(@bohring - Bot) 03 - 12 - 23 - JR - IIT - STAR - CO - SCM (@HeyitsyashXD)

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Sec: JR.

IIT _*CO-SC(MODEL-A) Date: 03-12-23


Time: 3 Hrs Max. Marks: 186
03-12-23_JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_CAT-17_SYLLABUS

PHYSICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 25-11-23

CHEMISTRY: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 25-11-23

MATHEMATICS: (100% CUMULATIVE)

Yashpatil TG~ @bohring_bot


SYLLABUS COVERED FROM 22-04-23 TO 25-11-23
Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
TIME: 3 HRS IMPORTANT INSTRUCTIONS Max Marks: 186

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 1 – 8) +4 -1 8 32
(partial marking scheme) (+1)

Questions with Numerical Value Type


Sec – II (Q.N : 9 – 14) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Matrix Matching Type
Sec – III (Q.N : 15 – 18) +3 -1 4 12
(Each match consist of 2 questions)
Total 18 62

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 19 – 26) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 27 – 32) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Matrix Matching Type
Sec – III (Q.N : 33 – 36) (Each match consist of 2 questions)
+3 -1 4 12

Total 18 62

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 37 – 44) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 45 – 50) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18

Yashpatil TG~ @bohring_bot 127.30)


Matrix Matching Type
Sec – III (Q.N : 51 – 54) (Each match consist of 2 questions)
+3 -1 4 12

Total 18 62

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Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
MATHEMATICS Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
5   
and P   cos  2r
4

1. Let S   cos  2r  1
11 
 , then which of the following
15 
r 1
r 1

is(are)incorrect?

A) log P  4 B)P = 3S
S

C) cosec S > cosec P D) tan 1 P  tan 1 S

e x
2. For the equation   which of the following statement(s) is (are) correct?
1 x

A) When    0,   the equation has 2 real and distinct roots

B) When     ,  e 2  the equation has 2 real and distinct roots

C) When    0,   the equation has 1 real root

D) When    e 2 ,0  the equation has no real root

3. Which of the following is (are)correct?

A) The number of distinct real roots of the equation

x 5  x 3  x 2  x  1  x  3x 3  4x 2  2x  4   1  0 is3

Yashpatil 5
TG~ @bohring_bot
B) Let a be an integer such that all the real roots of the polynomial
2x  5x  10x  10x  10x  10 lie in the interval  a,a  1 . Then, a is equal to 2
4 3 2

C) The number of distinct real roots of the equation

x 5  x 3  x 2  x  1  x  3x 3  4x 2  2x  4   1  0 is 2

D) Let a be an integer such that all the real roots of the polynomial

2x 5  5x 4  10x 3  10x 2  10x  10 lie in the interval  a,a  1 . Then, a is equal to 3

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Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
4. Which of the following is/are correct?

A) If f(x) is periodic and g(x) is non-linear and non-periodic, then f  g  x   is non-

periodic

B) If f  x  is periodic and g(x) is non-linear and non – periodic, then f  g  x   can be

periodic with a defined period

C) If f  x  and g  x  both are non-periodic, then f  g  x   can be periodic

D) If f  x  and g  x  both the non-periodic, then f  g  x   cannot be periodic with a

defined period

5. Which of the following is (are) correct?

A) The number of points on the curve y  54x 5  135x 4  70x 3  180x 2  210x at which the
normal lines are parallel to x  90y  2  0 is 2

B) If the curves x  y 4 and xy = k cut at right angles, then  4k  is equal to 3


6

C) The number of points on the curve y  54x 5  135x 4  70x 3  180x 2  210x at which the
normal lines are parallel to x  90y  2  0 is 4

D) If the curves x  y 4 and xy = k cut at right angles, then  4k  is equal to 4


6

6. Which of the following is (are)correct?



 x  0  , then the number of points in 
1 
A) Let f  x   x 2 sin ,1 at which f '  x   0 is
x  21 

Yashpatil
20
TG~ @bohring_bot
B)Let f  x   x  px  q  3 , if f  f 1   f  f  2    0 where f 1  f  2  and
2

g  x   x 2   8p 2  18p  x  q  2 , then 2g  2  is 27

C) Let f  x   x 9  3x 8  53x 7  8x 6  8x 5  8x 4  8x 3  8x 2  8x  9 , then f(9) will be equal to


18
 1 
 2

e x 
 1
1 1
1 
, then 15log e L is 23 (Where [. ]
 
D) Let L  lim 1  e x .tan 1  x .e .sin 4 
2 2 2
x
x 0 
 x 2
x 
represents greatest integer function)

JR.IIT_*CO-SC Page. No. 4


Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
7. Consider the following system of equations

 x  2y  z  1

2 x  3y  z  1

3x   y  2z  

For some  ,    . Then which of the following is (are)correct?

A) It has no solution if   1 and   2

B) It has no solution for   1 and for all   

C) It has no solution for   3 and for all   2

D) It has a solution for all   1 and   2

8. All the points lying inside the triangle formed by the points (1, 3), (5, 6), and (–1, 2)
satisfy

A) 3x  2y  0 B) 2x  y  1  0

C) 2x  11  0 D) 2x  3y  12  0

SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.

9.
 max
Let a function g : 0, 4  R be defined as g  x    0 t  x
t 3
 6t 2  9t  3 , 0  x  3
then
 4  x, 3 x  4

Yashpatil TG~
the number of points @bohring_bot
in the interval (0, 4) where g(x) is NOT differentiable, is _____

10. Let l1  lim


x 
 
x 2x  3 x 3  x 2  1  3 x 3  x 2  1 and l2  lim
x 0
e x tan  2025 x  1
x log e 1  x 
, then the value of l1l2

is equal to

11. If the equation x 2  2ax  4x  4a  13 has only one solution, then the number of
integral values of a is ____

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Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP

12. Let f  x   tan  4


1

 12  2 x 2  
 and m and M are respectively minimum and maximum
 x  2x 2  3 
 
values of f  x  and f  x  attains its maximum value atx = a (a > 0), then the value of

  2 
4 tan  a 4  sec1  2   M  m   is equal to
  a  
 3 1 2 
13. Let P   2 0   , where   R . Suppose Q  q ij  33 is a matrix satisfying PQ  kI3
 3 5 0 
k k2
for some non-zero k  R . If q 23   and Q  , then  2  k 2 is equal to ____
8 2

14. Let m1 , m 2 be the slopes of two adjacent sides of a square of side a such that
a 2  11a  3  m12  m 22   220 . If one vertex of the square is

10  cos   sin   ,10  sin   cos    , where    0,  and the equation of one diagonal
 2
is  cos   sin   x   sin   cos   y  10 , then 72  sin 4   cos 4    a 2  3a  13 is equal to _

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.15 and Q.16 by appropriately matching the lists based on the information
given in the paragraph.
2x
Consider the functions f  x   x 3  x 2  x  1, g  x   and
1 x2
h  x   sin 1 x  cos1 x  tan 1 x  cot 1 x .
List – I List - II
Yashpatil
A)
TG~
If the range of    @bohring_bot
is   then is
f g x
P) 1
a, b ab
equal to
The number of integers in the range of
B) g  f  x   is equal to
Q) 3

C) The maximum value of g  h  x   is R) 4


k
If the minimum value of h  g  f  x    is then
D) 2 S) 5
k is equal to

T) 2

JR.IIT_*CO-SC Page. No. 6


Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
15. Which of the following is correct ?

A) AP B) BR C) CS D) DS

16. Which of the following is incorrect?

A) AR B) BQ C) CR D) CP

Answer Q.17 and Q.18 by appropriately matching the lists based on the information
given in the paragraph.
The function f  x   ax 3  bx 2  cx  d has its non-zero local minimum and maximum
values at x = –2 and x = 2 respectively. If ‘a’ is one of the rootsof x 2  x  6  0 , then
match the following

List – I List - II
A) The value of ’a’ is P) 0
B) The value of ‘b’ is Q) 24
C) The value of ‘c’ is R) Greater than 32
D) The value of ‘d’ is S) –2

17. Which of the following is incorrect?

A) AS B) BP C) CR D) DR

18. Which of the following is correct?

A) AP B) BS C) CQ D) DQ

Yashpatil TG~ @bohring_bot

JR.IIT_*CO-SC Page. No. 7


Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
PHYSICS Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
19. Two tourists who are at a distance of 40 km from their camp must reach it together in
shortest possible time. They have one bicycle which they decide to use in turn. One of
them started walking at a speed of 5 km/hr and the other rode on the bicycle at a speed
of 15 km/hr. The tourists agreed to leave bicycle at intermediate points between which
one walks and other rides.
A) Average speed of the tourists to the camp is 7.5 Km/Hr

B) Bicycle remains unused for 2 hours and 40 minutes in the entire journey

C) Total time of the journey was 5 hours and 20 minutes

D) Total walking time of each rider was equal to the total riding time during the journey

20. 4 identical particles are connected with four massless springs and placed at corners of
square (as shown in figure). Strings (i) and (ii) are massless and vertical and whole
system is in equilibrium. Then choose correct statement.

Yashpatil TG~ @bohring_bot


A) If the string 1 is cut then immediately afterwards, acceleration of A will be g
downwards

B) If string 1 is cut then immediately afterwards acceleration of A will be 2g downwards

C) If string 1 is cut then immediately after cutting the string, the tension in string 2 will
be 2mg

D) If spring between A and B is cut, then immediately afterwards, tension in string 1


will be mg

JR.IIT_*CO-SC Page. No. 8


Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
21. A uniform chain A 'B' of length 2l having mass  per unit length is hanging from
ceiling of an elevator by two light, inextensible threads AA' and BB' of equal length as
shown in figure. Distance AB is very small. At a certain instant, elevator starts
ascending with constant acceleration a(< g). Two seconds after the beginning of motion,
thread BB' is burnt. Assuming that instant to be

t = 0. Assume links of the chain won`t rebound. The elevator is big enough and the chain
won`t touch the bottom of the elevator during its motion.

Choose the correct statement(s), during the motion of the chain in the elevator:
3
A) The tension in thread AA' at time t is  lg  (g  a)2 t 2 .
4
3
B) The tension in thread AA' at time t is l(g  a)  (g  a) 2 t 2
4
3
C) The tension in thread AA' at time t is l(g  a)  (g  a) 2 t 2 .
2
D) The tension in thread AA' at time t is same with respect to ground and lift frames.
22. A ring of mass m, radius R, cross sectional area“a” and Young’s modulus Y is kept and
equilibrium on a smooth cone of radius 2R and semi vertical angle 45º, as shown in the
figure. Assume that the extension in the ring is small.
Yashpatil TG~ @bohring_bot

JR.IIT_*CO-SC Page. No. 9


Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
A) The tension in the ring will be same throughout.
B) The tension in the ring will be independent of the radius of ring if radius of the ring is
less than 2R.
mgR
C) The extension in the ring will be
aY

m 2g 2 R
D) Elastic potential energy stored in the ring will be
8Ya
23. In the shown figure, there is a conical shaft rotating on a bearing of very small clearance
t. The space between the conical shaft and the bearing, is filled with a viscous fluid
having coefficient of viscosity  .The shaft is having radius R and height h. If the
external torque applied by the motor is  and the power delivered by the motor is P
working in 100% efficiency to rotate the shaft with constant  then

2R 3 R 2  h 2 R 3 R 2  h 2
A) P  B)  
2t 2t
2R 2 h 2 R 3h 2
C) P  D)  
2t 2t R 2  h 2
24. A system is shown in the figure, which is released from rest. There is no friction

Yashpatil TG~ @bohring_bot


between ground and mass 5m. The coefficient of friction between mass 5m and mass 2m
is  . The coefficient of friction between mass 5 m and mass m is also  .
Choose the correct option(s).

JR.IIT_*CO-SC Page. No. 10


Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
A) The horizontal component of acceleration of centre of mass of system is zero.

B) The magnitude of acceleration of mass 5m is zero if   0

4mg 1
C) The tension in the string is if  
3 3 3

1
D) The magnitude of acceleration of mass 5 m is zero if  
3

25. Two capillaries of small cross section are connected as shown in the figure. The right
tube has cross sectional radius R and left one has a radius of r   R  . The tube of radius
R is very long where as the tube of radius r is of short length. Water is slowly poured in
the right tube. Contact angle for the tube wall and water is   00 . Let h be the height
difference between water surface in the right and left tube. Surface tension of water is
T and its density is . Mark the CORRECT option(s)

2T
A) The value of h if the water surface in the left tube is found to be flat is h 
Yashpatil TG~ @bohring_bot Rg

T
B) The value of h if the water surface in the left tube is found to be flat is h 
Rg

C) The maximum value of h for which water will not flow out of the left tube is
2T  r  R 
 
g  rR 

D) The maximum value of h for which water will not flow out of the left tube is
T rR
 
g  rR 

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Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
26. A thin uniform rod of mass 5 kg and length 1m is held in horizontal position with the
help of strings attached to ends of rod. Other ends of strings are held by some external
agent. Now end A is pulled down with speed v A  3t and B is pulled down with speed
v B  t where t is time in sec. Choose the correct alternatives at time t = 0.  g  10 m / s 2 

A) Angular acceleration of rod is 2rad / s 2


B) Tension in the left string is 185/6 N
C) Acceleration of centre of mass of the rod is 1m / s 2
D) Tension in the right string is 170/3 N

SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
27. A tube of U – shape is accelerating in horizontal direction in such a way, that difference

of height in different water column is . Now tube is suddenly stopped at t  t 0 . If
2
hydrostatic pressure at right most point of the bottom in water, A just after t  t 0 is
P0  ng , where P0 is atmospheric pressure,  is density & g is acceleration due to
gravity. Find value of 10 n.

Yashpatil TG~ @bohring_bot


28.  
A particle moving with initial velocity i  3iˆ  5jˆ m / s, collides with a smooth plane
wall placed at some orientation to the particle’s trajectory. The resulting velocity of the

 
particle is f  2iˆ  ˆj m / s . The coefficient of restitution for this collision is ______

[Report your answer rounded to two decimals]

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Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
29. Two vertical communicating cylinders of different diameters contain a gas at a constant
temperature under pistons of mass m1  1kg and m 2  2kg . The cylinders are in vacuum,
and in equilibrium the pistons are at the same height h 0  0.2m .
What will be the difference h in their equilibrium heights if the mass of first piston is
made as large as the mass of the second piston?
[Report your answer in meters]
[Given temperature of gas remains unchanged in the process]
30. Two friends A and B are standing on a river bank L distance apart. They have decided
to meet at a point C on the other bank exactly opposite to B. Both of them start rowing
simultaneously on boats which can travel with velocity V  5 km / hr in still water. It
was found that both reached at C at the same time. Assume that path of both the boats
are straight lines. Width of the river is   3.0 km and water is flowing at a uniform
speed of u  3.0 km / hr . The value of L is _______ (in km)

31. During the motion of a locomotive in a circular path of radius R, wind is blowing in the
horizontal direction. The trace left by the smoke is shown in Fig. (Top view).
Using the figure, determine the velocity wind of the wind if it is known to be constant,
and if the velocity loc of the locomotive is 36 km/h.

Yashpatil TG~ @bohring_bot

[Given the shape of the trace is a cycloid, and smoke particles immediately come to rest
with respect to surrounding air after being ejected]

Report your answer in units of m/s

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Narayana IIT Academy 03-12-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-17_QP
32. A homogeneous, thin rod AB of mass m and length l leans in equilibrium with its lower
end against the wall and is kept in the inclined position by a string DC (Fig.). The string
is tied at point C to the wall and at point D to the rod so that AD = AB/3. The angles
formed by the string and the rod with the wall are  and  respectively.

 
Find the minimum coefficient of friction if   and  
6 3

[Report your answer rounded off to first decimal place.]

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.33 and Q.34 by appropriately matching the lists based on the information
given in the paragraph.
A belt is moving with constant speed u (Clockwise, as shown in figure) on two rotating
fixed wheels of negligible dimensions. The length of the belt between the wheels is
  10m , as shown. At time t = 0, a small block starts moving from the upper right end of
Yashpatil TG~ @bohring_bot
the belt with leftward speed v (w.r.t. ground).  is friction coefficient between belt and
block. The moving part of the belt between the wheels is always horizontal. Column – I
gives various values of u, v &  while column – II gives the subsequent motion.

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Column – I Column – II
21
(A) u  1 m / s; v  m / s;   0.1 (P) Block will fall off the left end of belt.
2
(B) u  1 m / s; v  4m / s;   0.2 (Q) Block will fall off the right end of belt.

u  5 m / s; v  2m / s;   0.4 Slipping stops before block falls off the


(C) (R)
belt.

u  2 m / s; v  1m / s;   0 Block will fall off the belt at time t = 1


(D) (S)
sec.
Block will fall off the belt at time
(T)
t  25 / 4sec
33. Which of the following is a correct match:

A) A  PT B) B  QRT C) D  PS D) C  QRT

34. Which of the following is an INCORRECT match:

A) A  (P,S) B) B  (Q,R) C) C  (Q,T) D) D  (P)

Answer Q.35 and Q.36 by appropriately matching the lists based on the information
given in the paragraph.
Column I describes the system and initial motion of its particles and column II
gives characteristics associated with subsequent motion.

Column – I Column – II

Two identical particles move under influence


of mutual gravitational force only. Particles
are given initial velocity perpendicular to line
Yashpatil TG~ @bohring_bot
joining as shown.
Centre of mass of system
(A) (P)
does not accelerate.

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Two identical balls kept on a smooth
horizontaltable. Elastic head on collision takes
place between them.
In centre of mass frame
(B) (Q) momentum of system is
zero.

Two identical balls kept on a smooth


horizontaltable. Oblique elastic collision takes
place between them.

Momentum of system is
(C) (R)
conserved.

Block is released on a wedge as shown in


figure. All the surfaces are smooth.

(D) (S) Mechanical energy of


system is conserved

Yashpatil TG~ @bohring_bot


(T) Total kinetic energy is
constant
35. Which of the following is an INCORRECT MATCH?

A) A  PQRS B) B  PQRS C) C  PQRS D) D  PQRS

36. Which of the following is a correct match ?

A) D  QRS B) D  QS C) D  PQST D) D  QST

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CHRMISTRY Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
37. Which of the following pairs of molecules is/are not isostructural?
A) NMe3 and N(SiMe3)3 B) XeOF4 and SOF4

C) CF3 and PF3 D) SiO2 and CO2

38. Which of the following substances expand when they form a solid from liquid state?
A) H2O B) Ga C) Ge D) B

39. Which of the following statements are correct regarding the diagonal relationship
between Al and Be?
A) BeO and Al2O3 are amphoteric in nature.
B) Carbides of both produce the same gas on hydrolysis.
C) Both can form complexes.
D) Hydrides of both the elements are covalent in nature.

40. One mole of helium and one mole of neon are taken in a vessel of particular volume, at a
fixed temperature. Which of the following statements are correct?
A) Molecules of helium strike the wall of vessel more frequently.
B) Molecules of neon apply more average force per collision on the wall of vessel.
C) Molecules of helium have greater average molecular speed.
D) Helium exerts higher pressure than neon.

Yashpatil
41.
TG~ @bohring_bot
Consider the following first-order decomposition reaction.
   
A4 g  4 A g

Which of the following statement(s) is/are correct regarding the reaction? (log 2 = 0.3)

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A) At 30 min, only 20% reaction is complete.
B) t1/2 of reaction is 90 min.
C) Rate of reaction decreases linearly with time.
D) The time of intersection of two curves is independent of initial concentration of A4

42. On addition of  NH 4 2 SO4 to 0.1MNH3

A) OH ion concentration will decrease B) H3O ion concentration will decrease
C) pH will increase D) pH will decrease

43. Consider the reaction :


2 A g   B g   2C g  , H  30 K cal /mol at 1atm, 300K

If 5 moles of ‘A’ reacts with 2.5 moles of ‘B’ at 1 atm& 300K, then which of the
following is /are correct? (R = 2 cal / mol-K)
A) workdone =1.5k cal) B) q=-75 k cal

C) U=+35k cal D) U= -70.5k cal

44. The hyper conjugation phenomena can be described as :


A)   p  empty  electron delocalization

B)    * electron delocalization
C)    * electron delocalization

D)    * electron delocalization

SECTION – II
(Numerical Value Answer Type )
Yashpatil TG~ @bohring_bot
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
45. An amount of 0.1 moles of OH− ions is obtained from 8.50 g of hydroxide of a metal.
What is the equivalent weight of the metal?

1
46. The number of possible sets of quantum numbers for which n  4, l  3 and s   is _____
2

47. The solubility product of Mg  OH 2 is 9.0 1012 . The pH of an aqueous saturated solution

of Mg  OH 2 is  log1.8  0.26,log3  0.48 is ___________

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48. The percentage water loss when a certain amount of gypsum is heated to get plaster of
Paris is _____.
(Formula mass of Calcium sulphate, CaSO4 is 136 g/mol and molecular mass of water is
18 g/mol)

49. Find the number of compounds from the following with which diborane cleaves
unsymmetrically forming  L2 H 2 B   BH 4  type of complex
 

NH3, Et3N, Me3N,Me2NH, MeNH2, CO, tetrahydrofuran.

50. Select the total no.of groups that can show only –M out of +M &–M.

SO2 H, SO3 H,  NO,  NO2 , CN, CHO

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.51 and Q.52 by appropriately matching the lists based on the information
given in the paragraph.
Bridge bonds can be formed by electron deficient 3C-2e bonds or electron rich 3C-4e
bonds with different possible hybridisations of involving atoms.

Yashpatil
51. TG~
Which of the following @bohring_bot
combinations are correct for electron deficient hydrogen bridge
bond?
A) A-P, B-Q B) A-R, B-S C) A-Q, B-R D) A-Q, B-P

52. Which of the following combinations are correct for methyl bridge in the given
compounds?
A) C-Q, D-R B) C-S, D-R C) C-R, D-S D) C-P, D-Q

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Answer Q.53 and Q.54 by appropriately matching the lists based on the information
given in the paragraph.
Aromaticity is defined as a property of the conjugated cycloalkenes which enhances the
stability of a molecule. The criteria to exhibit aromaticity are

1. The compound must be cyclic

2. Each element within the ring must have a p-orbital that is perpendicular to the ring,
hence the molecule is planar.

3. The compound must follow Hückel's Rule (the ring has to contain 4n+2 p-orbital
electrons).

Yashpatil
53.
TG~ @bohring_bot
Which of the following combinations are correct?
A) (a-q,s), (b-r,s) B) (a-r,s), (b-q,s) C) (a-p,s), (b-q,s) D) (a-r,s), (b-p,s)

54. Which of the following combinations are correct?


A) (c-p), (d-p) B) (c-r,s), (d-q,s) C) (c-p,s), (d-q,s) D) (c-r,s), (d-p,s)

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