Higher Technological Institute Chemical Engineering Department
Higher Technological Institute Chemical Engineering Department
Higher Technological Institute Chemical Engineering Department
a)
b)
c)
d)
4- If Kc = 8 at 100°C for the reaction, 2A (g) + B (g) ⇋2C (g), then what is
the value of Kc for the reaction, 2C (g) ⇋ 2A (g) + B (g)?
◦ = (1/8) = 0.125
7- If Kc = 2 at 100°C for the reaction, 2A (g) + B (g) ⇋2C (g), then what is the
value of Kc for the reaction, 4C (g) ⇋ 4A (g) + 2B (g)?
Kc for second reaction =(1/Kc for first reaction)^2
Kc = (1/2)^2 = 0.25
8- What is the value of Kp for the reaction; 2NOCl (g) ⇋ 2NO (g) + Cl 2(g) at 400
°C if Kc for this reaction is 2.1x10-2mol/L?
Kp = Kc (RT)^∆n
(where ∆n is sum no of moles of products – sum no of moles of reactants)
Kp = (2.1*10^-2) (0.082*(400+273))^(1+2-2) = 1.159
At equilibrium:
Conc of [NOCl] = n / vol = (4−1.32)/2 = 1.34 (mol/liter)
Conc [NO] = 1.32/2 = 0.66 (mol/liter)
Conc [Cl2] = (1.32/2)/2 = 0.33 (mol/liter)
Kc = (0.33∗(0.66)^2)/ (1.34)^2 = 0.08
Kp =kc * (RT)^n
N= no of mole product – no of mole reactant = 3-2 =1
11- The equilibrium constant Kp for the decomposition of PCl5 (g) ⇋PCl3 (g) +
`Cl2(g) Is 1.05at 250 oC. If the equilibrium partial pressures of PCl5, and PCl3 are
0.875 atm and 0.463 atm, respectively, what is the equilibrium partial pressure of
Cl2 at 250 oC.
14- At 300 οc the equilibrium constant for the reaction N2 (g) +O2 (g) ⇋ 2NO (g) is
Kc= 0.016 mole/L. at equilibrium the molar concentration of N2 and O2 are 0.04
M and 0.06 M respectively. Calculate the concentration of NO g at equilibrium.
c) Kp = Kc (RT)^-2
d) Kp = Kc (RT)^ 0 =Kc
16 - Which procedure will shift the equilibrium reaction from right to left?
A (g) +2B (g) ⇋C (g) + D (g)
◦ Decreasing pressure
◦ Add more from the products
◦ Remove any of the reactants
17. What happened if the temperature increased for the following reaction?
2SO3 (g) +ΔH ⇋ 2SO2 (g) + O2 (g)
The reaction will move in the forward direction