N E E T EXAMINATIONS

STD : 11th DATE : 23/11/24 MARKS : 180

SUB : CHEMISTRY TIME : 1 Hour
HYDROCARBONS (ALKANE AND ALKENE) 63. A hydrocarbon with formula C8H18 gives one
SECTION A monochloro derivative. The hydrocarbon is
51. Wurtz reaction using bromoethane yields: (a) n – Octane (b) 2 – Methylheptane
(a) 2 – bromobutane (b) n – butane (c) 2, 2, 4 – trimethylpentane
(c) Isobutene (d) Ethane (d) 2, 2, 3, 3 – tetramethylbutane
52. C2H5I + C5H11I + 2 Na Ether → C2H5 – C5H11 + 2 NaI 64. For the alkane C4H10 which of the following is not
(a) Hofmann’s reaction (b) Dow’s reaction correct structure of normal isomer?
(c) Wurtz synthesis (a) CH3 – CH2 – CH2 – CH3
(d) Reimer – Tiemann’s reaction (b) CH3 – CH2 – CH2
53. The number of possible isomers of alkane with CH3
the formula C6H14 is: CH3
(a) 2 (b) 3 (c) 4 (d) 5 (c) CH2 – CH2 – CH3
54. In the complete combustion of CnH2n+2, the (d) CH3 – CH – CH3
number of oxygen moles required is: CH3
𝑛
(a) ( 2 )O2 (b) (
𝑛+1
)O2 65. Which of the following is not another
2
3𝑛+1 𝑛+2 representation of isopentane?
(c) ( )O2 (d) ( )O2 H
2 2
55. Butene – 1 may be converted to butane by the (a) CH3 – CH2 – C – CH3 (b)
reaction with: CH3
(a) Zn – Hg (b) Pd – H2 (c) Zn – HCl (d) Sn – HCl (c) CH3 – CH(CH3)CH2 – CH2CH3
56. Conjugated double bonds are present in H
(a) Propylene (b) Isobutylene (d) H – C – CH3
(c) Butylene (d) 1, 3 – butadiene H3C – C – CH3
57. The formation of butane on heating C2H5I with Na H
in presence of ether is contaminated with 66. Percentage of hydrogen is maximum in
impurities of: (a) C2H2 (b) C2H4 (c) C2H6 (d) CH4
(a) C2H4 (b) C3H6 (c) CH4 (d) None of these 67. A tertiary carbon is bonded directly to
58. Iodination of alkane is made in presence of: (a) 2 Hydrogens (b) 3 Carbons
(a) KMnO4 (b) HgO or HIO3 (c) 2 Carbons (d) 4 Carbons
(c) K2Cr2O7 (d) None of these 68. How many isomers are possible for pentane?
59. In alkanes, the bond angle is (a) 2 (b) 3 (c) 4 (d) 5
(a) 109.5o (b) 109o (c) 120o (d) 180o 69. In the following structures which two forms are
60. Petroleum is formed by chemical changes in staggered conformation of ethane?
(a) inorganic matter
(b) vegetable matter only
(c) animal matter only
(d) both vegetable and animal matter
61. Paraffin wax is
(a) Ester (b) Alcohol
(c) Unsaturated hydrocarbons
(d) Saturated hydrocarbons
62. Which of the following statements is false about
propane?
(a) All bond angles are 109.5°
(b) Each carbon is sp3 hybridised
(c) The compound is combustible
(d) The compound undergoes polymerisation to
give polypropylene

(a) 1 and 4 (b) 2 and 3 (c) 1 and 2 (d) 1 and 3

70. Which of the following is a correct name 80. Domestic cooking gas consists of mostly
according to the IUPAC rules? (a) Methane and ethane
(a) 2 – Methylcyclohexane (b) Liquified butane and iso-butane
(b) 2 – Ethyl – 2 – methylpentane (c) Ethylene and carbon monoxide
(c) 3, 4 – Dimethylpentane (d) Hydrogen and acetylene
(d) 3 – Ethyl – 2 – methylpentane 81. The compound which has one isopropyl group is
71. Which molecular formula indicates 2, 2, 4 – (a) 2, 2, 3, 3 – tetramethylpentane
trimethylhexane? (b) 2, 2 – dimethylpentane
(a) C9H20 (b) C9H18 (c) C8H18 (d) C8H16 (c) 2, 2, 3 – trimethylpentane
72. Wurtz reaction is used to prepare (d) 2 – methylpentane
(a) Methane only (b) Symmetrical alkanes 82. Both methane and ethane may be obtained by a
(c) Unsymmetrical alkanes (d) All type of alkanes suitable one step reaction from
73. How many monochlorinated isomers would result (a) CH3I (b) C2H5I (c) CH3OH (d) C2H2OH
from the reaction of chlorine with n-butane in the 83. Grignard reagent gives alkane with
presence of UV light? (a) H2O (b) C2H5OH (c) C2H5NH2 (d) All of these
(a) 2 (b) 4 (c) 6 (d) 8 84. Which of the following statement is correct about
74. The combustion of one mole of propane, C3H8, alkanes?
produces how many moles of H2O? (a) Alkanes react with acids or bases in normal
(a) 2 (b) 3 (c) 4 (d) 5 conditions
75. The reaction conditions leading to best yields of (b) Alkanes react with oxidising or reducing
C2H5CI are temperature in normal conditions
(a) C2H6 Excess + Cl2 light (c) Alkanes are inert compounds
uv (d) Alkanes are unsaturated compounds
(b) C2H6 + Cl2 room temp. 85. How many primary and secondary carbon atoms
dark are present in neopentane respectively?
(c) C2H6 + Cl2 Excess light (a) 4, 1 (b) 4, 0 (c) 0, 4 (d) 4, 4
uv SECTION B
(d) C2H6 + Cl2 light ATTEMPT ANY 10
uv 86. The final product of complete oxidation of alkane
76. Complete the following reaction: is
C6H14 Cr2O3 + 773 K ? (a) Acid (b) Aldehyde (c) Alcohol
10 to 20 atm. (d) Water and carbon dioxide
87. Which of the following molecular formulae will
(a) + H2 (b) + 4 H2 correspond to an alkene with two double bonds?
(a) C4H10 (b) C2H12 (c) C6H10 (d) C8H16
88. The compound having only primary hydrogen
(c) C5H10 + CH4 (d) C4H8 + C2H6 atom is
77. The following reaction is an example of (a) Butane (b) Iso – butylene
C3H8 + Cl2 → C3H6Cl2 + 2 HCl (c) Cyclohexane (d) 2, 2 – dimethyl butene
(a) an addition reaction 89. How many  (sigma) bonds are there in
(b) a substitution reaction CH2 = CH – CH = CH2?
(c) an oxidation reaction (a) 3 (b) 6 (c) 9 (d) 12
(d) halogenation reaction 90. Ethene contain how many covalent bonds?
78. In paraffins the order of ease of substitution is (a) 6 (b) 5 (c) 4 (d) 2
(a) Tertiary hydrogen > Secondary > Primary 91. 3 – Methylpenta – 1, 3 – diene is
(b) Tertiary hydrogen > Primary> Secondary (a) CH2 = CH(CH2)2 CH3
(c) Secondary hydrogen >Tertiary > Primary (b) CH2 = CHCH(CH3) CH2CH3
(d) None (c) CH3CH = C(CH3) CH2 = CH2
79. Petroleum consists of (d) CH3 – CH = CH(CH3)2
(a) Aliphatic hydrocarbons (b) Aliphatic alcohols 92. Bond angle in alkenes is equal to
(c) Aromatic derivatives (d) None of these (a) 120o (b) 109o28’ (c) 180o (d) 60o
93. Which of the following compounds will show
geometrical isomerism?
(a) Propene (b) 2 – Butene
(c) Propyne (d) 2 – Butyne
94. The maximum number of isomers for an alkene
with molecular formula C4H8 is
(a) 2 (b) 3 (c) 4 (d) 5
95. Geometrical isomerism in alkene is due to
(a) restricted rotation about double bond
(b) change in number of carbon atom
(c) different type of groups
(d) planner structure of molecule
96. Which of the following alkene do not show
geometrical isomerism?
(a) CH3CH = CHCH3 (c) C2H5CH = CHCH3
(c) C2H5CH = CHC2H5 (d) C2H5CH2CH2CH = CH2
97. Hex – 2 – ene and 2 – methylpent – 2 – ene exhibit
(a) Chain isomerism (b) Position isomerism
(c) Geometrical isomerism (d) Optical isomerism
98. How many geometrical isomers are possible of
Hex – 3 – ene?
(a) 1 (b) 2 (c) 3 (d) 4
99. The IUPAC name of the compound
CH2CH – CH(CH3)2 is
(a) 1, 1 – Dimethyl – 2 – propene
(b) 3 – Methyl – 1 – butene
(c) 2 – Vinyl propane
(d) 1 – Isopropyl ethylene
100. The structure of the compound 2, 3, 3 –
trimethylocta – 1, 4, 6 – triene is
CH3
(a) H2C = CH – HC = CH – C – C = CH2
CH3CH3
CH3
(b) H3C – HC = CH – CH = CH – C – HC – CH2
CH3CH3
CH3
(c) H2C = CH – CH2 – HC – C – C = C – CH3
CH3CH3CH3
CH3 CH3
(d) H3C – CH = C = CH – C – CH2 – C = CH2
CH3