DSE CHEM MASTERY

MOLE 數地獄題庫
Marking Scheme

ATTENTION

核對時對 Marking 有任何疑問可以隨時 WhatsApp TC 發問！

1
Question 1

!.#$%×!$!"
= 2 mol
'.$#×!$!#

Question 2

Number of CO# molecules: 2.50 × 6.02 × 10#( = 1.505 × 10#%

Number of atoms in 2.50 mol CO# : 1.505 × 10#% × 3 = 4.515 × 10#%

Question 3

Number of aluminium sulphate molecules : 4.5 x 6.02 x 1023 = 2.709 x 1024

Number of ions in 4.50 mol of aluminium sulphate =2.709 × 10#% × 5 = 1.3545 × 10#) ions

Question 4
!
Number of moles of ethanol: '.$#×!$!# = 1.6611 × 10*#% mol

Mass of 1 molecule of ethanol: (1.6611 × 10*#% ) × (12.0 × 2 + 1.0 × 6 + 16.0) = 7.64 × 10*#( g

Question 5
!$.+
Number of moles of CaCl# : %$.$,().)×# = 0.0973 mol

Number of Cl* : 0.0973 × 2 × (6.02 × 10#( ) = 1.17 × 10#(

Question 6
!#-.$
Number of moles of Zn(NO( )# : ').%,!%.$×#,!'.$×' = 0.6705 mol

Number of zinc ions: 0.6705 × 6.02 × 10#( = 4.04 × 10#(

Number of nitrate ions: 0.6705 × 2 × 6.02 × 10#( = 8.07 × 10#(

2
Question 7
++
Number of moles of ethanoic acid: '.$#×!$!# = 1.4618 × 10*## mol

Mass of 88 ethanoic acid molecules: 1.4618 × 10*## × (12.0 × 2 + 1.0 × 4 + 16.0 × 2) = 8.77 × 10*#! g

Question 8
!
Number of Al(, : 2.408 × 10#% × % = 6.02 × 10#(

'.$#×!$!#
Number of moles of Al(, : = 1 mol
'.$#×!$!#

Number of moles of aluminium hydrogencarbonate: 1 mol

Mass of aluminium hydrogencarbonate: 1 × (27.0 + 1.0 × 3 + 12 × 3 + 16.0 × 9) = 210.0 g

Question 9
#'.$
Number of moles of calcium phosphate: %$.!×(,(!.$×#,!'.$×+ = 0.08379 mol

Number of Ca#, : 0.08379 × 3 × 6.02 × 10#( = 1.513 × 10#(

Number of PO(*
% : 0.08379 × 2 × 6.02 × 10
#(
= 1.009 × 10#(

Number of ions present: 1.513 × 10#( + 1.009 × 10#( = 2.522 × 10#(

Question 10
. !
Number of moles of 1 H# O molecule: !+.$ = '.$#×!$!#

a = 2.99 × 10*#%
!.$×#,!'.$×#
Mass of one H# O# molecule: '.$#×!$!#
= 5.648 × 10*#( g

).'%+×!$$!#
∴ Mass of one H# O# molecule in terms of a: = 1.89a
#.//×!$$!"

3
Question 11
)'
Number of moles of N# : !%.$×# = 2.0 mol

Number of N# : 2.0L = n
#(.$
Number of moles of NO# : = 0.5 mol
!%.$,!'.$×#

Number of NO# : 0.5L

$.)0
∴ #0
= 0.25n

Question 12
+./
Number of moles of CO: !#.$,!'.$ = 0.3179 mol

Number of CO: 0.3179 × 6.02 × 10#( = 1.914 × 10#( = n

'(.)-
Number of moles of SO( : (#.$,!'.$×( = 0.7946 mol

Number of SO( : 0.7946 × 6.02 × 10#( = 4.783 × 10#(

%.-+(×!$!#
∴ !./!%×!$!# = 2.5n

Question 13

#.#+×!$!!
Number of mole of electrons involved = '.$#×!$!# = 0.0379 mol
$.$(-/×'(.)
Mass of copper formed = #
= 1.20 g

4
Question 14
% #(%
a) Total mass of 4 Na+ ions and 4Cl- ions= (23 + 35.5) × 0 = g
0

#(%
b) 0
= 2.17 × (1.8 × 10*## )

L = 5.99 × 10#( mol*!

Question 15

14.0 × 2
× 100% = 35%
14.0 × 2 + 1.0 × 4 + 16.0 × 3

Question 16

35.5 × 2
× 100% = 34.9%
24.3 + 35.5 × 2 + 18.0 × 6

Question 17

2M
= 0.699
2M + 16.0 × 3
M = 55.73

Question 18
#(.$×#
Percentage by mass of Na: #(.$×#,!#.$,!'.$×(,!$×!+.$ × 100% = 16.084%

Total mass of the sample: 78.2 ÷ 16.084% = 486.197 g

!$×!+.$
Percentage by mass of H# O: #×#(.$,!#.$,!'.$×(,!$×!+.$ × 100% = 62.937%

Mass of H# O: 486.197 × 62.937% = 306.0 g

5
Question 19

Cu1 O + CO → XCu + CO#

Cu O

Mass (g) 1.242 1.554 − 1.242 = 0.312 g

Number of moles 1.242 0.312

= 0.0196 = 0.0195
63.5 16.0
Mole ratio 0.0196 0.195
≈1 =1
0.0195 0.195
∴x=1

Question 20

X 𝐇𝟐 𝐎

Mass (g) 100 − 55.38 = 44.62 55.38

Number of moles 44.92 55.38

= 0.769 = 3.077
58.0 18.0
Mole ratio 0.769 3.077
=1 =4
0.769 0.769

Question 21

Percentage by mass of oxygen :

16.0 × 9
× 100% = 57.5%
63.5 + 32.1 + 16.0 × 4 + 5 × 18.0
Mass of oxygen = 30 x 57.5% = 17.3 g

6
Question 22
!%
× 100% = 26.2%
!%.$,!.$×%,().)
!%.$×#
!%.$,!.$×%,(#.!,!'.$×%
× 100% = 21.2%
!%.$
(/.!,!%.$,!'.$×(
× 100% = 13.8%
!%.$
× 100% = 16.5%
#(.$,!%.$,!'.$×(

Question 23
#3
#3,(#.!
= 0.589

X = 23.0

Question 24

X O

Mass (g) 5.4 10.2 – 5.4 = 4.8

No. of moles 5.4 4.8

= 0.3
𝑥 16.0
Mole ratio 2 3
2
5.4 ÷ 𝑥 ÷ 0.3 =
3
𝑥 = 27.0

Question 25
!$$
Number of moles of Fe# O( : )).+×#,!'.$×( = 0.626566416 mol

Number of moles of Al: 0.626566416 × 2 = 1.253132832 mol

Mass of Al required for the reaction: 1.253132832 × 27.0 = 33.8 g

7
Question 26

2K + 2H# O → 2KOH + H#
!#.'/
Number of moles of K: = 0.3246 mol
(/.!

Number of moles of hydrogen formed: 0.3246 ÷ 2 = 0.1623 mol

Mass of hydrogen formed: 0.1623 × 1.0 × 2 = 0.3246 g

Question 27

a) CuO + H# → Cu + H# O
(!.+
b) = 0.4 mol
'(.),!'.$

c) 0.4 × 63.5 = 25.4 g

Question 28
#$+
Number of moles of Cu produced: '(.) = 3.276 mol

Number of moles of ammonia required: 3.276 ÷ 3 × 2 = 2.184 mol

Mass of ammonia required: 2.184 × (14.0 + 1.0 × 3) = 37.1 g

Question 29

(NH% )Cr# O- → Cr# O( + N# + 4H# O

(/
Number of moles of ammonium dichromate: !%.$×#,!.$×+,)#.$×#,!'.$×- = 0.155 mol

Number of moles of H# O produced: 0.155 × 4 = 0.62 mol

Mass of water produced: 0.62 × 18.0 = 11.16 g

8
Question 30

a) 2AO + C → 2A + CO#
'.%%
b) Number of moles of CO# formed: !#.$,!'.$×# = 0.146 mol

Number of moles of A formed: 0.416 × 2 = 0.292 mol

18.6
= 0.292
A
A = 63.5

Question 31
%./$
Number of moles of sodium azide: = 0.0754 mol
#(.$,!%.$×(

Number of moles of nitrogen formed: 0.0754 ÷ 2 × 3 = 0.1131 mol

Mass of nitrogen produced: 0.1131 × (14.0 × 2) = 3.17 g

Question 32

2CuO + C → 2Cu + CO2

Number of moles of copper = 0.4 mol ( = no. of moles of CuO)

Mass of copper = 0.4 x 63.5 = 25.4 g

Question 33

FeSO4 H2O

Mass (g) 20.1 – 9.1 = 11.0 9.1

No. of moles 11.0 9.1

= 0.0724 = 0.501
55.9 + 32.1 + 16.0 × 4 18.0
Mole ratio 0.0724 0.501
=1 =7
0.0724 0.0724

9
Question 34

CO# + Ca(OH)# → CaCO( + H# O

!)
Number of moles of CO# : = 0.341 mol
!#.$,!'.$×#

/$
Number of moles of Ca(OH)# : %$.!,!'.$×#,!.$×# = 1.215 mol

∴ CO# is the limiting reactant

Number of moles of CaCO( : 0.314 mol

Mass of CaCO( : 0,341 × (40.1 + 12.0 + 16.0 × 3) = 34.13 g

Question 35

6Li + N# → 2Li( N
Number of moles of Li: 6.32 ÷ 6.9 = 0.916 mol
-.++
Number of moles of N# : !%.$×# = 0.281 mol

Li is the limiting reactant.

Number of moles of 0.916 ÷ 6 × 2 = 0.3053 mol

Mass of Li( N formed: 0.3053 × (6.9 × 3 + 14.0) = 10.59 g

Question 36

TiCl% + 2Mg → Ti + 2MgCl#

#.((×!$%
Number of moles of TiCl% : %-./,().)×% = 1.23 × 10) mol

'.(#×!$&
Number of moles of Mg: #%.(
= 2.6 × 10) mol

∵ 1.23 × 10) mol of TiCl% reacts with 2.46 × 10) mol of Mg

∴ TiCl% is the limiting reactant

Number of moles of Ti formed: 1.23 × 10) mol

Mass of Ti formed: 1.23 × 10) × 47.9 = 5891700 g

10
Question 37

2Zn + O# → 2ZnO
Number of moles of Zn: 76.2 ÷ 65.4 = 1.165 mol
#(.!
Number of moles of O# : !'.$×# = 0.722 mol

Zn is the limiting reactant

Number of moles of ZnO formed: 1.165 mol

Mass of ZnO can be produced: 1.165 × (65.4 + 16.0) = 94.8 g

Question 38

2Fe + 6H# SO% → Fe# (SO% )( + 6H# O + 3SO#

Number of moles of Fe: 24 ÷ 55.8 = 0.43 mol

/$
Number of moles of conc. H# SO% : !.$×#,(#.!,!'.$×% = 0.917 mol

Conc. sulphuric acid is the limiting reactant

Number of moles of iron(III) sulphate formed: 0.917 ÷ 6 = 0.153 mol

Mass of Fe# (SO% )( formed: 0.153 × (55.8 × 2 + 32.1 × 3 + 16.0 × 12) = 61.18 g

Number of moles of water formed: 0.917 mol

Mass of water formed: 0.917 × (1.0 × 2 + 16.0) = 16.5 g

Question 39

∵p>q

∴ O# is the limiting reactant

∴ number of moles of O# = number of moles of CO# formed

11
Question 40

Number of moles of Fe2O3 = 2N mol (excess)

Number of moles of CO = 3N mol (limited)

Mole ratio of CO : Fe = 3 : 2

Number of moles of Fe = 2N (3N ÷ 3 × 2)

Question 41

0.4 mol of Ca should react with 0.8 mol of water

∴ Ca is the limiting reactant

Number of moles of H# formed: 0.4 ÷ 1 × 1 = 0.4 mol

Question 42

2Mg + O# → 2MgO

Number of moles of Mg: 40 ÷ 24.3 = 1.646 mol

(#
Number of moles of O# : = !'.$×# = 1.0 mol

Mg is the limiting reactant

Number of moles of MgO formed: 1.646 mol

Mass of MgO formed theoretically: 1.646 × (24.3 + 16.0) = 66.33 g

%!.$
% yield of the reaction: ''.(( × 100% = 61.8%

12
Question 43

2PbO + 2C + O# → 2Pb + 2CO#

#)
Number of moles of PbO: = 0.112 mol
#$-.$,!'.$

Number of moles of C: 1 ÷ 12.0 = 0.0833 mol

C is the limiting reactant

Number of moles of Pb formed: 0.0833 mol

Theoretical yield of Pb: 0.0833 × 207.0 = 17.25 g

)
% yield of the reaction: !-.#) × 100% = 28.99%

Question 44

Mass of Zn: 37.87 − 31.34 = 6.53 g

Mass of oxide of Zn: 39.47 − 31.34 = 8.13 g

Zn O

Mass (g) 6.53 8.13 − 6.53 = 1.60

Number of moles 6.53 1.60

= 0.1 = 0.1
65.3 16.0
Mole ratio 1 1

∴ empirical formula of the oxide of zinc: ZnO

Question 45

S O H

Mass (g) 39.1 58.5 2.4

Number of moles 39.1 58.5 2.4

= 1.218 = 3.656 = 2.4
32.1 16.0 1.0
Mole ratio 1.218 3.656 2.40
=1 ≈3 ≈2
1.218 1.218 1.218
∴ empirical formula of Y: H# SO(

13
Question 46

Ti O

Mass (g) 2.66 4.44 – 2.66 = 1.78

No. of moles 2.66 1.78

= 0.0555 = 0.111
47.9 16.0
Mole ratio 0.0555 0.111
=1 =2
0.0555 0.0555

Question 47

Rb O

Mass (g) 28.5 39.2 – 28.5 = 10.7

No. of moles 28.5 10.7

= 0.333 = 0.669
85.5 16.0
Mole ratio 0.333 0.669
=1 =2
0.333 0.333

14
Question 48

Marks

(a) Pb O (2)
𝟗𝟎.𝟔 𝟗.𝟒
mole ratio = :
𝟐𝟎𝟕.𝟐 𝟏𝟔

= 0.4373 : 0.5875

= 3 : 4

Empirical formula of X is 𝑷𝒃𝟑 𝑶𝟒

(b) Let mole ratio of 𝑃𝑏𝑂 to 𝑃𝑏𝑂# be 𝑥 ∶ 𝑦 (1)

𝑚𝑜𝑙𝑒 𝑜𝑓 𝑃𝑏 𝑥 + 𝑦 3
– =
𝑚𝑜𝑙𝑒 𝑜𝑓 𝑂 𝑥 + 2𝑦 4
X is a mixture of 𝑃𝑏𝑂 and 𝑃𝑏𝑂# in a mole ratio of 2 ∶ 1 (1)

or. X is not a mixture. In X. two-third of the lead exists in an oxidation number +2, while one-
third in an oxidation number +4.

Question 49
!#.$
Mass of C: 11.87 × = 3.237 g
%%

!.$×#
Mass of H: 4.04 × !+
= 0.449 g

Mass of O: 7.30 − 3.237 − 0.449 = 3.614 g

C H O

Mass (g) 3.237 0.449 3.614

Number of moles 3.237 0.449 3.614

= 0.27 = 0.449 = 0.226
12.0 1.0 16.0
Mole ratio 0.27 0.449 0.226
= 1.2 =2 =1
0.226 0.226 0.226
à6 à 10 à5

∴ empirical formula of Y: C' H!$ O)

(C' H!$ O) ); = 486

n(12.0 × 6 + 1.0 × 10 + 16.0 × 5) = 486

n=3

∴ molecular formula of Y: C!+ H($ O!)

15
Question 50
!#.$
Mass of C: 3.30 × = 0.9 g
%%

!.$×#
Mass of H: 1.13 × !+
= 0.126 g

Mass of O: 2.03 − 0.9 − 0.126 = 1.004 g

C H O

Mass (g) 0.9 0.126 1.004

Number of moles 0.9 0.126 1.004

= 0.075 = 0.126 = 0.063
12.0 1.0 16.0
Mole ratio 0.075 0.126 0.063
= 1.2 =2 =1
0.063 0.063 0.063
à6 à 10 à5

∴ empirical formula of Y: C' H!$ O)

(C' H!$ O) ); = 324.0

n(12.0 × 6 + 1.0 × 10 + 16.0 × 5) = 324.0

n=2
∴ molecular formula of Y: C!# H#$ O!$

Question 51

𝐌𝐠𝐒𝐎𝟒 𝐇𝟐 𝐎

Mass (g) 100 − 57.37 = 42.63 57.37

Number of moles 42.63 57.37

= 0.354 = 3.187
24.3 + 32.1 + 16.0 × 4 1.0 × 2 + 16.0
Mole ratio 0.354 3.187
=1 =9
0.354 0.354
∴n=9

16
Question 52

a)

Cl S

Mass (g) 100 − 69.0 = 31.0 31.0

Number of moles 69.0 31.0

= 1.944 = 0.966
35.5 32.1
Mole ratio 1.944 0.966
=2 =1
0.966 0.966
∴ empirical formula of the compound: SCl#

(SCl# ); = 103

n(32.1 + 35.5 × 2) = 103

n≈1

∴ molecular formula of the compound: SCl#

b)

Question 53

Na S

Mass (g) 58.97 100 − 58.97 = 41.03

Number of moles 58.97 41.03

= 2.564 = 1.282
23.0 32.0
Mole ratio 2.564 1.282
=2 =1
1.282 1.282

17
Question 54

Cs O

Mass (g) 4.4 5.46 − 4.4 = 1.06

Number of moles 4.4 1.06

= 0.0331 = 0.06625
132.9 16.0
Mole ratio 0.0331 0.06625
=1 =2
0.0331 0.0331

Question 55

Be F

Mass (g) 100 − 80.85 = 19.15 80.85

Number of moles 19.15 80.85

= 2.128 = 4.255
9.0 19.0
Mole ratio 2.128 4.255
=1 =2
2.128 2.128

Question 56

Ba N

Mass (g) 65.47 69.92 − 65.47 = 4.45

Number of moles 65.47 4.45

= 0.477 = 0.318
137.3 14.0
Mole ratio 0.477 0.318
= 1.5 =1
0.318 0.318
à3 à2

18
Question 57

a) Fe is less reactive than Al

b)

i)

Fe O

Mass (g) 4.55 7.28 − 4.55 = 2.73

Number of moles 4.55 2.73

= 0.082 = 0.171
55.8 16.0
Mole ratio 0.082 0.171
=1 =2
0.082 0.082
∴ empirical formula of the compound: FeO#

ii) FeO# + 2CO → Fe + 2CO#

iii) Carry out the experiment in the fume cupboard

Question 58

C H O

Atomic ratio 2.64 1.08 0.48

×2
44 18 16
2 4 1

Empirical formula: C2H4O

Molecular formula: (C2H4O)n

n x (12 x 2 + 1 x 4 + 16 x 1) = 88.0

n=2

Molecular formula of W is C4H8O2

19
Question 59
!$$
§ No. of moles of solute = molarity × volume = 1.2 × !$$$ = 0.12 mol
§ Mass of silver nitrate = 0.12 × (107.9 + 14 + 16 × 3) = 20.388 g

Question 60
#.()
<=>?@
§ Volume = = #*.+,+&,+
= 0.0298 dm( = 29.8 cm(
<=>.ABCD #.(

Question 61
!$$
§ No. of moles = molarity × volume = 1.5 × !$$$ = 0.15 mol
§ Mass of NaCl = 0.15 × (23.0 + 35.5) = 8.775 g

Question 62

5.0 × 10*(
moles 2
Molarity = = = 0.05 M
volume 50
1000

Question 63
!!.!
<=>?
§ Molarity = E=>F<? = "-.+,+&×!,+×!
!-- = 1.50 M
+---

Question 64

§ Mole of Fe# (SO% )( : SO#*

% = 1: 3
!$$
§ Mole of SO#*
% = Mole of Fe# (SO% )( × 3 = 0.5 × !$$$ × 3 = 3 × 0.1 × 0.5

20
Question 65
$.$!
§ Mole of ZnCl# = = 0.005 mol
#
$.$$)
§ [ZnCl# ] = !- = 0.25 M
+---

Question 66

In the resulting mixture,

Number of moles of SO42-(aq) = (0.6)(50.0 × 10-3) ÷ (0.2)(150.0 × 10-3)

= 0.12 mol

Concentration of SO42-(aq) = 0.12 + [(50.0 + 150.0) × 10-3]

= 0.6 M

Question 67

§ Mass of sulphuric acid in 0.75dm3 = 1.68 x 0.75 x 1000 x 78% = 982.8 g

§ No. of mole of sulphuric acid = 982.8 / (2+32+4x16) = 10.029 mol

§ Molarity = 10.029 / 0.75 =13.4 M

Question 68

§ Mass of HNO3 = 1.32 x 100 x 1000 x 25% = 33000 g

§ No of mole of HNO3 = 33000 / (1+14+3x16) = 524 mol

§ Molarity = 524 / 100 = 5.24 M

Question 69

§ Density of sulphuric acid in the sample = 1.83 x 98% = 1.7934 g cm-3

§ Molarity= (1.7934 x 1000) / (2+32.1+4x16) = 1.83 M

Question 70

Number of moles of Na3PO4(aq) used = 0.10 × (300.0 × 10-3)

21
= 0.03 mol

Number of moles of CaCl2(aq) used = 0.30 × (100.0 × 10-3)

= 0.03 mol

The equation of the reaction is given below.

2Na( PO% (aq) + 3 CaCl# (aq) → Ca( (PO% )# (s) + 6NaCl (aq)

According to the equation, the mole ratio of Na3PO4 to CaCl2 is 2 : 3.

#
Since Number of moles of Na3PO4 Number of moles of CaCl2 = 0.03: 0.03 = 1 > ( , the limiting reagent is CaCl2.

According to the equation, the mole ratio of CaCl2 to Ca3(PO4)2 is 3 : 1 .

∴The theoretical number of moles=0.03 × 13

=0.010 mol of calcium phosphate obtained

Question 71

§ MV=MV
§ (0.200)(250)=(0.0100)(V)

§ V = 5000 cm3

§ Vol. of water added = 5000 – 250 = 4750 cm3

Question 72

§ MV=MV
§ (2)(100)=(0.1)(V)

§ V = 2000 cm3

§ Vol. of water added = 2000 – 100 = 1900 cm3

Question 73

§ MV=MV
§ (2)(V) = (0.25)(200)

§ Vol required = 25 cm3

Question 74

§ MV=MV
§ (8)(100)=(2)(V)

22
§ V = 400 cm3

§ Vol. of water added = 400-100 = 300 cm3

Question 75

§ Total no. of mole of K+= 1 x 30/1000 + 2 x 2 x 15/1000 = 0.09mol

§ Concentration = 0.09 / (45/1000) = 2M

Question 76

§ Total no. of mole of Na+ = 2 x 0.75 x 50/1000 + 2 x 0.5 x 100/1000 = 0.175 mol
§ Concentration = 0.175 / (150/1000) = 1.17 M

Question 77

§ No of mole of sodium ion from sodium nitrate = 0.4M

§ No of mole of sodium ion from sodium sulphate = 0.6M

§ No of mole of sodium sulphate = 0.3 M

§ No of mole of sulphate ion = 0.3 M

Question 78

§ Total no of mole of K+ = 2 x 2 x 100/1000 + 1 x 50/1000 = 0.45 mol

§ Concentration of K+ = 0.45 / (150/1000) = 3M

Question 79

§ Total no of mole of KOH = 1.5 x 0.45+ 0.5 x 0.15 = 0.75 mol

$.-)
§ Concentration = &-- = 1.25 𝑀
+---

23
Question 80

§ No of mole of HCl used = 1.5 x 0.1 = 0.15 mol

§ No of mole of CaCO3 reacted = 0.075 mol

§ Mass reacted / 100 = 0.075

§ Mass reacted = 7.5 g

§ Mass retained = 33-7.5 = 25.5 g

Question 81

§ No of mole of KOH = 0.1 x 60/1000 = 0.006 mol

§ No of mole of acid reacted = 0.003 mol

§ M (50/1000) = 0.003

§ M= 0.06 M

24
Question 82

Mark

(a) CuCO3+2H+ à H2O + Cu2+ + CO2 1

(b) To ensure all acid is reacted with sample 1

!$$
(c) No of mole of sulphate ion = 1 × !$$$ = 0.1 𝑚𝑜𝑙 2

No of mole of crystal = 0.1 𝑚𝑜𝑙

Mass of crystal = 0.1 x (63.5 + 32.1 + 16 x 4 + 18 x 5) = 24.96 g

(d) 20.86/24.96 = 83.6 % 1

Question 83

Mark

(a) Vinegar 1

(b) phenolphthalein 1

(c) (i) CH( COOH + KOH → CH( COO* K , + H# O

(ii) Average vol of KOH used = 200 cm3 3

No of mole of KOH used = 0.2 x 1.2 = 0.24 mol

= no of mole of ethanoic acid

Mass of acid = 0.24 x 60 = 14.4 g

(iii) Mass of acid reacted with metal = 50-14.4 = 35.6g 3

No of mole of acid reacted = 35.6 / 60 = 0.593 mol

No of mole of metal reacted = 0.297 mol

19.41/molar mass = 0.297

Molar mass = 65.4

Z is Zn

25
Question 84

Mark

(a) No of mole of NaOH used = 0.27 mol 3

Zn(NO( )# + 2NaOH → Zn(OH)# + 2NaNO(

'.$+
Mole of Zn(OH)2 formed = = 0.061167 mol
').%,!'×#,#

Mole of NaOH reacted with the acid = 0.27 − 0.061167 × 2 = 0.147666 mol
!+
No of mole of acid = = 0.148 mol
!##

No. of mole of acid : NaOH = 1: 1

Therefore, the basicity of the acid is 1/The acid is monobasic.

(b) Let the 100g be the mass of acid 2

No of mole of C : 68.9/12 = 5.74 mol

No of mole of H = 4.9 / 1 = 4.9 mol

No of mole of O = 26.2 / 16 = 1.6375 mol

C:H:O = 7:6:2

Empirical formula = C7H6O2

Molar mass of C7H6O2 = 122 g/mol

Molecular formula = C7H6O2

26
Question 85

Mark

(a) Let 100g be the mass of the acid 2

No of mole of :

H = 3.13 /1 =3.13 mol

N = 14.42/14 = 1.03 mol

S = 33.58/32.1= 1.05mol

O = 48.87/16 = 3.05 mol

H:N:S:O = 3:1:1:3

Empirical formula is =H3NSO3

(b) Molar mass of H3NSO3 = 97.1 g/mol 1

Molecular formula = H3NSO3

(c) Water is used to ionise the hydrogen ion for the function of acidic property 1

(d) Mass of acid= 12.5 x 23.6% = 2.95 g 2

No of mole of the acid= 2.95 / 97.1=0.0303 mol

Molarity = 0.0303 / 0.4 = 0.0760 M

Question 86

§ [H+] = 10-3.5M
§ 10-3.5 x 50 = M x 100

§ M = 10-3.5 /2

§ pH = -log (10-3.5/2)

27
Question 87

§ Concentration of hydrogen ion at the beginning = 0.2M

§ After diluting 10 times, concentration of hydrogen ion = 0.02M

§ pH = -log0.02 = 1.70

Question 88

§ pH of W = −log2 = −0.301
§ pH of X = 14 + log0.2 = 13.3

§ pH of Y = 14 + log0.3 = 13.477

§ pH of Z = −log3 = −0.477

Question 89

§ Only A is alkaline, which will have the highest pH.

Question 90

§ pH = 2.2 ⟹ [H, ] = 10*#.# M

§ M! V! = M# V# ⟹ 10*#.# × 100 = M# × 200 ⟹ M# = 0.5 × 10*#.# M

§ pH = −log(0.5 × 10*#.# ) = 2.5

28
Question 91

§ No. of mole of sulphuric acid in 250 cm3 : 23.34 / (2 + 32 + 4 x 16 ) = 0.238 mol

§ No of mole of sulphuric acid in 25 cm3 = 0.0238 mol

§ Mole ration of sulphuric acid and potassium hydroxide = 2 : 1

§ No of mole of KOH required = 0.0238 x 2 = 0.0476 mol

§ 0.0476 / Vol. = 0.250

§ Vol. = 0.190 dm3

Question 92
!#.((
§ Mole of NaOH = 0.75 × !$$$ = 9.2475 × 10*( mol
! #)$
§ Mole of acid = 9.2475 × 10*( × # × #)
= 0.0462375 mol

+.++
§ Molar mass of the acid = $.$%'#(-) = 192.1 g mol*!

Question 93

Mark

(a) CO32- + 2 H+ à H2O + CO2 1

(b) No of mole of nitric acid used = 0.335 x 33.0/1000 = 0.011055 mol 2

Mole ratio of hydrogen ion and carbonate ion is 2 : 1

No of mole of carbonate ion = 0.0055275 mol

No of mole of the sodium carbonate in the sample = 0.0055275 mol

(c) 1.577 / (23 x 2 + 12 + 3 x 16 + 18n) = 0.0055275 2

n = 9.96 =10

x = 10

(d) Yellow to orange 1

29
Question 94

§ No of mole of KOH used = 1.00 x 25/1000 = 0.025 mol

§ No of mole of the acid used = 1.6/192 = 0.00833 mol

§ 0.025 / 0.00833 = 3

§ Basicity = 3

Question 95

§ No of mole of sulphuric acid = 0.6 x 0.1 = 0.06 mol

§ No of mole of KOH = 1.2 x 0.1 = 0.12 mol

§ No of mole of potassium sulphate = 0.06 mol

§ Concentration = 0.06 / 0.2 = 0.3 M

Question 96

pH of HCl = 0.222; pH of CH3COOH > 0.34

Concentration of hydrogen ion in 0.60M of HCl is higher than that of 0.45M of CH3COOH.

→The rate of X is faster

No of mole of acid in X = 0.60 x 90/1000 = 0.054 mol

No of mole of acid in Y = 0.45 x 120/1000 = 0.054

Both acid is monobasic, the no of mole of NaOH used is also the same
The concentration of both solution is not the same, also the electrical conductivity is not the same

30
Question 97

§ No of mole of HCl used = 2 x 25/1000 = 0.05 mol

§ Mole ratio of Na2CO3 : HCl = 1 : 2

§ No of mole of Na2CO3 = 0.025 mol

§ Mass of sodium carbonate = 0.025 x (23 x 2 + 12 + 3 x 16) = 2.65 g

§ Mass of water in the hydrated salt = 3.10 – 2.65 = 0.45 g

§ No of mole of water = 0.45 / 18 = 0.025 mol = No of mole of sodium carbonate

§ Mole ratio = 1 : 1

Question 98

Mark

(a) Pipette 1

(b) H++ OH- à H2O 1

(c) (22.83+22.7+22.7)/3 = 22.7 cm3 1

##.-
(d) No of mole of KOH used = !$$$ × 0.30 = 6.81 × 10*( 𝑚𝑜𝑙 2

! )$$
No. of mole of acid = 6.81 × 10*( × # × )$
= 0.03405 𝑚𝑜𝑙
$.$(%$)
Molarity of the acid = )-- = 0.0681 𝑀
+---

%.#-
(e) Molar mass of the hydrated acid = 90 + 18𝑥 = $.$(%$) 2

𝑥≈2

31
Question 99

Mark

(a) NH%, + OH* → NH( + H# O 1

(b) HCl is corrosive 1

(c) Only the (NH4)2SO4 will react with KOH 1

(d) (i) pipette 1

(ii) From colourless to pink 1

(iii) No of mole of NaOH used = 82/1000 x 0.200 = 0.0164 mol 3

= no of mole of HCl for titration

No of mole of HCl unreacted = 0.0164 x 4 = 0.0656 mol

No of mole of HCl reacted = 0.0827 – 0.0656 = 0.0171mol

No of mole of ammonium sulphate = 0.00855 mol

Mass of ammonium sulphate = 0.00855 x 132 = 1.1286 g

Percentage by mass = 1.1286 / 3.150 = 35.8%

(e) By flame test, the presence of potassium ion will give a lilac flame 1

Question 100

Mark

(a) Mg + 2OH-à Mg(OH)2 1

(b) From yellow to orange 1

(c) (i) No of mole of Hydrogen ion = no of mole of hydroxide ion 1

= 0.251 x 37/1000 = 0.009287 mol

(ii) No of mole of ammonia = 0.503 x 50/1000 = 0.02515 mol 1

$.$#)!)*$.$$/#+-
(d) No of mole of Mg = = 7.9315 × 10*( 𝑚𝑜𝑙
#

-./(!)×!$$#
Molarity = )- = 0.15863 mol dm*(
+---

32