455-0012 1Y Materialdocs MSDS 8810614292484 0 0
455-0012 1Y Materialdocs MSDS 8810614292484 0 0
455-0012 1Y Materialdocs MSDS 8810614292484 0 0
2017
Safety Data Sheet
According to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS
· Product Identifier
· Trade name: Battery Pack 452-6499 & 455-0012
· Article number: 452-6499, 455-0012
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the preparation Lithium based battery product
· 1.3 Details of the supplier of the Safety Data Sheet
· Manufacturer/Supplier:
ACR Electronics, Inc.
5757 Ravenswood Rd., Ft. Lauderdale, FL. 33312 USA
PHONE: (954)-981-3333
FAX: (954)-961-4403
WEBSITE: www.acrartex.com
E-MAIL: [email protected]
2 Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS05 corrosion
Eye Dam. 1 H318 Causes serious eye damage
…………………………………………………………………………………………..
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
C; Corrosive
R35: Causes severe burns
………………………………………………………………………………………….
Xn; Harmful
R20: Harmful by inhalation
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· Hazard description: Information references exposures to battery contents, and not exposures to
whole units. Exposures to whole units are unlikely to product health hazards. Note: The
hazards listed in this document reference only the contents of cells and/or batteries that are
leaking and/or ruptured. Undamaged cells and/or batteries possess no expected health or physical
hazards during normal use. Intentional abuse of cells or batteries increases the risk of harm or damage to
the product, to the user, and to surrounding materials and personnel. Do not attempt to open sealed cells
or batteries. Do not intentionally short-circuit cells or batteries. Do not expose these products to
temperatures exceeding the maximum manufacturers rating. Do not dispose of cells/batteries in landfills.
Please follow all manufacturer guidelines in the use, storage, and disposal of these products. Consult
manufacturer in cases of questions involving specific product usage. Do not short circuit, recharge,
puncture, incinerate, crush, force discharge or expose to temperatures above the specified range. Upon
severe mechanical, electrical or thermal abuse, the cell may vent with the expulsion of some of the
content.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company
and literature data. The classification is in accordance with the latest editions of international
substances lists, and is supplemented by information from technical literature and by
information provided by the company.
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· 2.2 Label elements
· Labeling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
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P303 +P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
· Additional information:
Information references exposures to battery contents, and not exposures to whole units.
Exposures to whole units are unlikely to product health hazards.
· Hazard description:
· WHMIS-symbols:
D1B - Toxic material causing immediate and serious toxic effects
D2B - Toxic material causing other toxic effects
E - Corrosive material
· HMIS—ratings (scale 0 – 4)
HEALTH *2
Health - *2
Fire = 0 FIRE 0
Reactivity = 0
REACTIVITY 0
3 Composition/information on ingredients
· 3.2 Mixtures
· Description: Mixture of substances listed below with nonhazardous additions
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· Dangerous Components:
CAS: 1313-13-9 manganese dioxide
EINECS: 215-202-6 25-50%
Xn R20/22
Index number: 025-001-00-3
Lithium
CAS: 7439-93-2 <10%
C R34; F R14/15
EINECS: 231-102-5
Index number: 003-001-00-4
Water-react. 1, H260
Skin corr. 1B, H314
· Additional information: For the wording of the listed risk phrases refer to section 16.
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· 4.2 Most important symptoms and effects, both acute and delayed
Gastric or intestinal disorders
Breathing difficulty
Coughing
Nausea
Profuse sweating
· Hazards:
Danger of gastric perforation.
Danger of pulmonary oedema.
· 4.3 indication of any immediate medical attention and special treatment needed
Note to Physician: Published reports recommend removal from the esophagus be done endoscopically
(under direct visualization). Batteries beyond the esophagus need not be retrieved unless there are signs
of injury to the GI tract or a large diameter battery fails to pass the pylorus. If asymptomatic, follow-up x-
rays are necessary only to confirm the passage of larger batteries. Confirmation by stool inspection is
preferable under most circumstances. For information on treatment, telephone (202) 625-3333 collect,
day or night. Various corrosive, harmful or toxic substances is possible in certain cases. These
substances may include lithium and/or fluoride salts; specific antidotes may be required in cases of
ingestion for lithium salts and in cases of oral/dermal/inhalation contact with fluorides. If fluoride contact
is suspected, calcium salts may be of value in treatment. Do not give ipecac.
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5 Firefighting measures
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· Additional information about design of technical facilities: No further data; see item 7
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
1313-13-9 manganese dioxide
109-99-9 tetrahydrofuran
110-71-4 1,2-dimethoxyethane
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Safety glasses
· Body protection: Not required under normal conditions of use.
· Limitation and supervision of exposure into the environment:
No further relevant information available.
· Risk management measures:
See Section 7 for additional information.
No further relevant information available.
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· Viscosity:
Dynamic: Not applicable
Kinematic: Not applicable
· Solvent content:
Organic solvents: Not determined
· Solids Content: Not determined
· 9.2 Other information: No further relevant information available
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11 Toxicological information
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12 Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
The product contains materials that are harmful to the environment.
· 12.2 Persistence and degradability
The product is partly biodegradale. Significant residuals remain. A part of the components are
biodegradable
· 12.3 Bioaccumulative potential:
Does not accumulate in organisms
· 12.4 Mobility in soil:
No further relevant information available.
· Additional ecological information:
· General notes:
The product contains materials that are harmful to the environment.
This statement was deduced from products with a similar structure or composition.
Avoid transfer into the environment.
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects:
No further relevant information available.
13 Disposal considerations
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
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14 Transport information
· 14.1 UN-Number
· DOT, ADR, IMDG, IATA UN3090
· 14.2 UN proper shipping name
· DOT, IMDG, IATA LITHIUM METAL BATTERIES.
· ADR 3090 LITHIUM METAL BATTERIES.
· 14.3 Transport hazard class(es)
· DOT, IMDG, IATA
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15 Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· United States (USA)
· SARA
· Section 355 (Extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients are listed.
· Proposition 65 (California):
· Chemicals known to cause cancer:
References to chemical components listed below are based on unbound respirable particles
and are not generally applicable to product as supplied.
1333-86-4 Carbon black
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic Categories
· EPA ( Environmental Protection Agency)
1313-13-9 Manganese dioxide D
7791-03-9 Lithium perchlorate NL
· IARC (International Agency for Research on Cancer)
109-99-9 Tetrahydrofuran A3
1333-86-4 Carbon black A4
· TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
1333-86-4 Carbon black
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
· Canada
· Canadian Domestic Substances Lisa (DSL)
All ingredients are listed.
· Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 1%)
108-32-7 Propylene carbonate
109-99-9 Tetrahydrofuran
1333-86-4 Carbon black
· 15.2 Chemical safety assessment: A chemical Safety Assessment has not been carried out.
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16 Other information
This information is based on our present knowledge. However, this shall not constitute a
guarantee for any specific product features and shall not establish a legally valid contractual
relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H260 In contact with water releases flammable gases which may ignite spontaneously.
H271 May cause fire or explosion; strong oxidiser.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H360FD May damage fertility. May damage the unborn child.
R11 Highly flammable.
R14/15 Reacts violently with water, liberating extremely flammable gases.
R19 May form explosive peroxides.
R20 Harmful by inhalation.
R20/22 Harmful by inhalation and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R36/37 Irritating to eyes and respiratory system.
R36/37/38 Irritating to eyes, respiratory system and skin.
R60 May impair fertility.
R61 May cause harm to the unborn child.
R9 Explosive when mixed with combustible material.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American
Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada) DNEL: Derived No-Effect Level
(REACH)
PNEC: Predicted No-Effect Concentration (REACH)
· Sources
SDS Prepared by: ChemTel Inc.
1305 North Florida Avenue,
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924
Intl. +01 813-248-0573
Website: www.chemtelinc.com
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