2019 Quiz 1
2019 Quiz 1
2019 Quiz 1
in P, v and T
J, Show Chatan ideal gna followsthe cyclic relntionnliip
'3 mark'
[unctions (plot potential vs distance)
2. Sketch the following inter-molecular
(1)
t,-b Tv 2
with constant
a = 42(JKm 3/rn01 21 and b = 3.2 x 10¯5m 3/mol
4. Given the critical temperature and pressure for propane (Pc=42.24bar and Tc=370K) and ethane (Pc=4S.qy
bar and K), calculate the following(Note 1 bar=100000 Pa and R = 8.314J/(mol.K)):
(a) The pressure needed to fill a 0.1 rn3 vessel at room temperature (295 K) to store 50 mol of propane
of
(b) The pressure needed to fill a 0.1 mgvessel at room temperature (295 K) to store a mixture of 20 mol
propane and 30 mol of ethane
[7 marks]
[Endl
A. Equation or seate
Redlich-Kwong
1
= —0.2599 + 0.2599)'
Soave-Redlich-Kwong
RI' aa(T) 0.42748R21? 0.08664RTc
v —b¯ v(v + b)'
Peng-Robinson
aa(T) 0.45724R2T? 0.07780RTc
v —b v(v + b) + b(v
dv; Au = c-vdT+ T —
CPU'+