Chemical Equilibrium

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NCERT-DECODE SERIES

CHEMICAL EQUILIBRIUM
1. At 450K, Kp = 2 × 1010 bar–1 for the reaction ; 6. At 1000 K, the value of KP for the reaction :
2SO2(g) + O2(g) 2SO3(g) A(g) + 2B(g) 3C(g) + D(g)
What is KC at this temperature ? is 0.05 atm. The value of KC in terms of R
(1) 7.47 × 1011 M–1 would be :-
(2) 7.47 × 109 M–1 (1) 20000 R (2) 0.02 R
(3) 7.47 × 108 M–1 (3) 5 × 10–5 R (4) 5 × 10–5 × R–1
(4) 7.47 × 1013 M–1 7. For the reaction C(s) + CO2(g) 2CO(g) the
2. For : partial pressure of CO and CO2 are 2.0 and 4.0
NO(g) + O3(g) NO2(g) + O2(g); KC = 6.3 × 1014 atm respectively at equilibrium. The KP for
Both forward and reverse reactions in the the reaction is
equilibrium are elementary bimolecular (1) 0.5 (2) 4.0
reactions. Find KC for reverse reaction. (3) 8.0 (4) 1
(1) 2 × 1014 (2) 1.59 × 10–15 8. For which reaction is Kp = Kc :-
(3) 1.6 × 10–10 (4) 1.6 × 10–20 (1) 2NOCl(g) 2NO(g) + Cl2(g)
3. At equilibrium, the concentrations of N2, O2 (2) N2(g) + 3H2(g) 2NH3(g)
and NO in a sealed vessel at 800K are (3) H2(g) + Cl2(g) 2HCl(g)
3 × 10–3 M, 4.2 × 10–3 M and 2.8 × 10–3 M (4) 2SO2(g) + O2(g) 2SO3(g)
respectively. What will be the KC for the 9. Consider the two gaseous equilibrium
reaction: involving SO2 and the corresponding
N2(g) + O2(g) 2NO(g) equilibrium constants at 299 K
(1) 0.622 (2) 0.311 1
SO2 (g) + O2 (g) SO3 (g) ; K1
(3) 0.287 (4) 0.234 2
4. For the equilibrium 4SO3 (g) 4 SO2 (g) + 2O2 (g) ; K2
2NOCl(g) 2NO(g) + Cl2(g) The value of the equilibrium constants are
The value of equilibrium constant, KC is related by :-
3.75 × 10–6 at 1069 K. Calculate the KP for the 1
(1) K2 = (2) K2 = K14
reaction at this temperature ? (K 1 )4

(1) 0.00066 (2) 0.00033 1


 1 4
(3) 0.00022 (4) 0.00011 (3) K2 =   (4) K2 = 1
5. Which is correct statement/statements ?  K1  K1

(1) If KC > 103, products predominate over 10. For the reactions :- A B ; KC = 2,
reactants. B C ; KC = 4, C D ; KC = 6
(2) If KC < 10–3, reactants predominate over KC for the reaction A D :-
products
(1) 12 (2) 4/3
(3) If KC is in the range of 10–3 to 103,
(3) 24 (4) 48
appreciable concentrations of both
reactant and product are present
(4) All of these

 Digital [1]


NCERT-DECODE SERIES

ANSWER KEY
Question 1 2 3 4 5 6 7 8 9 10
Answer 1 2 1 2 4 4 4 3 1 4

[2]  Digital

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