NEP Syllabus-2023-14-02-2024

SYLLABUS FOR U.G.
[2024]
NEP- Course Structure (NEP-2020)
SEM Major (Core Discipline) DSE GE/IDM/DSM SEC
I CC-1, Inorganic Paper -1, Gr. A SEC-1 (Th)
II CC-2, Organic Paper -1, Gr. B SEC-2 (Pr)
III CC-3, Physical Paper -2, Gr. A SEC-3 (Th)

CC-4, Organic
IV CC-5, Inorganic Paper -2, Gr. B SEC-4 (Pr)
CC-6, Physical
CC-7, Organic
V CC-8, Inorganic DSE-1 Paper -3, Gr. A
CC-9, Physical
CC-10, Organic
CC-11, Inorganic
VI CC-12, Inorganic DSE-2 Paper -3, Gr. B
CC-13, Physical
CC-14, Organic
VII CC-15, Organic DSE-3, DSM-A,
CC-16, Inorganic Physical Interdisciplinary
DSE-4,
Organic
VIII CC-17, Inorganic DSM-B, Physical
Total
Organic Papers: 07; Inorganic Papers 07; Physical papers; 06, DSE; 02, DSM-
A(Interdisciplinary); 01, SEC; 04, IDM, 06
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Semester I INORGANIC: Credit 03
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Course: CC1 (TH)
Total Lecture 40
Course Objective: Learning the atomic structure, shapes of orbital, various Principles regarding orbital
energy, periodicity of s, p, d, f block elements, ionic bonding, Born-Haber cycle, chemical bonding,
Oxidation–Reduction reaction and Redox equation.
CC1.1 Atomic Structure:
Bohr’s theory and its limitations, Atomic spectrum of hydrogen atom. Wave mechanics: de Broglie
equation, Heisenberg’s Uncertainty Principle and its significance, Schrödinger’s wave equation
(equation only)., significance of ψ and . Pauli’s Exclusion Principle, Hund’s rule of maximum
multiplicity, Exchange energy, Aufbau’s principle and its limitations.
(10 Lectures)
CC1.2 Periodicity of Elements:
The long form of periodic table detailed discussion of the following properties of the elements.
(a) Shielding or screening effect and Slater rules,
(b) Effective nuclear charge,
(c) Covalent radii
(d) Atomic radii and Ionic radii
(e) Ionization enthalpy
(f) Electron Affinity.
(g) Electronegativity
(10 Lectures)
CC1.3 Chemical Bonding:
T1.3.1 Ionic bond: Radius ratio rule and its limitations. Born-Landé equation (equation only). Lattice
energy, Born-Haber cycle and its application, Solvation energy, polarizing power and polarizability:
Fagan’s rules and consequences of polarization.
(10 Lectures)
CC1.4 Oxidation-Reduction:
Elementary idea on standard redox potentials with sign conventions, Nernst equation (without derivation)
and Feasibility of a redox titration. Formal potential: Influence of complex formation, precipitation and
change of pH on redox potentials. Redox potential at the equivalence point, redox indicators. Redox potential
diagram (Latimer and Frost diagrams) of common elements and their applications.
(10 Lectures)
Reference Books:
 Lee, J.D. Concise Inorganic ChemistryELBS,1991.
 Douglas, B. E. and McDaniel, D.H. Concepts &Models of Inorganic Chemistry Oxford, 1970
 Atkins, P.W.& Paula, J. Physical Chemistry,10thEd., Oxford University Press,2014.

 Day, M.C. and Selbin, J. Theoretical Inorganic Chemistry, ACSPublications,1962.
 Rodger, G.E. Inorganic and Solid-State Chemistry, Cengage Learning India Edition, 2002.
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Semester I INORGANIC LAB: Credit 01
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Course: CC1 (Pr)
Lecture 15
Course Objective: Learn about Preparation of solution for Quantitative analysis, Redox Titrations and
Oxidation-Reduction Titrations.
1. Oxidation-Reduction Titrimetry
i) Preliminary idea of Standard solutions, Redox potential and Nernst Equation.
ii) Elementary idea of Formal potential and Redox Indicators.
iii) Standardization of KMnO4 solution by standard Oxalic acid.
iv) Estimation of Fe(II) and oxalic acid using standardized KMnO4 solution.
v) Estimation of Fe(II) with standard K2Cr2O7 solution..
Reference text:
 Nad, A.K., Mahapatra, B., Ghoshal, A.; An advanced course in practical chemistry, 3rd Ed. New
central book agency (P) Ltd (2007).
 Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis 6thEd., Pearson, 2009.

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Semester I Subject -A, Paper 1
Inter Disciplinary Minor (GE, Theory): Credit 03
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Total Lecture 40
Course Objectives: To learn about different thermodynamic laws, equilibrium and their relation with
energy. Fundamentals of Organic Chemistry and stereochemistry together with aliphatic hydrocarbons also
are learned. Knowledge about the atomic structure and chemical periodicity of the elements are also being
gained.
GEA1.1 Chemical Energetics

Review of the Laws of Thermodynamics. Work calculation for reversible, irreversible, isothermal and
adiabatic process, Concept of Internal energy, Enthalpy, Entropy and free energy.
Important principles and definitions of thermochemistry. Concept of standard state and standard enthalpies
of formations, enthalpies of solution, dilution, neutralisation.
(6 Lectures)
GEA1.2 Chemical Equilibrium
Free energy change in a chemical reaction (ΔG and ΔGo). Le Chatelier’s principle. Relationships between
Kp, Kc and Kx for reactions involving ideal gases.
(4 Lectures)
GEA1.3 Solutions
Thermodynamics of ideal solutions: Ideal solutions and Raoult’s law, deviations from Raoult’s law–
non-ideal solutions. Vapour pressure-composition curves of ideal and non-ideal solutions.
(4 Lectures)
GEA1.4 Fundamentals of Organic Chemistry
Inductive Effect, Electromeric Effect, Resonance and Hyperconjugation. Cleavage of Bonds:
Homolysis and Heterolysis, nucleophiles and electrophiles. Reactive Intermediates: Carbocations,
Carbanions and free radicals, dipole moment, strength of organic acids and bases: Comparative study
with emphasis on factors affecting pK values.
(6 Lectures)
GEA1.5 Stereochemistry
Conformations with respect to ethane, butane and cyclohexane. Interconversion of Wedge Formula,
Newmann, Sawhorse and Fischer representations. Concept of chirality (upto two carbon atoms).
Configuration: Geometrical and Optical isomerism; Enantiomerism, Diastereomerism and Meso
compounds). Threo and erythro; D and L; cis – trans nomenclature; CIP Rules: R /S (for upto 2 chiral
carbon atoms) and E/Z Nomenclature (for uptotwoC=Csystems).
(4 Lectures)
GEA1.6 Aliphatic Hydrocarbons
Alkanes: Wurtz reaction, Kolbe’s synthesis, from Grignard reagent.
Alkenes: (Upto 5 Carbons) Preparation: Elimination reactions: Dehydration of alkenes and
dehydrohalogenation of alkyl halides (Saytzeff’s rule); cis alkenes (Partial catalytic hydrogenation)
and trans alkenes (Birch reduction). Reactions: cis-addition (alk. KMnO4) and trans-addition
(bromine), Addition of HX (Markownikoff’s and anti-Markownikoff’s addition), Hydration,
Ozonolysis.
(4 Lectures)
GEA1.7 Atomic Structure
Review of Bohr’s theory and its limitations, dual behaviour of matter and radiation, de Broglie’s
relation, Rules for filling electrons in various orbitals, Heisenberg Uncertainty principle, Hydrogen
atom spectra. Shapes of s, p and d atomic orbitals, Aufbau rule, Pauling Exclusion Principle, Hund’s
rule of spin multiplicity.
(6 Lectures)
GEA1.8 Periodicity and s- and p-block elements
Periodicity in s- and p-block elements with respect to electronic configuration, atomic and ionic size,
ionization enthalpy, electron gain enthalpy, electronegativity (Pauling scale).
Oxidation states of s- and p-block elements, inert-pair effect, diagonal relationships and anomalous
behavior of first member of each group.
(6 Lectures)
Reference Books:
 Lee, J. D., Concise Inorganic Chemistry, 5th Ed., Wiley India (2008).
 Housecroft, C. E; Sharpe, A. G., Inorganic Chemistry, 5th Ed., Pearson Education (2018).
 Atkins, P.; Overton, T.; Rouke, J.; Weller, M.; Armstrong, F.; Hagerman, M., Shriver Atkins’s
Inorganic Chemistry, 6th Ed., Oxford University Press India (2015).
 Miessler, G.; Tarr, D. A., Inorganic Chemistry, 3rd Ed., Pearson Education India (2008).
 Huheey, J. E.; Keiter, E. A.; Keiter, R. L.; Medhi, O. K., Inorganic Chemistry: Principles of
Structures and Reactivity, 4th Ed., Pearson Education India (2006).
 Cotton, F. A.; Wilkinson, G.; Gaus, P. L., Basic Inorganic Chemistry, 3rd Ed., Wiley India
(2007).
 Puri, B. R.; Sharma, L. R.; Kalia, K. C., Principles of Inorganic Chemistry, 33rd Ed., Vishal
Publishing (2017).
 Morrison, R. N. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd.
(Pearson Education).
 Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd. (Pearson
Education).
 Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural
Products), Dorling Kindersley (India) Pvt. Ltd. (Pearson Education).
 Kalsi, P. S. Stereochemistry Conformation and Mechanism; New Age International, 2005.
 Nasipuri, D. Stereochemistry of organic compounds: Principles and applications. New age
international (P) limited.
 Bahl, B. S.; Bahl, A., A Textbook of Organic Chemistry, 22nd Ed., S. Chand and Company
(2016).
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Semester I Subject -A, Paper 1
Inter Disciplinary Minor (GE, Pr): Credit01
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Lectures; 15
Course Objectives: Learning about the standardization of secondary standard solutions, Redox and Acid-
Base Titrations
1. Volumetric titration of (a) Strong Acid vs Strong Base (b) Weak acid vs Strong Base
2. Standardization of Oxalic acid by KMnO4
3. Estimation of Mohr salt by standard K2Cr2O7 and KMnO4 Solutions
4. Determination of Na2CO3 and NaHCO3 in a mixture with standard HCl solution.
Reference Books:
 A.I. Vogel, Qualitative Inorganic Analysis, Prentice Hall, 7th Edn.
 A.I. Vogel, Quantitative Chemical Analysis, Prentice Hall, 6th Edn.
 B.D. Khosla, Senior Practical Physical Chemistry, R. Chand & Co.
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Semester I SEC I (Theory) Credit-03
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Total Lecture 40
CHEMISTRY OF COSMETICS & PERFUMERY PRODUCTS

Course Objective: Learning the synthesis and uses of various cosmetic and perfumery products.
SC1.1 A general study including preparation and uses of the following: Hair dye, shampoo, suntan
lotions, lipsticks, talcum powder, nails enamel, creams (cold, vanishing and shaving creams), and
artificial flavours.
(25 Lectures)
SC1.2 Essential oils and their importance in cosmetic industries with reference to Eugenol, Geraniol,
sandalwood oil, eucalyptus, roseoil,2-phenylethyl alcohol, Jasmone, Civetone, Muscone.
(15 Lectures)
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Semester II ORGANIC: Credit 03
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Course: CC2 (TH)
Total Lecture 40
Course Objective: Understanding the structures, bonding, stability and physical properties of organic
molecule and intermediates. Concept of M.O., aromaticity, and electron moving arrows to describe the
reaction mechanism. Learning the three-dimensional structure, chirality, measurement of optical activity and
conformation of organic acyclic molecules.
CC2.1 Bonding and physical properties

Valence Bond Theory: Concept of hybridisation, shapes of molecules, resonance (including
hyperconjugation); calculation of formal charges and double bond equivalent (DBE)/Index of Hydrogen
deficiency (IHD); orbital pictures of bonding (sp3, sp2, sp: C-C, C-N & C-0 systems and s-cis and s-trans
geometry for suitable cases).
Electronic displacements: Inductive effect, field effect, mesomeric effect, resonance energy; bond
polarization and bond polarizability; electromeric effect; steric effect, steric inhibition of resonance.
MO theory: Qualitative idea about molecular orbitals, bonding and antibonding interactions, idea about σ, σ
*, ᴨ, ᴨ*, n- MOs; basic idea about Frontier MOs (FMO); concept of HOMO, LUMO and SOMO;
interpretation of chemical reactivity in terms of FMO interactions; sketch and energy levels of n MOs of i)
acyclic p orbital system (C=C, conjugated diene, triene, allyl and pentadienyl systems) ii) cyclic p orbital
system (neutral systems: [4], [6]-annulenes; charged systems: 3-,4-,5-membered ring systems); Huckel's
rules for aromaticity up to [10]-annulene (including mononuclear heterocyclic compounds up to 6-membered
ring); concept of antiaromaticity and non-aromatic molecules.
Physical properties: Influence of hybridization on bond properties: bond dissociation energy (BDE) and
bond energy; bond distances, bond angles; concept of bond angle strain (Baeyer's strain theory); melting
point/boiling point and solubility of common organic compounds in terms of covalent & non-covalent
intermolecular forces; polarity of molecules and dipole, moments; relative stabilities of isomeric
hydrocarbons in terms of heat of hydrogenation, heat of combustion and heat of formation.
Concept of organic acids and bases: Effect of structure, substituent and solvent on acidity and basicity;
proton sponge; gas-phase acidity and basicity; comparison between nucleophlicity and basicity; HSAB
principle; application of thermodynamic principles in acid-base equilibria.
Tautomerism: Prototropy (keto-enol, nitro - aci-nitro, nitroso-oximino, diazo-amino and enamine-imine
systems); valence tautomerism and ring-chain tautomerism; composition of the equilibrium in different
systems (simple carbonyl; 1,2- and 1,3-dicarbonyI systems, phenols and related systems), factors affecting
keto-enol tautomerism; application of thermodynamic principles in tautomeric equilibria.
(15 Lectures)
CC2.2 Reaction mechanism
Mechanistic classification: Ionic, radical and pericylic (definition and example); reaction type: addition,
elimination and substitution reactions (definition and example); nature of bond cleavage and bond formation:
homolytic and heterolytic bond fission, homogenic and heterogenic
Bond formation; curly arrow rules in representation of mechanistic steps; reagent type: electrophiles and
nucleophiles (elementary idea); electrophilicity and nucleophilicity in terms of FMO approach.
Reactive intermediates: Carbocations (carbenium and carbonium ions), carbanions, carbon radicals,
carbenes: generation and stability, structure using orbital picture and electrophilic/nucleophilic behavior of
reactive intermediates (elementary idea).
Reaction thermodynamics: Free energy and equilibrium, enthalpy and entropy factor, calculation of
enthalpy change via BDE, intermolecular & intramolecular reactions.
Reaction kinetics: Rate constant and free energy of activation; concept of order and molecularity; free
energy profiles for one-step, two-step and three-step reactions; catalyzed reactions: electrophilic and
nucleophilic catalysis; kinetic control and thermodynamic control of reactions; isotope effect: primary and
secondary kinetic isotopic effect (kH/kD); principle of microscopic reversibility; Hammond's postulate.
(10 Lectures)
CC2.3 Stereochemistry - I
Bonding & geometries of carbon compounds and representation of molecules: Tetrahedral nature of
carbon and concept of asymmetry; Fischer, sawhorse, flying-wedge and Newman projection formulae and
their inter translations.
Concept of chirality and symmetry: symmetry elements and point groups (Cv, Cnh, Cnv, Cn, Dh, Dnh,
Dnd, Dn, Sn (Cs, Ci); molecular chirality and centre of chirality; asymmetric and dissymmetric molecules;
enantiomers and diastereomers; concept of epimers; concept of stereogenicity, chirotopicity and
pseudoasymmetry; chiral centres and number of stereoisomerism: systems involving 1/2/3-chiral centre(s)
(AA, AB, ABA and ABC types).
Relative and absolute configuration: D/L and R/S descriptors; erythro/threo and meso nomenclature of
compounds; syn/anti nomenclatures for aldols; E/Z descriptors for C=C, conjugated diene, triene, C=N and
N=N systems; combination of R/S- and E/ Z- isomerisms.
Optical activity of chiral compounds: optical rotation, specific rotation and molar rotation; racemic
compounds, racemisation (through cationic, anionic, radical intermediates and through reversible formation
of stable achiral intermediates); resolution of acids, bases and alcohols via diastereomeric salt formation;
optical purity and enantiomeric excess; invertomerism of chiral trialkylamines.
(10 Lectures)
CC2.4 Stereochemistry - II
Concept of prostereoisomerism: prostereogenic centre; concept of (pro)n-chirality: topicity of ligands and
faces (elementary idea); pro-R/pro-S, pro-E/pro-Z and Re/Si descriptors; pro-r and pro-s descriptors of
ligands on propseudoasymmetric centre.
Conformation: nomenclature, eclipsed, staggered, gauche, syn and anti; dihedral angle, torsion angle;
Klyne-Prelog terminology; P/M descriptors; energy barrier of rotation, concept of torsional and steric strains;
relative stability of conformers on the basis of steric effect, dipole-dipole interaction and H-bonding; butane
gauche interaction; conformational analysis of ethane, propane, n-butane. 2-methylbutane and 2,3-
dimethylbutane; haloalkane, 1,2-dihaloalkanes and l,2-diols(up to four carbons); 1,2-halohydrin;
conformation of conjugated systems (s-cis and s-trans).
(05 Lectures)
Reference Books:
 Morrison, R. N. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd. (Pearson
Education).
Education).
 Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural Products),
Dorling Kindersley (India) Pvt. Ltd. (Pearson Education).
 Eliel, E. L. & Wilen, S. H. Stereochemistry of Organic Compounds; Wiley: London, 1994.
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Semester II ORGANIC PRACTICAL: Credit 01
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Course: CC2 (PR)
Lecture : 15
Course Objective: Knowledge of purification of organic compounds by crystallization and their melting
point checking. Learn about the boiling point determination of any liquid compounds. Learning about the
qualitative analysis of unknown single organic compounds containing mono-functional groups.
1. Checking the calibration of the thermometer

2. Purification of organic compounds by crystallization using the following solvents:
a. Water
b. Alcohol
c. Alcohol-Water
3. Determination of the melting points of above compounds and unknown organic compounds (Kjeldahl
method and electrically heated melting point apparatus)
4. Effect of impurities on the melting point – mixed melting point of two unknown organic compounds
5. Determination of boiling point of liquid compounds. (boiling point lower than and more than 100 °C by
distillation and capillary method)
6. Qualitative analysis of unknown organic compounds containing monofunctional groups (Single
compound detection):
7. (Liquid): Methyl alcohol, Ethyl alcohol, Chloroform, Benzaldehyde, Acetone, Acetaldehyde, Benzyl
alcohol, Formic acid, Acetic acid, Aniline, Dimethyl aniline, Nitrobenzene.
8. (Solid): Oxalic acid, Succinic acid, Citric acid, Tartaric acid, Benzoic acid, Salicylic acid, Resorcinol, β-
napthol, Glucose, Fructose, Urea,
Reference Books
 Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009)
 Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry, 5th Ed.,
Pearson (2012).
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Semester II Subject -B, Paper 1
Inter Disciplinary Minor (GE, Theory), Credit-03
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Total Lecture 40
Course objectives: Learing about chemical energies, equilibrium, dilute solutions, properties of organic
molecules and stereochemistry. Atomic structures and periodic properties of elements are also be learned.
GEB1.1 Chemical Energetics
Review of the Laws of Thermodynamics. Work calculation for reversible, irreversible, isothermal and
adiabatic process, Concept of Internal energy, Enthalpy, Entropy and free energy.
Important principles and definitions of thermochemistry. Concept of standard state and standard enthalpies
of formations, enthalpies of solution, dilution, neutralisation.
(5 Lectures)
GEB1.2 Chemical Equilibrium
Free energy change in a chemical reaction (ΔG and ΔGo). Le Chatelier’s principle. Relationships between
Kp, Kc and Kx for reactions involving ideal gases.
(5 Lectures)
GEB1.3 Solutions
Thermodynamics of ideal solutions: Ideal solutions and Raoult’s law, deviations from Raoult’s law–
non-ideal solutions. Vapour pressure-composition curves of ideal and non-ideal solutions.
(5 Lectures)
GEB1.4 Fundamentals of Organic Chemistry
Inductive Effect, Electromeric Effect, Resonance and Hyperconjugation. Cleavage of Bonds:
Homolysis and Heterolysis, nucleophiles and electrophiles. Reactive Intermediates: Carbocations,
Carbanions and free radicals, dipole moment, strength of organic acids and bases: Comparative study
with emphasis on factors affecting pK values.
(5 Lectures)
GEB1.5 Stereochemistry
Conformations with respect to ethane, butane and cyclohexane. Interconversion of Wedge Formula,
Newmann, Sawhorse and Fischer representations. Concept of chirality (upto two carbon atoms).
Configuration: Geometrical and Optical isomerism; Enantiomerism, Diastereomerism and Meso
compounds). Threo and erythro; D and L; cis – trans nomenclature; CIP Rules: R /S (for upto 2 chiral
carbon atoms) and E/Z Nomenclature (for upto two C=C systems).
(6 Lectures)
GEB1.6 Aliphatic Hydrocarbons
Alkanes: Wurtz reaction, Kolbe’s synthesis, from Grignard reagent.
Alkenes: (Upto 5 Carbons) Preparation: Elimination reactions: Dehydration of alkenes and
dehydrohalogenation of alkyl halides (Saytzeff’s rule); cis alkenes (Partial catalytic hydrogenation)
and trans alkenes (Birch reduction). Reactions: cis-addition (alk. KMnO4) and trans-addition
(bromine), Addition of HX (Markownikoff’s and anti-Markownikoff’s addition), Hydration,
Ozonolysis.
(9Lectures)
GEB1.7 Atomic Structure
Review of Bohr’s theory and its limitations, dual behaviour of matter and radiation, de Broglie’s
relation, Rules for filling electrons in various orbitals, Heisenberg Uncertainty principle, Hydrogen
atom spectra. Shapes of s, p and d atomic orbitals, Aufbau rule, Pauling Exclusion Principle, Hund’s
rule of spin multiplicity.
(5 Lectures)
GEB1.8 Periodicity and s- and p-block elements
Periodicity in s- and p-block elements with respect to electronic configuration, atomic and ionic size,
ionization enthalpy, electron gain enthalpy, electronegativity (Pauling scale).
Oxidation states of s- and p-block elements, inert-pair effect, diagonal relationships and anomalous
behavior of first member of each group.
(5 Lectures)
Reference Books:
(2007).
Education).
 Eliel, E. L. & Wilen, S. H. Stereochemistry of Organic Compounds; Wiley: London, 1994.
 Solomons, T. W. G.; Fryhle, C. B., Organic Chemistry, 11th Ed., Wiley India (2015).
(2016).
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Semester II Subject -B, Paper 1
Inter Disciplinary Minor (GE, Practical), Credit-01
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Lecture; 15
Course Objectives: Learning about the standardization of secondary standard solutions, Redox and Acid-
Base Titrations
1. Volumetric titration of (a) Strong Acid vs Strong Base (b) Weak acid vs Strong Base
2. Standardization of Oxalic acid by KMnO4
3. Estimation of Mohr salt by standard K2Cr2O7 and KMnO4 Solutions
4. Determination of Na2CO3 and NaHCO3 in a mixture with standard HCl solution.
Reference Books:
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Semester II SEC 2 (PRACTICAL), Credit-03
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Total Lecture 15
Course Objective: Learning the synthesis and uses of various cosmetic and perfumery products,
1. Preparation of talcum powder.
2. Preparation of shampoo.
3. Preparation of hair remover.
4. Preparation of face cream.
5. Preparation of nail polish and nail polish remover.
6. Preparation of Lipstick
7. Determination Of Saponification Value of an Oil/Fat
8. Determination Of manganese in Phosphoric Acid by Colorimetric Method
Reference Books:
 Stocchi,E.IndustrialChemistry,Vol-I,EllisHorwoodLtd.UK(1990).
 Jain,P.C. & Jain,M. Engineering Chemistry Dhanpat Rai &Sons, Delhi.
 Sharma, B.K. & Gaur, H. Industrial Chemistry, Goel Publishing House, Meerut (1996).
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Semester III PHYSICAL: Credit 03
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Course: CC3 (TH)
Total Lecture 40
Course Objective: Learning the states of matter, velocity and speed distribution of gas molecule and their
kinetic energy and energy distribution, barometric distribution, collision phenomenon, deviation from ideal
behaviors of real gas, critical parameter, various real gas equation, first law of thermodynamics and its
consequence, surface tension and viscosity of fluid, equilibrium constants and their inter-relation, pH scale,
buffer solution, solubility product.
CC3.1 Gaseous state:

Kinetic molecular model of a gas: postulates and derivation of the kinetic gas equation; collision
frequency; collision diameter; mean free path and viscosity of gases, including their temperature and
pressure dependence, relation between mean free path and coefficient of viscosity, calculation of σ from
η; variation of viscosity with temperature and pressure.
Maxwell distribution and its use in evaluating molecular velocities (average, root mean square and most
probable) and average kinetic energy, law of equipartition of energy, degrees of freedom and molecular
basis of heat capacities.
Behaviour of real gases: Deviations from ideal gas behaviour, compressibility factor, Z, and its
variation with pressure for different gases. Causes of deviation from ideal behaviour. Van der Waals
equation of state, its derivation and application in explaining real gas behaviour, mention of other
equations of state (Berthelot, Dieterici); virial equation of state; van der Waals equation expressed in
virial form. Isotherms of real gases, continuity of states, critical state, relation between critical
constants and van der Waals constants, law of corresponding states.
Intermolecular forces (Debye and London interactions), Lennard-Jones potential – Elementary idea.
(15 Lectures)
CC3.2 Chemical Thermodynamics - I:
Intensive and extensive variables; state and path functions; isolated, closed and open systems; zeroth law
of thermodynamics.
First law: Concept of heat, q, work, w, internal energy, U, and statement of first law; enthalpy, H,
relation between heat capacities, calculations of q, w, U and H for reversible, irreversible and free
expansion of gases (ideal and van der Waals) under isothermal and adiabatic conditions. Joule-Thomson
experiment, Joule-Thomson coefficient; inversion temperature;
Thermochemistry: Heats of reactions: standard states; enthalpy of formation, enthalpy of combustion;
calculation of bond energy and bond dissociation energy from thermochemical data, effect of
temperature (Kirchhoff’s equations) on enthalpy of reactions.
(15 Lectures)
CC3.3 Liquid state:
Qualitative treatment of the structure of the liquid state; physical properties of liquids; vapour pressure,
surface tension and coefficient of viscosity, and their determination. Effect of addition of various
solutes on surface tension and viscosity. Temperature variation of viscosity of liquids and comparison
with that of gases.
(4 Lectures)
CC3.4 Ionic equilibria:
Strong and weak electrolytes, Arrhenius theory of electrolytic dissociation, Ostwald law of dilution,
degree of ionization, factors affecting degree of ionization, ionization constant and ionic product of
water. Ionization of weak acids and bases, pH scale, common ion effect; dissociation constants of
mono and diprotic acids, concept of isoelectric point.
Salt hydrolysis-calculation of hydrolysis constant, degree of hydrolysis and pH for different salts.
Buffer solutions; derivation of Henderson equation and its applications; buffer capacity, buffer range,
buffer action.
Solubility and solubility product of sparingly soluble salts–applications of solubility product principle.
Theory of acid–base indicators; selection of indicators and their limitations. Qualitative treatment of acid
– base titration curves.
(6 Lectures)
Reference Books:
a. Atkins, P. W. & Paula, J. de Atkin’s Physical Chemistry 10thEd., Oxford University
Press (2014).
b. Ball,D.W.Physical Chemistry Thomson Press,India(2007).
c. Castellan, G. W. Physical Chemistry 4thEd. Narosa (2004).
d. Mortimer, R. G. Physical Chemistry 3rdEd. Elsevier: NOIDA, UP (2009).
e. Engel, T. & Reid, P. Physical Chemistry 3rdEd. Pearson (2013).
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Semester III PHYSICAL (PRACTICAL): Credit 01
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Paper CC-3 (PR)
Lecture; 15
Course Objective: Learning the measuring technique of surface tension and viscosity of different fluid,
colorimetry using buffer, dissociation constant of weak acid and base using pH-meter.
1. Determine the strength of unknown solution of acetic acid.
2. Surface tension measurements.

a. Determine the surface tension by drop number method.
b. Study the variation of surface tension of detergent solutions with
concentration.
3. Viscosity measurement using Ostwald’s viscometer.
a. Determination of viscosity of aqueous solutions of (i) ethanol and (ii) sugar at room
temperature.
b. Study the variation of viscosity of sucrose solution with the concentration of solute.
4. pH metry
a. Study the effect on pH of addition of HCl/NaOH to solutions of acetic acid, sodium
acetate and their mixtures.
b. Preparation of buffer solutions of different pH
i. Sodium acetate-acetic acid
ii. Ammonium chloride - ammonium hydroxide
c. pH metric titration of (i) strong acid vs. strong base, (ii) weak acid vs. strong base.
d. Determination of dissociation constant of a weak mono- and dibasic acid.
Any other experiment carried out in the class.
Reference Books
 Khosla, B. D.; Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry, R. Chand &
Co.: New Delhi (2011).
 Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry 8th Ed.;
McGraw-Hill: New York (2003).
 Halpern, A. M. & McBane, G. C. Experimental Physical Chemistry 3rd Ed.; W.H.
Freeman & Co.: New York (2003).
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Semester III ORGANIC: Credit 03
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Course: CC4 (TH)
Total Lecture 40
Course Objective: Understanding the three-dimensional arrangement of different ring systems and
conformational analysis of cyclohexane. Learning basic knowledge about organic reactions, mechanisms
and reaction kinetics involving the preparation, properties and uses of alkenes and alkynes. Mechanistic
understand of the substitution and elimination reactions acyclic and alicyclic system, aromatic substitution.
Gaining basic knowledge about organic nitrogenious compounds.
CC4.1 Stereochemistry – III

Chirality arising out of stereoaxis: stereoisomerism of substituted cumulenes with even and odd number of
double bonds; chiral axis in allenes, spiro compounds, alkylidenecycloalkanes and biphenyls; related
configurational descriptors (R/S) and (P/M); atropisomerism; racemisation of chiral biphenyls; buttressing
effect.
Stereochemistry in alicyclic systems and conformational analysis: Types of cycloalkanes and their relative
stability, Baeyer strain theory, energy diagrams of cyclohexane, Chair, Boat and Twist boat forms; relative
stability with energy diagrams, conformational analysis of mono & di substituted cyclohexanes.
(6 Lectures)
CC4.2 Substitution and Elimination Reaction
Nucleophilic substitution reactions: Substitution at sp3 centre: mechanisms (with evidence), relative rates &
stereochemical features: SN1, SN2, , (allylic rearrangement) and ; effects of solvent, substrate
structure, leaving group and nucleophiles (including ambident nucleophiles, cyanide & nitrite); substitutions
involving NGP; role of crown ethers and phase transfer catalysts; [systems: alkyl halides, allyl halides,
benzyl halides, alcohols, ethers, epoxides],
Elimination reactions: El, E2, ElcB and Ei (pyrolytic syn eliminations); formation of alkenes and alkynes;
mechanisms (with evidence), reactivity, regioselectivity (Saytzeff/Hofmann) and stereoselectivity;
comparison between substitution and elimination; importance of Bredt's rule relating to the formation of
C=C.
Reactions in the cyclohexane system: substitution, elimination, oxidation, reduction, Pinacol-Pinacolone and
Semi Pinacolone rearrangement.
(6 Lectures)
CC4.3 Chemistry of alkane, alkenes and alkynes
Reactions of alkanes: (Free-radical substitution reaction): Halogentaion of alkanes, mechanism (with
evidence) and stereochemical features; reactivity-selectivity principle in the light of Hammond's postulate.
Formation of alkanes by Wurtz reaction, Fittig, Wurtz-Fittig reaction, Corey-House synthesis, using metal
hydride: lithium aluminiumhydide and tributyltin hydride.
Reactions of alkenes: Addition to C=C: mechanism (with evidence wherever applicable), reactivity,
regioselectivity (Markownikoff and anti-Markownikoff additions) and stereoselectivity; reactions:
hydrogenation, halogenations, iodolactonisation, hydrohalogenation, hydration, oxymercuration-
demercuration, hydroboration-oxidation, epoxidation, syn and anti-hydroxylation, ozonolysis, addition of
singlet and triplet carbenes; electrophilic addition to diene (conjugated dienes and allene); radical addition:
HBr addition; mechanism of allylic and benzylic bromination in competition with brominations across C=C;
use of NBS; Birch reduction of benzenoid aromatics; interconversion of E - and Z - alkenes; contra-
thermodynamic isomerization of internal alkenes.
Reactions of alkynes: Addition to C≡C (in comparison to C=C), mechanism, reactivity, regioselectivity
(Markownikoff and anti-Markownikoff addition) and stereoselectivity; reactions: hydrogenation,
halogenations, hydrohalogenation, hydration, oxymercuration- demercuration, hydroboration-oxidation,
dissolving metal reduction of alkynes (Birch); reactions of terminal alkynes by exploring its acidity;
interconversion of terminal and nonterminal alkynes. Rupe Rearrangement.
(12 Lectures)
CC4.4 Aromatic Substitution
Electrophilic aromatic substitution: Mechanisms and evidences in favour of it; orientation, reactivity and
energy diagram of nitration, nitrosation, sulfonation, halogenation, Friedel-Crafts reaction; preparation of
phenolics; Cumene phenol process, halogenated phenols, di and tri-hydric phenols and their reactions, one-
carbon electrophiles (reactions: chloromethylation, Gatterman-Koch, Gatterman, Houben-Hoesch,
Vilsmeier-Haack, Reimer-Tiemann, Kolbe-Schmidt; Etard, Ipso substitituion. Diazocoupling Reaction
Nucleophilic aromatic substitution: Addition-elimination mechanism and evidences in favour of it; SN1
mechanism; cine substitution (benzyne mechanism), structure of benzyne.
Chemistry of polycyclic Aromatic Hydrocarbons:, Naphthalene; Structure, Oxidation and reduction,
Electrophilic substitution on naphthalene and substituted naphthalene. Synthesis (Haworth), Anthracene and
Phenanthrene; Structure and properties, Synthes is of anthracene (By using F/C Acylation, Diels-Alder and
Elbs reactions.) Synthesis of Phenanthrene (Haworth, Pschorr, Bardhan- Sengupta and Bogert-Cook
synthesis) .
(12 Lectures)
CC4.5 Nitrogenous Compounds
Amines (Aliphatic & Aromatic): preparation, separation (Hinsberg's method) and identification of primary,
secondary and tertiary amines; reaction (with mechanism), Gabriel phthalimide synthesis, Eschweiler-Clarke
methylation, Mannich reaction; formation and reactions of phenylenediamines, diazomethane and
diazoacetic ester. Diazotization of the aromatic primary amines.
Nitro compounds (aliphatic and aromatic): Preparation and reaction (with mechanism); reduction under
different conditions; Nef carbonyl synthesis, Henry reaction and conjugate addition of nitroalkane anion.
Alkylnitrile and isonitrile: Preparation and reaction (with mechanism): Thorpe nitrile condensation, von
Richter reaction,
Diazonium salts and their related compounds: Reactions (with mechanism) involving replacement of diazo
group; reactions: Gomberg, Meerwein, Japp-Klingermann Sandmayer, Gatterman, Finkelstein Balz-
Schiemann.
(4 Lectures)
Reference Books:
 Morrison, R. T. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd. (Pearson
Education).
Education).
 Graham Solomons, T.W. Organic Chemistry, John Wiley & Sons, Inc.
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Semester III ORGANIC LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC4 (PR)
Total Lecture 15
Course Objective: Provides training in the detection of special elements (N, S, Cl, Br, I) and qualitative
analysis of unknown organic compounds.
Qualitative detection of organic compounds by using the following techniques:
1. Detection of special elements (N,S,Cl,Br,I)
2. Detection of Non-nitrogenous functional group: Carboxylic acid, Ester, Phenolic-OH, Carbonyl
groups (aldehyde & keto group) and Unsaturation.
3. Nitrogenous: Nitro, Amino, Anilido and Amide groups.
4. Melting point determination of the given compound.
Reference Books
Pearson (2012)
 Ahluwalia, V.K. & Aggarwal, R. Comprehensive Practical Organic Chemistry: Preparation and
Quantitative Analysis, University Press (2000).
 Ahluwalia, V.K. & Dhingra, S. Comprehensive Practical Organic Chemistry: Qualitative
Analysis, University Press (2000).
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Semester III Subject -A, Paper 2
Inter Disciplinary Minor (GE, Theory), Credit03
--------------------------------------------------------------------------------------------------
Total Lecture 40
Course objectives; Idea about electrochemistry, aromatic character of organic compounds.
Preliminary reactions of alcohols, phenols, ethers. Idea about chemical bonding and molecular
structure and inorganic acids and bases together with SHAB principle.
GEA2.1 Electrochemistry
Concept and measurement of EMF of a cell. Standard electrode potential. Electrochemical series.
Nernst equation. Calculation: ΔG, ΔH, ΔS and equilibrium constant from EMF data. Types of
electrodes. Liquid junction potential and salt bridge. pH determination using hydrogen electrode.
Types of Cell and basic principle of Li+ ion and Fuel Cell.
(6 Lectures)
GEA2.2Conductance
Conductivity, equivalent and molar conductivity and their variation with dilution for weak and strong
electrolytes. Kohlrausch law of independent migration of ions, Transference number, Ionic mobility.
Determination of degree of ionization of weak electrolyte, solubility and solubility products of sparingly
soluble salts, ionic product of water, hydrolysis constant of a salt.
(6 Lectures)
GEA2.3Aromatic compounds
Aromaticity; Huckel rules, Reactions: (Case benzene): Electrophilic substitution: nitration,
halogenation and sulphonation. Friedel-Craft’s reaction (alkylation and acylation) (upto 4 carbons on
benzene). Nucleophilic substitution. Diazonium Salts, Diazonium salts: Preparation: from aromatic amines
and its reaction.
(6 Lectures)
GEA2.4 Alcohols, Phenols, Ethers
Preparation and reaction: Preparation of 1о, 2о and 3о alcohols: using Grignard reagent, Ester hydrolysis,
Reduction of aldehydes, ketones, carboxylic acid and esters. Reaction with sodium, HX (Lucas test),
esterification, oxidation (with PCC, alk. KMnO4). Oppeneauer oxidation Diols: oxidation of diols. Pinacol-
Pinacolone rearrangement.
Phenols (Preparation and reaction): Cumene hydroperoxide method, Electrophilic substitution: Nitration,
halogenation and sulphonation. Reimer-Tiemann, Gattermann-Koch Reaction.
Ethers (aliphatic and aromatic): Cleavage of ethers with HI.
Aldehydes and ketones: Reaction with HCN, ROH, NaHSO3, NH2- derivatives. Iodoform test. Aldol
Condensation, Cannizzaro’s reaction, Wittig reaction, Benzoin condensation. Clemensen and Wolff Kishner.
Meerwein-Pondorff Verley reduction.
(8 Lectures)
GEA2.5 Acids and Bases
Brönsted–Lowry concept, conjugate acids and bases, relative strengths of acids and bases, effects of
substituent and solvent, differentiating and levelling solvents. Lewis acid-base concept, classification
of Lewis acids and bases, Lux-Flood concept and solvent system concept. Hard and soft acids and bases
(HSAB concept), applications of HSAB process.
(6 Lectures)
GEA2.6Chemical Bonding and Molecular Structure
Ionic Bonding: lattice energy, solvation energy and their importance in the context of stability and
solubility of ionic compounds. Born-Landé equation, Born-Haber cycle, bond moment, dipole
moment, percentage ionic character.
Covalent bonding: VB Approach: Shapes of inorganic molecules and ions on the basis of VSEPR and
hybridization with suitable examples.
MO Approach: Rules for the LCAO, bonding and antibonding MOs. MO treatment of homonuclear
diatomic molecules (H2, B2, C2, N2 and O2).
(8 Lectures)
Reference Books:
(2007).
Publishing (2017).
Education).
(2016).
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Semester III Subject -A, Paper 2
Inter Disciplinary Minor (GE, Theory), Credit01
--------------------------------------------------------------------------------------------------
Lecture; 15
Course objective: Learning about various titration method
1. Estimation of oxalic acid by titrating with KMnO4.
2. Estimation of Mohr’s salt by titrating with KMnO4.
3. Estimation of Fe (II) ions by titrating it with K2Cr2O7using internal indicator.
4. Estimation of Cu (II) ions iodometrically using Na2S2O3.
Reference Books:
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Semester III SEC 3 (Theory): Credit 03
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Course: SEC 3 (TH)
Total Lecture 40
Course Objective: Learning the synthesis and uses of various drug molecules which is used in the
pharmaceutical industry. Learning about the preparations of industrially important compounds and their uses
in industry.
SC3.1 Drugs & Pharmaceuticals
Drug discovery, design and development; Basic Retrosynthetic approach. Synthesis of the
representative drugs of the following classes: analgesics agents, antipyretic agents, anti-inflammatory
agents (Aspirin, paracetamol, lbuprofen); antibiotics (Chloramphenicol); antibacterial and antifungal
agents (Sulphonamides; Sulphanethoxazol, Sulphacetamide, Trimethoprim); antiviral agents
(Acyclovir), Central Nervous System agents (Phenobarbital, Diazepam), Cardiovascular (Glyceryl
trinitrate), antilaprosy (Dapsone), HIV-AIDS related drugs (AZT-Zidovudine).
(20 Lecture)
SC3.2 Industrial chemistry
Portland Cement; Average Chemical composition, preparation, setting and hardening of the Portland
cement. Fertilizer; Preparation of urea, ammonium sulfate, Fats and oils, Hydrogenation of oil,,
saponification , acid and iodine value. Preparation of glycerine from spent lye. Paints and pigments:
Ultramarine blue, Lithopone, Mercuriochrome. Fuel; Low temperature and high temoerature
carbonization of coal, Flash and fire point.
(20 Lecture)
Reference Books:
 Patrick, G. L. Introduction to Medicinal Chemistry, Oxford University Press, UK, 2013.
 Singh, H. & Kapoor, V.K. Medicinal and Pharmaceutical Chemistry, Vallabh Prakashan,
Pitampura, NewDelhi,2012.
 Foye, W.O., Lemke, T.L. & William, D.A.: Principles of Medicinal Chemistry, 4thed., B.I.
Waverly Pvt. Ltd. New Delhi.
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Semester IV INORGANIC: Credit 03
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Course: CC5 (TH)
Total Lecture 40
Course Objective: Study of general principle of acids and bases, molecular orbital diagrams, various
reactions and compounds of s and p block elements, preparation, property and shapes of noble gases.
CC5.1 Chemical Bonding:

Covalent bond: Lewis’s structure, Valence Bond theory (VBT), Valence shell electron pair repulsion
theory (VSEPR), shapes of simple molecules and ions containing lone pairs and bond pairs of electrons,
multiple bonding (σ and π bond approach) and bond lengths. Bent’s rule, Formal charge, Bond moment
and dipole moment, Percentage of ionic character from dipole moment and electronegativity difference.
Metallic Bond: Qualitative idea of valence bond and band theories. Semiconductors and insulators,
defects in solids.
Weak Chemical Forces: van der Waals forces, ion-dipole forces, dipole-dipole interactions, induced
dipole interactions, Instantaneous dipole-induced dipole interactions. Melting and Boiling point.
(20 Lectures)
CC5.2 Molecular Orbital Theory: Principles of Molecular orbital theory. Molecular orbital diagrams
of Homodiatomic molecules H2, N2, O2, C2, B2, F2 and Hetero diatomic molecules of CO, NO, CN-,
HCl, and their ions. Molecular orbital diagrams of Triatomic BeF2, CO2, H2O (idea of s-p mixing and
orbital interaction to be given).
(10 Lectures)
CC5.3 Acids and Bases:
Brönsted-Lowry concept of acid-base reactions, solvated proton, relative strength of acids, types of
acid-base reactions, Levelling effect of the solvents, Lewis acid-base concept, Classification of Lewis
acids, Hard and Soft Acids and Bases (HSAB) Application of HSAB principle, Symbiosis, Super
Acids.
(10 Lectures)
Reference Books:
 Lee, J.D. Concise Inorganic Chemistry, ELBS, 1991.
 Douglas, B.E; Mc Daniel, D.H. & Alexander, J.J. Concepts & Models of Inorganic Chemistry 3rd
Ed., John Wiley Sons, N.Y. 1994.
 Greenwood, N.N. & Earnshaw. Chemistry of the Elements, Butterworth- Heinemann.
1997.
 Cotton, F.A. & Wilkinson, G. Advanced Inorganic Chemistry, Wiley, VCH, 1999.
 Rodger, G.E. Inorganic and Solid State Chemistry, Cengage Learning India Edition, 2002.
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Semester IV INORGANIC LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC5 (PR)
15 lecturers
Course Objective: Learning of iodimetric titrations and preparation of some inorganic compounds.
1 Iodo/Iodimetric Titrations:
i) Estimation of Cu(II) using Standard K2Cr2O7and sodium thiosulphate solution
(Iodimetrically).
ii) Estimationof calcium.
2 Inorganic compound preparations:
i) Preparation and purification of Cuprous Chloride, Cu2Cl2
ii) Preparation of Manganese (III)phosphate, MnPO4.H2O
Reference Books:
 A.K., Nad, B., Mahapatra, A .Ghoshal,.; An advanced course in practical chemistry, 3rd Ed.
New central book agency (P) Ltd (2007).
 J., Mendham, A. I. Vogel’s Quantitative Chemical Analysis 6thEd., Pearson, 2009.

o
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Semester IV PHYSICAL: Credit 03
--------------------------------------------------------------------------------------------------
Course: CC6 (TH)
Total Lecture 40
Course Objective: Learning basic knowledge of thermodynamics, different type of variables of a
macroscopic system and their inter-relation, 2nd and 3rd laws of thermodynamics and their
consequencestudy of chemical equilibrium and different types of equilibrium constant, , solid states,
type of unit cell, packing efficiency, plane of symmetry of crystal, Bragg’s reflection.
CC6.1 Chemical Thermodynamics - II:

Second Law: Carnot heat engine and Carnot theorem; Concept of entropy; thermodynamic scale
of temperature, statement of the second law of thermodynamics; molecular and statistical
interpretation of entropy. Calculation of entropy change for reversible and irreversible processes
Third Law: Statement of third law, concept of residual entropy, calculation of absolute entropy
of molecules.
Free Energy Functions: Gibbs and Helmholtz energy; variation of S, G, A with T, V, P; Free
energy change and spontaneity. Gibbs-Helmholtz equation; Maxwell relations; thermodynamic
equations of state.
(16 Lectures)
CC6.2 Systems of Variable Composition:
Partial molar quantities, dependence of thermodynamic parameters on composition; Gibbs-
Duhem equation, chemical potential of ideal mixtures, change in thermodynamic functions in
mixing of ideal gases.
(6 Lectures)
CC6.3 Chemical Equilibrium:
Criteria of thermodynamic equilibrium, degree of advancement of reaction, chemical equilibria
in ideal gases, fugacity. Thermodynamic derivation of relation between free energy of reaction
and reaction quotient. Equilibrium constants and their quantitative dependence on temperature,
pressure and concentration. Free energy of mixing and spontaneity; thermodynamic derivation
of relations between the various equilibrium constants Kp, Kc and Kx. Le Chatelier principle;
equilibrium between ideal gases and a pure condensed phase.
(8 Lectures)
CC6.4 Solid state:
Nature of the solid state, law of constancy of interfacial angles, law of rational indices, Miller
indices, elementary ideas of symmetry, symmetry elements and symmetry operations,
qualitative idea of point and space groups, crystal systems and Bravais lattices; X-ray
diffraction, Bragg’s law, a simple account of rotating crystal method and powder pattern
method and their analysis. Defects in crystals, electrical and magnetic properties of solids.
(10 Lectures)
Reference Books
 Peter,A.&Paula,J.de.PhysicalChemistry10thEd.,OxfordUniversityPress(2014).
 Castellan, G. W. Physical Chemistry 4thEd., Narosa(2004).
 Engel, T. & Reid, P. Physical Chemistry 3rdEd., Prentice-Hall(2012).
 McQuarrie,D.A.&Simon,J.D.MolecularThermodynamicsVivaBooksPvt.Ltd.:
NewDelhi(2004).
 Assael,M.J.;Goodwin,A.R.H.;Stamatoudis,M.;Wakeham,W.A.&Will,S.
Commonly Asked Questions in Thermodynamics. CRC Press: NY (2011).
 Levine, I .N. Physical Chemistry 6thEd., Tata Mc Graw Hill (2010).
 Metz,C.R.2000solvedproblemsinchemistry,SchaumSeries(2006).
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Semester IV PHYSICAL: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC6 (PR)
Lecture 15
Course Objective: Learning about the calorimetry, heat capacity, determination of enthalpy of ionization
and heat of neutralization, effect of temperature on solubility product of sparingly soluble salt, calculate
equilibrium constants of chemical reactions. Developed hand on analytical instruments.
1. Thermochemistry
(a) Determination of heat capacity of the calorimeter and enthalpy of neutralization of hydrochloric
acid with sodium hydroxide.
(b) Calculation of the enthalpy of ionization of ethanoic acid.
(c) Determination of heat capacity of the calorimeter and integral enthalpy (endothermic and
exothermic) solution of salts.
(d) Determination of enthalpy of hydration of copper sulphate.
(e) Study of the solubility of benzoic acid in water and determination of ∆H.
2. Chemical Equilibrium
(a) Determination of equilibrium constant for esterification reaction between acetic acid and ethanol.
Reference Books
 Khosla, B. D.; Garg, V. C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand &
Co.: New Delhi(2011).
 Athawale, V. D. & Mathur, P. Experimental Physical Chemistry New Age International:
New Delhi(2001).
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Semester IV ORGANIC: Credit 03
--------------------------------------------------------------------------------------------------
Course: CC7 (TH)
Total Lecture 40
Course Objective: Understanding the concept of carbonyl reactions and their mechanisms, nucleophilic
addition to α,β-unsaturated carbonyl compounds, substitution at sp2 carbon of carbonyl compounds and
reactions of carboxylic acids. Understand the mechanism with evidence and stereochemical features of
different rearrangements and their synthetic utility. Learning basic principles & applications of retrosynthetic
analysis. Understanding the basic concept of asymmetric synthesis.
CC7.1Carbonyl reaction-I
Addition to C=O: Structure, reactivity and preparation of carbonyl compounds; mechanism (with evidence),
reactivity, equilibrium and kinetic control; Burgi-Dunitz trajectory in nucleophilic additions; formation of
hydrates, hemiacetal, acetal, halo hydrins, cyanohydrins and bisulphite adduct; nucleophilic addition-
elimination reactions with alcohols, thiols, dithian and nitrogen- based nucleophiles; imines and enamine
formation, Stork Enamine reaction, Typical reactions: Benzoin condensation, Cannizzaro and Tischenko
reactions, reactions with ylides: Wittig and Corey-Chaykovsky reaction.
Oxidations and reductions: Clemmensen, Wolff-Kishner, Mozingo, Rosenmund LiAIH4, NaBH4, MPV,
Bouveault-Blanc, acyloin condensation; Pinacol formation, oxidation of alcohols with PDC, PCC, Swern;
Oppenauer, MnO2, periodic acid and lead tetraacetate oxidation of 1,2-diols, Tollens, Fehling’s, McMurry
reaction.
(8 Lectures)
CC7.2 Carbonyl reaction-II
Exploitation of acidity of α-H of C=O: Formation of enols and enolates; kinetic and thermodynamic
enolates; reactions (mechanism with evidence): halogenation of carbonyl compounds under acidic and basic
conditions (Haloform reaction), Heil-Volhard-Zelinsky (HVZ.) reaction, nitrosation, SeO2 (Riley) oxidation;
condensations (mechanism with evidence): Aldol, Tollens', Knoevenagel, Claisen-Schmidt, Claisen ester
including Dieckmann, Stobbe; Reformatski, Pechmann Mannich reaction, Perkin reaction, Darzen’s glycidic
ester condensation, alkylation of active methylene compounds; preparation and synthetic applications of
diethyl malonate and ethyl acetoacetate; specific enol equivalents (lithium enolates, enamines, aza-enolates
and silyl enol ethers) in connection with alkylation, acylation and aldol type reaction.
Nucleophilic addition to α,β unsaturated carbonyl system: General principle and mechanism (with evidence);
direct and conjugate addition, addition of enolates (Michael reaction),, Robinson annulation.
Substitution at sp2 carbon (C=O system): mechanism (with evidence): BAC2, AAC2, AAC1, AAL1 (in
connection to acid and ester); acid derivatives: amides, anhydrides & acyl halides (formation and hydrolysis
including comparison).
Reactions of carboxylic acids: Typical reactions of dicarboxylic, hydroxy, halo and unsaturated acids, epoxy
acids, Fischer esterification, decarboxylation of the acids.
(12 Lectures)
CC7.3 Molecular Rearrangement
Rearrangement to electron-deficient carbon: Wagner-Meerwein rearrangement, Pinacol rearrangement,
Dienone-phenol; Wolff rearrangement in Arndt-Eistert synthesis, Benzilbenzilic acid rearrangement,
Demjanov rearrangement, Tiffeneau-Demjanov rearrangement, Baker–Venkataraman rearrangement.
Favorskii rearrangement;
Rearrangement to electron-deficient nitrogen: Rearrangements: Hofmann, Curtius, Lossen, Schmidt and
Beckmann.
Rearrangement to electron-deficient oxygen: Baeyer-Villiger oxidation, Cumene hydroperoxide-phenol
rearrangement and Dakin reaction.
Aromatic rearrangements: Migration from oxygen to ring carbon: Fries rearrangement and Claisen
rearrangement.
Migration from nitrogen to ring carbon: Hofmann-Martius rearrangement, Fischer-Hepp rearrangement, N-
azo to C-azo rearrangement, Bamberger rearrangement, Orton rearrangement and Benzidine rearrangement.
Rearrangement reactions by green approach: Fries rearrangement, Claisen rearrangement, Beckmann
rearrangement, Baeyer-Villiger oxidation.
(12 Lectures)
CC7.4 The Logic of Organic Synthesis
Retrosynthetic analysis: Disconnections; synthons, donor and acceptor synthons; natural reactivity and
umpolung; latent polarity in bifunctional compounds: consonant and dissonant polarity; illogical
electrophiles and nucleophiles; synthetic equivalents; functional group interconversion and addition (FGI and
FGA); C-C disconnections and synthesis: one-group and two-group (1,2- to 1,5-dioxygenated compounds),
reconnection (1,6-dicarbonyl); protection-deprotection strategy (alcohol, amine, carbonyl, acid).
Strategy of ring synthesis: Thermodynamic and kinetic factors; synthesis of large rings, application of high
dilution technique.
Asymmetric synthesis: Stereoselective and stereospecific reactions; diastereoselectivity and
enantioselectivity; enantioselectivity: kinetically controlled MPV reduction; diastereoselectivity: addition of
nucleophiles to C=O adjacent to a stereogenic centre: Cram’s and Felkin-Anh model.
(8 Lectures)
Reference Books:
 Morrison, R. T. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd. (Pearson
Education).
Education).
 Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural Products),
Dorling Kindersley (India) Pvt. Ltd. (Pearson Education).
 Acheson, R.M. Introduction to the Chemistry of Heterocyclic compounds, John Welly & Sons
(1976).
 Kalsi, P. S. Textbook of Organic Chemistry 1st Ed., New Age International (P) Ltd. Pub.
 Clayden, J.; Greeves, N.; Warren, S.; Wothers, P.; Organic Chemistry, Oxford University Press.
 Singh, J.; Ali, S.M. & Singh, J. Natural Product Chemistry, Prajati Parakashan (2010).
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Semester IV ORGANIC LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC7 (PR)
Lectures; 15
Course Objective: To develop the skill in organic preparations using some specific reactions such as
acetylation of amines, benzoylation of amines, oxidation of alcohols, bromination, nitration, selective
reductions, hydrolysis of amides/esters, semicarbazone formation, aldol condensation and benzil-benzilic
acid rearrangement. To expand the skill of student for preparation of organic compounds using green
approach.
Organic preparations:
i) Oxidation of ethanol (Iodoform reaction).

ii) Bromination of the following:
b. Acetanilide using green approach (Bromate-bromide method)
iii) Hydrolysis of amides and esters.
iv) Semicarbazone of any one of the following compounds: acetone, benzaldehyde.
v) S-Benzylisothiouronium salt of one each of water soluble and water insoluble acids (benzoic acid,
oxalic acid, phenyl acetic acid and phthalic acid).
vi) Benzil-Benzilic acid rearrangement.
The above derivatives should be prepared using 0.5-1g of the organic compound. The solid samples must
be collected and may be used for recrystallization, melting point.
Reference Books
Pearson (2012)
 Ahluwalia, V.K. & Aggarwal, R. Comprehensive Practical Organic Chemistry: Preparation and
Quantitative Analysis, University Press (2000).
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Semester IV Subject -B, Paper 2
--------------------------------------------------------------------------------------------------
Total Lecture 40
Course objectives; Idea about electrochemistry, aromatic character of organic compounds.
Preliminary reactions of alcohols, phenols, ethers. Idea about chemical bonding and molecular
structure and inorganic acids and bases together with SHAB principle.
GEB2.1 Electrochemistry
Concept and measurement of EMF of a cell. Standard electrode potential. Electrochemical series.
Nernst equation. Calculation: ΔG, ΔH, ΔS and equilibrium constant from EMF data. Types of
electrodes. Liquid junction potential and salt bridge. pH determination using hydrogen electrode.
Types of Cell and basic principle of Li+ ion and Fuel Cell.
(6 Lectures)
GEB2.2 Conductance
Conductivity, equivalent and molar conductivity and their variation with dilution for weak and strong
electrolytes. Kohlrausch law of independent migration of ions, Transference number, Ionic mobility.
Determination of degree of ionization of weak electrolyte, solubility and solubility products of sparingly
soluble salts, ionic product of water, hydrolysis constant of a salt.
(6 Lectures)
GEB2.3Aromatic compounds
Aromaticity; Huckel rules, Reactions: (Case benzene): Electrophilic substitution: nitration,
halogenation and sulphonation. Friedel-Craft’s reaction (alkylation and acylation) (upto 4 carbons on
benzene). Nucleophilic substitution. Diazonium Salts, Diazonium salts: Preparation: from aromatic amines
and its reaction.
(6 Lectures)
GEB2.4 Alcohols, Phenols, Ethers
Preparation and reaction: Preparation of 1о, 2о and 3о alcohols: using Grignard reagent, Ester hydrolysis,
Reduction of aldehydes, ketones, carboxylic acid and esters. Reaction with sodium, HX (Lucas test),
esterification, oxidation (with PCC, alk. KMnO4). Oppeneauer oxidation Diols: oxidation of diols. Pinacol-
Pinacolone rearrangement.
Phenols (Preparation and reaction): Cumene hydroperoxide method, Electrophilic substitution: Nitration,
halogenation and sulphonation. Reimer-Tiemann, Gattermann-Koch Reaction.
Ethers (aliphatic and aromatic): Cleavage of ethers with HI.
Aldehydes and ketones: Reaction with HCN, ROH, NaHSO3, NH2- derivatives. Iodoform test. Aldol
Condensation, Cannizzaro’s reaction, Wittig reaction, Benzoin condensation. Clemensen and Wolff Kishner.
Meerwein-Pondorff Verley reduction.
(8 Lectures)
GEB2.5 Acids and Bases
Brönsted–Lowry concept, conjugate acids and bases, relative strengths of acids and bases, effects of
substituent and solvent, differentiating and levelling solvents. Lewis acid-base concept, classification
of Lewis acids and bases, Lux-Flood concept and solvent system concept. Hard and soft acids and bases
(HSAB concept), applications of HSAB process.
(6 Lectures)
GEB2.6 Chemical Bonding and Molecular Structure
Ionic Bonding: lattice energy, solvation energy and their importance in the context of stability and
solubility of ionic compounds. Born-Landé equation, Born-Haber cycle, bond moment, dipole
moment, percentage ionic character.
Covalent bonding: VB Approach: Shapes of inorganic molecules and ions on the basis of VSEPR and
hybridization with suitable examples.
MO Approach: Rules for the LCAO, bonding and antibonding MOs. MO treatment of homonuclear
diatomic molecules (H2, B2, C2, N2 and O2).
(8 Lectures)
Reference Books:
(2007).
Publishing (2017).
Education).
(2016)
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Semester IV Subject -B, Paper 2
Inter Disciplinary Minor (GE, Practical): Credit 01
--------------------------------------------------------------------------------------------------
Lectures; 15
Course objective: Understanding quantitative estimations by tritrimatric method
1. Estimation of oxalic acid by titrating with KMnO4.

2. Estimation of Mohr’s salt by titrating with KMnO4.
3. Estimation of Fe (II) ions by titrating it with K2Cr2O7using internal indicator.
4. Estimation of Cu (II) ions iodometrically using Na2S2O3.
Reference Books:
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Semester IV SEC-4 (PRACTICAL): Credit 03
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Course: SEC-4(PR)
Total Lecture 15
Course objective: Learning about the gravimetric estimation method and preparation of antacid and
analgesic.
1. Preparation of Aspirin and its analysis.
2. Preparation of Antacid (magnesium bisilicate, etc)
3. Estimation of Iron in Portland cement
4. Estimation of available oxygen in pyrulosite
5. Percentage of available chlorine in bleaching powder.
Reference Books
1. Practical Organic Chemistry, 4th edition, F.G. Mann and B.C. Saunders , Pearson Education Limited
, UK, 2001
2. Advanced Practical Chemistry, S.C. Das , Sector 1 Salt lake City, Kolkata 64, 2010
3. Practical Organic Chemistry, A.K. Manna, Books And Allied ( P) LTD. Kolkata -700010, 2018
4. Advanced Practical Chemistry, R. Mukhopadhyay and P. Chatterjee, Books And Allied ( P) LTD.
Kolkata -700010, 2016
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Semester V INORGANIC: Credit 03
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Course: CC8 (TH)
Total Lecture 40
Course objective: Idea about of s and p block elements and their properties. Idea about noble gases
particularly xenon chemistry.
CC8.1 Chemistry of s and p Block Elements:
Inert pair effect, Relative stability of different oxidation states, diagonal relationship and anomalous
behaviour of first member of each group. Allotropy and catenation.
(10 Lectures)
CC8.2 Complex formation of s and p Block Elements:
Crown ether. Complexes of Li, Na, K, Be, Ca and Mg, Basic beryllium acetate and nitrate.
(05 Lectures)
CC8.3 Hydrides and Halides of s and p Block Elements:
Hydrides and their classification ionic, covalent and interstitial. Thermal stability, Reducing
properties, basic strength of hydrides. Preparation, properties and reaction of halides.
(5 Lectures)
CC8.4 Preparation, Structure, bonding and properties:
Boric acid and borates, boron nitrides (Borazine), borohydrides (diborane) silanes, Silicates, silicone,
Graphite, Oxides and oxoacids of nitrogen, Phosphorus and chlorine. Oxoacids of S, Se and Te. S4N4
and Polythiazyl [(SN)x].
(10 Lectures)
CC8.5 Chemistry of Halogen compounds:
Interhalogen compounds, polyhalideions, pseudo halogens and basic properties of halogens.
(5 Lectures)
CC8.6 Noble Gases:
Occurrence and uses, rationalization of inertness of noble gases, Clathrates; preparation and properties
of XeF2, XeF4and XeF6; Nature of bonding in noble gas compounds (Valence bond treatment and MO
treatment for XeF2). Molecular shapes of noble gas compounds (VSEPR theory).
(5 Lectures)
Reference Books:
 Lee,J.D. Concise Inorganic Chemistry,ELBS,1991.
 Douglas, B.E; Mc Daniel, D.H. & Alexander, J.J. Concepts & Models of Inorganic Chemistry
3rdEd., John Wiley Sons, N.Y.1994.
 Greenwood, N.N. & Earnshaw. Chemistry of the Elements, Butterworth-
Heinemann.1997.
 Cotton,F.A.&Wilkinson,G. Advanced Inorganic Chemistry,Wiley,VCH,1999.
 Rodger, G.E. Inorganic and Solid State Chemistry, Cengage Learning India Edition,2002.
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Semester V INORGANIC LAB: Credit 01
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Course: CC8 (PR)
15 Lectures
Course Objective: Learning of gravimetric analysis, preparation of complex compounds.
Gravimetric Analysis:
i) Estimation of nickel (II) using Dimethylglyoxime (DMG).
ii) Estimation ofc operas CuSCN
iii) Estimation of iron as Fe2O3by precipitating iron as Fe (OH)3.
Reference Books:

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Semester V PHYSICAL: Credit 03
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Course: CC9 (TH)
Total Lectures 40
Course Objective: Learn about the rate of chemical process I.e., the change of concentration of a substance
with time, disintegration time of a radio-active substance, kinetics of fermentation, transition state theory,
mechanism of catalytic reaction, mechanism of adsorption of gas or liquid on solid surface, concept of
colligative properties and partition coefficient of a solute between two solvents.
CC9.1 Solutions and Colligative Properties:

Raoult’s and Henry’s Laws for ideal and ideally dilute solution using the concept of chemical potential
and relevant applications.
Thermodynamic derivation using chemical potential to derive relations between the four colligative
properties [(i) relative lowering of vapour pressure, (ii) elevation of boiling point, (iii) Depression of
freezing point, (iv) osmotic pressure] and amount of solute. Concept of van’t Hoff factor; calculating molar
masses of normal, dissociated and associated solutes in solution.
Nernst distribution law: derivation and applications.
(12 Lectures)
CC9.2 Chemical Kinetics and Homogenous Catalysis
Order and molecularity of a reaction, rate laws in terms of the advancement of a reaction, differential
and integrated form of rate expressions up to second order reactions, experimental methods of the
determination of rate laws, kinetics of complex reactions (integrated rate expressions up to first order
only): (i) Opposing reactions (ii) parallel reactions and (iii) consecutive reactions and their differential
rate equations (steady-state approximation in reaction mechanisms) (iv) chain reactions.
Temperature dependence of reaction rates; Arrhenius equation; activation energy. Collision theory of
reaction rates, Lindemann mechanism, qualitative treatment of the theory of absolute reaction rates.
Kinetics of Homogeneous catalysis: acid-base catalysis, Enzyme catalysis, Michaelis-Menten
mechanism.
(20 Lectures)
CC9.3 Adsorption and Heterogenous Catalysis:
Physical and chemical adsorption; nature of adsorbed state. Freundlich and Langmuir adsorption
isotherms; applications, multilayer adsorption and BET isotherm (no derivation required); Gibbs
adsorption isotherm (no derivation required); and surface excess.
Types of catalyst, homogeneous and heterogeneous catalysis; specificity and selectivity, mechanisms
and rates of catalyzed reactions on solid surfaces.
(8 Lectures)
Reference Books:
 Peter Atkins &Julio De Paula, Physical Chemistry10thEd.,Oxford University Press (2014).
 Castellan, G. W. Physical Chemistry, 4thEd., Narosa(2004).
 McQuarrie,D.A. & Simon,J.D., Molecular Thermodynamics, Viva Books Pvt .Ltd.:
NewDelhi(2004).
 Assael,M.J.; Goodwin,A.R.H.;Stamatoudis,M.;Wakeham,W.A.&Will,S. Commonly Asked
Questions in Thermodynamics. CRC Press: NY (2011).
 Zundhal,S.S .Chemistry concepts and applications Cengage India(2011).
 Ball,D.W. Physical Chemistry Cengage India (2012).
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Semester V PHYSICAL LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC9 (PR)
Lectures; 15
Course Objective: Learning the effective handling the apparatus, following the reaction with respect to
time, technique to determine the partition coefficient, applying the theory in the area of phase diagram and
transition temperature.
Nernst distribution law

1. Distribution of acetic/benzoic acid between water and cyclohexane.
Study the kinetics of the following reactions.

2. Integrated rate method:
a. Acid hydrolysis of methyl acetate with hydrochloric acid.
b. Saponification of ethylacetate/methyacetate.
3. Compare the strengths of HCl and H2SO4 by studying kinetics of hydrolysis of methyl acetate.
Adsorption
4. Verify the Freundlich and Langmuir isotherms for adsorption of acetic acid on activated
charcoal.
Reference Books:
 Khosla,B.D.; Garg,V.C.&Gulati,A.Senior Practical Physical Chemistry,R. Chand
&Co.:New Delhi (2011).
 Garland,C.W.;Nibler,J.W.& Shoemaker,D.P. Experimentsin Physical Chemistry 8thEd.;
McGraw-Hill: NewYork(2003).
 Halpern,A.M. & McBane,G.C. Experimental Physical Chemistry3rdEd.;W.H. Freeman
&Co.: New York(2003).
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--
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Semester V ORGANIC: Credit 03
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Course: CC10 (TH)
Total Lectures 40
Course Objective: Basic understanding of spectroscopic methods such as UV, IR ,NMR and MASS to
characterize and identify the chemical structures of simple organic molecules. Learning basic knowledge
about heterocyclic reactions, amino acids, structure of biomolecules peptide, protein, nucleic acid, enzymes.
CC10.1Organic Spectroscopy
UV Spectroscopy: Introduction; types of electronic transitions, end absorption; transition dipole moment and
allowed/forbidden transitions; chromophores and auxochromes; Bathochromic and Hypsochromic shifts;
intensity of absorptions (Hyper-/Hypochromic effects); application of Woodward's Rules for calculation of
λmax for the following systems: conjugated diene, α,β-unsaturated aldehydes and ketones (alicyclic,
homoannular and heteroannular); extended conjugated systems (dienes, aldehydes and ketones); relative
positions of λmax considering conjugative effect, steric effect, solvent effect, effect of pH; effective
chromophore concentration: keto-enol, diketone; benzenoid transitions.
IR Spectroscopy: Introduction; modes of molecular vibrations (fundamental and nonfundamental); IR active
molecules; application of Hooke's law, force constant; fingerprint region and its significance; effect of
deuteration; overtone bands; vibrational coupling in IR; characteristic and diagnostic stretching frequencies
of C-H, N-H, O-H, C-O, C-N, C-X, C=C (including skeletal vibrations of aromatic compounds), C=O, C=N,
N=O, C=C, ON; characteristic/diagnostic bending vibrations are included; factors affecting stretching
frequencies: effect of conjugation, electronic effects, mass effect, bond multiplicity, ring size & solvent
effects, H-bonding on IR absorptions.
NMR Spectroscopy: Introduction; nuclear spin; NMR active molecules; basic principles of Proton Magnetic
Resonance; Relaxation (spin-spin, spin lattice), equivalent and non-equivalent protons; chemical shift and
factors influencing it; ring current effect; significance of the terms: up-/downfield, shielded and deshielded
protons; spin coupling and coupling constant (1st order spectra); relative intensities of first-order multiplets:
Pascal's triangle; chemical and magnetic equivalence in NMR ; elementary idea about non-first-order
splitting; anisotropic effects in alkene, alkyne, aldehydes and aromatics; NMR peak area, integration; relative
peak positions with coupling patterns of common organic compounds (both aliphatic and benzenoid-
aromatic); rapid proton exchange; interpretation of NMR spectra of simple compounds.
Mass spectrometry: Introduction, Basic principle, factors determining mass spectral fragments (Simple
cleavage, RDA fragmentation, α Cleavage, Acyl cleavage, Mclafferty Rearrangement)
13
C NMR Spectroscopy: The 13C Nucleus, 13C Chemical shifts (Correlation Charts, Calculation 13C chemical
shifts) 13C coupling constants.
(10 Lectures)
CC10.2 Heterocyclic Compounds
Heterocyclic compounds: 5- and 6-membered rings with one heteroatom; reactivity, orientation and
important reactions (with mechanism) of furan, pyrrole, thiophene and pyridine; synthesis (including
retrosynthetic approach and mechanistic details): pyrrole: Knorr synthesis, Paal-Knorr synthesis, Hantzsch;
furan: Paal-Knorr synthesis, Feist- Benary synthesis and its variation; thiophenes: Paal-Knorr synthesis,
Hinsberg synthesis; pyridine: Hantzsch synthesis; benzo-fused 5- and 6-membered rings with one
heteroatom: reactivity, orientation and important reactions (with mechanistic details) of indole, quinoline and
isoquinoline; synthesis (including retrosynthetic approach and mechanistic details): indole: Fischer,
Madelung and Reissert; quinoline: Skraup, Doebner- Miller, Friedlander; isoquinoline: Bischler-Napieralski
synthesis.
(10 Lectures)
CC10.3Bio-molecules
Amino acids: Characteristics, structure, notation of α-amino acids, Synthesis with mechanistic details:
Strecker, Gabriel, acetamido malonic ester, azlactone, Bucherer hydantoin synthesis, synthesis involving
diketopiperazine; isoelectric point, zwitterions; electrophoresis, reaction (with mechanism): ninhydrin
reaction, Dakin-West reaction; resolution of racemic amino acids.
Peptides: Peptide linkage and its geometry; syntheses (with mechanistic details) of peptides using N-
protection & C-protection, solid-phase (Merrifield) synthesis; peptide coupling agents, resin, peptide
sequence: C-terminal and N-terminal unit determination (Edman, Sanger & 'Dansyl' methods); partial
hydrolysis; specific cleavage of peptides: use of CNBr.
Nucleic acids: Pyrimidine and purine bases (only structure & nomenclature); nucleosides and nucleotides
corresponding to DNA and RNA; mechanism for acid catalysed hydrolysis of nucleosides (both pyrimidine
and purine types); comparison of alkaline hydrolysis of DNA and RNA; elementary idea of double helical
structure of DNA (Watson-Crick model); complimentary base-pairing in DNA.
(16 Lectures)
CC10.4Enzymes
Introduction, classification and characteristics of enzymes: Salient features of active site of enzymes,
mechanism of enzyme action (trypsin, chymotrypsin as example), factor affecting enzyme action, coenzymes
and cofactors and their role in biological reactions, specificity of enzyme action (including stereospecificity),
enzyme inhibitors and their importance, phenomenon of inhibition (competitive, uncompetitive and non-
compititive inhibition including allosteric inhibition).
(4 Lectures)
Reference Books:
 Berg, J.M., Tymoczko, J.L. and Stryer, L. (2006) Biochemistry. VIth Edition. W.H. Freeman and
Co.
 Nelson, D.L., Cox, M.M. and Lehninger, A.L. (2009) Principles of Biochemistry. IV Edition. W.H.
Freeman and Co.
 Murray, R.K., Granner, D.K., Mayes, P.A. and Rodwell, V.W. (2009) Harper’s Illustrated
Biochemistry. XXVIII edition. Lange Medical Books/ McGraw-Hill.
 Kemp, W. Organic Spectroscopy, Palgrave.
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Semester V ORGANIC LAB: Credit 01
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Course: CC10 (PR)
15 Lectures
Course Objective: To develop the skill for the identification of simple organic compounds by IR and NMR
spectroscopy. Learning the estimation and titration methods in laboratory such as estimation of glucose,
sucrose, aniline, phenol, glycine and proteins and study of titration curve of glycine.
1. Identification of simple organic compounds by IR and NMR and 13-C NMR spectroscopy. (Spectra of
some simple molecules to be provided).
2. Estimation of glycine by Sorenson’s formalin method.
3. Study of the titration curve of glycine.
4. Estimation of Glucose.
5. Estimation of Glucose and Sucrose in a mixture.
6. Estimation of Aniline by bromated-bromide method.
Reference Books:
 Manual of Biochemistry Workshop, 2012, Department of Chemistry, University of Delhi.
 Arthur, I. V. Quantitative Organic Analysis, Pearson.
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Semester V INORGANIC: Credit 03
--------------------------------------------------------------------------------------------------
Course: CC11 (TH)
Total Lectures 40
Course Objective: Introduction to co-ordination chemistry with learning of Crystal field theory, Jahn-Teller
theorem, IUPAC nomenclature, study of transition elements, Spinels and inverted Spinel structure.
CC11.1 Coordination Chemistry:
Defination and classification of compounds, IUPAC nomenclature of coordination compounds,
spectrochemical series, Classification of ligands, Ambidentate ligands, Chelate effect: Defination,
stability and application, Stability (Labile and inert) of complexes.
(12 Lectures)
CC11.2 Werner’s theory:
Postulates of Werner’s theory, structure of Co(III) and Pt(IV) ammines complexes valence bond
theory (inner and outer orbital complexes).
Isomerism in coordination compounds: Structural Isomerism and classifications, Geometrical and

Optical isomerism with 4 and 6 coordination numbers.
(4 Lectures)
CC11.3 Crystal field theory:
Important features of CFT, Splitting of d-orbitals in octahedral and Tetrahedral complexes, High spin and Low spin
complexes, measurementof10Dq(Δo), CFSE in weak and strong fields, factors affecting the magnitude
of 10 Dq (Δo, Δt). Octahedral vs. tetrahedral coordination, Crystal field stabilization energy (CFSE),
Mean pairing energy (P), octahedral site preference energy (OSPE) and its application. d-Orbital splitting in
tetragonal and square planar complexes, Thermodynamic aspects of crystal field splitting (variation of
ionic radii, lattice energy, hydration enthalpy), Preferred geometry in dn ions.
Tetragonal distortions from octahedral geometry Jahn-Teller theorem: Weak and Strong distortion in
octahedral complexes, Distortion in Tetrahedral and Chelate complexes, Applications of Jahn-Teller
theorem.
(20 Lectures)
CC11.4 Spinels:
Crystal structure of spinels, types of spinel-Normal and Invert spinels with examples.
(4 Lectures)
Reference Books:
 Purcell,K.F&Kotz,J.C.InorganicChemistryW.B.SaundersCo,1977.
 Huheey,J.E.,InorganicChemistry,PrenticeHall,1993.
 Lippard,S.J.&Berg,J.M.PrinciplesofBioinorganicChemistryPanimaPublishing Company1994.
 Cotton,F.A.&Wilkinson,G,AdvancedInorganicChemistryWiley-VCH,1999
 Basolo, F, and Pearson, R.C. Mechanisms of Inorganic Chemistry, John Wiley & Sons,
NY,1967.
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Semester V (DSC) INORGANIC LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC11 (PR)
15 Lectures
Course Objective: Learning of gravimetric analysis, preparation of complex compounds and
chromatographic separation of metal ions.
1. Inorganic Preparations:
i) Tetraamminecopper (II) sulphate,[Cu(NH3)4]SO4.H2O
ii) Cis and trans K[Cr(C2O4)2. (H2O)2] Potassium dioxalatodiaquachromate (III)
iii) Potassium tris(oxalate) ferrate (III)
2. Analysis of Metals and Alloys
i) Quantitative estimation of Zn (II) and Cu(II) in brass sample by Volumetry
3. Analysis of Ores and Minerals

i) Quantitative estimation of manganese inpyrolusite
Reference Book:

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Semester V DSE I: Credit 03
--------------------------------------------------------------------------------------------------
Course: DSE-1(TH)
Total Lecture 40
Course Objectives: Knowledge about the green chemistry, various separation techniques thermal analysis
and fermentation reaction.
DS1.1. Green Chemistry-1

What is Green Chemistry? Need for Green Chemistry. Twelve principles of Green Chemistry with their
explanations and examples and special emphasis on the following: Designing a Green Synthesis using these
principles; Prevention of Waste/ byproducts; maximum incorporation of the materials used in the process
into the final products, Atom Economy, calculation of atom economy of the rearrangement, addition,
substitution and elimination reactions.
Prevention/ minimization of hazardous/ toxic products reducing toxicity. risk = (function) hazard × exposure;
waste or pollution prevention hierarchy. Green solvents– supercritical fluids, water as a solvent for organic
reactions, ionic liquids, PEG, solventless processes,
Green Synthesis of the following compounds: adipic acid, catechol, disodium iminodiacetate (alternative to
Strecker synthesis). Planning of green synthesis of common organic reactions and their application: Aldol,
Friedel-Crafts, Knoevenagel, Cannizzaro, Benzoin condensation and Dieckmann condensation.
Microwave assisted reactions in water, methyl benzoate to benzoic acid, oxidation of toluene and alcohols;
microwave assisted reactions in organic solvents Diels-Alder reaction.
Ultrasound assisted reactions: sonochemical Simmons-Smith Reaction (Ultrasonic alternative to Iodine)
(15 Lectures)
DS1.2 Separationtechniques-1
Solvent extraction: Classification, principle and efficiency of the technique.
Mechanism of extraction: extraction by solvation and chelation.
Technique of extraction: batch, continuous and counter current extractions.
Qualitative and quantitative aspects of solvent extraction: extraction of metal ions from aqueous
solution, extraction of organic species from the aqueous and nonaqueous media.
Flame Atomic Absorption and Emission Spectrometry: Basic principles of instrumentation (choice of
source, monochromator, detector, choice of flame and Burner designs. Techniques of atomization and
sample introduction; Method of background correction, sources of chemical interferences and their
method of removal. Techniques for the quantitative estimation of trace level of metal ions from water
samples.
(15 Lectures)
DS1.3 Fermentation
Aerobic and anaerobic fermentation. Production of (i) Ethyl alcohol and citric acid, (ii)Antibiotics;
Penicillin, Cephalosporin, Chloromycetin
Thermal methods of analysis:
Theory of thermogravimetry (TG), basic principle of instrumentation. Techniques for quantitative
estimation of Ca and Mg from their mixture
(10 Lectures)
Reference Books:
 Ahluwalia, V.K. & Kidwai, M.R. New Trends in Green Chemistry, Anamalaya Publishers (2005).
 Anastas, P.T. & Warner, J.K.: Green Chemistry - Theory and Practical, Oxford University Press
(1998).
 Matlack, A.S. Introduction to Green Chemistry, Marcel Dekker (2001).
 Cann, M.C. & Connely, M.E. Real-World cases in Green Chemistry, American Chemical Society,
Washington (2000).
 Ryan, M.A. &Tinnesand, M. Introduction to Green Chemistry, American Chemical Society,
Washington (2002).
 Lancaster, M. Green Chemistry: An Introductory Text RSC Publishing, 2nd Edition, 2010.
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Semester V DSE I LAB: Credit 01
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Course: DSE-1(PR)
15 Lecture
Course Objective: To learn about the synthesis of various compounds, Bio-Diesels and gold nanoparticles
byb green techniques.
1. Safer starting materials
i) Preparation and characterization of nanoparticles of gold using tea leaves.
2. Using renewable resources
i) Preparation of biodiesel from vegetable/ waste cooking oil.
3. Use of enzymes as catalysts
i) Benzoin condensation using Thiamine Hydrochloride as a catalyst instead of cyanide.
4. Alternative sources of energy
i) Solvent free, microwave assisted one pot synthesis of phthalocyanine complex of copper (II).
Reference Books:
 Anastas, P.T & Warner, J.C. Green Chemistry: Theory and Practice, Oxford University Press (1998).
 Kirchoff, M. & Ryan, M.A. Greener approaches to undergraduate chemistry experiment. American
Chemical Society, Washington DC (2002).
 Ryan, M.A. Introduction to Green Chemistry, Tinnesand; (Ed), American Chemical Society,
Washington DC (2002).
 Sharma, R.K.; Sidhwani, I.T. & Chaudhari, M.K. I.K. Green Chemistry Experiment: A monograph
International Publishing House Pvt Ltd. New Delhi. Bangalore CISBN 978-93-81141-55-7 (2013).
 Cann, M.C. & Connelly, M. E. Real world cases in Green Chemistry, American Chemical Society
(2008).
 Cann, M. C. & Thomas, P. Real world cases in Green Chemistry, American Chemical Society
(2008).
 Pavia, D.L., Lampman, G.M., Kriz, G.S. & Engel, R.G. Introduction to Organic Laboratory
Techniques: A Microscale and Macro Scale Approach, W.B.Saunders, 1995.
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Semester V Subject -A, Paper 3
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Toatal Lecture 40
Course objectives: Basic knowledge about various equilibrium process, coordination Chemistry. Learning
the preliminary idea about amino acids , carbohydrates, green chemistry and polymer chemistry.
GEA3.1 Ionic Equilibria
Strong, moderate and weak electrolytes, degree of ionization, factors affecting degree of ionization,
ionization constant and ionic product of water. Ionization of weak acids and bases, pH scale, common ion
effect. Buffer solutions&Henderson-Hasselbach equation (no derivation).
(6 Lectures)
GEA3.2 Heterogeneous Equilibrium and Phase Rule
Phase, Component, Degree of freedom, Phase Rule , Phase diagram ( one and two component systems),
Solid-Gas Equilibrium, Feflorescence and Deliquescence, Two Component Solid-Liquid system, Salt-Water
system, Freezing mixture, alloys and simple Eutectic.
(6 Lectures)
GEA3.3 Coordination Chemistry & Transition Elements
Werner’s theory, valence bond theory (inner and outer orbital complexes), IUPAC nomenclature,
Isomerism, VBT, Crystal field theory, measurement of 10Dq(Δo), CFSE in weak and strong fields,
factors affecting CFSE. Octahedral vs. tetrahedral coordination.
(6 Lectures)
GEA3.4 Amino Acids
Preparation: Strecker synthesis, using Gabriel’s phthalimide synthesis. Zwitterion, Isoelectric point and
Electrophoresis. Reactions of Amino acids: acetylation, ninhydrin test.
(4 Lectures)
GEA3.5 Carbohydrates
Classification and general properties, Glucose and Fructose (open chain and cyclic structure), Determination
of configuration of monosaccharides, absolute configuration of Glucose and Fructose, Mutarotation,
ascending and descending in monosaccharides.
(6 Lectures)
GEA3.6 Green Chemistry
Need for green Chemistry, Twelve Principles of green chemistry with their explanations and examples.
Preparation of some organic compounds by green technique, Green solvents
GEA3.7 Polymer
Introduction and Classification, Molecular Wights, Degree of [polymerization, Cationic, anionic and free
radical addition polymerization, Preparation and applications of PVC, Bakelite, Biodegradable and
conducting polymers with examples.
(6 Lectures)
Reference Books:
(2007).
Publishing (2017).
Education).
(2016).
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Semester V Subject -A, Paper 3
--------------------------------------------------------------------------------------------------
15 Lectures
Course objectives: To learn about the detection methods and their chemical reactions of special elements
and various functional groups in organic compounds.
1. Detection of extra elements (N, S, Cl, Br, I) in organic compounds (containing upto two extra
elements)
2. Systematic Qualitative Organic Analysis of Organic Compounds possessing monofunctional groups
(-COOH, phenolic, aldehydic, ketonic, amide, nitro, amines).
3. Determination of melting point of the organic compounds.
Reference Books:
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Semester VI INORGANIC: Credit 03
--------------------------------------------------------------------------------------------------
Course: CC 12(TH)
Total Lecture 40
Course objectives: Understanding bioinorganic Chemoistry, organometallic compounds and basic
knowledge about coordination compounds.
CC12.1 Electronic Spectra of Coordination Chemistry:
Qualitative aspect of Ligand field and MO Theory. Electronic spectra: Term symbolic and
electronic spectral features, Orgel diagram, d-d spectra of dn ions. Charge transfer spectra-
LMCT, MLCT, LLCT and MMCT with molecular orbital approach. Trans- effect, theories of
trans effect, Mechanism of nucleophilic substitution in square planar complexes.
(12 Lectures)
CC12.2 Organometallic Compounds:
Definition and classification of organometallic compounds on the basis of bond type. Application
of 18- electron and 16- electron rules to transition metal organometallics, EAN rule and its
applications, Concept of hapticity and denticity of organic ligands.Zeise’s salt: Preparation and
structure, properties, evidences of synergic effect and comparison of synergic effect with that in
carbonyls.
Ferrocene: Preparation and reactions (acetylation, alkylation, metallation, Mannich

Condensation). Structure and aromaticity. Comparison of aromaticity and reactivity with that of
benzene.
(16 Lectures)
CC12.3 Bioinorganic Chemistry:
Metal ions present in biological systems, classification of elements according to their action in
biological system. Sodium/pump, Excess and deficiency of some trace metals. Toxicity of metal
ions (Hg, Pb, Cd and As), reasons for toxicity, Use of chelating agents in medicine.
Iron and its application in bio-systems, Hemoglobin; Storage and transfer of iron.
(12 Lectures)
Reference Books:
 Lee,J.D. Concise Inorganic Chemistry,ELBS,1991.
 Douglas, B.E; Mc Daniel, D.H. & Alexander, J.J. Concepts & Models of Inorganic
Chemistry 3rdEd., John Wiley Sons, N.Y.1994.
 Greenwood, N.N. & Earnshaw. Chemistry of the Elements, Butterworth-
Heinemann.1997.
 Cotton,F.A.&Wilkinson,G. Advanced Inorganic Chemistry,Wiley,VCH,1999.
 Rodger, G.E. Inorganic and Solid State Chemistry, Cengage Learning India Edition,2002.
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Semester VI INORGANIC LAB: Credit 01

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Course: CC 12(PR)
15 Lecture
Course objectives: Learning of qualitative semi-micro analysis of ions from ionic mixture and
introduction to spot test of various inorganic compounds.
P13.1 Identification of acid radicals, basic radicals, interfering acid radicals and insoluble salts.
P13.1.1 Acid radicals
NH4+, K+, Pb2+, Cu2+, Cd2+, Bi3+, Sn2+, Sb3+, Fe3+, Al3+,, Cr3+, Zn2+, Mn2+, Co2+, Ni2+,
Ba2+,Sr2+, Ca2+, Mg2+
P13.1.2 Basic radicals
CO32-, NO2-, S2-, SO32-, S2O32-, Cl-, Br-, I-, NO3-.
P13.1.3 interfering acid radicals
BO33-, PO43-, F-
P13.1.4 Insoluble Salt
BaSO4, SrSO4, PbSO4, CaF2or Al2O3
Mixtures should preferably contain one interfering anion, or insoluble component (BaSO4, SrSO4,
2- 2- - - - -
PbSO4, CaF2or Al2O3) orcombination of anions e.g. CO3 and SO3 , NO2 and NO3 , Cl and Br ,
Cl- and I-, Br-and I-, NO3- and Br-, NO3- and I-.
Spot tests should be done whenever possible.
Reference Books:
 Nad, A.K., Mahapatra, B., Ghoshal, A.; An advanced course in practical chemistry, 3rd Ed.
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Semester VI PHYSICAL: Credit 03
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Course: CC 13(TH)
Total Lecture 40
Course Objective: Learning the principles, importance of applications of conductance of electrolytes,
usage of electrode kinetics, formation of cells and their reactions, use of electrochemical series in real
life, operators in quantum mechanics, wave property of a system, application of quantum mechanics to
particle in 1-D, 2-D and 3-D boxes
CC13.1 Conductance
Brief introduction of conduction in metal and electrolytic solution; conductivity, equivalent and
molar conductivity and their variation with dilution for weak and strong electrolytes. Molar
conductivity at infinite dilution. Kohlrausch law of independent migration of ions. Debye-
Hückel-Onsager equation, Wien effect, Debye-Falkenhagen effect.
Activity and activity coefficients of various types (uni-uni; uni-bi, etc) of electrolytic solution,
Debye-Hückel-limiting law (without derivation) and ionic strength.
Ionic velocities, mobilities and their determinations, transference numbers and their relation to
ionic mobilities, determination of transference numbers. Applications of conductance
measurement: (i) degree of dissociation of weak electrolytes, (ii) ionic product of water (iii)
solubility and solubility product of sparingly soluble salts, (iv) conductometric titrations, and (v)
hydrolysis constants of salts
(10 Lectures)
CC13.2 Electrochemistry
Quantitative aspects of Faraday’s laws of electrolysis, rules of oxidation/reduction of ions based
on half-cell potentials, applications of electrolysis in metallurgy and industry.
Chemical cells, reversible and irreversible cells with examples. Electromotive force of a cell and
its measurement, Nernst equation; Standard electrode (reduction) potential and its application to
different kinds of half-cells. Application of EMF measurements in determining (i) free energy,
enthalpy and entropy of a cell reaction, (ii) equilibrium constants, and (iii) pH values, using pH
electrodes.
Concentration cells with and without transference, liquid junction potential; determination of
activity coefficients and transference numbers.
Qualitative discussion of potentiometric titrations (acid-base, redox, precipitation).
(14 Lectures)
CC13.3 Quantum Chemistry-I
Wave-particle duality and Heisenberg Uncertainty principle. Schrodinger time-independent
equation; nature of the equation, acceptability conditions imposed on the wave functions and
probability interpretations of wave function. Elementary concepts of operators, eigenfunctions
and eigenvalues; Linear operators; Commutation of operators, Expectation value; Hermitian
operator; Postulates of Quantum Mechanics.
Schrödinger equation and its application to free particle and “particle-in-a-box” (rigorous
treatment), quantization of energy levels, zero-point energy and Heisenberg Uncertainty
principle; wavefunctions, probability distribution functions, nodal properties, Extension to two-
and three-dimensional boxes, separation of variables, degeneracy.
(16 Lectures)
Reference Books:
 Atkins,P.W & Paula,J.D. Physical Chemistry,10thEd.,Oxford University Press
(2014).
 Castellan, G. W. Physical Chemistry 4thEd., Narosa(2004).
 Mortimer, R. G. Physical Chemistry 3rdEd., Elsevier: NOIDA, UP(2009).
 Barrow, G. M., Physical Chemistry 5thEd., Tata McGraw Hill: New Delhi(2006).
 Rogers,D.W. Concise Physical Chemistry Wiley(2010).
 Silbey,R.J.;Alberty,R.A.&Bawendi,M.G. Physical Chemistry 4thEd.,John Wiley &
Sons, Inc.(2005).
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Semester VI PHYSICAL LAB: Credit 01
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Course: CC 13(PR)
15 Lecture
Course Objective: Learning the effective handling of conductometer, pH-meter and use of
electrodes, understand the potential of storage device, Standard EMF determination of various
electrode and compare with the electrochemical series, validation of the Ostwald’s dilution law for a
weak electrolyte.
Conductometry
1. Determination of cell constant
2. Determination of equivalent conductance, degree of dissociation and dissociation
constant of a weak acid.
3. Perform the following conductometric titrations:
i. Strong acid vs. strong base
ii. Weak acid vs. strong base
iii. Mixture of strong acid and weak acid vs. strong base
iv. Strong acid vs. weak base
Potentiometry
1. Perform the following potentiometric titrations:
i. Strong acid vs. strong base
ii. Weak acid vs. strong base
iii. Dibasic acid vs. strong base
iv. Potassium dichromate vs. Mohr's salt
Reference Books:
 Khosla, B. D.; Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry, R.
Chand & Co.: New Delhi (2011).
 Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry
8th Ed.; McGraw-Hill: New York (2003).
 Halpern, A. M. & McBane, G. C. Experimental Physical Chemistry 3rd Ed.; W.H.
Freeman & Co.: New York (2003).
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Semester VI ORGANIC: Credit 03
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Course: CC 14 (TH)
Total Lecture 40
Course Objective: Understanding the basic concept of pericyclic reactions and their mechanisms,
organic biomolecules such as carbohydrates and lipids. To familiarize students with the chemistry and
applications of dyes and polymers. To grow concept of organometallic reagents and pharmaceutical
compounds.
CC14.1 Pericyclic Reactions-1

Mechanism, stereochemistry, regioselectivity: 1. Eletrocyclic Reaction: FMO approach involving 2 ,
4ᴨ- and 6ᴨ- electrons (thermal and photochemical) and corresponding cycloreversion reaction. 2.
Cycloaddition Reaction: FMO approach, Diels-Alder reaction, photochemical [2+2] cycloadditions. 3.
Sigmatropic Reaction: FMO approach, sigmatropic shifts and their order; [1,3] - and [1,5]-H shifts and
[3,3]-shifts with reference to Claisen and Cope rearrangements.
(8 Lectures)
CC14.2 Carbohydrates
Monosaccharides: Aldoses up to 6 carbons; structure of D-glucose & D-fructose (configuration &
conformation); ring structure of monosaccharides (furanose and pyranose form): Haworth
representation and non-polar conformations; anomeric effect (including stereoelectronic explanation);
mutarotation; epimerization; reactions ( mechanism In relevant cases): Fischer glycosidation, osazone
formation, bromine-water oxidation, HNO3oxidation, selective oxidation of terminal-CH2OH of
aldose, reduction to alditols, Lobry de Bruyn-van Ekenstein rearrangement; stepping-up (Killani-
Fischer method) and stepping-down (Ruff's & Wohl's methods) of aldoses; Amadori rearrangement,
end-group-interchange of aldoses; acetonide (isopropylidene) and benzylidene protections; ring-size
determination; Fischer's proof of configuration of (+)- glucose.
Disachharides: Glycosidic linkages, concept of glycosidic bond formation by glycosyl donor-acceptor;
structure of sucrose, inversion of cane sugar.
Polysachharide: Starch (structure and its use as an indicator in titrimetric analysis).
(8 Lectures)
CC14.4 Dyes
Classification, colour and constitution; Mordant and Vat Dyes; Chemistry of dyeing; Synthesis and
application of : Azo dyes - Methyl Orange and Congo Red (mechanism of Diazo Coupling); Triphenyl
Methane Dyes - Malachite Green, Rosaniline and Crystal Violet; phthalein Dyes - Phenolpthalein and
Fluorescein; Natural dyes - structure elucidation and synthesis of Alzarin and Indogotin; Edible Dyes
with examples.
(4 Lectures)
CC14.5 Polymers
Introduction and classification: Including di-block, tri-block and amphilic polymers; Number average
molecular weight, weight average molecular weight, Degree of polymerisation, polydispersity Index.
Polymerisation reactions: Addition and condensation - Mechanism of cationic, anionic and free radical
addition polymerisation; Metallocene- based Ziegler-Natta polymerisation of alkenes; Preparation and
applications of plastic - thermosetting (phenol- formaldehyde, polyurethanes) and thermosoftening
(PVC, polythene).
Fabrics: Natural and synthetic (acrylic, polyamido, polyester); Rubber - natural and synthetic: Buna-S,
Chloroprene and Neoprene; Vulcanization; Polymer additives;
Introduction to liquid crystal polymers; Biodegradable and conducting polymer with examples.
(8 Lectures)
CC14.6 Chemistry of Organometallic Compounds
Organomagnesium compounds (Grignard reagents); Preparation, Present view structure, Application
in organic synthesis, Zerewitinoff method, tertiary butyl ether synthesis.
Organolithium compounds; Bonding and structure, Preparation, Reactivity and Reactions of
organolithium compounds, Alkyl lithium as strong base.
New era of organometallics: Transition metal complexes; The 18-electron rule, Ligand types and
number of electrons contributed. Assigning oxidation state of the central metal atom.
Some organometallic (Name) Reactions: Heck reaction, Suzuki cross coupling reaction, Stille cross-
coupling reaction, Sonogosira coupling reaction, Chan-Lam coupling reaction.
Chromatography
A brief overview on chromatography technique, basic principle of thin layer chromatography (TLC),
column chromatography, stationary phase, mobile phase, retention factor (rf), factor influencing on rf.
(06 Lectures)
CC14.7 Pharmaceutical Compounds: Structure and Importance
Classification, structure and therapeutic uses of antipyretics: Paracetamol (with synthesis), Analgesics:
Ibuprofen (with synthesis), Antimalarials: Chloroquine (with synthesis). An elementary treatment of
Antibiotics and detailed study of chloramphenicol, Medicinal values of curcumin (haldi), azadirachtin
(neem), vitamin C and antacid (ranitidine).
(06 Lectures)
Reference Books:
 Kalsi, P. S. Textbook of Organic Chemistry 1st Ed., New Age International (P) Ltd. Pub.
 Morrison, R. T. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd.
 Billmeyer, F. W. Textbook of Polymer Science, John Wiley & Sons, Inc.
 Gowariker, V. R.; Viswanathan, N. V. & Sreedhar, J. Polymer Science, New Age
International (P) Ltd. Pub.
 Clayden, J.; Greeves, N.; Warren, S.; Wothers, P.; Organic Chemistry, Oxford University
Press.
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Semester VI ORGANIC LAB: Credit 01
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Course: CC14(PR)
15 Lecture
Course Objective: To develop the skill of the students about the chromatographic analysis of organic
compounds and provides training in chromatographic separation of mixture of two or more than two
organic compounds. To expand the skill of student for preparation & estimation of some important
compounds.
Chromatography
1. Separation of a mixture of two amino acids by ascending and horizontal paper
chromatography.
2. Separation of a mixture of following compounds by thin layer chromatography (TLC).
i) Ortho-and para-nitrophenol.
ii) Ortho-and para-aminophenol.
iii) Benzyl alcohol and benzaldehyde.
iv) Benzoic acid, benzophenone, m-nitrobenzoic acid.
v) Phenol. 2-nitrophenol, 4-nitropenol.
vi) Benzyl alcohol, benzaldehyde and toluene.
vii) Benzyl chloride, benzyl alcohol.
viii) Benzyl alcohol, benzoic acid and benzaldehyde.
3. Estimation of ammonium ion (NH4+) in an ammonium salt by formol solution
4. Preparation of methyl orange.
5. Preparation of urea formaldehyde.
Reference Books:
 Vogel, A.I. Quantitative Organic Analysis, Part 3, Pearson (2012).
 Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry,
5th Ed., Pearson (2012)
 Ahluwalia, V.K. & Aggarwal, R. Comprehensive Practical Organic Chemistry: Preparation
and Quantitative Analysis, University Press (2000).
 Ahluwalia, V.K. & Dhingra, S. Comprehensive Practical Organic Chemistry: Qualitative
Analysis, University Press (2000).
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Semester VI DSE 2: Credit 03
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Course: DSE 2 (TH)
Course Objectives: Learning about concept of energy in biosystems, environments and
its segments. To know about the lipids, terpenoids and alkaloids.
Total Lecture 40
Course objectives: Learning about concept of energy in biosystems, environments and its sigments.
To know the lipids, terpenenoids and alkaloids.
DS2.1 Concept of Energy in Biosystems
Cell obtain energy by the oxidation of foodstuff (organic molecules)
Introduction to metabolism (catabolism, anabolism).
ATP: The universal currency of cellular energy, ATP hydrolysis and free energy change. Agents for
transfer of electrons in biological redox system: NAD+, FAD.
Conversion of food to energy: Outline of catabolic pathways of carbohydrate-glycolysis, fermentation,
Krebs cycle.
Overview of catabolic pathway of fat and protein.
Interrelationship in metabolic pathways of protein, fat and carbohydrate.
Caloric value of food, standard caloric content of food types.
(12 Lectures)
DS2.2 Lipids
Introduction to oil and fats; common fatty acids present in oil and fats, Hydrogenation of fats and oil,
Saponification value, acid value, iodine number, Reversion and rancidity
(4 Lectures)
DS2.3 Environment and its segments
Ecosystems. Biogeochemical cycles of carbon, nitrogen and Sulphur.
Air Pollution: Major regions of atmosphere. Chemical and photochemical reactions in
atmosphere. Air pollutants: types, sources, particle size and chemical nature; Photochemical
smog: its constituents and photochemistry. Environmental effects of ozone, Major sources of air
pollution.
Pollution by SO2, CO2, CO, NOx, H2S and other foul smelling gases. Methods of estimation of
CO, NOx, SOx and control procedures.
Effects of air pollution on living organisms and vegetation. Greenhouse effect and Global
warming, Ozone depletion by oxides of nitrogen, chlorofluorocarbons and Halogens, removal of
sulphur from coal. Control of particulates.
Water Pollution: Hydrological cycle, water resources, aquatic ecosystems, Sources and nature
of water pollutants, Techniques for measuring water pollution, Impacts of water pollution on
hydrological and ecosystems.
Water purification methods. Effluent treatment plants (primary, secondary and tertiary
treatment). Industrial effluents from the following industries and their treatment: electroplating,
textile, tannery, dairy, petroleum and petrochemicals, agro, fertilizer, etc. Sludge disposal.
(12 Lectures)
DS2.4 Energy & Environment
Sources of energy: Coal, petrol and natural gas. Nuclear Fusion / Fission, Solar energy,
Hydrogen, geothermal, Tidal and Hydel, etc.
Nuclear Pollution: Disposal of nuclear waste, nuclear disaster and its management
(4 Lectures)
DS2.5 Alkaloids
Natural occurrence, General structural features, Isolation and physiological action Hoffmann's
exhaustive methylation, Emde's modification, Structure elucidation and synthesis Including bio
synthesis of Ephedrine and Nicotine. Medicinal importance of Nicotine
(4 Lectures)
DS2.6 Terpenes
Occurrence, classification, isoprene rule; Elucidation of structure and synthesis of Citral, Neral, and α-
terpineol.
(4 Lectures)
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Semester VI DSE 2 LAB: Credit 01
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Course: DSE 2 (PR)
15 Lectures
Course Objective: The course forms the basis of various estimations of pollution indicators
of water.
1. Determination of dissolved oxygen in water.
2. Determination of Chemical Oxygen Demand (COD)
3. Determination of Biological Oxygen Demand (BOD)
4. Measurement of chloride, sulphate and salinity of water samples by simple titration method
(AgNO3 and potassium chromate).
5. Estimation of total alkalinity of water samples (CO2-3, HCO3-) using double titration method.
6. Measurement of dissolved CO2.
Reference Books:
 E. Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK.
 R.M. Felder, R.W. Rousseau: Elementary Principles of Chemical Processes, Wiley
Publishers, New Delhi.
 J. A. Kent: Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Delhi.
 S. S. Dara: A Textbook of Engineering Chemistry, S. Chand & Company Ltd. New
Delhi.
 K. De, Environmental Chemistry: New Age International Pvt., Ltd, New Delhi.
 S. M. Khopkar, Environmental Pollution Analysis: Wiley Eastern Ltd, New Delhi.
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Semester VI Subject -B, Paper 3
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Total Lecture 40
Course objectives; Basic knowledge about various equilibrium process, coordination Chemistry.
Learning the preliminary idea about amino acids , carbohydrates, green chemistry and polymer
chemistry.
GEA3.1 Ionic Equilibria
Strong, moderate and weak electrolytes, degree of ionization, factors affecting degree of ionization,
ionization constant and ionic product of water. Ionization of weak acids and bases, pH scale, common
ion effect. Buffer solutions&Henderson-Hasselbach equation (no derivation).
(6 Lectures)
GEA3.2 Heterogeneous Equilibrium and Phase Rule
Phase, Component, Degree of freedom, Phase Rule , Phase diagram ( one and two component
systems), Solid-Gas Equilibrium, Feflorescence and Deliquescence, Two Component Solid-Liquid
system, Salt-Water system, Freezing mixture, alloys and simple Eutectic.
(6 Lectures)
GEA3.3 Coordination Chemistry & Transition Elements
Werner’s theory, valence bond theory (inner and outer orbital complexes), IUPAC nomenclature,
Isomerism,VBT,Crystalfieldtheory,measurementof10Dq(Δo),CFSEinweak and strong fields,
factors affecting CFSE. Octahedral vs. tetrahedral coordination.
(6 Lectures)
GEA3.4 Amino Acids
Preparation: Strecker synthesis, using Gabriel’s phthalimide synthesis. Zwitterion, Isoelectric point
and Electrophoresis. Reactions of Amino acids: acetylation, ninhydrin test.
(4 Lectures)
GEA3.5 Carbohydrates
Classification and general properties, Glucose and Fructose (open chain and cyclic structure),
Determination of configuration of monosaccharides, absolute configuration of Glucose and Fructose,
Mutarotation, ascending and descending in monosaccharides.
(6 Lectures)
GEA3.6 Green Chemistry
Need for green Chemistry, Twelve Principles of green chemistry with their explanations and
examples. Preparation of some organic compounds by green technique, Green solvents
(6 Lectures)
GEA3.7 Polymer
Inytroduction and Classification, Molecular Wights, Degree of [polymerization, Cationic, anionic and
free radical addition polymerization, Preparation and applications of PVC, Bakelite, Biodegradable
and conducting polymers with examples.
(6 Lectures)
Reference Books:
 Housecroft, C. E; Sharpe, A. G., Inorganic Chemistry, 5th Ed., Pearson Education
(2018).
 Atkins, P.; Overton, T.; Rouke, J.; Weller, M.; Armstrong, F.; Hagerman, M., Shriver
Atkins’s Inorganic Chemistry, 6th Ed., Oxford University Press India (2015).
 Miessler, G.; Tarr, D. A., Inorganic Chemistry, 3rd Ed., Pearson Education India
(2008).
 Huheey, J. E.; Keiter, E. A.; Keiter, R. L.; Medhi, O. K., Inorganic Chemistry:
Principles of Structures and Reactivity, 4th Ed., Pearson Education India (2006).
 Cotton, F. A.; Wilkinson, G.; Gaus, P. L., Basic Inorganic Chemistry, 3rd Ed., Wiley
India (2007).
 Puri, B. R.; Sharma, L. R.; Kalia, K. C., Principles of Inorganic Chemistry, 33rd Ed.,
Vishal Publishing (2017).
 Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd.
 Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of
Natural Products), Dorling Kindersley (India) Pvt. Ltd. (Pearson Education).
 Kalsi, P. S. Stereochemistry Conformation and Mechanism; New Age International,
2005.
 Nasipuri, D. Stereochemistry of organic compounds: Principles and applications. New
age international (P) limited.
 Bahl, B. S.; Bahl, A., A Textbook of Organic Chemistry, 22nd Ed., S. Chand and
Company (2016).
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Semester VI Subject -B, Paper 3
Inter Disciplinary Minor (GE, Practical): Credit 01
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15 Lecture
Course objectives: To learn about the detection methods and their chemical reactions of special
elements and various functional groups in organic compounds
1. Detection of extra elements (N, S, Cl, Br, I) in organic compounds (containing upto two extra
elements)
2. Systematic Qualitative Organic Analysis of Organic Compounds possessing monofunctional
groups (-COOH, phenolic, aldehydic, ketonic, amide, nitro, amines).
3. Determination of melting point of the organic compounds.
Reference Books:
 Nad, A.K., Mahapatra, B., Ghoshal, A.; An advanced course in practical chemistry, 3rd Ed.
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Semester VII ORGANIC: Credit 03
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Course: CC15(TH)
Total Lecture 40
Course objective (CO):
1. To impart advanced knowledge on the bonding, stereochemistry and pericyclic reactions.To
understand the fundamental aspects of organic reactions, reagents, stereochemistry and
conformational analysis.
CC15.1 Pericyclic Reaction

Perturbation of molecular orbital (PMO) approach, concept of aromaticity of pericyclic transition
states..Diels Alder reaction and inverse electron demand, 2,2 addition of ketenes, 1,3 dipolar
cycloadditions and cheleotropic reactions. Sigmatropic rearrangements: 3,3- and 5,5- sigmatropic
rearrangements. Ene and retro ene reaction, Chelotropic reaction, Coarctate reactions, Cope, Claisen,
and aza-Cope rearrangements. Orbital coefficient, energy diagram of different substituted ethylene and
butadiene systems. Study of cycloaddition reaction using different substituted ethylene and butadiene
systems by considering regioselectivity, periselectivity, site selectivity and secondary orbital
interactions. Retro cycloaddition.
(12 Lecture)
CC15.2 Organic reaction mechanism
Sharpless asymmetric epoxidation, Hofmann Loffler Freytag reaction, Peterson olefination reaction,
Julia olefination, Wittig reaction, Birch reduction, Fukuyama reduction, Fukuyama amine synthesis.
Fragmentation reaction; Robinson annulations, Iodolactonization, Bergman cyclization, Büchner
method of ring expansion, synthesis of transfused ring. Baldwins rule of ring closure and related
examples.
(12 Lecture)
CC15.3 Stereochemistry and conformational analysis

Chirality, molecules with more than one chiral centres straight chain or branched. Optical activity in
absence of chiral carbon (biphenyls, allenes and spirans). Chirality due to helical shape,
stereochemistry of organonitrogen, sulfur and phosphorous compounds. Conformational analysis of
acyclic systems. Cyclohexene, cyclohexanone. Topicity and chemical reactivity.
(10 Lecture)
CC15.4 Dynamic aspects of stereochemistry:
Stereoselective and streospecific synthesis, enantio and diastereo-selective synthesis; kinetic and
thermodynamic control; π-facial selectivity,
(6 Lecture)
References
 I. L. Finar, ‘Organic chemistry’, New York, AWL, Vol.1, 6th Ed., 1973.
 M. B Smith and J. March, ‘March’s Advanced organic chemistry’, New Jersy, Wiley, 6th Ed.,
2007.
 Peter Sykes, ‘A guide book to mechanism in organic chemistry’ New Delhi, Orient Longman,
1997.
 Ernst L. Elliel, ‘Stereochemistry of organic compounds’, New Jersy, Wiley, 1st Ed., 1994.
 D. Nasipuri, ‘Stereochemistry of organic compounds: Principles and Applications’, New
Delhi, New Age International, 2nd Ed., 1994.
 T. H. Lowry and K. S. Richardson, ‘Mechanism and theory in organic reactions’, New York,
AWL, 3rd Ed., 1998.
 Clayden, Greeves, Warren, Wothers, ‘Organic chemistry’, UK, Oxford University Press; 2nd
Ed, 2012.
 Reinhard Buckner, ‘Advanced organic reaction’, New Delhi, Academic press, Elsevier, 1st
Ed., 2003.
 Mundy, Ellerd and Favaloro Jr, ‘Name reaction and reagents in organic synthesis’ New Jersy,
Wiley, 2nd Ed., 2005.
 Ian Fleming, ‘Frontier Orbitals and organic chemical reactions’, New Jersy, Wiley, 1978.
 E. V. Anslyn and D. A. Dougherty, ‘Modern physical organic chemistry’, California,
University of Science Books, 2006.
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Semester VII ORGANIC LAB: Credit 01
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Course: CC15 (PR)
15 Lecture
Course Objectives.
To learn the theory, principles and practical skill of performing green reactions of common organic
reactions within laboratory time scale. .
1. Green photochemical reaction (Photo reduction of benzophenene to benzopinacol)

2. Radical Coupling reaction (Prepation of 1,1,-bis-2-naphthol)
3. Solvent–free Reaction (Microwave –assisted ammonium formate mediated Knovenegal
reaction)
4. Dibenzal acetone from acetone and benzaldehyde.
5. Cannizzro reaction: Using p-chlorobenzaldehyde as the substrate.
Reference Books:
 An Advanced Course in Practical Chemistry – A. K. Nad, B. Mahapatra & A. Ghoshal
 Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis 6th Ed., Pearson, 2009
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Semester VII INORGANIC: Credit 03
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Course: CC 16(TH)
Total Lecture 40
Course Objective: Study of polyhedral Boron Compounds, STYX number, metal carbonyls,
Ferrocene and introduction to transition metal chemistry and Carbene complexes.
CC16.1 Boron Clusture: Clusters of boranes: Wade,s rules. ‘styx’ system of numbering,
nomenclature; carboranes, metalloboranes (5 Lecture)
CC16.2 Metal carbonyls: 18 electron rule, electron count of mononuclear, polynuclear and
substituted metal carbonyls of 3d series. Structures of mononuclear and binuclear carbonyls of
Cr, Mn, Fe, Co and Ni using VBT. -acceptor behaviour of CO (MO diagram of CO to be
discussed), synergic effect and use of IR data to explain extent of back bonding.
(10 Lecture)
CC16.3 Metal Nitrosyls: Linear, Bent and polynuclear nitrosyls, Calculate EAN of metallic
nitrosyls, Synthesis, structure and properties of [Fe(H2O)5NO]SO4 and Na2[Fe(CN)5NO].
(10 Lecture)
CC16.4Transition Metal Chemistry
General group trends with special reference to electronic configuration, variable valency,
magnetic and catalytic properties, ability to form complexes. Stability of various oxidation
states. Difference between the first, second and third transition series.
(10 Lecture)
CC16.5 Carbene:
Carbene (Fischer and Schrock), Synthess, Structure, Reactivity, Difference between Fischer and Schrock
Carbene. Carbyne complexes (synthesis, bonding and reactivity).
(05 Lecture)
Reference Books:
 Svehla, G. Vogel's Qualitative Inorganic Analysis, 7th Edition, Prentice Hall, 1996.
 Cotton, F.A.G.; Wilkinson &Gaus, P.L. Basic Inorganic Chemistry 3rdEd.; Wiley India,
 Huheey, J. E.; Keiter, E.A. & Keiter, R.L. Inorganic Chemistry, Principles of
StructureandReactivity4thEd., HarperCollins1993, Pearson,2006.
 Sharpe, A.G. Inorganic Chemistry, 4thIndian Reprint (Pearson Education) 2005
 Douglas, B. E.; McDaniel, D.H. & Alexander, J.J. Concepts and Models in
InorganicChemistry3rdEd.,JohnWileyandSons,NY,1994.
 Greenwood, N.N. & Earnshaw, A. Chemistry of the Elements, Elsevier 2ndEd, 1997
(Ziegler Natta Catalyst and Equilibriain Grignard Solution).
 Lee, J.D. Concise Inorganic Chemistry 5thEd., John Wiley and sons 2008.
 Powell,P.PrinciplesofOrganometallicChemistry,ChapmanandHall,1988.
 Shriver, D.D. & P. Atkins, Inorganic Chemistry 2ndEd., Oxford University Press, 1994.
 Basolo, F. & Pearson, R. Mechanisms of Inorganic Reactions: Study of Metal
Complexes in Solution2ndEd., JohnWiley&SonsInc;NY.
 Purcell,K.F.& Kotz,J.C.,InorganicChemistry,W.B.SaundersCo.1977
 Miessler, G. L. & Tarr, D.A. Inorganic Chemistry 4thEd., Pearson, 2010.
 Collman, J. P. et al. Principles and Applications of Organotransition Metal Chemistry.
MillValley, CA: University Science Books,1987.
 Crabtree,R.H. The Organometallic Chemistry of the Transition Metals. New York, NY:
JohnWiley,2000.
--------------------------------------------------------------------------------------------------
Semester VII INORGANIC LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC16 (PR)
15 Lecture
Course Outcome: Learning of qualitative semi-micro analysis of ions from ionic mixture and
introduction to spot test of various inorganic compounds.
1. Estimation of Al(III) by precipitating with oxine and weighing as Al(oxine)3

aluminium oxinate).
Synthesis and Characterization of inorganic compounds
2. [Cu(en)2(H2O)2]SO4
3. [Mn(acac)3] /Mn(OAc)33
4. [Ni(en)2]Cl2
Reference Books:
--------------------------------------------------------------------------------------------------
Semester VII PHYSICAL: Credit 03
--------------------------------------------------------------------------------------------------
Course: DSE-3(TH)
Total Lecture 40
Course Objective: Learning the spectroscopy and structural property of molecule, moment of inertia,
mode of vibration and vibrational energy of a molecule, zero-point energy of a quantum oscillator,
Raman scattering, wave function and energy of rigid rotor and hydrogen like systems
DS3.1 Quantum Chemistry-II

Qualitative treatment of simple harmonic oscillator model of vibrational motion: Setting up of
Schrödinger equation and discussion of solution and wavefunctions. Vibrational energy of
diatomic molecules and zero-point energy.
Angular momentum: Commutation rules, quantization of square of total angular momentum and
z-component. Particle in a ring and its application.
Rigid rotator model of rotation of diatomic molecule. Schrödinger equation, transformation to
spherical polar coordinates. Separation of variables. Spherical harmonics. Discussion of
solution.
Qualitative treatment of hydrogen atom and hydrogen-like ions: setting up of Schrödinger
equation in spherical polar coordinates, radial part, quantization of energy (only final energy
expression). Average and most probable distances of electron from nucleus, shapes of orbitals.
(18 Lectures)
DS3.2 Molecular Spectroscopy - I:
Interaction of electromagnetic radiation with molecules and various types of spectra; Born-
Oppenheimer approximation.
Rotational spectroscopy: Selection rules, intensities of spectral lines, determination of bond
lengths of diatomic and linear triatomic molecules, isotopic substitution.
Vibrational spectroscopy: Classical equation of vibration, computation of force constant,
amplitude of diatomic molecular vibrations, anharmonicity, Morse potential, dissociation
energies, fundamental frequencies, overtones, hot bands, degrees of freedom for polyatomic
molecules, modes of vibration, concept of group frequencies.
Vibration-rotation spectroscopy: diatomic vibrating rotator, P, Q, R branches, variation of
rotational constant and spacings of P, R lines with vibrational quantum number
Raman spectroscopy: Qualitative treatment of Rotational Raman effect; Effect of nuclear spin,
Vibrational Raman spectra, Stokes and anti-Stokes lines; their relative intensities, rule of mutual
exclusion.
(16 Lectures)
DS3.3 Photochemistry
Characteristics of electromagnetic radiation, Lambert-Beer’s law and its limitations, physical
significance of absorption coefficients. Laws, of photochemistry, quantum yield, actinometry,
examples of low and high quantum yields, photochemical equilibrium, photosensitized
reactions, quenching. Role of photochemical reactions in biochemical processes, photostationary
states, chemiluminescence.
(6 Lectures)
Reference Books:
 Banwell, C. N. & McCash, E. M. Fundamentals of Molecular Spectroscopy 4thEd. Tata
McGraw-Hill: New Delhi(2006).
 Chandra,A.K. Introductory Quantum Chemistry Tata McGraw-Hill(2001).
 House,J.E. Fundamentals of Quantum Chemistry2ndEd. Elsevier: USA(2004).
 Kakkar,R. Atomic & Molecular Spectroscopy: Concepts & Applications, Cambridge
University Press(2015).
 Lowe,J.P. & Peterson,K. Quantum Chemistry, Academic Press(2005).
-------------------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------------------------------------
Semester VII PHYSICAL LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: DSE-3 (PR)
15 Lecture
Course Objective: Learning the validation of Lambert-Beer’s law and some colourimetric
determination.
1. Verify Lambert-Beer’s law and determine the concentration of

CuSO4 / KMnO4 / K2Cr2O7 in a solution of unknown concentration
2. Determine the amount of iron present in a sample using 1,10-phenathroline.
3. Determine the dissociation constant of an indicator (phenolphthalein or bromocresol
green)..
Reference Books
 Khosla,B.D.;Garg,V.C.&Gulati,A., Senior Practical Physical Chemistry, R. Chand
&Co.:New Delhi(2011).
 Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical
Chemistry8thEd.;McGraw-Hill:NewYork(2003).
 Halpern,A.M.&McBane,G.C .Experimental Physical Chemistry3rdEd.;W.H.
Freeman & Co.:NewYork(2003).
-------------------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------------------------------------
Semester VII ORGANIC: Credit 03
--------------------------------------------------------------------------------------------------
Course: DSE-4(TH)
Total Lecture 40
Course objective (CO): To Impart advanced knowledge on organic reaction mechanism and their
synthetic transformation. To understand the chemistry of heterocyclic molecules.
DS4.1 Organic synthetic methods-I

Chemistry of organo silicon and sulfur towards organic synthesis.
Organo silicon: Preparation, α, β, γ, ω effect of Si, C vs. Si reaction, SN2—Si reactions, Brook
rearrangement, Silyl Protection, Silyl enol ether, Mukaiyama Aldol Reaction, Silyl ketene acetals,
Peterson Olefination,
(10 Lecture)
Organo Sulfur: Preparation, Acidity, basicity, oxidation state of organosulfur, nucleophilic reaction,
NGP (mustard gas), Pummerer reaction, Julia-Lythgoe Olefination, Corey-Chaykovsky Reaction,
Sulfur Ylides, Reactions with stabilized sulfur Ylide, Swern oxidation, Kornblum Oxidation, Dimethyl
Sulfoxide–Iodine, Dimethyl Sulfoxide–induced oxidation,
(10 Lecture)
DS4.2 Organic synthetic methods-II
Organo tin and boron compounds: Stille Coupling reaction. Reactions of Tributyltinhydride (TBTH).
Hydroboration, Reaction of alpine borane, CBS reduction
Multi component reactions-early examples: Ugi reaction, Passerini reaction, Biginelli Condensation,
Baylis-Hillman reaction, Olefin metathesis (simple examples).
(10 Lecture)
DS4.4 Heterocyclic Compounds:
General approaches to heterocycle synthesis using cyclisation and cycloaddition routes, Umpolung,
synthon approach; Stork annulation reactions. Synthesis, reactivity, and uses of the following
Heteroaromatics with one two heteroatoms. Pyridazine, Pyrimidine, Pyrazine, Imidazole, Pyrazole,
Oxazole, Isooxazole, Thiazole, Iso-Thiazole
(10 Lecture)
References
 L. Finar, ‘Organic chemistry’, New York, AWL, Vol.1, 6th Ed., 1973.
 M. B Smith and J. March, ‘March’s Advanced organic chemistry’, New Jersy, Wiley, 6th Ed.,
2007.
 Peter Sykes, ‘A guide book to mechanism in organic chemistry’ New Delhi, Orient Longman,
1997.
 Ernst L. Elliel, ‘Stereochemistry of organic compounds’, New Jersy, Wiley, 1st Ed., 1994.
 D. Nasipuri, ‘Stereochemistry of organic compounds: Principles and Applications’, New
Delhi, New Age International, 2nd Ed., 1994.
 T. H. Lowry and K. S. Richardson, ‘Mechanism and theory in organic reactions’, New York,
AWL, 3rd Ed., 1998.
 Clayden, Greeves, Warren, Wothers, ‘Organic chemistry’, UK, Oxford University Press; 2nd
Ed, 2012.
 Reinhard Buckner, ‘Advanced organic reaction’, New Delhi, Academic press, Elsevier, 1st
Ed., 2003.
 Mundy, Ellerd and Favaloro Jr, ‘Name reaction and reagents in organic synthesis’ New Jersy,
Wiley, 2nd Ed., 2005.
 Ian Fleming, ‘Frontier Orbitals and organic chemical reactions’, New Jersy, Wiley, 1978.
 E. V. Anslyn and D. A. Dougherty, ‘Modern physical organic chemistry’, California,
University of Science Books, 2006.
 William Carruthers and Ian Coldhan, ‘Modern methods in organic synthesis’, Cambridge
University Press, UK, 4th Ed., 2004.
 Jie Jack Li, ‘Name reaction: a collection of detailed organic mechanism’, New York, Springer,
2009.
 F. A. Carry and R. J. Sundberg, ‘Advanced organic chemistry’, New York, Springer, 4th Ed.,
2000.
-----------------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------------------------------------
Semester VII ORGANIC LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: DSE-4 (PR)
Total Lecture 15
Course Objective:
To learn the theory, principles and practical skill of performing green reactions of common chemical
reactions within laboratory time scale and column chromatographic separation. .
1.. Tetrabutylammonium tribromide (TBATB) and its application

2. 1-methyl-3-pentyl-imidazolium bromide (pmIm) Br and its application
3. Adipic acid from cyclohexanol by Chromic acid oxidation
4. Preparation of p-Chlorotoluene from p-toluidine by sandmayer reaction
5. Column Chromatographic separation of mixture of dyes. ( Methyl orange and indigo)
6. Column Chromatographic separation of mixture of 0 & p – aminophenol.
Reference Books:
 Findlay’s Practical Chemistry – Revised by J.A. Kitchner (V edition)
 Text Book of Quantitative inorganic analysis: A.I. Vogel.
 Experimental Physical Chemistry: R. C. Das and B. Behera
 Practical Physical Chemistry: B. Viswanathan and P.S. Raghavan
 Experimental Physical Chemistry:V.D. Athawale and Parul Mathur.
 Systematic Experimental Physical Chemistry: S.W. Rajbhoj and T.K. Chondhekar
 Advanced practicals in physical chemistry-Datar and Doke.
 Practical Physical Chemistry- B. D. Khosla, V. C. Garg, A. Gulati
--------------------------------------------------------------------------------------------------
Semester VII Interdisciplinary Chemistry: Credit 03
--------------------------------------------------------------------------------------------------
Course: DSM-A(TH)
Total Lecture 40
Course Objective (CO): To learn the theory, principles and applications of various supramolecular
ensembles and nanomaterials and their functions, Green chemistry, Nanometaliic chemistry and
Chemistry of Inorganic materials.
DMA1.1 Supramolecular chemistry

Origin of supramolecular chemistry- “Chemistry beyond the molecules”. Concepts and terminology of
supramolecular chemistry. Crown ether and cyclodextrins and their application. Moleculer
recognition. Nature and types of supramolecular interactions: (Hydrogen bonding, van-der-Waal
interactions, electrostatic interactions, hydrophobic interactions, π-stacking, C-H- interactions etc.)
Synthetic design of receptor.
(13 Lecture)
DMA1.2 Green chemistry

The current status of chemistry and the environment. Twelve principles of green chemistry, green
synthetic methods, green reagents, green solvents and reaction conditions, green catalysis, organic
reactions in aqueous medium, organic reactions using supporting reagents, solvent – free organic
reactions, MCR reaction, microwave assisted organic reactions, use of ionic liquid, supercritical fluids
and nanoparticles as catalyst.
(12 Lecture)
DMA1.3 Nanomaterial Chemistry
Concept of nanomaterial, Preparation of nanoparticles: Synthesis of nanoparticles, properties of
nanoparticles, variation of properties with size, Applications of nanoparticles, Charactrization of nano-
materials by transmission electron microscope (TEM), Scanning Electron Microscope (SEM), Atomic
Force Microscope (AFM), Dynamic Light Scattering (DLS),
(10 Lecture)
DMA1.4 Inorganic materials
Inorganic crystal engineering and design principle of metal organic framework (MOF) and
inorganicorganic hybrid materials. Application of MOFs in material science.
(05 Lecture)
Reference Books
 Steven Rose, (1999), The Chemistry of Life, New Edition, Penguin Press Science.
 VK Ahluwalia, (2015), Biomolecules: Chemistry of Living System, manakin Press.
 Editors: Songjun Li, Peter Lieberzeit, Sergey Piletsky, Anthony Turner, Smart Polymer
Catalysts and Tunable Catalysis (2019), ISBN: 9780128118405.
 Srinivasan Palaniappan and Amalraj John, (2008), Conjugated Polymers as Heterogeneous
Catalyst in Organic Synthesis, 12, 98-117, DOI: 10.2174/138527208783330037
 Muralisrinivasan Natamai Subramanian (2019), Plastics Waste Management, Wiley,
DOI:10.1002/9781119556176
 D. Frenkel and B. Smith, (2002), Understanding Molecular Dynamics Simulations,1st
Edition, Academic Press
 Mark Tuckermann, (2010), Statistical Mechanics and Molecular Simulations, 1st Edition,
Oxford University
 Purcell,K.F&Kotz,J.C.InorganicChemistryW.B.SaundersCo,1977.
 Huheey,J.E.,InorganicChemistry,PrenticeHall,1993.
 Lippard,S.J.&Berg,J.M.PrinciplesofBioinorganicChemistryPanimaPublishing
Company1994.
 Cotton,F.A.&Wilkinson,G,AdvancedInorganicChemistryWiley-VCH,1999.
-----------------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------------------------------------
Semester VII Interdisciplinary Chemistry LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: DSM-A (PR)
15 Lectures
Course Objective:
To learn of common chemical reactions within laboratory time scale.
1. Preparation and purification of tris-triphenylphosphine copper(I) nitratee.

2. Preparation and purification of cis and trans-dichlorobis (ethylenediamine) cobalt(III) chloride
3. Preparation and Purification of Aluminium Oxinate Al (Oxine)3
4. Determination of the activation energy of viscous flow of polymer solutions using a
viscometer
5. Determination of molecular weight of polymers from viscosity measurements
Reference Books:
 Findlay’s Practical Chemistry – Revised by J.A. Kitchner (V edition)
 Text Book of Quantitative inorganic analysis: A.I. Vogel.
 Experimental Physical Chemistry: R. C. Das and B. Behera
 Practical Physical Chemistry: B. Viswanathan and P.S. Raghavan
 Experimental Physical Chemistry:V.D. Athawale and Parul Mathur.
 Systematic Experimental Physical Chemistry: S.W. Rajbhoj and T.K. Chondhekar
 Advanced practicals in physical chemistry-Datar and Doke.
 Practical Physical Chemistry- B. D. Khosla, V. C. Garg, A. Gulati
--------------------------------------------------------------------------------------------------
Semester VIII INORGANIC: Credit 03
--------------------------------------------------------------------------------------------------
Course: CC17 (TH)
Total Lecture 40
Course Objectives: Knowledge about Lanthide and Actinide metals, Organometallic
catalyst, Magnetochemistry and Bioinorganic Chemistry.
CC17.1 Lanthanoids and Actinoids:
Electronic configuration, oxidation states, colour, spectral and magnetic properties, lanthanide
contraction, separation of lanthanides (ion-exchange method only).
(10 Lectures)
CC17.2 Catalysis by Organometallic Compounds
Study of the following industrial processes and their mechanism:
i) Alkene hydrogenation (Wilkinsons Catalyst), ii) Hydroformylation (Cosalts), iii) Wacker

Process, iv) Synthetic gas oline (Fischer Tropsch reaction), v) Synthesis gas by metal carbonyl
complexes, vi) Ziegler – Natta Catalyst
(10 Lectures)
,
CC17.3 Magnato chemistry: Gauss s law and magnetic induction, Susceptibility, Curie law, Curie-
Weiss law, Diamagnetiss, Paramagnetism, Ferromagnetism, Antiferromagnetism, Type of
antiferromagnetism, Orbital contribution and Spin-orbit coupling.
(10 Lectures)
CC17.4 Bioinorganic Chemistry: Transport and storage of dioxygen- active site structure and
biofunctions of O2 – uptake proteins: myoglobin, hemerythrin and hemocyanin.Model synthetic
dioxygen complexes. Electron transport protein: Fe-S proteins, Zn-containing protein, Cytochromes.
(10 Lectures)
Reference Books:
 Svehla, G. Vogel's Qualitative Inorganic Analysis, 7th Edition, Prentice Hall, 1996.
 Cotton, F.A.G.; Wilkinson &Gaus, P.L. Basic Inorganic Chemistry 3rdEd.; Wiley India,
 Huheey, J. E.; Keiter, E.A. & Keiter, R.L. Inorganic Chemistry, Principles of
StructureandReactivity4thEd., Harper Collins1993, Pearson,2006.
 Sharpe, A.G. Inorganic Chemistry, 4thIndian Reprint (Pearson Education) 2005
 Douglas, B. E.; McDaniel, D.H. & Alexander, J.J. Concepts and Models in
InorganicChemistry3rdEd.,JohnWileyandSons,NY,1994.
 Greenwood, N.N. & Earnshaw, A. Chemistry of the Elements, Elsevier 2ndEd, 1997
(Ziegler Natta Catalyst and Equilibriain Grignard Solution).
 Lee, J.D. Concise Inorganic Chemistry 5thEd., John Wiley and sons 2008.
--------------------------------------------------------------------------------------------------
Semester VIII INORGANIC LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: CC17 (PR)
15 Lectures
Course Outcome: Learning of qualitative semi-micro analysis.
Quantitative analysis
1. Gravimetric estimation of Zn(II) as Zn(NH4)(PO4)
2. Gravimetric estimation of Ba(II) as BaSO4
3-
3. Gravimetric estimation of PO4 as (Pb)3(PO4)2
Reference Books:
--------------------------------------------------------------------------------------------------
Semester VIII PHYSICAL: Credit 03
--------------------------------------------------------------------------------------------------
Course: DSM-B(TH)
Total Lecture 40
Course Objective: To develop an understanding of UV-visible spectra, fluorescence and

phosphorescence and their mechanism, spin-resonance spectroscopy, fundamentals of statistical
mechanics and develop concepts of degrees of freedom and distillation of liquids, using the phase
rule
DMB1.1 Molecular Spectroscopy - II:
Electronic spectroscopy: Electronic transitions, singlet and triplet states, Franck-Condon principle
and vibrational fine structure, fluorescence and phosphorescence, dissociation and predissociation,
calculation of electronic transitions of polyenes using free electron model.
Nuclear Magnetic Resonance (NMR) spectroscopy: Principles of NMR spectroscopy, Larmor

precession, chemicalshift, differentscales, spin-spincoupling, interpretation of 1H-NMR
spectra of organic molecules.
Electron Spin Resonance (ESR) spectroscopy: Principle, hyperfine structure, ESR of simple
radicals.
(12 Lectures)
DMB1.2 Statistical Mechanics:
Probability distribution, Stirling approximation, microstate and microstate, weights and
configurations, thermodynamic probability, Boltzmann distribution (with derivation), Bose Einstein
and Fermi-Dirac statistics (without derivation, basic ideas only) partition function and its
significance, rotational, vibrational and electronic partition functions, relationship between partition
function and thermodynamic properties
(12 Lectures)
DMB1.3 Phase Equilibria:
Concept of phases, calculation of components and degrees of freedom, derivation of Gibbs
Phase Rule for nonreactive and reactive systems; dependence of chemical potential on
temperature for different phases and effect of pressure, Clausius-Clapeyron equation and its
applications to understanding of solid- liquid, liquid-vapour and solid-vapour equilibria, triple
point, phase diagrams of one component systems (H2O, CO2 and S) with applications
Phase diagrams for systems of solid-liquid equilibria involving eutectic, congruent and
incongruent melting points.
Binary solutions: Gibbs-Duhem-Margules equation and Konowaloff rule, its derivation and
applications to fractional distillation of binary miscible liquids (ideal and nonideal), lever rule,
tie line, azeotropes, partial miscibility of liquids, CST, principle of steam distillation
(16 Lectures)
Reference Books:
 Banwell, C. N. & McCash, E. M. Fundamentals of Molecular Spectroscopy 4thEd. Tata
McGraw-Hill: NewDelhi(2006).
 House,J.E. Fundamentals of Quantum Chemistry2ndEd.Elsevier: USA(2004).
 Kakkar,R.Atomic & Molecular Spectroscopy: Concepts & Applications, Cambridge
University Press(2015).
 Castellan, G. W. Physical Chemistry, 4thEd., Narosa (2004).
 Engel, T. & Reid, P. Physical Chemistry 3rdEd., Prentice-Hall (2012).
-------------------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------------------------------------
Semester VIII PHYSICAL LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: DSM-B (PR)
15 Lecture
Course Objective: Learning about the Critical Solution Temperature (CST) and their determination
and study of kinetics.
1. Determination of critical solution temperature (CST) of phenol-water system

2. Effect of added solutes on miscibility of phenol and water and on the CST
3. Determine the concentrations of KMnO4 and K2Cr2O7in a mixture.
4. Study the kinetics of interaction of crystal violet/ phenolphthalein with NaOH
Reference Books
 Khosla,B.D.;Garg,V.C.&Gulati,A.,SeniorPracticalPhysicalChemistry,R.
Chand&Co.:New Delhi(2011).
 Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical
Chemistry8thEd.; McGraw-Hill: NewYork(2003).
 Halpern,A.M. & McBane,G.C.ExperimentalPhysicalChemistry3rdEd.; W.H.
Freeman &Co.: New York(2003).
--------------------------------------------------------------------------------------------------
Semester VIII DSE-5 THEORY: Credit 03
--------------------------------------------------------------------------------------------------
Course: DSE-5(TH)
Total Lecture 40
Course objectives : understanding of green chemistry in advance level, electrochemical method of
detection and idea about industrial gases and chemicals.
DS5.1 Green Chemistry -2
Surfactants for carbon dioxide – replacing smog producing and ozone depleting solvents with CO2 for
precision cleaning and dry cleaning of garments.
Designing of Environmentally safe marine antifoulant.
Rightfit pigment: synthetic azopigments to replace toxic organic and inorganic pigments.
Use of catalytic reagents (wherever possible) in preference to stoichiometric reagents; catalysis and
green chemistry, comparison of heterogeneous and homogeneous catalysis, biocatalysis, asymmetric
catalysis and photocatalysis.
Prevention of chemical accidents designing greener processes, inherent safer design, principle of ISD
“What you don’t have cannot harm you”, greener alternative to Bhopal Gas Tragedy (safer route to
carcarbaryl) and Flixiborough accident (safer route to cyclohexanol) subdivision of ISD,
minimization, simplification, substitution, moderation and limitation.
( 20 Lectures)
DS5.2 Electroanalytical Methods:
Potentiometry & Voltammetry
( 5 Lectures)
DS5.3 Industrial Gases and Inorganic Chemicals

Industrial Gases: Large scale production, uses, storage and hazards in handling of the following
gases: oxygen, nitrogen, argon, neon, helium, hydrogen, acetylene, carbon monoxide, chlorine,
fluorine, sulphur dioxide and phosgene.
Inorganic Chemicals: Manufacture, application, analysis and hazards in handling the following
chemicals: hydrochloric acid, nitric acid, sulphuric acid, caustic soda, common salt, borax,
bleaching powder, sodium thiosulphate, hydrogen peroxide, potash alum, chrome alum,
potassium dichromate and potassium permanganate.
(15 Lectures)
--------------------------------------------------------------------------------------------------
Semester VIII DSE-5 LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: DSE-5 (PR)
Total Lecture 15
Course Objectives: Understanding of estimation of pollutants quantitatively and preparation of boron
compounds.
1. Study of some of the common bio-indicators of pollution.
2. Preparation of borax/ boric acid.
3. Determination of acetic acid in commercial vinegar
4. Determination of alkali content of antacid tablets using HCl
Reference Books
1. Practical Organic Chemistry, 4th edition, F.G. Mann and B.C. Saunders , Pearson
Education Limited , UK
3. Practical Organic Chemistry, A.K. Manna, Books And Allied ( P) LTD. Kolkata -700010,
2018
4. Advanced Practical Chemistry, R. Mukhopadhyay and P. Chatterjee, Books And Allied (
P) LTD. Kolkata -700010, 2016
--------------------------------------------------------------------------------------------------
Semester VIII DSE-6 THEORY: Credit 03
--------------------------------------------------------------------------------------------------
Course: DSE-6(TH)
Total Lecture 40
Course Objectives: Understanding of qualitative and quantitative aspects of analysis, Industrial
metallurgy, atomic spectroscopy and various separation techniques
DS6.1 Qualitative and quantitative aspects of analysis:

Sampling, evaluation of analytical data, errors, accuracy and precision, methods of their
expression, normal law of distribution if indeterminate errors, statistical test of data; F, Q and t
test, rejection of data, and confidence intervals.
(5 Lectures)
DS6.2Theoretical Principles in Qualitative Analysis (H2S Scheme)

Basic principles involved in analysis of cations and anions and solubility products, common ion
effect. Principles involved in separation of cations into groups and choice of group reagents.
Interfering anions (fluoride, borate, oxalate and phosphate) and need to remove them after
Group-II.
(12-lectures)
DS6.3 Industrial Metallurgy
Nuclear stability and nuclear binding energy. Meson exchange theory. Nuclear models (elementary
idea): Nuclear Forces, magic numbers. Nuclear spin and nuclear isomerism, Nuclear Reactions:
fission, fusion and spallation. Radio chemical methods: Applications of radioactivity, Tracer
techniques principles of determination of age of rocks and minerals, radio carbon dating, hazards of
radiation and safety measures.
( 8-Lectures)
DS6.4 Atomic spectroscopy:
Atomic absorption, Atomic emission, and Atomic fluorescence.
Excitation and getting sample into gas phase (flames, electrical discharges, plasmas), Wavelength
separation and resolution (dependence on technique), Detection of radiation (simultaneous/scanning,
signal noise), Interpretation.
( 5-Lectures)
DS6.5 Separation techniques-2
Chromatography: Gas chromatography, liquid chromatography, supercritical fluids, Importance of
column technology (packing, capillaries), Separation based on increasing number of factors
(volatility, solubility, interactions with stationary phase, size, electrical field).
( 10-Lectures)
--------------------------------------------------------------------------------------------------
Semester VIII DSE-6 LAB: Credit 01
--------------------------------------------------------------------------------------------------
Course: DSE-6 (PR)
15 Lecture
Course Objectives: Learning of estimation of pollutants and error analysis
1. Estimation of calcium in milk
2. To determine the solubility of KNO3 in water in different temperature and to plot the
solubility curve
3. Error analysis
Reference Books
1. Practical Organic Chemistry, 4th edition, F.G. Mann and B.C. Saunders , Pearson
Education Limited , UK
3. Practical Organic Chemistry, A.K. Manna, Books And Allied ( P) LTD. Kolkata -700010,
2018
4. Advanced Practical Chemistry, R. Mukhopadhyay and P. Chatterjee, Books And Allied (
P) LTD. Kolkata -700010, 2016
--------------------------------------------------------------------------------------------------
Semester VIII DSE-7 PROJECT: Credit 04
--------------------------------------------------------------------------------------------------
Course:
OPTION: -A
Honours with Research Project: Total Credit: 12

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SYLLABUS FOR U.G.

II CC-2, Organic Paper -1, Gr. B SEC-2 (Pr)

III CC-3, Physical Paper -2, Gr. A SEC-3 (Th)

 Atkins, P.W.& Paula, J. Physical Chemistry,10thEd., Oxford University Press,2014.

 Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis 6thEd., Pearson, 2009.

GEA1.1 Chemical Energetics

CHEMISTRY OF COSMETICS & PERFUMERY PRODUCTS

CC2.1 Bonding and physical properties

1. Checking the calibration of the thermometer

CC3.1 Gaseous state:

1. Determine the strength of unknown solution of acetic acid.

2. Surface tension measurements.

Any other experiment carried out in the class.

CC4.1 Stereochemistry – III

CC5.1 Chemical Bonding:

 J., Mendham, A. I. Vogel’s Quantitative Chemical Analysis 6thEd., Pearson, 2009.

CC6.1 Chemical Thermodynamics - II:

i) Oxidation of ethanol (Iodoform reaction).

1. Estimation of oxalic acid by titrating with KMnO4.

 Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis 6thEd., Pearson, 2009.

CC9.1 Solutions and Colligative Properties:

Nernst distribution law

Study the kinetics of the following reactions.

Isomerism in coordination compounds: Structural Isomerism and classifications, Geometrical and

3. Analysis of Ores and Minerals

 Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis 6thEd., Pearson, 2009.

DS1.1. Green Chemistry-1

Ferrocene: Preparation and reactions (acetylation, alkylation, metallation, Mannich

Semester VI INORGANIC LAB: Credit 01

CC14.1 Pericyclic Reactions-1

CC15.1 Pericyclic Reaction

CC15.3 Stereochemistry and conformational analysis

1. Green photochemical reaction (Photo reduction of benzophenene to benzopinacol)

1. Estimation of Al(III) by precipitating with oxine and weighing as Al(oxine)3

DS3.1 Quantum Chemistry-II

1. Verify Lambert-Beer’s law and determine the concentration of

DS4.1 Organic synthetic methods-I

1.. Tetrabutylammonium tribromide (TBATB) and its application

DMA1.1 Supramolecular chemistry

DMA1.2 Green chemistry

1. Preparation and purification of tris-triphenylphosphine copper(I) nitratee.

Study of the following industrial processes and their mechanism:

i) Alkene hydrogenation (Wilkinsons Catalyst), ii) Hydroformylation (Cosalts), iii) Wacker

Course Objective: To develop an understanding of UV-visible spectra, fluorescence and

DMB1.1 Molecular Spectroscopy - II:

Nuclear Magnetic Resonance (NMR) spectroscopy: Principles of NMR spectroscopy, Larmor

1. Determination of critical solution temperature (CST) of phenol-water system

3. Determine the concentrations of KMnO4 and K2Cr2O7in a mixture.

4. Study the kinetics of interaction of crystal violet/ phenolphthalein with NaOH

DS5.3 Industrial Gases and Inorganic Chemicals

DS6.1 Qualitative and quantitative aspects of analysis:

DS6.2Theoretical Principles in Qualitative Analysis (H2S Scheme)

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