s model of hydrogen atom? Discuss the importance of this model to
explain various series of line spectra in hydrogen atom?
2) How are the quantum numbers n, l and m, s arrived at? Explain the significance of these quantum.
numbers.?
3) (a) Explain (i) Aufbau Principle (ii) Hund’s Rule (iii) Pauli’s Principle?
(b) Advantages and Limitations of Bohr’s theory
QUESTION NO-20
1) What is a periodic property? How the following properties vary in a group and in a period? Explain
(a) Atomic radius (b) IE (c) EN
(d) Electron gain enthalpy or electron affinity (e) Nature of oxides
2) Write an essay on s,p,d and f- block elements.
3) Define IE1 and IE2. Why is IE2 > IE1 for a given atom? Discuss the factors that affect IE

of an element.
QUESTION NO-21
1) Describe any two methods of preparation of benzene? Explain the halogenation, alkylation, acylation,
nitration and sulphonation of benzene.
2) Describe two methods of preparation of ethylene. Give equation for the reaction of ethylene with the
following
(a) Ozone (b) Hypohalous acid
(c) Cold and dil.alk KMnO4 (d) Heated with O2 at high pressure
3) How does acetylene react with the following reagents? Give the corresponding equation send and
name the product formed in the reactions.
(a) Acetic acid (b) Water (c) Hydrogen (d) Halogens
(e) Hydrogen halide (f) Ammonical AgNO3 andCu2Cl2

4) a) Complete the following reaction and name the product A, B and C.

AlCl3  CH3Cl
CaC2  
H2o
 A 
hot metal tube
 B  C
b) Name the products A, B and C formed in the following reactions. Give the equations for the
 reactions. Ethylene 
Br2 / CCl4
 A 
Alc . KOH
 B 
Br2
C
(Or)
1) What do you understand by Hybridisation? Explain different types of hybridization involving s and
p orbitals.
2) Give an account of VSEPR Theory, and its applications
3) Explain the factors favourable for the formation of Ionic compounds
4) Give the Molecular Orbital Energy Diagram of (a) N2 and (b) Calculate the respective bond order.
Write the magnetic nature of and molecules