Hydrogen Notes
Hydrogen Notes
Hydrogen Notes
hydrogen
1.
KMnO4 + H2SO4 + H2 → No reaction
Concept Ladder
2.
Difference of hydrogen with alkali metals :
(i) Non-metallic character : Hydrogen is a
non–metal while alkali metal are metalic.
Concept Ladder
(ii) Nature of oxide : Nature of oxide of hydrogen
is neutral while oxides of alkali metals Hydrogen shows dual
are basic in nature. nature. It behaves as
(iii) Atomicity : Hydrogen is diatomic in electropositive element
nature (H2) while alkali metals are like alkali metals as it
monoatomic. can lose the planetary
(iv) Nature of compounds : Nature of compounds electron. It also behaves as
of hydrogen with halogens (HCl, HBr, HF, HI) an electronegative element
are low boiling covalent compound while like halogens as it can
halides of alkali metals are low melting gain one more electron to
ionic solids (LiF, NaCl, KBr, etc.) saturate 1s subshell.
(v) Ionisation energy : Ionisation energy
of hydrogen is very high in comparison
to alkali metals.
3.
Compound NaH NaCl NaBr NaI
Oxidation No. –1 –1 –1 –1
Element H F Cl Br I
4.
Note :
Representation 1
1
H 2
1
D 3
1
T
Neutrons 0 1 2
Concept Ladder
Isotopic Effect :
y In Isotopic effect minimum changes occurs The bond energy of H–H
in chemical properties like state of chemical bond is least and hence it
reaction etc. and maximum changes occurs is most reactive among the
in physical properties like boiling point, isotopes of hydrogen.
bond energy, melting point while Bond energy H2 < D2 < T2
Hydrogen
5.
y The Isotopic effect is found only in hydrogen
isotopes (1H1, 1D2, 1D3). Because there is large
Definitions
difference in mass.
isotopes can be defined as the
variants of chemical elements
that possess the same number
of proton and electrons, but a
different number of neutrons.
Ex. 1H (Protium), 21 D (Deuterium),
1
1 T (Tritium)
3
A.1 (1)
Protium, Deutorium and Tritium are the Isotopes of hydrogen.
A.2 (i) because C-H bond energy is less in comparison to C-D bond energy.
A.3 (4)
Hydrogen atom ‘H’ is termed nascent hydrogen when it has excess of energy.
Hydrogen
6.
Ortho and Para Hydrogen :
y Hydrogen molecule contains two hydrogen Definitions
atoms, each atom has one proton in the
nucleus with an electron. Like electron, Ortho hydrogen molecules
proton is also spinning about its axis. are those in which the spins
y If two protons in the hydrogen of both the nuclei are in the
molecule have spins in the same same direction. Molecules of
direction then the form is termed as ortho hydrogen in which the spins
hydrogen and if the protons spins are in of both the nuclei are in the
opposite direction, the form is known as opposite direction are called
para hydrogen. Para hydrogen
A.4 (4)
Factual statement
Hydrogen
7.
Method of preparation of hydrogen :
Lab method :
8.
Q.5 What is false about Lane’s process ?
(1) Method is used for manufacture of dihydrogen
(2) It involves the oxidation of iron by steam
(3) It involves the reduction of H2O(g) by iron
(4) It involves the oxidation of water gas
Hydrogen
9.
Coal gasification :
Previous Year’s Question
Properties of hydrogen :
Physical properties : Hydrogen gas is colourless,
odourless and tasteless.
S.No. Property
4 Electronegativity 2.1
10.
Hydrides :
Types of hydrides : Concept Ladder
(A) Ionic or saline or salt like hydrides.
(B) Covalent or molecular hydrides. During the preparation
(C) Metallic or interstitial hydrides. of hydrides, the metal
(A) Ionic hydrides : Ex : LiH, NaH, KH, RbH, CaH2, should be hydrogenated in
BaH2 etc. the presence of a surface
y Formed by s-block elements. (Highly active agent in kerosene
electropositive) except Be and Mg. or some form of agitation
y Ionic hydrides have high melting and boiling should be used to prevent
point. the decomposition of
y Stability of hydrides : LiH > NaH > KH > RbH surface film of hydride on
> CsH Similarly the metal which leads to
incomplete conversion
CaH2 > SrH2 > BaH2
y Ionic hydrides are non-volatile and non-
conducting in solid states but conduct
electricity in molten state.
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Hydrogen
11.
Q.6 When electric current is passed through an ionic hydride in molten state :
(1) Hydrogen is liberated at anode
(2) Hydrogen is liberated at cathode
(3) Hydride ion migrates towards cathode
(4) Hydride ion remains in solution
A.6 (1)
At anode : 2HQ → H2+ 2eQ Concept Ladder
12.
Electron rich covalent hydrides :
y Group 15th, 16th, 17th form electron rich Concept Ladder
covalent hydrides.
y Presence of 1, 2 and 3 lone pair of electrons Hydrides of group 13
with highly electronegative element-like O, like AlH3, B2H6 being
N and F. electrophiles behave like
y These hydrides form hydrogen bonding. lewis acids.
Ex : NH3, H2O etc.
Ex-(1)
Properties :
y These hydrides are held together by weak
van der Waal’s forces and in some cases
by hydrogen bonding.
y These hydrides are volatile in nature having
low electrical conductivity.
y The thermal stability of 15th group hydrides Concept Ladder
are NH3 > PH3 > AsH3 > SbH3 > BiH3.
Uses : Hydrogen is also used as
y Boron hydrides are used as energy fuel and a rocket fuel where liquid
hydrogen is combined with
propellants.
liquid oxygen to produce
y Phosphine (PH3) is used for Holme’s singal. a powerful explosion.
y HF is used for etching of glass. Hydrogen can be used as
a clean fuel alternative to
y Act as Lewis base.
gasoline.
y Acidic character increases from left to right.
Hydrogen
13.
y Hydrides of group 13th are electron deficient.
Concept Ladder
14.
Properties :
y Black powdery, metallic lustre and magnetic
property. Concept Ladder
y They are good conductors of electricity
Conductivity decreases with increase in Group-7, 8, 9 do not form
temperature. hydrides (Group 6 to 9 is
y Density of hydrides is lower than those referred to the hydride
of metals from which are formed since gap). Also in 6th group
crystal lattice expands due to absorption of only Cr from hydride.
hydrogen.
y High thermal conductivity.
y These generally undergo reversible
decomposition into H2 gas and metal.
A.7 (4)
Hydrogen atoms occupy the interstitial spaces of d & f-block elements and
they form interstitial hydrides.
Q.8 Which of the following easily reacts with water producing hydrogen ?
(1) PH3 (2) B2H6 (3) CH4 (4) H2S
A.8 (2)
B2H6 + 6H2O → 2B(OH)3 + 6H2
Water :
y Water is a universal solvent, exists as a solid Previous Year’s Question
below 0°C temperature and as a gas above
100°C temperature. Which of the following is electron-
y Pure form of H2O is bad conductor of deficient? [NEET]
electricity due to very low degree of (1) (BH3)2 (2) PH3
ionization. (3) (CH3)2 (4) (SiH3)2
Hydrogen
15.
Definitions
Concept Ladder
16.
Q.9 Explain, why the density of ice is less than water ?
A.9 Maximum density of H2O is at 4°C. Ice floats on water because of density is
less than that of water which in turn is due to the empty space in its crystal
structure. Crystal structure of ice is regular hexagon with empty space at the
centre. The crystal structure of ice is partly broken at 4°C.
A.10 Water free from all types of cations and anions is called deionized water.
Preparation :
4 Polarity Polar
6 Geometry Tetrahedral
Hydrogen
17.
7 Shape Bent or V-shape
18.
Q.11 What happens when hydrolith is treated with water.
Q.11 Hydrolith, i.e. CaH2 on hydrolysis gives calcium hydroxide, Ca(OH)2 with the evo-
lution of dihydrogen gas, H2.
Decomposition :
Previous Year’s Question
19.
Hard and soft water :
y A water is soft if it produces sufficient Concept Ladder
lather with soap and water is described
as being hard. It forms insoluble scum Hard water can not
before a lather with soap. form leather with soap
y The hardness of natural water is (C17H35COONa). It forms
generally caused by presence of (C17H35COO)2Ca in ppt
bicarbonates and sulphates of calcium and form after reacting with
magnesium but all soluble salts form a Ca2+when react with Ca+2.
scum with soap cause hardness.
20.
y Only calculated amount of Ca(OH)2
used because excess of Ca(OH)2 cause
artificial hardness.
Q.12 Soft water lathers with soap, but not hard water. Why ?
A.12 Hard water contains Ca and Mg salts. These react with soap to form insoluble
Ca and Mg salts of fatty acids. i.e. form scum and not lather.
Permanent Hardness :
y Permanent hardness due to presence of
sulphates or chloride or both of calcium Concept Ladder
and magnesium.
y The various method to remove permanent Permanent hardness is
hardness are : not removed by boiling or
(a) Washing soda method addition of slaked lime the
(b) Permutit method substances used to
(c) Calgon method remove the hardness of
(d) Ion exchange resins method water are known as water
softners.
(a) Washing soda (Na2CO3.10H2O) :
It removes both temporary and permanent
hardness.
21.
(b) Permutit :
y Permutit is the hydrated silicates of Concept Ladder
aluminium and sodium (Al2Na2Si2O8.xH2O)
obtained by fusing sodium carbonate, china Permutit method is also
clay, silica or quartz. The crystalline sodium termed as zeolite method.
aluminosilicates (sodium zeolite) formed It is regenerated by
exchange sodium ions with calcium and treating NaCl.
magnesium ions.
22.
Q.13 The exhausted permutit is generally regenerated by percolating through it a
solution of
(1) Sodium chloride (2) Calcium chloride
(3) Magnesium chloride (4) Barium chloride
A.13 (1)
Factual statement
Q.14 When zeolite, which is hydrated sodium aluminium silicate is treated with hard
water, the sodium ions (NaÅ) are exchanged with :
(1) HÅ ions (2) Ca2+ ions
(3) SO2-4 ions (4) OH– ions
Q.14 (2)
Factual statement
(c) Calgon method : Concept Ladder
y complex salt of sodium hexametaphosphate
(NaPO3)6 and metaphosphoric acid is called Calgon method is specially
as Calgon. It is represented as Na2[Na4(PO3)2] used in softening of water
calcium and magnesium salts present in for boiler use.
hard water with Calgon to give complex
salts.
Q.15 (3)
Factual statement
Hydrogen
23.
(d) By ion exchange resins :
y Resins are synthetic substances the cation
Concept Ladder
exchange consists of granular insoluble
organic acid resin having gaint molecules
Hard water : Water that
with sulphonic group or carboxylic groups
contain high amount of
while the anion exchange contains giant
dissolved minerals or
organic molecules with basic groups derived
ions such as calcium,
from amines.
magnesium etc.
y Ion exchange resins remove all soluble
Soft water: Soft water
minerals from water. The hard water is
is surface water that
first passed through a bed of cation
contains very low
exchanger which removes the cations like
concentration of ions r
Na+, Mg2+, Ca2+ and other by exchange with
minerals, e.g., Rainwater
H+ ions.
and distilled water.
24.
Disadvantages of hard water :
(1) Not fit for domestic use because it spoils
lustre of utensils.
(2) Not fit for industrial use because it contain
Ca2+/Mg2+ ions in H2O.
(3) Not fit for boiler use because it causes Rack your Brain
rusting.
(4) Corrosion Explain the process of rusting by
MgCl2 + H2O → Mg(OH)Cl + HCl attack of HCl?
HCl attacks metal surface of boiler and
thereby shortens its life by rusting.
(5) Not fit for washing the clothes because it
forms scum.
Degree of hardness :
Hydrogen
25.
Q.16 A sample of hard water contains 1 mg CaCl2 and 1 mg MgCl2 per litre. Calculate
the hardness of water in terms of CaCO3 present in per 106 parts of water.
(1) 2.5 ppm (2) 1.95 ppm (3) 2.15 ppm (4) 195 ppm
Q.16 (2)
Molecular weight of CaCl2 = 111.0 g
Molecular weight of CaCO3 = 100 g
Molecular weight of MgCl2 = 95.0 g
CaCl2 + Na2CO3 → CaCO3 + 2NaCl
MgCl2 + Na2CO3 → MgCO3 + 2NaCl
(i) 111.0 g CaCl2 = 100 g CaCO3
100
1 mg CaCl2 = mg CaCO3 = 0.9 mg CaCO3 ]
111
26.
Structure of H2O2 :
Preparation :
27.
By oxidation of 2-Butylanthraquinol
Electrolytic Process :
y In this process, the electrolysis of 50%
H2SO4 is carried out at low temperature
using platinum electrodes and a current
of high density. Peroxy disulphuric acid is
Concept Ladder
formed.
Properties of H2O2 :
y Pure H2O2 syrupy liquid, colourless,
odourless, specific gravity 1.45 at 0°C.
y Soluble in H2O, ether and alcohol, bitter
taste, injurious to skin, boils at 152°C,
freezes at –0.89°C, begain to decompose
on boiling, shows hydrogen bonding, having Rack your Brain
dipole movement (m) = 2.1 D
Which compound is formed when
Chemical properties : H2O2 is react with dil. H2SO4?
1. Decomposition :
y Pure hydrogen peroxide is an unstable liquid
Hydrogen
28.
and decomposes into water and oxygen on
long standing or heating.
Previous Year’s Question
Concept Ladder
29.
(i) It oxidises acidified ferrous sulphate to
ferric sulphate :
30.
(x) It oxidises formaldehyde to formic acid
Previous Year’s Question
(xi) It oxidises benzene to phenol
The O—O—H bond angle in H2O2
is [AIPMT]
(xii) It oxidises mercury to mercuric oxide in
(1) 106° (2) 109°28’
acidic medium
(3) 120° (4) 97°
Concept Ladder
31.
4. Bleaching Action :
y The bleaching action of H2O2 is due to
the nascent oxygen which liberates on
decomposition. Rack your Brain
H2O2
→ H2O + [O] (nascent oxygen) Explain how nascent O which
is the product of H2O2, makes it
y he nascent oxygen (O) combines with
T colourless?
colouring matter which, in turn, gets
oxidised. It’s used for bleaching of delicate
materials like silk, ivory, wool, feather etc.
32.
Uses of hydrogen peroxide :
(i) It is used as antichlor (to remove Cl2) in
Concept Ladder
textile industry to remove excess of chlorine
after bleaching operations. H2O2 is used for bleaching
(ii) It is used in manufacture of many inorganic delicate materials like
and organic (sodium perborate, epoxides) hair, silk, wool, ivory,
compounds. textile, wood and
(iii) It is used to restore the colour of lead paper pulp.
paintings which have blackened due to the
action of H2S present in the air on lead
paints.
(iv) It is used in the laboratory for detecting
the presence of chromium, titanium and
vanadium salts with which it ‘yields
peroxides of characteristic colours.
(v) It is used as an antiseptic under the name Rack your Brain
perhydrol (30% H2O2) for washing wounds,
teeth and ears.
Explain how H2O2 is used as an
(vi) 93% H2O2 solution is used as an oxidant
antiseptic for woulds?
for rocket fuel and as a propellant for
torpedoes and submarines.
33.
Storage of hydrogen peroxide :
The following precautions are taken while storing
hydrogen peroxide solution. Concept Ladder
(i) H2O2 cannot be stored in glass bottles
since rough surface of glass, alkali metal
oxides present in it, and exposure to light Hydrogen peroxide is
catalyse its decomposition. Therefore, H2O2 biochemically formed in
is usually stored in coloured paraffin wax human boides and the
coated or Teflon bottles. bodies of other animals but
(ii) Negative catalyst such as glycerine, it is actually toxic to cells.
acetanilide, phosphoric acid etc. must also
be added to stabilize the H2O2.
34.
Rack your Brain
1 mL of H2O2 contains 0.03035 g of H2O2
100 mL of H2O2 contains 0.3035 × 100 = Calculate the strength of 10
3.035 g of H2O2 volume solution of hydrogen
Hence, concentration of ’10 volume’ of H2O2 peroxide.
solution is 3.035% (w/v) orconcentration or
strength of ’10 volume’ of H2O2 solution is
3.035 × 10 = 30.35 g L–1.
2H2O2
→ 2H2O + O2
2 mol 1 mol
Previous Year’s Question
2 mol of H2O2 = 22.4 L of O2
1 mol of H2O2 = 11.2 L of O2 The volume strength of 1.5 N H2O2
solution is [AIPMT]
1M H2O2 = 11.2 L of O2
(1) 8.8 (2) 8.4
1 N H2O2 = 5.6 L of O2 = 5.6 volume of O2 (3) 4.8 (4) 5.2
Hydrogen
35.
Q.18 In which group of the periodic table, hydrogen is placed?
A.18 No fixed position, sometimes placed in IA with alkali metals and sometimes in
VIIA (or 17th) group with halogens.
Q.19 Which metals react with H2O or dilute HCl or dilute H2SO4 to evolve hydrogen?
A.19 Metals having positive oxidation potential values or placed above hydrogen in the
electrochemical series evolve hydrogen with water or dilute HCl or dilute H2SO4.
Q.21 Why are the melting and boiling points of D2O are higher than those of ordinary
water?
A.21 D2O has more molecular mass and greater degree of association than H2O and thus
shows higher m.pt and b.pt.
36.
Q.23 Hydrogen forms compounds with elements having atomic numbers: 9, 11, 12
and 17. What are their chemical formulas? Compare their chemical behaviour.
A.23
Atomic Chemical formula of the
S. No. Element
Number hydride
1. 9 F HF
2. 11 Na NaH
3. 12 Mg MgH2
4. 17 Cl HCl
A.24 H O 2
decomposes slowly on exposure to light.
2
2 H O
2 2H O O
2 (l) 2 (l) 2 (g )
37.
Q.26 Ionic hydrides are frequently used to remove traces of water from organic
compounds. What is the underlying basis of this process?
38.
Chapter Summary
3. Uses of H2
(i) Hydrogenation of oil.
(ii) haber’s process for menufacture of Ammonia.
(iii) Liquid O2 + liquid H2 —rocket fuel in space research.
(iv) 85% He and 15% H2 is used in filling of balloons.
39.
6. Heavy water (H2O2) or Oxygenated water: It was discovered by Thennard.
(i) Methods of preparation
(a) Lab emthod: By action of H2SO4 on hydrated barium peroxide (BaO2.8H2O)
BaO .8 H O H SO BaSO H O 8 H O
2 2 2 4 4 2 2 2
40.
(iii) Uses of H2O2
(a) Bleaching of delicate material - hair, wool, feather.
H2O2
(b) restoration of colour of lead painting (black PbS white
PbSO4)
(c) Perhydrol (trade name of 30% H2O) used as antiseptic and germicide.
(d) As antichlore (Cl2 → HCl)
(iv) Structure of H2O2 - Has open book structure
Hydrogen
41.