PINNAACLE CLASSES

46. The order of susceptibility of nucleophilic attack on

aldehydes follows the order 56. Which of the following will form two isomers with
(a) 1° > 3° > 2° (b) 1° > 2° > 3° semi carbazide
(c) 3° > 2° > 1° (d) 2° > 3° > 1° (a) Benzaldehyde (b) Acetone
(c) Benzoquinone (d) Benzophenone
47. In Wolf-Kishner reduction, the carbonyl group of
aldehydes and ketones is converted into A→C 5 H 10 Cl 2
¿ CH 2 −CH 3 57. A compound on hydrolysis gives
(a) group (b) group C 5 H 10 O NH 2 OH
−CH 2 OH
which reacts with , forms iodoform
(c) group (d) ¿ CHOH group but does not give fehling test. A is
Cl
|
NaHSO 3 CH 3 −C− CH 2 −CH 2 −CH 3
48. Which of the following react with |
CH 3 COCH 3 CH 3 CHO (a) Cl
(a) (b)
Cl
(c) HCHO (d) All of these |
CH 3 CH 2 −C− CH 2 CH 3
|

49. Fehling solution is (b) Cl

Cl
CuSO 4
(a) + lime (b) CuSO 4 + NaOH ( aq ) |
CH 3 CH 2 CH 2 CH 2 CH
CuSO 4 + Na2 CO 3 |
(c) (d) None of these
(c) Cl

Cl Cl
| |
50. Wolf kishner reduction, reduces CH 3 −CH −CH −CH 2 −CH 3
(a) −COOH group (b) −C≡C – group (d)

(c) −CHO group (d) −O− group

58. CH 3  CHO  HCN  A ; Compound A on hydrolysis
gives
51. Which responds to +ve iodoform test ?
(a) Butanol (b) Butan-1-al (a) CH 3  CH 2  COOH
(c) Butanol-2 (d) 3-pentanone (b) CH 3  CH 2  CH 2  NH 2
(c) CH 3  CO  COOH
52. Paraldehyde is CH 3  CH  COOH
(a) A trimer of formaldehyde |
OH
(d)
(b) A trimer of acetaldehyde
(c) A hexamer of formaldehyde
(d) A hexamer of acetaldehyde
59. Which one does not give cannizzaro's reaction

53. Hexamethylene tetramine is used as (a) Benzaldehyde

(a) Analgesic (b) Antipyretic
(b) 2-methyl propanal
(c) Urinary antiseptic (d) All of these
(c) p-methoxy benzaldehyde
(d) 2,2 dimethyl propanal
54. How will you convert butan2one to propanoic
acid?
(a) Tollen’s reagent (b) Fehling’s solution
(c) NaOH/I2/H+ (d) NaOH/NaI/H+ 60. Acetone and acetaldehyde are differentiated by
NaOH + I 2 Ag( NH 3 )+2
(a) (b)
55. Ketones react with Mg-Hg over water gives HNO 2 I2
(c) (d)
(a) Pinacolone (b) Pinacols
(c) Alcohols (d) None of these
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 PINNAACLE CLASSES
PCl ,
61. When acetaldehyde reacts with 5 the resulting

compound is 68. Which of the following is used in the manufacture

(a) Ethyl chloride (b) Ethylene chloride of thermosetting plastics
(a) Formaldehyde (b) Acetaldehyde
(c) Ethylidene chloride (d) Trichloro
acetaldehyde (b) Acetone (d) Benzaldehyde

62. Grignard's reagent reacts with ethanal 69. Which does not react with Fehling solution
(acetaldehyde) and propanone to give (a) Acetaldehyde (b) Benzaldehyde
(a) Higher aldehydes with ethanal and higher (c) Glucose (d) Formic acid
ketones with propanone
(b) Primary alcohols with ethanal and secondary 70. Schiff's reagent gives pink colour with
alcohols with propanone (a) Aldehydes (b) Ethers
(c) Ethers with ethanal and alcohols with (c) Ketones (d) Carboxylic acid
propanone
(d) Secondary alcohols with ethanal and tertiary 71. Which one of the following is reduced with zinc and
alcohols with propanone hydrochloric acid to give the corresponding
hydrocarbon
(a) Acetamide (b) Acetic acid
63. Benzaldehyde reacts with ammonia to form
(a) Benzaldehyde ammonia (c) Ethyl acetate (d) Butan–2–one
(b) Urotropine
72. Acetone reacts with iodine to form iodoform in the
(c) Hydrobenzamide
presence of
(d) Aniline CaCO 3
(a) (b) NaOH
MgCO 3
64. Fehling solution is (c) KOH (d)
(a) Ammoniacal cuprous chloride solution
(b) Acidified copper sulphate solution 73. Which of the following aldehydes give red
precipitate with Fehling solution ?
(c) Copper sulphate and sodium hydroxide +
(a) Benzaldehyde (b) Salicylaldehyde
Rochelle salt
(c) Acetaldehyde (d) None of these
(d) None of these

74. The IUPAC name for the following compound is

65. Which of the following on reaction with conc.
NaOH gives an alcohol
(a) Methanal (b) Ethanal
(c) Propanal (d) Butanal

66. Which one of the following on oxidation will not (a) 6-formyl-2-methyl-hex-3-enoic acid
give a carboxylic acid with the same number of (b) 2 , 5 -dimethyl-6 -carboxy-hex-3-enal
carbon atoms (c) 2 , 5- dimethyl -5- carboxy-hex -3- enal
CH 3 COCH 3 CCl 3 CH 2 CHO
(a) (b) (d) 2 , 5-dimethyl-6 -oxo-hex-3-enoic acid
CH 3 CH 2 CH 2 OH CH 3 CH 2 CHO
(c) (d)
75. Using the provided information in the following
67. The reagent with which both aldehyde and acetone paper chromatogram:
react easily is
(a) Fehling's reagent (b) Grignard reagent
(c) Schiff's reagent (d) Tollen's reagent

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 PINNAACLE CLASSES
+

(b) CH 3 −C H −CH 3 − 8 hyperconjugating

structures
+

(c) CH 3 −C H 2 - 3 hyperconjugating structures

+

(d) C H 3 - No hyperconjugating structures

Fig: Paper chromatography for compounds A
and B. 80. The increasing order of electron donating inductive
effect of alkyl group is.
The calculated R f value of A ____ ×10−1
(a)
−H <−CH 3 <−C 2 H 5 <−C3 H 7
76. Which of the following is 'a' FALSE statement?
(b)
−H >−CH 3 >−C 2 H 5 >−C3 H 7
(a) Carius tube used in the estimation of
(c)
−H <−C 2 H 5 <−CH 3 <−C3 H 7
sulphur in an organic compound
(b) Kjedahl's method is used for the estimation
−H >−C 2 H 5 >−CH 3 >−C3 H 7
(d)
of nitrogen in an organic compound
(c) Phosphoric acid produced on oxidation of
81. Answer the following questions based on the
phosphorus present in an organic compound is given paragraph.
precipitated as Mg 2 P2 O7by adding magnesia mixture Stability of carbocation, alkyl free radical and
(d) Carius method is used for the estimation of alkene can be explained on the basis of
nitrogen in an organic compound hyperconjugation. In all these cases, there is
presence of hydrogen atom at the adjacent carbon
77. The IUPAC name of the compound having formula 2
CH 3 atom of sp hybridised carbon atom. Thotal
| number of hyperconjugation structures depends
H 3 C−C−CH =CH 2 upon the number of hydrogen atoms present at
| 2
CH 3 adjacent carbon atom of sp C – atom. More the
(a) 3,3,3 – trimethylprop – 1 – ene hyperconjugating structures, more is the stability of
(b) 1,1,1- trimethylprop – 2 – ene the ion.
(c) 3,3 – dimethylbut – 1 – ene (i) Hyperconjugation is not possible in.
(d) 2,2 dimethylbut – 3 – ene.
(a)
CH 3 −CH=CH 2 (b)
CH 2 =CH 2
CH 3 −C =C −CH 3
78. Hyperconjugation is. | |
(a) σ −π conjugation.
(d) CH 3 CH 3
(b) Noticed due to delocalization of σ and π
bonds. (c)
(c) No bond resonance.
(d) All the above. (ii) Decreasing order of stability of following
alkenes is.
79. The number of hyperconjugating structures shown (i)
CH 3 −CH=CH 2
by the carbocations are given below. Which one is CH 3 −CH =CH −CH 3
not correctly matched? (ii)
+ CH 3 −C =CH −CH 3
CH 3 −C −CH 3 |
|
(iii) CH 3
(a) CH 3 - 9 hyperconjugating structures

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 PINNAACLE CLASSES
CH 3 CH 3
| |
87. Which of the following alkenes will show maximum
(iv)CH 3 −C == C −CH 3 number of hyperconjugation forms ?
(a) (i) > (ii) > (iii) > (iv) (b) (iv) > (iii) > (ii) > (i)
(c) (iii) > (ii) > (i) > (iv) (d) (ii) > (iii) > (iv) > (i) (a) CH2 = CH2 (b) CH3–CH=CH2

82. Select the correct statement about Inductive

(c) CH3–CH2–CH=CH2 (d)
effect :

(a) Inductive effect transfer electrons from one 88. Which of the following cannot exhibit
carbon atom to another. hyperconjugation ?
(b) Inductive effect is the polarisation of  bond
electrons.
(c) Net charge develops in the molecule by (a) CH3 (b)
inductive effect.
(c) CH3CH = CH2 (d)
(d) Inductive effect is distance independent.

83. Decreasing –I effect of given groups is : 89. The C–C bond length in propene is little shorter
(1.49 Å) than the C–C bond length (1.54 Å) in
(i) –CN (ii) –NO2 ethane. This is due to
(iii) –NH2 (iv) –Cl
(a) + effect of CH3 (b) Mesomeric effect
(a) iii > ii > i > iv (b) ii > iii > iv > i
(c) Resonance effect (d) Hyperconjugation
(c) iii > ii > iv > i (d) ii > i > iv > iii
effect

84. Which of the following is not acceptable

90. Among the following alkenes the order of
resonating structure of Buta-1, 2, 3-triene.
decreasing stability is :

(a) (I) 1-Butene (II) Cis-2-butene (III) Trans-2-

(b) CH 2 = C = C = CH 2 butene
(a) II > I > III (b) III > I > II
(c) (c) I > II > III (d) III > II > I

(d)

85. Which of the following group show –m and –I effect

?

(a) –NO2 (b) –NH2

(c) –OH (d) –F

86. Arrange the following groups in order of decreasing

–m effect.

(i) NO2 (ii) COOH (iii) CN

(iv) CHO
(a) i > iii > ii > iv (b) i > ii > iii > iv
(c) i > iii > iv > ii (d) iv > iii > ii > i
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