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Long Answers: Cac A B Ethylene D

The document contains 9 long answer questions and 20 short answer questions on various topics in chemistry including quantum numbers, Bohr's model of the hydrogen atom, emission and absorption spectra, periodic properties, chemical bonding including hybridization examples, states of matter, thermodynamics, hydrogen and its compounds, group 13 and 14 elements, chemical equilibrium, acids and bases. The questions require explanations of concepts, definitions, derivations, examples and reactions.

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Akkireddi Anil
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41 views4 pages

Long Answers: Cac A B Ethylene D

The document contains 9 long answer questions and 20 short answer questions on various topics in chemistry including quantum numbers, Bohr's model of the hydrogen atom, emission and absorption spectra, periodic properties, chemical bonding including hybridization examples, states of matter, thermodynamics, hydrogen and its compounds, group 13 and 14 elements, chemical equilibrium, acids and bases. The questions require explanations of concepts, definitions, derivations, examples and reactions.

Uploaded by

Akkireddi Anil
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
Download as pdf or txt
Download as pdf or txt
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Long Answers

1. How are the quantum numbers n, l and ml arrived at? Explain the signigicance of these
quantum numbers

2. What are the postulates of Bohr’s model of hydrogen atom? Discuss the importance of this
model to explain various series of line spectra in hydrogen atom.

3. a) Difference between emission and absorption spectra.


b) Explain the advantages and disadvantages of Bohr’s theory for hydrogen atom.
c) Give the 1) Pauli exclusion principle 2) aufbau principle 3) Hunds rule

4. Write an essay on s,p,d and f block elements.

5. Define IE1 and IE2. Why is IE2 > IE1 for a given atom? Discuss the factors that effect IE of an
element.

6. What is periodic property? How the following properties vary in a group and a period? Explain
1) Atomic radius 2) Electron gain enthalpy 3) EN 4) IE 5) Nature of oxides

7. Describe any two methods of preparation of Benzene with corresponding equation. Explain
following benzene reactions.

a) Halogenation b) Alkylation c) Acylation d) Nitration e) Sulphonation

8. Give two methods of preparation of Ethylene.

How does it react with a) hallozen b) reaction with water c) Baeyars reagent d) O3

9. a) Give two methods of preparation of Acetylene


H O Hot metal tub AlCl
b) CaC2 
2
 A 
 B  3
CH Cl
 3

Br / CCl
c) Ethylene 
2 4
D
SHORT ANSWERS (4 MARKS)
Chemical Bonding

1. Explain Sp3 d2 hybridisation with an example (SF6)

2. Explain the hybridisation of PCl5

3. State Fajan’s rules with suitable examples.

4. What is Hydrogen bond? Explain the different types of Hydrogen bonds with example.

5. A) Define dipole momement. Give the application.

b) Dipole moment of NH3 is greater than dipole moment of NF3 Why?

6. Explain the formation of coordinate covalent bond.

States of Matter

7. Give the important postulates of kinetic molecular theory of gases

8. State and explain Grahm’s law of diffusion.

9. State and explain the Dalton’s law

10. Deduce a) Boyle’s law b) Charle’s law c) Grahm’s law d) Dalton’s law from kinetic gas equation

11. Derive the ideal gas equation from gas laws

12. 360 cm3 of CH4 gas diffused through a porous membrane in 15 minutes. Under similar

conditions.

Thermodynamics

13. State & explain “Hess law of constant heat summation “ with example

14. a) State 1st law and 2nd law of thermodynamics

b) Entropy, gibbs energy


15. a) Define intensive and extensive properties

b) Define system, open system, closed system, isolated system

Hydrogen and its Compounds

16. Write any four reducing properties of hydrogen peroxide. Give equations.

17. What is Hardness of water? How is hardness of water removed by permutit process or ion

exchange method or Calgon method?

18. Explain, with suitable examples, the following: a) Electron deficient b) Electron-precise and c)

Electron-rich hydrides.

19. Write a few lines on the utility of hydrogen as a fuel.

20. Discuss the position of hydrogen in the periodic table.

13th Group Elements

21. Explain the structure of Diborane

22. Explain Borax bead test with a suitable examples

23. Write the preparation of properties of diborane

14th Group Elements

24. Give the difference between Diamond and graphite

25. Explain a) inert pair effect b) allotropy c) catenation

Chemical Equilibrium and acids and basis

26. Derive the relation between Kp & Kc for equilibrium reation. A) N 2 ( g )  3H 2 ( g ) 2 NH 3 ( g )

27. State Le-chatlier’s principle and apply the same to the following equilibrium
N 2 ( g )  3H 2 ( g ) 2 NH 3 ( g ) : H  92 KJ

28. What is conjugate Acid-Base pari? Write the conjugate acid and conjugate base of

NH 3 and H 2O , OH  , HCO 3

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