Irganox® - 1010 - Fispq
Irganox® - 1010 - Fispq
Irganox® - 1010 - Fispq
Irganox 1010
Revision date : 2019/11/04 Page: 1/11
Version: 6.0 (30546637/SDS_GEN_US/EN)
1. Identification
Irganox 1010
Recommended use of the chemical and restriction on use
* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of
the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or
implied, including by incorporation into or reference in the seller's sales agreement.
Company:
BASF CORPORATION
100 Park Avenue
Florham Park, NJ 07932, USA
CHEMTREC: 1-800-424-9300
BASF HOTLINE: 1-800-832-HELP (4357)
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Label elements
Safety Data Sheet
Irganox 1010
Revision date : 2019/11/04 Page: 2/11
Version: 6.0 (30546637/SDS_GEN_US/EN)
Signal Word:
Warning
Hazard Statement:
May form combustible dust concentration in air.
Under the referenced regulation, this product does not contain any components classified for health
hazards above the relevant cut off value.
4. First-Aid Measures
General advice:
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
If on skin:
Remove contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes. If
irritation develops, seek medical attention.
If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
If swallowed:
Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting. Immediate medical
attention required.
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
Safety Data Sheet
Irganox 1010
Revision date : 2019/11/04 Page: 3/11
Version: 6.0 (30546637/SDS_GEN_US/EN)
5. Fire-Fighting Measures
Extinguishing media
Further information:
Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire.
Impact Sensitivity:
Number of positive 0
reactions:
Assessment: not shock-sensitive
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Closed containers should only be opened in well-ventilated areas. Avoid dust formation. Do not use
any sparking tools.
Safety Data Sheet
Irganox 1010
Revision date : 2019/11/04 Page: 4/11
Version: 6.0 (30546637/SDS_GEN_US/EN)
Protection against fire and explosion:
Avoid dust formation. Dust in sufficient concentration can result in an explosive mixture in air. Handle
to minimize dusting and eliminate open flame and other sources of ignition. Routine housekeeping
should be instituted to ensure that dusts do not accumulate on surfaces. Dry powders can build static
electricity charges when subjected to the friction of transfer and mixing operations. Provide adequate
precautions, such as electrical grounding and bonding, or inert atmospheres. Refer to NFPA 654,
Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and
Handling of Combustible Particulate Solids (2013 Edition) for safe handling.
Dust explosion class: Dust explosion class 2 (Kst-value 200 up to 300 bar m s-1).
Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place.
Storage stability:
Storage temperature: < 40 °C
Protect from temperatures above: 40 °C
Particles, not otherwise OSHA PEL TWA value 15 mg/m3 Total dust ; TWA value
specified, inhalable 15 mg/m3 Total dust ; TWA value 50 millions of
particles per cubic foot of air Total dust ;
ACGIH TLV TWA value 10 mg/m3 Inhalable particles ;
Eye protection:
Safety glasses with side-shields.
Body protection:
Body protection must be chosen based on level of activity and exposure.
Form: powder
Odour: odourless
Odour threshold: No data available.
Colour: white
pH value: not soluble
melting range: 113 - 126 °C (measured)
boiling temperature: 281 °C (OECD Guideline
( 1,013 hPa) 103)
Sublimation point: No data available.
Flash point: not applicable
Flammability: not flammable (Directive
92/69/EEC, A.10)
Lower explosion limit: For solids not relevant for
classification and labelling.
Upper explosion limit: For solids not relevant for
classification and labelling.
Autoignition: 400 °C
Vapour pressure: < 0.00001 Pa (measured)
( 20 °C)
Density: 1,116 g/cm3
( 20 °C)
Bulk density: 300 - 600 kg/m3
Vapour density: No data available.
Partitioning coefficient n- >8 (Calculation
octanol/water (log Pow): ( 25 °C) Hansch/Leo)
Self-ignition not relevant
temperature:
Thermal decomposition: > 350 °C
Viscosity, dynamic: not applicable, the product is a solid
Particle size: D50 141 µm (134001)
Solubility in water: < 0.1 mg/l
( 20 °C)
Solubility (quantitative): No data available.
Solubility (qualitative): No data available.
Evaporation rate: The product is a non-volatile solid.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.
Safety Data Sheet
Irganox 1010
Revision date : 2019/11/04 Page: 6/11
Version: 6.0 (30546637/SDS_GEN_US/EN)
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated.
Oxidizing properties:
Based on its structural properties the product is not classified as oxidizing.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Conditions to avoid
Avoid dust formation. Avoid deposition of dust. Avoid all sources of ignition: heat, sparks, open
flame. Avoid electro-static charge.
Incompatible materials
strong acids, strong bases, strong oxidizing agents
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.
Thermal decomposition:
> 350 °C
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a
single skin contact. Virtually nontoxic by inhalation.
Safety Data Sheet
Irganox 1010
Revision date : 2019/11/04 Page: 7/11
Version: 6.0 (30546637/SDS_GEN_US/EN)
Oral
Type of value: LD50
Species: rat (male)
Value: > 5,000 mg/kg (OECD Guideline 423)
Inhalation
Type of value: LC50
Species: rat (male/female)
Value: > 1.95 mg/l (similar to OECD guideline 403)
Exposure time: 4 h
An aerosol was tested.
No mortality was observed.
Dermal
Type of value: LD50
Species: rat
Value: > 3,160 mg/kg (other)
Irritation / corrosion
Assessment of irritating effects: Not irritating to eyes and skin.
Skin
Species: rabbit
Result: non-irritant
Method: OPP 81-5 (EPA-Guideline)
Eye
Species: rabbit
Result: non-irritant
Method: similar to OECD guideline 405
Sensitization
Assessment of sensitization: Skin sensitizing effects were not observed in animal studies.
Aspiration Hazard
No aspiration hazard expected.
Chronic Toxicity/Effects
Genetic toxicity
Assessment of mutagenicity: No mutagenic effect was found in various tests with bacteria and
mammals.
Safety Data Sheet
Irganox 1010
Revision date : 2019/11/04 Page: 8/11
Version: 6.0 (30546637/SDS_GEN_US/EN)
The substance was not genotoxic in a test with mammals.
Carcinogenicity
Assessment of carcinogenicity: In long-term studies in rats and mice in which the substance was
given by feed, a carcinogenic effect was not observed.
Reproductive toxicity
Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility
impairing effect.
Teratogenicity
Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen
in animal studies.
Symptoms of Exposure
The most important known symptoms and effects are described in the labelling (see section 2)
and/or in section 11.
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition
of the degradation activity of activated sludge is not anticipated when introduced to biological
treatment plants in appropriate low concentrations.
No toxic effects occur within the range of solubility.
Toxicity to fish
LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 92/69/EEC, C.1, static)
The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has
been tested. Limit concentration test only (LIMIT test). The details of the toxic effect relate to the
nominal concentration. No toxic effects occur within the range of solubility.
Aquatic invertebrates
EC50 (24 h) > 86 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has
been tested. The statement of the toxic effect relates to the analytically determined concentration. No
toxic effects occur within the range of solubility.
Aquatic plants
EC50 (72 h) > 100 mg/l (growth rate), Scenedesmus subspicatus (Directive 88/302/EEC, part C, p.
89, static)
The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has
been tested. The details of the toxic effect relate to the nominal concentration. No toxic effects occur
within the range of solubility.
No observed effect concentration (72 h) 100 mg/l (growth rate), Scenedesmus subspicatus (Directive
88/302/EEC, part C, p. 89, static)
The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has
been tested. The details of the toxic effect relate to the nominal concentration.
No data available.
Toxicity to microorganisms
OECD Guideline 209 aerobic
activated sludge, domestic/EC50 (3 h): > 100 mg/l
Limit concentration test only (LIMIT test). The details of the toxic effect relate to the nominal
concentration.
Elimination information
4 % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-
C) (aerobic, activated sludge, domestic, non-adapted) Poorly biodegradable.
45.2 % Specific analysis (35 d) (OECD 303A; ISO 11733; 92/69 EEC,V, C.10) (aerobic, aerobic
microorganisms) Moderately/partially eliminated from water.
Bioaccumulative potential
Bioaccumulation potential
Bioconcentration factor: < 2.3 (OECD Guideline 305 C)
Mobility in soil
Container disposal:
Dispose of in accordance with national, state and local regulations. Recommend crushing,
puncturing or other means to prevent unauthorized use of used containers.
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
Federal Regulations
Registration status:
Cosmetic TSCA, US released / exempt
EPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicable
for this product.
A risk assessment indicates CA Proposition 65 Safe Harbor criteria are not exceeded when the
product is used for Plastic Additives.
We support worldwide Responsible Care® initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.