Snsir JR Chemistry Imp Questions

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JR.CHEMISTRY IMP QUESTIONS

Long Answer Question - 8 marks

1. What are the postulates of Bohr’s model of hydrogen atom? Discuss the
Importance of this model to explain various series of line spectra in
hydrogen atom.
2. What are quantum numbers? Explain the significance of these quantum
numbers.
3. Write an essay on s, p, d and f block elements.
4. Define IE1 and IE2.Why IE2> IE1 for a given atom? Discuss the factors that
effect IE of an element.
5. What is periodicity? How the following properties vary in a group and in
a period? (a) Atomic radius(b) IE (c) EA (d) EN (e) Nature of oxides
(f) Metallic and Non-metallic nature
6. What do you understand by Hybridization? Explain different types of
hybrisation involving S and P orbital’s.
7. Describe two methods of preparation of Benzene? Give equations for the
reactions of Benzene if the following(a) Alkylation (b) Halogenations
(c) Nitration (d) sulphonation (e) Friedel craft’s Acylation
8. Describe two methods of preparation of Ethylene. Give equation for the
reactions of Ethylene with the following (a) Ozone (b) Hypo halous acid(c)
Cold and dil AlkKMnO4(d) Heated with O2 at high pressure (e) Br2in CCl4.
9. Write the following reactions with equations (a) Wurz reaction
(b) Polymerization of ethylene (c) Addition of water to acetylene
(d) Kolbe’s electrolytic Method.(e) Sabatier –Sanderson reaction(f)Ozonalysis
(g) Decarboxylation (h) Dehydration (i)dehalogenation
(j) Dehydrohalogenation
10. Write any two preparation methods of acetylene ? How does it reacts
with the following (a) water (b) ozone (c)Br 2 (d) hydrogenhalide (e)
ammonical silver nitrate(AgNO3) and (f) ammonical cuprous chloride (Cu2Cl2)
Short Answer Questions: 4 marks
*1. Give the molecular orbital energy diagrams of N2 and O2 molecule.
*2. What is hybridization? Explain the hybridization involved in PCl 5 and
SF6molecules.
3. Explain the formation of coordinate covalent bond with one example.
*4. State Fajan’s rules and give suitable examples.
5. Give an account of VSEPR Theory, and its applications.
6. Define Dipole moment? Even though both NH3 and NF3 are pyramidal.
NH3 has a higher dipole moment compared to NF3. Why?
7. How do you predict the shapes of the following molecules making use of

VSEPR Theory?(a) (b) (c) (d) (e) (f) NH3


8. What is meant by the term Bond Order? Calculate the bond orders in the

following.(a) N2(b) O2(c) (d) (e) (f)


*9. What is Hydrogen bond? Explain the different types of Hydrogen bonds with
examples.
10. State and explain the Hess’s law of constant heat summation.
*11. Explain (a) Enthalpy (b) Entropy (c) Internal Energy and (d) Gibb’s energy
*12. Explain the state function Enthalpy? What is the relation between

.
13.what is heat capacity ? Derive Cp-Cv=R.
14. Write the postulates of kinetic molecular theory of gases.
*15. Deduce (a) Boyle’s law (b) Charle’s law (c) Graham’s law (d)
Dalton’s law and(e) Kinetic energy equation from kinetic gas equation.
*16. (a) State and explain graham’s law of diffusion and applications.(b) 360 cm 3
of CH4 gas diffused through a porous membrane in 15 minutes. Under similar
conditions . 120 cm3 of another gas diffused in 10 minutes. Find the molar mass of
the gas.
17. Derive an ideal gas equation?
18. Balance the following equation by Ion Electron Method

*(a) (Basic medium)

(b) (Basic medium)

(c) (Basic medium)

(d) (Acidic medium)

(e) (Acidic medium)


(f) (Acidic medium)

19. (A) Chemical analysis of a carbon compound gave the following percentage
composition by weight of the elements present, carbon = 10.6%, hydrogen = 0.84%,
Chlorine = 89.10% calculate the empirical formula of the compound.
(B) Calculate the empirical formula of a compound having percentage composition.
Potassium (k) = 26.57, Chromium (Cr) = 35.36, Oxygen (O) = 38.07 (Give the atomic
weights of K, Cr and O as 39, 52 and 16 respectively.
(C) A carbon compound contains 12.8% carbon 2.1% hydrogen, 85.1% bromine.
The molecular weight of compound is 187.9. Calculate the molecular formula.
20. What is Lechatelier’s principles? Discuss the applications of Lechaterlier’s
principle for the industrial synthesis of Ammonia (NH3) and sulphurtrioxide (So3).
21. Derive the relation between kp and ke for the following equilibrium reactions.

(a) (b)

*(c) (d)

(e)
*22. What is conjugate acid-base pair? Write conjugate acid and base of the

following.(a) H2O(b) NH3 (c) H2O2(d) (e) (f)


*23. Explain lewis acid- base theory with suitable example. Classify the following

species intoLewis acids and Lewis bases (a) (b) (c) (d)
*24. Explain the concept of Bronsted acids and Bronsted bases with examples.
25. What is hard water, soft water and hardness of water? Explain the removal of
hardness of water by using (a) calgon’s method (b) Ion exchange resin method or
synthetic resin method and(c) Ganpermutit process (or) Zeolite method (or) Ion
exchang method.
26. Explain the following hydrides (a) Electron deficient (b)Electron precise
(c) Electron rich (d) Ionic hydrides and (e) Interstitial hydrides.
27.write any two oxidizing and reducing properties of H2O2 .
*28. Write a few lines on the utility of hydrogen as a fuel.
*29. write any two preparation methods of H2O2 (Electrolysis, auto oxidation)
calgon method.
*30. Explin the structure of diborane ?
31. What is borax ? Explain borax bead test with example ?
32. write any two preparation methods of diborane ? How does it’s reacts with (a)
H2O (b) CO(c)NH3 (d)N(CH3)3 or N(Me)3 (e) O2
33. What are electron deficient compound? Explain why BF3or BCl3acts as Lewis
acid.
*34. Suggest reasons why the B-F bond length in BF3(130Pm) and (143Pm)
differ.
*35. Write the differences between diamond and graphite.
36. What do you understand by (a) Allotropy (b) Inert pair effect and(c) Catenation
37. Explain chain , position, functional isomerism and metamerism ? .
38. Name the products A, B and C formed in the following reactions.
Give the Equations forthe reactions.

(a) Ethylene

(b)
39. Explain Geometrical Isomerism with suitable example?
40. (a) State hund’s rule, Aufba and paulis exclusive principle.
(b) Write the limitations of Bohr’s atomic model.
41. Write the differences between emission and absorption spectrum.
42. (a) State Debroglies Hypothesis(b) State Heisenberg uncertainty principle.
43. What is lanthanide contraction? Give its consequences.
44. Give the charcterstic properties of transition elements?
45. Explain the postulate of Planck’s quantum theory.

ALL THE BEST – ( chemistry department)

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