Mist Elimination and Phase Separations
Mist Elimination and Phase Separations
Mist Elimination and Phase Separations
Phase Separations
MIST ELIMINATORS
Reduce loss of valuable chemicals: Mist eliminators markedly cut glycol, amine, or solvent consumption in absorption and
regeneration towers.
Increase throughput capacity: Mist eliminators allow a significant increase in throughput anywhere gases and liquids come into
contact in process equipment.
Improve product purity: Mist eliminators prevent contamination of side draws and overheads in refinery atmospheric and
vacuum towers and other distillation columns.
Minimize contamination: Mist eliminators can prevent the poisoning of expensive downstream catalysts or provide boiler feed
water quality condensate from evaporator overheads.
Provide equipment protection: Mist eliminators protect turbine, blower, and compressor blades, which can eliminate serious
maintenance problems.
Reduce air pollution: Mist eliminators help diminish droplet emissions to environmentally acceptable levels.
I COMMON APPLICATIONS
Knockout Drums
Designing knockout drums to include mist eliminators will reduce capital equipment costs and improve efficiency. Knockout
drums relying solely on gravity settling typically remove drops larger than 100 microns. Using an efficient mist eliminator will
remove entrainment of all drops larger than 5 to 10 microns. This higher efficiency reduces product loss; downstream corrosion;
contamination; and damage to equipment such as compressors, molecular sieve driers, and blowers. Vessel weights can easily
be reduced to half, and handling of liquid slugs is improved.
Evaporators
Customized mist eliminators reduce carryover of dissolved and undissolved solids to obtain specified steam condensate purity
levels below 1 to 50 ppm. This not only prevents product loss, but it also protects compressor internals in vapor recompression
systems, provides boiler feed water quality condensate, and prevents potential pollution problems.
Industrial installations vary from chemical plants (caustic and inorganic chemical concentrators), to pulp and paper (black liquor
and pulping chemical recovery), to the food industry (sugar, salt, and corn syrup production).
Steam Drums
In a typical steam
Customized mist eliminators reduce carryover of dissolved solids to
drum, mist eliminators
obtain specified steam condensate purity levels from 1 ppm down properly located below
to 5 ppb without the need for external separator vessels. Operating the outlet nozzles
assure high steam
pressures can range from 20 to 2500 psig [1 to 170 bar].
purity.
DEMISTER®
mist eliminator Distillation Towers
Model 119
feed pipe Liquid entrainment can cause performance problems and limit capacity in packed and
Model 186
trough distributor trayed distillation towers in two ways.
FLEXIPAC® HC® • At intermediate draw-off trays, entrainment from below reduces product purity
structured packing
and can allow non-volatile contaminants into the draw-off liquid.
Model 802
structured packing
support grid • The overhead gas product can also be contaminated with liquid entrainment.
Model 117
orifice deck In both cases, the problem is often misinterpreted as a problem with the trays or
distributor
packing. In reality, it is a problem of entrainment, which can be solved by a properly
INTALOX® ULTRA
random packing designed mist eliminator.
Model 804
random packing
gas injection
support plate Scrubbers
From clean gas scrubbers and process vents to fouling services, such as flue gas
FLEXITRAY ® desulfurization (FGD) systems or steel mill blast furnace exhausts, mist eliminators
valve tray
help improve efficiency and capacity. In severe services, high performance wash
systems from Koch-Glitsch are specially engineered to meet the process requirements
and considerably extend service life with minimum wash liquid usage.
Refineries
Mist eliminators in fractionators increase throughput capacity and allow deeper cuts for
greater yields.
• In atmospheric and vacuum pipestills, reduced entrainment from the wash oil zones
allows deeper cuts and greater throughput.
• In downstream crackers and reformers, mist eliminators prolong catalyst life by
reducing carbon and metals in side draws.
Petrochemical Plants
Mist eliminators are used in the interstage knock-out drums of the compressor trains to
extend compressor run length and service life. They are also used in quench towers to
prevent contamination and protect downstream equipment.
Payback in most systems will be less than one month when upgrading from traditional mesh styles to higher efficiency
DEMISTER® mist eliminator styles 822, 822H, or 82.
• Mechanical action
• Chemical reaction
• Condensation
The figure below illustrates the typical particle size distribution caused by various mechanisms. Combining this knowledge with
experience, the droplet sizes produced can often be estimated with reasonable accuracy.
Mechanical
sprays
trays
evaporation surface
column packing
Condensation
on surface
Chemical Reaction
Mechanical: Experience shows that droplets generated by mechanical means are commonly 5-10μ and larger in diameter. But a
boiling or bubbling liquid surface will form droplets down to just a few microns in diameter.
Condensation: Entrainment swept off the surface of heat exchanger tubes consists mostly of large (50+ microns) droplets.
However, extremely fine submicron entrainment is often generated when a liquid condenses directly in the vapor phase due to
cooling of a saturated vapor. This type of very fine entrainment can be seen when lubricating oil in a compressor is locally heated
and vaporized and then quickly condensed causing a “blue smoke.”
Chemical Reaction: When two gases react to form a liquid product, large quantities of submicron droplets are formed, which, in
turn, requires high efficiency separation equipment.
SOLUTIONS SELECTION GUIDE
Products are available in a variety of metals, plastics, thermoplastics, and fiber-reinforced plastics for applications, such as
absorber towers, scrubbers, knockout drums, evaporators, pollution control, and general mist elimination.
While the suggestions on this page provide a starting point for the selection of a mist eliminator, your final choice should be
made only after reviewing your application with an equipment designer of proven expertise. Koch-Glitsch provides expert
resources to help you make the best choice for your particular application.
Particles may also be collected by direct interception. The particle may follow a gas streamline and be collected without inertial
impaction or Brownian diffusion if the streamline is relatively close to the fiber. Consider a particle with a diameter of 1 micron.
If it follows a gas streamline which passes within 0.5 microns of the fiber, the particle will touch the fiber and be collected.
Smaller particles, generally smaller than one micron in diameter, tend to follow the gas streamline around obstacles. However,
the illustrations below show considerable Brownian movement and thus diffuse from the gas to the surface of the fiber. A
particle having a 0.1 micron diameter will have approximately five times the Brownian displacement of a 1.0 micron particle and
about 15 times the Brownian displacement of a 5.0 micron particle. Through proper fiber bed design, submicron particles can
thus be effectively collected. With Brownian diffusion, the collection efficiency increases as the particle size decreases because
the Brownian displacement actually increases with smaller particle size.
The fouling resistant FLEXICHEVRON mist eliminator often offers the best solution if the mist contains solid particulates;
viscous, sticky liquids; or if large slugs of liquid occur.
® ® ® ®
DEMISTER FLEXICHEVRON DEMISTER-PLUS FLEXIFIBER VORSOMAX
mist mist mist mist cyclone mist
eliminator eliminator eliminator eliminator eliminator
DEMISTER mist eliminators are made to any size and shape from
a wide range of materials, both metal and non-metal. Stainless
steels and exotic alloys are fully annealed to provide maximum
corrosion resistance.
2. The inertia of the droplets causes them to contact the wire surfaces and coalesce.
2
3. The large, coalesced droplets formed in the mesh ultimately drain and drop to the
vessel bottom.
1 3
I CHARACTERISTICS OF DEMISTER® MIST ELIMINATORS
• Easy to install in all process equipment
• Most cost-effective solution when equipment sizes are set by other requirements
• High efficiency with low pressure drop
• Emergency delivery available
I MATERIALS OF CONSTRUCTION
• Stainless steel
• Nickel-based alloys
• Titanium
• Aluminum
• Copper
• Polypropylene
• Fluoroplastics
• Other special materials available on request. For example, Alloy 66 and SX® are
specially designed materials used to extend service life in sulfuric acid plants.
DESIGN PARAMETERS Units for Equation 1
For general design, Equation 1 has been used as a guideline for many years. English Metric
EQUATION 1 V - design velocity ft/sec m/sec
(ρL – ρv) ½ ρL - liquid density lb/ft3 Kg/m3
V=K
ρv
ρv - vapor density lb/ft3 Kg/m3
The recommended design value of “K” varies depending on several system K - capacity factor ft/sec m/sec
Otto H. York developed the DEMISTER® mist eliminator and introduced it in 1947. Some of the first styles were traditional mist
eliminator styles that became the worldwide standards in the chemical process industries. The industry adopted a standard guideline
for K-factor of 0.35 ft/sec (0.107 m/sec) for calculations based on these traditional styles. Improved high capacity mesh styles were
introduced shortly after the Otto H. York Company became part of Koch-Glitsch. Today, Koch-Glitsch continues the research and
development of knitted mesh technology.
Excellent performance is often obtained from 30-110% of the calculated design value. Operating pressure drop is usually
negligible, < 1 in. [25 mm] wc. For high vacuum applications, high performance is routinely achieved with ∆P on the order of 0.1
in. [2-3 mm] wc.
The new high capacity styles take advantage of improved knowledge about the way internal wire geometry affects capacity and
performance in the same way that structured packing surpassed random packing performance in distillation columns.
Traditional High Capacity Efficiency Compared to the traditional styles, the high capacity
Style Capacity Gain Gain Description
Glass fiber & metal for DEMISTER styles from Koch-Glitsch can provide:
371 215 >35% Same maximum efficiency
Ultra-efficiency design • 20% or more design capacity
326 194 >25% Same for fine particles
• Lower pressure drop
Heavy duty, high
421 709 >20% Same efficiency design • Higher efficiency at design velocity
General purpose
431 172 >20% Same style • Equal or better corrosion and
931 708 >22% Same
High open area for fouling resistance
viscous or dirty liquid
FLEXICHEVRON® mist eliminators are baffle or zigzag blade modules tailored for either vertical or horizontal flow installations.
Depending on design parameters, operating conditions, and blade characteristics, these mist eliminators collect essentially
100% of all particles greater than 8 microns in diameter.
Manufactured in virtually any size from a wide range of metal alloys, thermal-set plastics, and fiber-reinforced plastic (FRP),
many styles are available for custom-designed solutions.
The reentrainment point is also highly sensitive to the geometry of the blade
profile. The superior liquid draining capability and optimum blade spacing can
be operated at a higher reentrainment point, yielding a higher capacity.
I APPLICATIONS
FLEXICHEVRON mist eliminators should be used any time that plugging of wire mesh mist eliminators is a risk. These
applications include:
• Air pollution control scrubbers where dissolved or undissolved solids can be present.
• Applications where droplets will be sticky or viscous and will plug conventional knitted wire mesh mist eliminators.
• High vacuum applications, such as evaporators and vacuum crude units, where minimum pressure drop is critical.
High Capacity FLEXICHEVRON® Mist Eliminators
Special designs for higher pressure systems.
The FLEXICHEVRON® style 250 and 350 mist eliminators rely primarily on separate liquid drainage channels to achieve higher
capacity. This results in more efficient mist removal, especially at higher pressures where the allowable velocity decreases with
the increasing gas density.
The unique characteristic of the style 250 or 350 designs is their “double pocket” construction. Strategically located slots allow
coalesced liquid on the blade surfaces to be collected and directed into internal channels shielded from the gas flow. Once inside
these channels, the collected liquid is then directed to drains that lead to a liquid sump in the bottom of the vessel or a seal
system (cup).
Compared to the unshielded single pocket designs, they also provide higher turndown before noticeable efficiency losses are
experienced.
FLEXICHEVRON® style 250 high capacity mist eliminator FLEXICHEVRON® style 350 high capacity mist eliminator
for horizontal gas flow. for vertical gas flow.
2. The collected liquid (green arrow) flows into separate channels (purple).
3. The separate channels move the liquid away from the gas (red arrow).
Because the liquid is now isolated from the gas stream and less subject to reentrainment, gas velocities can be increased in both
horizontal and vertical gas flow configurations.
VORSOMAX® cyclone mist eliminators consist of single or multiple elements mounted onto a deck plate. Each element contains
an activator which generates centrifugal force to provide the separation of vapor and liquid(s). The units are provided in easily-
handled subassemblies, which are installed through vessel manways. If the vessel is equipped with a body flange, the elements
may be consolidated into a single piece for installation via the body flange.
NEW CONSTRUCTION
For grassroots projects involving high pressure separators, cyclone mist eliminators can provide the lowest overall cost solution
by minimizing the diameter and height requirements of the vessel. This reduction in footprint can result in several benefits to the
end user such as: faster vessel delivery, lower transportation costs, simplified installation and lower overall vessel costs.
RETROFITS
For existing high-pressure separators, where significant additional capacity is required, cyclone mist eliminators can extend the
gas capacity well beyond any other mist elimination technology available from Koch-Glitsch.
I BENEFITS
• Minimizes grassroots vessel diameter and weight, which is particularly
important in high-pressure applications
• Ideal for debottlenecking existing separators/scrubbers for
capacity upgrades
• High gas turndown
• Easily installed through vessel manways
I MATERIALS OF CONSTRUCTION
• All common metal alloys
I DESIGN PARAMETERS
The design and selection of cyclone mist eliminators are based on:
• Gas and liquid physical properties
• Liquid loading
• Desired efficiency and pressure drop
DEMISTER-PLUS Mist Eliminators
Reduce new vessel size or increase capacity in existing vessel.
The DEMISTER-PLUS mist eliminator is an advanced engineering design that is often used to minimize the size of new vessels or
increase capacity in existing vessels.
In these cases, traditional mist eliminator designs will readily meet the capacity. In some equipment, particularly in knockout
drums, the vessel size is typically set by the requirements of the mist eliminator itself. When plants are revamped for additional
capacity, it is almost always more economical to reuse existing vessels rather than replace them with larger equipment.
• In new plant construction, these designs reduce knockout drum investment substantially while maintaining separation
efficiency. Vessel diameter can usually be reduced by 25 to 40% and, because the shell thickness is a function of diameter,
vessel weight can be reduced by 50 to 75%.
• In revamp situations, more than 300% capacity gain can be achieved, depending on the existing vessel geometry.
• When needed, revamp modifications can be accomplished without welding.
Vertical flow DEMISTER-PLUS Horizontal flow DEMISTER- Vertical flow DEMISTER-PLUS Vertical-flow DEMISTER-PLUS
type VM-V mist eliminator PLUS type MV-H mist eliminator type MV-V mist eliminators use type MC-V separators use
combines the high liquid handling designs allow substantial high capacity FLEXICHEVRON® VORSOMAX mist eliminators
capacity of a conventional increases in throughput capacity mist eliminators for higher for higher capacity. Solutions
FLEXICHEVRON® mist eliminator in any knockout or flash drum. efficiency at increased capacity. also available for horizontal
with the high efficiency of a separators.
DEMISTER® mist eliminator.
Inlet Devices
Equipment for improving flow distribution in multiphase separation vessels.
I BENEFITS
• Due to high efficiency separation of liquid from vapor, reduces liquid load to mist elimination equipment
• Foam breaking or suppression
• Compact design compared to conventional inlet cyclones
• Prevents shear forces acting on liquid levels which can lead to re-entrainment of previously collected liquid
• Modular construction allows for easy installation through vessel manways
• Custom engineered for vertical or horizontal vessels
Computational Fluid Dynamics Modeling
A reliable tool for design optimization, troubleshooting, and product development.
Flow distribution is critical in multiphase separation vessels. As vessel sizes are reduced or more capacity is expected from
existing equipment, traditional design rules for vessel geometry and flow distribution must be reviewed for all elements that can
affect separation performance, such as:
3
FLEXIFIBER® Mist Eliminators
Reduce visible stack gas plumes and provide unlimited turndown.
The custom designed and fabricated FLEXIFIBER® mist eliminators consist of a special
media contained between either two concentric screens or two flat parallel screens.
Depending upon design parameters, FLEXIFIBER mist eliminators can achieve high
separation efficiency of all submicron liquid particles.
3. Liquids pass through the drain leg and are collected at the bottom of the vessel.
Using the Brownian Diffusion mechanism, the type BD element is able to achieve
collection efficiencies of up to 100% on all submicron liquid particles even below
0.1 microns. Operating pressure drops are normally designed in the range of
2-20 in. [50-500 mm] wc.
When gravity forces alone do not produce an efficient separation of immiscible fluids, implementing a Koch-Glitsch liquid-liquid
coalescer solution can improve performance to provide minimal dispersion in the liquid effluent stream.
The size of the resulting droplets (dispersed phase) and the ease of their separation from the continuous phase are partially
dependent on how the dispersion is created, as shown in the chart below.
Mechanical
static mixers
mechanical agitator
centrifugal pump
Condensation
heat exchanger from vapor
Chemical Reaction
Equally important are the physical properties of the two liquids, including interfacial tension, density difference and viscosity.
The presence of solids and trace impurities, as well as pH and temperature changes can completely alter the characteristics and
ease of separation. For example, it is quite possible for even a small presence of impurities to change an easy separation into a
difficult emulsion.
Because of this complexity, a theoretical calculation describing the separation of two liquids can only be done based on
assumptions of pure liquids, which never occurs in the real world. Therefore, the selection and design of liquid separation
equipment is based on a combination of basic principles, experience, and trial testing.
Design of Coalescer Vessels
Many separators consist merely of a horizontal vessel, as shown in the diagram below, where the separation occurs by
allowing the droplets to settle by gravity.
Droplets rise (when they are the lighter phase liquid) or fall (when they are the heavier phase) based on the following
equation, which is derived from Stoke’s Law.
g (ρH − ρL ) D2
Vs=
18μ
where:
V = Settling velocity (cm/sec)
g = Gravitational constant (98/cm/sec2)
μ = Viscosity of continuous phase (poise)
ρH = Density of heavy liquid (g/cm3)
ρL = Density of liquid liquid (g/cm3)
D = Droplet diameter (cm)
3
Settling Velocity, cm/sec
0
O 50 100 150 200 250 300 350 400 450 500
Droplet settling is strongly affected by both the droplet size and the distance the droplet must settle before it reaches the
interface between the two liquid phases. Both of these factors can be influenced through the selection of internals to accelerate
the separation.
Similar to the FLEXIFIBER® mist eliminator, these elements are installed via mounting
flange onto a tube sheet contained in the separator. The liquid phases are forced to flow
radially through the media, which coalesces the small droplets in the dispersed phase for
separation from the continuous liquid phase.
The performance characteristics of KY-FIBER media make it a good fit for dispersions
that create a hazy appearance. Typically, these dispersions are tough to separate with
long settling times or conventional media. KY-FIBER media is not recommended for
fouling services.
I PHASE SEPARATION SOLUTIONS FOR COMMON APPLICATIONS
Created using inlets, turbulence isolation plates, and combinations of KY-MESH and KY-FLEX® liquid-liquid coalescing media
and parallel plate settling media, the exact combination of products in each solution varies depending on the application. With
over 50 years of experience providing phase separation solutions, Koch-Glitsch engineers have the knowledge and experience
to select an effective solution to meet specific application requirements. The solutions pictured below are representative of the
designs provided by Koch-Glitsch for common applications. Each solution will vary based on specific process requirements.
Hazy Distillates
As product cools in storage tanks, dissolved water comes out of solution to form water
droplets. These water droplets, which make up a small percentage of the feed, create a
haze that results in off-specification product. Without proper coalescing media,
use of the product is delayed until the water settles out by gravitational
forces alone.
Alkylation Units
In refineries, there are several steps where sulfuric acid, caustic, or water mix with
hydrocarbon streams and then are separated. It is critical that these separations are as
sharp and clean as practical to minimize acid and caustic consumption as well as to
minimize the potential for fouling/corrosion in downstream equipment
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+39-039-638-6010 Tel
+39-06-928-911 (Italy), +44 (0) 1782-744-561 (United Kingdom),
Koch-Glitsch BV or your local Koch-Glitsch office.
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+32 (0) 3-647-2847 Tel
+65-6831-6500 (Singapore) or your local Koch-Glitsch office.
ASIA
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260 Orchard Road, #11-01/09 | The Heeren | Singapore 238855
+65-6831-6500 Tel
Legal Notice
The information contained in this bulletin is believed to be accurate and reliable,
but is not to be construed as implying any warranty or guarantee of performance.