Safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280 date of compilation: 2015-11-25

Version: 4.0 en Revision: 2021-05-05
Replaces version of: 2020-08-19
Version: (3)

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Hydrochloric acid ≥30 %, technical
Article number 9280
Registration number (REACH) not relevant (mixture)
Index number in CLP Annex VI [ 017-002-01-X ]
EC number [ 231-595-7 ]
CAS number [ 7647-01-0 ]
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for squirting or spraying. Do not use
for products which come into direct contact with
the skin. Do not use for products which come in-
to contact with foodstuffs. Do not use for private
purposes (household).
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany

Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: [email protected]
Website: www.carlroth.de
Competent person responsible for the safety data :Department Health, Safety and Environment
sheet:
e-mail (competent person): [email protected]
1.4 Emergency telephone number
Name Street Postal Telephone Website
code/city

National Poisons Information Dudley Rd B187QH 844 892 0111

Service Birmingham
City Hospital

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Cat- Hazard class and Hazard
egory category statement

2.16 Substance or mixture corrosive to metals 1 Met. Corr. 1 H290

3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314

3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318

3.8R Specific target organ toxicity - single exposure (respirat- 3 STOT SE 3 H335
ory tract irritation)

For full text of abbreviations: see SECTION 16

The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi-
dermis and into the dermis.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word Danger

Pictograms

GHS05, GHS07

Hazard statements
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H335 May cause respiratory irritation

Precautionary statements
Precautionary statements - prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection/hear-
ing protection/…
Precautionary statements - response
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower]
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P312 Call a POISON CENTRE/doctor/... if you feel unwell
Hazardous ingredients for labelling: Hydrochloric acid .... %

Labelling of packages where the contents do not exceed 125 ml

Signal word: Danger

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

Symbol(s)

H314 Causes severe skin burns and eye damage.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/….
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
contains: Hydrochloric acid .... %

2.3 Other hazards

Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
not relevant (mixture)
Molecular formula HCl
Molar mass 36,46 g/mol

3.2 Mixtures
Description of the mixture
Name of sub- Identifier Wt% Classification acc. to Pictograms Notes
stance GHS

Hydrochloric acid .... % CAS No 30 – 32 Met. Corr. 1 / H290 B(a)

7647-01-0 Skin Corr. 1B / H314 GHS-HC
Eye Dam. 1 / H318 IOELV
EC No STOT SE 3 / H335
231-595-7

Index No
017-002-01-X

REACH Reg. No
01-2119484862-
27-xxxx

Notes
B(a): The classification refers to an aqueous solution
GHS-HC: Harmonised classification (the classification of the substance corresponds to the entry in the list according to 1272/
2008/EC, Annex VI)
IOELV: Substance with a community indicative occupational exposure limit value

Name of sub- Identifier Specific Conc. Limits M-Factors ATE Exposure

stance route

Hydrochloric CAS No Met. Corr. 1; H290: C ≥ 0,1 % - -

acid .... % 7647-01-0 Skin Corr. 1B; H314: C ≥ 25 %
Skin Irrit. 2; H315: 10 % ≤ C < 25 %
EC No Eye Dam. 1; H318: C ≥ 25 %
231-595-7 Eye Irrit. 2; H319: 10 % ≤ C < 25 %
STOT SE 3; H335: C ≥ 10 %
Index No
017-002-01-X

For full text of abbreviations: see SECTION 16

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Take off immediately all contaminated clothing. Self-protection of the first aider.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
After contact with skin, wash immediately with plenty of water. Immediate medical treatment re-
quired because corrosive injuries that are not treated are hard to cure.
Following eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist. Protect uninjured eye.
Following ingestion
Rinse mouth immediately and drink plenty of water. Call a physician immediately. If swallowed
danger of perforation of the esophagus and the stomach (strong corrosive effects).
4.2 Most important symptoms and effects, both acute and delayed
Corrosion, Risk of blindness, Gastric perforation, Risk of serious damage to eyes, Irritation, Cough,
Dyspnoea
4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

co-ordinate firefighting measures to the fire surroundings
water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Non-combustible.
Hazardous combustion products
In case of fire may be liberated:
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas-
onable distance. Wear self-contained breathing apparatus. Wear full chemical protective clothing.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not
breathe vapour/spray.
6.2 Environmental precautions
Keep away from drains, surface and ground water. The product is an acid. Before discharge into
sewage plants the product normally needs to be neutralised.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains.
Advice on how to clean up a spill
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Use extractor hood (laboratory). When diluting/dissolving, always have the water ready first, then
slowly stir in the product. Handle and open container with care. Provision of sufficient ventilation.
Clear contaminated areas thoroughly.
Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed. Keep only in original container.
Incompatible substances or mixtures
Observe hints for combined storage.
Consideration of other advice:
Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C
7.3 Specific end use(s)
No information available.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Cou Name of agent CAS No Identi- TW TWA STE STEL Ceil Ceil- Nota- Source
ntr fier A [mg/ L [mg/ ing- ing-C tion
y [pp m³] [pp m³] C [mg/
m] m] [pp m³]
m]

EU hydrogen chloride 7647-01- IOELV 5 8 10 15 2000/39/

0 EC

GB hydrogen chloride 7647-01- WEL 1 2 5 8 ga EH40/

0 2005

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
ga As gases and aerosols
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)

Relevant DNELs of components of the mixture

Name of sub- CAS No End- Threshol Protection Used in Exposure time

stance point d level goal, route of
exposure

Hydrochloric acid .... 7647-01-0 DNEL 8 mg/m³ human, inhalat- worker (industry) chronic - local ef-
% ory fects

Hydrochloric acid .... 7647-01-0 DNEL 15 mg/m³ human, inhalat- worker (industry) acute - local ef-
% ory fects

8.2 Exposure controls

Individual protection measures (personal protective equipment)
Eye/face protection

Use safety goggle with side protection. Wear face protection.

Skin protection

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. The times are approximate values from measurements at 22 ° C and permanent con-
tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-
ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in
doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective
breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred
to substance mixtures, they may only be considered as a guide.
• type of material
NBR (Nitrile rubber)
• material thickness
>0,3 mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection

Respiratory protection necessary at: Aerosol or mist formation. Type: E (against acidic gases like sul-
phur dioxide or hydrogen chloride, colour code: Yellow).
Environmental exposure controls
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state liquid
Colour colourless - light yellow
Odour stinging
Melting point/freezing point -50 °C
Boiling point or initial boiling point and boiling >80 °C
range
Flammability non-combustible
Lower and upper explosion limit not determined
Flash point not determined
Auto-ignition temperature not determined
Decomposition temperature not relevant
pH (value) <1 (in aqueous solution: 320 g/l, 20 °C)

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

Kinematic viscosity not determined

 
Solubility(ies)
Water solubility miscible in any proportion
 
Partition coefficient
Partition coefficient n-octanol/water (log value): not relevant (inorganic)
 
Vapour pressure 21 hPa at 20 °C
 
Density 1,16 g/cm³ at 20 °C

Relative vapour density information on this property is not available

 
Particle characteristics not relevant (liquid)
 
Other safety parameters
Oxidising properties none
9.2 Other information
Information with regard to physical hazard
classes:
Corrosive to metals category 1: corrosive to metals
Other safety characteristics:
Miscibility completely miscible with water

SECTION 10: Stability and reactivity

10.1 Reactivity
Substance or mixture corrosive to metals.
10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
10.3 Possibility of hazardous reactions

Dangerous/dangerous reactions with: strong oxidiser, Aldehydes, Aluminium, Amines, Carbide,

Fluorine, Metals, Permanganates, Strong alkali,
Danger of explosion: Alkali metals, Sulphuric acid, concentrated
10.4 Conditions to avoid
Keep away from heat.
10.5 Incompatible materials
different metals
Release of flammable materials with
Light metals (due to the release of hydrogen in an acid/alkaline medium).

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

10.6 Hazardous decomposition products
Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Test data are not available for the complete mixture.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity
formula).
Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Shall not be classified as acutely toxic.
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects)
• If in eyes
causes burns, Causes serious eye damage, risk of blindness
• If inhaled
Irritation to respiratory tract, cough, Dyspnoea, pulmonary oedema
• If on skin
causes severe burns, causes poorly healing wounds

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

• Other information
Other adverse effects: Circulatory collapse, Cardiac arrhythmias, Symptoms can occur only after sev-
eral hours
11.2 Endocrine disrupting properties
None of the ingredients are listed.
11.3 Information on other hazards
There is no additional information.

SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
.
Biodegradation
The methods for determining the biological degradability are not applicable to inorganic substances.
12.2 Process of degradability
Data are not available.
12.3 Bioaccumulative potential
Data are not available.
12.4 Mobility in soil
Data are not available.
12.5 Results of PBT and vPvB assessment
Data are not available.
12.6 Endocrine disrupting properties
None of the ingredients are listed.
12.7 Other adverse effects
Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process. Waste catalogue ordinance (Germany).

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.

SECTION 14: Transport information

14.1 UN number or ID number
ADR/RID/ADN UN 1789
IMDG-Code UN 1789
ICAO-TI UN 1789
14.2 UN proper shipping name
ADR/RID/ADN HYDROCHLORIC ACID
IMDG-Code HYDROCHLORIC ACID
ICAO-TI Hydrochloric acid
14.3 Transport hazard class(es)
ADR/RID/ADN 8
IMDG-Code 8
ICAO-TI 8
14.4 Packing group
ADR/RID/ADN II
IMDG-Code II
ICAO-TI II
14.5 Environmental hazards non-environmentally hazardous acc. to the dan-
gerous goods regulations
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.

14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Proper shipping name HYDROCHLORIC ACID
Particulars in the transport document UN1789, HYDROCHLORIC ACID, 8, II, (E)
Classification code C1
Danger label(s) 8

Special provisions (SP) 520

Excepted quantities (EQ) E2

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restriction code (TRC) E
Hazard identification No 80
Emergency Action Code 2R
International Maritime Dangerous Goods Code (IMDG) - Additional information
Proper shipping name HYDROCHLORIC ACID
Particulars in the shipper's declaration UN1789, HYDROCHLORIC ACID, 8, II
Marine pollutant -
Danger label(s) 8

Excepted quantities (EQ) E2

Limited quantities (LQ) 1L
EmS F-A, S-B
Stowage category C
Segregation group 1 - Acids
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Proper shipping name Hydrochloric acid
Particulars in the shipper's declaration UN1789, Hydrochloric acid, 8, II
Danger label(s) 8

Special provisions (SP) A3

Excepted quantities (EQ) E2
Limited quantities (LQ) 0,5 L

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII

Dangerous substances with restrictions (REACH, Annex XVII)

Name of substance Name acc. to inventory CAS No Restriction No

Hydrochloric acid this product meets the criteria for R3 3

classification in accordance with Reg-
ulation No 1272/2008/EC

Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in orna-

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

Legend
mental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume,
or both, if they:
— can be used as fuel in decorative oil lamps for supply to the general public, and
— present an aspiration hazard and are labelled with H304.
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the
European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation
(CEN).
5. Without prejudice to the implementation of other Union provisions relating to the classification, labelling and pack-
aging of substances and mixtures, suppliers shall ensure, before the placing on the market, that the following require-
ments are met:
(a) lamp oils, labelled with H304, intended for supply to the general public are visibly, legibly and indelibly marked as
follows: “Keep lamps filled with this liquid out of the reach of children”; and, by 1 December 2010, “Just a sip of lamp oil
– or even sucking the wick of lamps – may lead to life-threatening lung damage”;
(b) grill lighter fluids, labelled with H304, intended for supply to the general public are legibly and indelibly marked by
1 December 2010 as follows: ‘Just a sip of grill lighter fluid may lead to life threatening lung damage’;
(c) lamps oils and grill lighters, labelled with H304, intended for supply to the general public are packaged in black
opaque containers not exceeding 1 litre by 1 December 2010.’;

List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list

None of the ingredients are listed. (Or Concentration of the substance in a mixture: <0.1 % Mass con-
centration)
Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements

not assigned

Deco-Paint Directive

VOC content 0%
0 g/l

Industrial Emissions Directive (IED)

VOC content 0%

VOC content 0 g/l

Water content was discounted

Directive on the restriction of the use of certain hazardous substances in electrical and
electronic equipment (RoHS)
none of the ingredients are listed
Regulation concerning the establishment of a European Pollutant Release and Transfer
Register (PRTR)
none of the ingredients are listed
Water Framework Directive (WFD)
none of the ingredients are listed
Regulation on the marketing and use of explosives precursors
none of the ingredients are listed

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

Regulation on drug precursors
Name of substance CAS No Classification CN Code Threshold
level

Hydrochloric acid .... % 7647-01-0 Category 3 2806 10 00

Regulation on substances that deplete the ozone layer (ODS)

none of the ingredients are listed
Regulation concerning the export and import of hazardous chemicals (PIC)
none of the ingredients are listed
Regulation on persistent organic pollutants (POP)
none of the ingredients are listed
UN Convention against Illicit Traffic in Narcotic Drugs and Psychotropic Substances
Name of substance CAS No Listed in HS code

Hydrochloric acid .... % 7647-01-0 Table II 2806.10

National inventories
Country Inventory Status

AU AICS all ingredients are listed

CA DSL all ingredients are listed

CN IECSC all ingredients are listed

EU ECSI all ingredients are listed

EU REACH Reg. all ingredients are listed

JP CSCL-ENCS all ingredients are listed

KR KECI all ingredients are listed

MX INSQ all ingredients are listed

NZ NZIoC all ingredients are listed

PH PICCS all ingredients are listed

TR CICR not all ingredients are listed

TW TCSI all ingredients are listed

US TSCA all ingredients are listed

Legend
AICS Australian Inventory of Chemical Substances
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

SECTION 16: Other information

Indication of changes (revised safety data sheet)
Alignment to regulation: Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Restructuring: section 9, section 14

Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant

2.1 Classification according to Regulation (EC) No yes

1272/2008 (CLP):
change in the listing (table)

2.1 The most important adverse physicochemical, yes

human health and environmental effects:
Skin corrosion produces an irreversible dam-
age to the skin; namely, visible necrosis through
the epidermis and into the dermis.

2.2 Precautionary statements - prevention: yes

change in the listing (table)

2.2 Labelling of packages where the contents do yes

not exceed 125 ml:
change in the listing (table)

2.3 Other hazards: Other hazards yes

There is no additional information.

2.3 Results of PBT and vPvB assessment: yes

This mixture does not contain any substances
that are assessed to be a PBT or a vPvB.

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2000/39/EC Commission Directive establishing a first list of indicative occupational exposure limit values in imple-
mentation of Council Directive 98/24/EC

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)

ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)

ADR/RID/ADN European Agreements concerning the International Carriage of Dangerous Goods by Road/Rail/Inland
Waterways (ADR/RID/ADN)

ATE Acute Toxicity Estimate

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

CN Code Combined Nomenclature

DGR Dangerous Goods Regulations (see IATA/DGR)

DNEL Derived No-Effect Level

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

Abbr. Descriptions of used abbreviations

EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-

cence/)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

Eye Dam. Seriously damaging to the eye

Eye Irrit. Irritant to the eye

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions

HS Harmonized Commodity Description and Coding System (Harmonized System, drawn up by the World
Customs Organisation)

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation
(EC) No 1272/2008

IOELV Indicative occupational exposure limit value

Met. Corr. Substance or mixture corrosive to metals

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)

Skin Corr. Corrosive to skin

Skin Irrit. Irritant to skin

STEL Short-term exposure limit

STOT SE Specific target organ toxicity - single exposure

SVHC Substance of Very High Concern

TWA Time-weighted average

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

WEL Workplace exposure limit

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ≥30 %, technical

article number: 9280

Key literature references and sources for data
Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Mari-
time Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).
Classification procedure
Physical and chemical properties. The classification is based on tested mixture.
Health hazards. Environmental hazards. The method for classification of the mixture is based on in-
gredients of the mixture (additivity formula).
List of relevant phrases (code and full text as stated in chapter 2 and 3)
Code Text

H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H335 May cause respiratory irritation.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

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