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Safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078 date of compilation: 2019-10-15


Version: 5.0 en Revision: 2022-11-10
Replaces version of: 2021-09-09
Version: (4)

SECTION 1: Identification of the substance/mixture and of the company/


undertaking
1.1 Product identifier
Identification of the substance Sodium hypochlorite solution 12 % Cl, Biocide
Grade, stabilized
Article number 0078
Index number in CLP Annex VI [ 017-011-00-1 ]
EC number [ 231-668-3 ]
CAS number [ 7681-52-9 ]
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Biocidal product
Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for squirting or spraying. Do not use
for products which come into direct contact with
the skin. Do not use for private purposes (house-
hold).
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany

Telephone:+49 (0) 721 - 56 06 0


Telefax: +49 (0) 721 - 56 06 149
e-mail: [email protected]
Website: www.carlroth.de
Competent person responsible for the safety data :Department Health, Safety and Environment
sheet:
e-mail (competent person): [email protected]
1.4 Emergency telephone number
Name Street Postal Telephone Website
code/city

National Poisons Information Beaumont Road Dublin 9 01 809 2166 https://


Centre www.poisons.ie/
Beaumont Hospital

Ireland (en) Page 1 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Cat- Hazard class and Hazard
egory category statement

2.16 Substance or mixture corrosive to metals 1 Met. Corr. 1 H290

3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314

3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318

4.1A Hazardous to the aquatic environment - acute hazard 1 Aquatic Acute 1 H400

4.1C Hazardous to the aquatic environment - chronic hazard 2 Aquatic Chronic 2 H411

Supplemental hazard information


Code Supplemental hazard information

EUH031 contact with acids liberates toxic gas

For full text of abbreviations: see SECTION 16

The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi-
dermis and into the dermis. Spillage and fire water can cause pollution of watercourses.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word Danger

Pictograms

GHS05, GHS09

Hazard statements
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H410 Very toxic to aquatic life with long lasting effects

Precautionary statements
Precautionary statements - prevention
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection

Ireland (en) Page 2 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


Precautionary statements - response
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower]
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER/doctor
Supplemental hazard information
EUH031 Contact with acids liberates toxic gas.
Hazardous ingredients for labelling: Sodium hypochlorite, solution … % Cl active, Sodi-
um hydroxide

Labelling of packages where the contents do not exceed 125 ml


Signal word: Danger

Symbol(s)

H314 Causes severe skin burns and eye damage.


P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
EUH031 Contact with acids liberates toxic gas.
contains: Sodium hypochlorite, solution … % Cl active, Sodium hydroxide

2.3 Other hazards


Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients


3.1 Substances
not relevant (mixture)
3.2 Mixtures
Description of the mixture
Name of sub- Identifier Wt% Classification acc. to Pictograms Notes
stance GHS

Sodium hypochlorite, CAS No 5 – 15 Skin Corr. 1B / H314 B(a)


solution … % Cl active 7681-52-9 Eye Dam. 1 / H318 GHS-HC
Aquatic Acute 1 / H400
EC No Aquatic Chronic 1 / H410
231-668-3 EUH031

Index No
017-011-00-1

Ireland (en) Page 3 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

Name of sub- Identifier Wt% Classification acc. to Pictograms Notes


stance GHS

Sodium hydroxide CAS No 1–<3 Met. Corr. 1 / H290 GHS-HC


1310-73-2 Skin Corr. 1A / H314
Eye Dam. 1 / H318
EC No
215-185-5

Index No
011-002-00-6

Notes
B(a): The classification refers to an aqueous solution
GHS-HC: Harmonised classification (the classification of the substance corresponds to the entry in the list according to 1272/
2008/EC, Annex VI)

Name of sub- Identifier Specific Conc. Limits M-Factors ATE Exposure


stance route

Sodium hypo- CAS No - M-factor 1.100 mg/kg oral


chlorite, solu- 7681-52-9 (acute) = 10
tion … % Cl act- M-factor
ive EC No (chronic) = 1
231-668-3

Index No
017-011-00-1

Sodium hydrox- CAS No Skin Corr. 1A; H314: C ≥ 5 % - -


ide 1310-73-2 Skin Corr. 1B; H314: 2 % ≤ C < 5 %
Skin Irrit. 2; H315: 0,5 % ≤ C < 2 %
EC No Eye Dam. 1; H318: C ≥ 2 %
215-185-5 Eye Irrit. 2; H319: 0,5 % ≤ C < 2 %

Index No
011-002-00-6

For full text of abbreviations: see SECTION 16

SECTION 4: First aid measures


4.1 Description of first aid measures

General notes
Take off immediately all contaminated clothing. Self-protection of the first aider.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
After contact with skin, wash immediately with plenty of water. Immediate medical treatment re-
quired because corrosive injuries that are not treated are hard to cure.
Following eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist. Protect uninjured eye.
Following ingestion
Rinse mouth immediately and drink plenty of water. Call a physician immediately. If swallowed
danger of perforation of the esophagus and the stomach (strong corrosive effects).

Ireland (en) Page 4 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


4.2 Most important symptoms and effects, both acute and delayed
Corrosion, Gastric perforation, Risk of serious damage to eyes, Risk of blindness, Cough, Dyspnoea
4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures


5.1 Extinguishing media

Suitable extinguishing media


co-ordinate firefighting measures to the fire surroundings
water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Non-combustible.
Hazardous combustion products
In case of fire may be liberated: Hydrogen chloride (HCl), Chlorine (CI₂)
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Do not allow firefighting water to enter drains
or water courses. Fight fire with normal precautions from a reasonable distance. Wear self-contained
breathing apparatus. Wear full chemical protective clothing.

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel


Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not
breathe vapour/spray.
6.2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose
of it.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains.
Advice on how to clean up a spill
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.

Ireland (en) Page 5 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Handle and open container with care. Provide adequate ventilation. Clear contaminated areas thor-
oughly.
Measures to protect the environment
Avoid release to the environment.
Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
7.2 Conditions for safe storage, including any incompatibilities
Protect from sunlight. Keep only in original container.
Incompatible substances or mixtures
Observe hints for combined storage.
Consideration of other advice:
Specific designs for storage rooms or vessels
Do not keep the container sealed.
Recommended storage temperature: 15 – 25 °C
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Cou Name of agent CAS No Identi- TW TWA STE STEL Ceil Ceil- Nota- Source
ntr fier A [mg/ L [mg/ ing- ing-C tion
y [pp m³] [pp m³] C [mg/
m] m] [pp m³]
m]

IE sodium hydroxide 1310-73- OELV 2 S.I. No.


2 619 of
2001

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)

Ireland (en) Page 6 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

Relevant DNELs of components of the mixture

Name of sub- CAS No End- Threshol Protection Used in Exposure time


stance point d level goal, route of
exposure

Sodium hypochlor- 7681-52-9 DNEL 1,55 mg/ human, inhalat- worker (industry) chronic - systemic
ite, solution … % Cl m³ ory effects
active

Sodium hypochlor- 7681-52-9 DNEL 3,1 mg/m³ human, inhalat- worker (industry) acute - systemic
ite, solution … % Cl ory effects
active

Sodium hypochlor- 7681-52-9 DNEL 1,55 mg/ human, inhalat- worker (industry) chronic - local ef-
ite, solution … % Cl m³ ory fects
active

Sodium hypochlor- 7681-52-9 DNEL 3,1 mg/m³ human, inhalat- worker (industry) acute - local ef-
ite, solution … % Cl ory fects
active

Relevant PNECs of components of the mixture

Name of sub- CAS No End- Threshol Organism Environmental Exposure time


stance point d level compartment

Sodium hypochlor- 7681-52-9 PNEC 0,21 µg/l aquatic organ- freshwater short-term (single
ite, solution … % Cl isms instance)
active

Sodium hypochlor- 7681-52-9 PNEC 0,042 µg/l aquatic organ- marine water short-term (single
ite, solution … % Cl isms instance)
active

Sodium hypochlor- 7681-52-9 PNEC 4,69 mg/l aquatic organ- sewage treatment short-term (single
ite, solution … % Cl isms plant (STP) instance)
active

8.2 Exposure controls


Individual protection measures (personal protective equipment)
Eye/face protection

Use safety goggle with side protection. Wear face protection.


Skin protection

• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. The times are approximate values from measurements at 22 ° C and permanent con-
tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-
ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in
doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective

Ireland (en) Page 7 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred
to substance mixtures, they may only be considered as a guide.
• type of material
Butyl caoutchouc (butyl rubber)
• material thickness
0,5 mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• Splash protection - Protective gloves
• type of material: NBR (Nitrile rubber)
• material thickness: >0,11 mm
• breakthrough times of the glove material: >60 minutes (permeation: level 3)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection

Respiratory protection necessary at: Aerosol or mist formation. Type: B-P2 (combined filters for acidic
gases and particles, colour code: Grey/White).
Environmental exposure controls
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Physical state liquid
Colour light yellow - light green
Odour like: - chlorine
Melting point/freezing point -25 °C
Boiling point or initial boiling point and boiling 98 °C (slow decomposition)
range
Flammability non-combustible
Lower and upper explosion limit not determined
Flash point not determined
Auto-ignition temperature not determined
Decomposition temperature >111 °C
pH (value) 12 – 13 (20 °C)
Kinematic viscosity 2,222 mm²/s at 20 °C

Dynamic viscosity 2,8 mPa s at 20 °C

Ireland (en) Page 8 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

Solubility(ies)
Water solubility miscible in any proportion

Partition coefficient
Partition coefficient n-octanol/water (log value): -3,42 (20 °C)

Vapour pressure 23 hPa

Density and/or relative density


Density 1,22 – 1,26 g/cm³ at 20 °C

Relative vapour density information on this property is not available

Particle characteristics not relevant (liquid)

Other safety parameters


Oxidising properties none
9.2 Other information
Information with regard to physical hazard
classes:
Corrosive to metals category 1: corrosive to metals
Other safety characteristics:
Miscibility completely miscible with water

SECTION 10: Stability and reactivity


10.1 Reactivity
Substance or mixture corrosive to metals.
10.2 Chemical stability
May cause decomposition by long-term light influence.
10.3 Possibility of hazardous reactions

Violent reaction with: strong oxidiser, Formic acid, Amines, Ammonia (NH3), Acetic anhydride, Meth-
anol, Reducing agents, Strong acid, Cyanides,
Dangerous/dangerous reactions with: Acids => Release of an acute toxic gas: Chlorine
10.4 Conditions to avoid
Keep away from heat. Decompostion takes place from temperatures above: >111 °C.
10.5 Incompatible materials
different metals
Release of flammable materials with
Metals, Light metals (due to the release of hydrogen in an acid/alkaline medium)

Ireland (en) Page 9 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


Release of toxic materials with
Acids.
10.6 Hazardous decomposition products
Hazardous combustion products: see section 5.

SECTION 11: Toxicological information


11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Test data are not available for the complete mixture.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity
formula).
Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Shall not be classified as acutely toxic.

Acute toxicity estimate (ATE) of components of the mixture

Name of substance CAS No Exposure route ATE

Sodium hypochlorite, solution … % Cl active 7681-52-9 oral 1.100 mg/kg

Acute toxicity of components of the mixture

Name of substance CAS No Exposure Endpoint Value Species


route

Sodium hypochlorite, solution … % 7681-52-9 oral LD50 1.100 mg/kg rat


Cl active

Sodium hypochlorite, solution … % 7681-52-9 dermal LD50 >20.000 mg/kg rabbit


Cl active

Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure

Ireland (en) Page 10 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

Shall not be classified as a specific target organ toxicant (repeated exposure).


Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

Symptoms related to the physical, chemical and toxicological characteristics


• If swallowed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects)
• If in eyes
causes burns, Causes serious eye damage, risk of blindness
• If inhaled
cough, Dyspnoea
• If on skin
causes severe burns, causes poorly healing wounds
• Other information
none
11.2 Endocrine disrupting properties
None of the ingredients are listed.
11.3 Information on other hazards
There is no additional information.

SECTION 12: Ecological information


12.1 Toxicity
Very toxic to aquatic life with long lasting effects.
.

Aquatic toxicity (acute) of components of the mixture

Name of sub- CAS No Endpoint Value Species Exposure


stance time

Sodium hypochlorite, 7681-52-9 EC50 35 µg/l aquatic invertebrates 48 h


solution … % Cl active

Sodium hypochlorite, 7681-52-9 ErC50 0,036 mg/l algae 72 h


solution … % Cl active

Sodium hydroxide 1310-73-2 LC50 <180 mg/l fish 96 h

Sodium hydroxide 1310-73-2 EC50 40,4 mg/l aquatic invertebrates 48 h

Aquatic toxicity (chronic) of components of the mixture

Name of sub- CAS No Endpoint Value Species Exposure


stance time

Sodium hydroxide 1310-73-2 EC50 22 mg/l microorganisms 15 min

Biodegradation
The methods for determining the biological degradability are not applicable to inorganic substances.

Ireland (en) Page 11 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


12.2 Process of degradability
Data are not available.
12.3 Bioaccumulative potential
Does not significantly accumulate in organisms.

Bioaccumulative potential of components of the mixture

Name of substance CAS No BCF Log KOW BOD5/COD

Sodium hypochlorite, solution … 7681-52-9 -3,42 (pH value: 12,5, 20 °C)


% Cl active

12.4 Mobility in soil


Data are not available.
12.5 Results of PBT and vPvB assessment
Data are not available.
12.6 Endocrine disrupting properties
None of the ingredients are listed.
12.7 Other adverse effects
Data are not available.

SECTION 13: Disposal considerations


13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data
sheets.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process.
Properties of waste which render it hazardous
HP 4 irritant - skin irritation and eye damage
HP 8 corrosive
HP 12 release of an acute toxic gas
HP 14 ecotoxic
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.

Ireland (en) Page 12 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

SECTION 14: Transport information


14.1 UN number or ID number
ADRRID UN 1791
IMDG-Code UN 1791
ICAO-TI UN 1791
14.2 UN proper shipping name
ADRRID HYPOCHLORITE SOLUTION
IMDG-Code HYPOCHLORITE SOLUTION
ICAO-TI Hypochlorite solution
14.3 Transport hazard class(es)
ADRRID 8
IMDG-Code 8
ICAO-TI 8
14.4 Packing group
ADRRID II
IMDG-Code II
ICAO-TI II
14.5 Environmental hazards hazardous to the aquatic environment
Environmentally hazardous substance (aquatic Sodium hypochlorite, solution … % Cl active
environment):
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.

14.8 Information for each of the UN Model Regulations


Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Proper shipping name HYPOCHLORITE SOLUTION
Particulars in the transport document UN1791, HYPOCHLORITE SOLUTION, 8, II, (E), en-
vironmentally hazardous
Classification code C9
Danger label(s) 8, "Fish and tree"

Environmental hazards yes (hazardous to the aquatic environment)


Special provisions (SP) 521
Excepted quantities (EQ) E2

Ireland (en) Page 13 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restriction code (TRC) E
Hazard identification No 80
Regulations concerning the International Carriage of Dangerous Goods by Rail (RID)Additional
information
Classification code C9
Danger label(s) 8
Fish and tree

Environmental hazards Yes


Hazardous to water
Special provisions (SP) 521
Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
Transport category (TC) 2
Hazard identification No 80
International Maritime Dangerous Goods Code (IMDG) - Additional information
Proper shipping name HYPOCHLORITE SOLUTION
Particulars in the shipper's declaration UN1791, HYPOCHLORITE SOLUTION, (contains:
Sodium hypochlorite, solution … % Cl active, Sodi-
um hydroxide), 8, II, MARINE POLLUTANT
Marine pollutant yes (P) (hazardous to the aquatic environment), (Sodium hy-
pochlorite, solution … % Cl active)

Danger label(s) 8, "Fish and tree"

Special provisions (SP) 274, 900


Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
EmS F-A, S-B
Stowage category B
Segregation group 8 - Hypochlorites
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Proper shipping name Hypochlorite solution
Particulars in the shipper's declaration UN1791, Hypochlorite solution, 8, II
Environmental hazards yes (hazardous to the aquatic environment)
Danger label(s) 8

Ireland (en) Page 14 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

Special provisions (SP) A3


Excepted quantities (EQ) E2
Limited quantities (LQ) 0,5 L

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII

Dangerous substances with restrictions (REACH, Annex XVII)

Name of substance Name acc. to inventory CAS No Restriction No

Sodium hypochlorite solution this product meets the criteria for R3 3


classification in accordance with Reg-
ulation No 1272/2008/EC

Sodium hydroxide substances in tattoo inks and perman- R75 75


ent make-up

Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in orna-
mental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume,
or both, if they:
— can be used as fuel in decorative oil lamps for supply to the general public, and
— present an aspiration hazard and are labelled with H304.
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the
European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation
(CEN).
5. Without prejudice to the implementation of other Union provisions relating to the classification, labelling and pack-
aging of substances and mixtures, suppliers shall ensure, before the placing on the market, that the following require-
ments are met:
(a) lamp oils, labelled with H304, intended for supply to the general public are visibly, legibly and indelibly marked as
follows: “Keep lamps filled with this liquid out of the reach of children”; and, by 1 December 2010, “Just a sip of lamp oil
– or even sucking the wick of lamps – may lead to life-threatening lung damage”;
(b) grill lighter fluids, labelled with H304, intended for supply to the general public are legibly and indelibly marked by
1 December 2010 as follows: ‘Just a sip of grill lighter fluid may lead to life threatening lung damage’;
(c) lamps oils and grill lighters, labelled with H304, intended for supply to the general public are packaged in black
opaque containers not exceeding 1 litre by 1 December 2010.’;

Ireland (en) Page 15 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


Legend
R75 1. Shall not be placed on the market in mixtures for use for tattooing purposes, and mixtures containing any such sub-
stances shall not be used for tattooing purposes, after 4 January 2022 if the substance or substances in question is or
are present in the following circumstances:
(a) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as carcinogen category
1A, 1B or 2, or germ cell mutagen category 1A, 1B or 2, the substance is present in the mixture in a concentration
equal to or greater than 0,00005 % by weight;
(b) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as reproductive toxicant
category 1A, 1B or 2, the substance is present in the mixture in a concentration equal to or greater than 0,001 % by
weight;
(c) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as skin sensitiser cat-
egory 1, 1A or 1B, the substance is present in the mixture in a concentration equal to or greater than 0,001 % by
weight;
(d) in the case of a substance classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 as skin corrosive cat-
egory 1, 1A, 1B or 1C or skin irritant category 2, or as serious eye damage category 1 or eye irritant category 2, the
substance is present in the mixture in a concentration equal to or greater than:
(i) 0,1 % by weight, if the substance is used solely as a pH regulator;
(ii) 0,01 % by weight, in all other cases;
(e) in the case of a substance listed in Annex II to Regulation (EC) No 1223/2009 (*1), the substance is present in the
mixture in a concentration equal to or greater than 0,00005 % by weight;
(f) in the case of a substance for which a condition of one or more of the following kinds is specified in column g
(Product type, Body parts) of the table in Annex IV to Regulation (EC) No 1223/2009, the substance is present in the
mixture in a concentration equal to or greater than 0,00005 % by weight:
(i) “Rinse-off products”;
(ii) “Not to be used in products applied on mucous membranes”;
(iii) “Not to be used in eye products”;
(g) in the case of a substance for which a condition is specified in column h (Maximum concentration in ready for use
preparation) or column i (Other) of the table in Annex IV to Regulation (EC) No 1223/2009, the substance is present in
the mixture in a concentration, or in some other way, that does not accord with the condition specified in that column;
(h) in the case of a substance listed in Appendix 13 to this Annex, the substance is present in the mixture in a concen-
tration equal to or greater than the concentration limit specified for that substance in that Appendix.
2. For the purposes of this entry use of a mixture “for tattooing purposes” means injection or introduction of the mix-
ture into a person’s skin, mucous membrane or eyeball, by any process or procedure (including procedures com-
monly referred to as permanent make-up, cosmetic tattooing, micro-blading and micro-pigmentation), with the aim of
making a mark or design on his or her body.
3. If a substance not listed in Appendix 13 falls within more than one of points (a) to (g) of paragraph 1, the strictest
concentration limit laid down in the points in question shall apply to that substance. If a substance listed in Appendix
13 also falls within one or more of points (a) to (g) of paragraph 1, the concentration limit laid down in point (h) of
paragraph 1 shall apply to that substance.
4. By way of derogation, paragraph 1 shall not apply to the following substances until 4 January 2023:
(a) Pigment Blue 15:3 (CI 74160, EC No 205-685-1, CAS No 147-14-8);
(b) Pigment Green 7 (CI 74260, EC No 215-524-7, CAS No 1328-53-6).
5. If Part 3 of Annex VI to Regulation (EC) No 1272/2008 is amended after 4 January 2021 to classify or re-classify a sub-
stance such that the substance then becomes caught by point (a), (b), (c) or (d) of paragraph 1 of this entry, or such
that it then falls within a different one of those points from the one within which it fell previously, and the date of ap-
plication of that new or revised classification is after the date referred to in paragraph 1 or, as the case may be, para-
graph 4 of this entry, that amendment shall, for the purposes of applying this entry to that substance, be treated as
taking effect on the date of application of that new or revised classification.
6. If Annex II or Annex IV to Regulation (EC) No 1223/2009 is amended after 4 January 2021 to list or change the listing
of a substance such that the substance then becomes caught by point (e), (f) or (g) of paragraph 1 of this entry, or
such that it then falls within a different one of those points from the one within which it fell previously, and the
amendment takes effect after the date referred to in paragraph 1 or, as the case may be, paragraph 4 of this entry,
that amendment shall, for the purposes of applying this entry to that substance, be treated as taking effect from the
date falling 18 months after entry into force of the act by which that amendment was made.
7. Suppliers placing a mixture on the market for use for tattooing purposes shall ensure that, after 4 January 2022, the
mixture is marked with the following information:
(a) the statement “Mixture for use in tattoos or permanent make-up”;
(b) a reference number to uniquely identify the batch;
(c) the list of ingredients in accordance with the nomenclature established in the glossary of common ingredient
names pursuant to Article 33 of Regulation (EC) No 1223/2009, or in the absence of a common ingredient name, the
IUPAC name. In the absence of a common ingredient name or IUPAC name, the CAS and EC number. Ingredients shall
be listed in descending order by weight or volume of the ingredients at the time of formulation. “Ingredient” means
any substance added during the process of formulation and present in the mixture for use for tattooing purposes. Im-
purities shall not be regarded as ingredients. If the name of a substance, used as ingredient within the meaning of
this entry, is already required to be stated on the label in accordance with Regulation (EC) No 1272/2008, that ingredi-
ent does not need to be marked in accordance with this Regulation;
(d) the additional statement “pH regulator” for substances falling under point (d)(i) of paragraph 1;
(e) the statement "Contains nickel. Can cause allergic reactions." if the mixture contains nickel below the concentra-
tion limit specified in Appendix 13;
(f) the statement "Contains chromium (VI). Can cause allergic reactions." if the mixture contains chromium (VI) below
the concentration limit specified in Appendix 13;
(g) safety instructions for use insofar as they are not already required to be stated on the label by Regulation (EC) No
1272/2008.
The information shall be clearly visible, easily legible and marked in a way that is indelible.
The information shall be written in the official language(s) of the Member State(s) where the mixture is placed on the
market, unless the Member State(s) concerned provide(s) otherwise.
Where necessary because of the size of the package, the information listed in the first subparagraph, except for point
(a), shall be included instead in the instructions for use.
Before using a mixture for tattooing purposes, the person using the mixture shall provide the person undergoing the
procedure with the information marked on the package or included in the instructions for use pursuant to this para-
graph.
8. Mixtures that do not contain the statement “Mixture for use in tattoos or permanent make-up” shall not be used for
tattooing purposes.

Ireland (en) Page 16 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


Legend
9. This entry does not apply to substances that are gases at temperature of 20 °C and pressure of 101,3 kPa, or gener-
ate a vapour pressure of more than 300 kPa at temperature of 50 °C, with the exception of formaldehyde (CAS No 50-
00-0, EC No 200-001-8).
10. This entry does not apply to the placing on the market of a mixture for use for tattooing purposes, or to the use of
a mixture for tattooing purposes, when placed on the market exclusively as a medical device or an accessory to a
medical device, within the meaning of Regulation (EU) 2017/745, or when used exclusively as a medical device or an
accessory to a medical device, within the same meaning. Where the placing on the market or use may not be exclus-
ively as a medical device or an accessory to a medical device, the requirements of Regulation (EU) 2017/745 and of this
Regulation shall apply cumulatively.

List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list


None of the ingredients are listed.
Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements

E1 environmental hazards (hazardous to the aquatic en- 100 200 56)


vironment, cat. 1)

Notation
56) Hazardous to the Aquatic Environment in category Acute 1 or Chronic 1

Deco-Paint Directive

VOC content 0%
-0 g/l

Industrial Emissions Directive (IED)

VOC content 0%

VOC content (Water content was discounted) -0 g/l

Directive on the restriction of the use of certain hazardous substances in electrical and
electronic equipment (RoHS)
none of the ingredients are listed
Regulation concerning the establishment of a European Pollutant Release and Transfer
Register (PRTR)
none of the ingredients are listed
Water Framework Directive (WFD)

List of pollutants (WFD)

Name of substance Name acc. to inventory CAS No Listed in Remarks

Sodium hypochlorite solution Biocides and plant protection a)


products

Sodium hydroxide Metals and their compounds a)

Sodium hypochlorite, solution … Metals and their compounds a)


% Cl active

Legend
A) Indicative list of the main pollutants

Ireland (en) Page 17 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


Regulation on the marketing and use of explosives precursors
none of the ingredients are listed
Regulation on drug precursors
none of the ingredients are listed
Regulation on substances that deplete the ozone layer (ODS)
none of the ingredients are listed
Regulation concerning the export and import of hazardous chemicals (PIC)
none of the ingredients are listed
Regulation on persistent organic pollutants (POP)
none of the ingredients are listed

Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un-
der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
National inventories
Country Inventory Status

AU AIIC all ingredients are listed

CA DSL all ingredients are listed

CN IECSC all ingredients are listed

EU ECSI all ingredients are listed

EU REACH Reg. all ingredients are listed

JP CSCL-ENCS all ingredients are listed

KR KECI all ingredients are listed

MX INSQ all ingredients are listed

NZ NZIoC all ingredients are listed

PH PICCS all ingredients are listed

TR CICR not all ingredients are listed

TW TCSI all ingredients are listed

US TSCA all ingredients are listed

Legend
AIIC Australian Inventory of Industrial Chemicals
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment


Chemical safety assessments for substances in this mixture were not carried out.

Ireland (en) Page 18 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

SECTION 16: Other information


Indication of changes (revised safety data sheet)
Alignment to regulation: Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Restructuring: section 9, section 14


Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant

2.2 Precautionary statements - prevention: yes


change in the listing (table)

2.2 Labelling of packages where the contents do yes


not exceed 125 ml:
change in the listing (table)

Abbreviations and acronyms


Abbr. Descriptions of used abbreviations

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)

ADR Accord relatif au transport international des marchandises dangereuses par route (Agreement concern-
ing the International Carriage of Dangerous Goods by Road)

Aquatic Acute Hazardous to the aquatic environment - acute hazard

Aquatic Chronic Hazardous to the aquatic environment - chronic hazard

ATE Acute Toxicity Estimate

BCF Bioconcentration factor

BOD Biochemical Oxygen Demand

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

COD Chemical oxygen demand

DGR Dangerous Goods Regulations (see IATA/DGR)

DNEL Derived No-Effect Level

EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing
50 % changes in response (e.g. on growth) during a specified time interval

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

ErC50 ≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either
growth (EbC50) or growth rate (ErC50) relative to the control

Eye Dam. Seriously damaging to the eye

Eye Irrit. Irritant to the eye

Ireland (en) Page 19 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078

Abbr. Descriptions of used abbreviations

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation
(EC) No 1272/2008

LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval

LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval

log KOW n-Octanol/water

Met. Corr. Substance or mixture corrosive to metals

M-factor Means a multiplying factor. It is applied to the concentration of a substance classified as hazardous to the
aquatic environment acute category 1 or chronic category 1, and is used to derive by the summation
method the classification of a mixture in which the substance is present

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

PNEC Predicted No-Effect Concentration

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)

S.I. No. 619 of Safety, Health and Welfare at Work (Chemical Agents) Regulations 2001
2001

Skin Corr. Corrosive to skin

Skin Irrit. Irritant to skin

STEL Short-term exposure limit

SVHC Substance of Very High Concern

TWA Time-weighted average

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

Key literature references and sources for data


Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU.
Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). Regulations
concerning the International Carriage of Dangerous Goods by Rail (RID). International Maritime Dan-
gerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

Ireland (en) Page 20 / 21


Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Sodium hypochlorite solution 12 % Cl, Biocide Grade, stabilized

article number: 0078


Classification procedure
Physical and chemical properties. The classification is based on tested mixture.
Health hazards. Environmental hazards. The method for classification of the mixture is based on in-
gredients of the mixture (additivity formula).
List of relevant phrases (code and full text as stated in section 2 and 3)
Code Text

H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

Ireland (en) Page 21 / 21

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