Carco, Inc.

- Safety Data Sheet SDS Revision Date: 04/01/2020

MM-150 all except Black, Red

1. Identification

1.1. Product identifier

Product Identity MM-150 all except Black, Red
Alternate Names MM-150 all except Black, Red

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use See Technical Data Sheet.

1.3. Details of the supplier of the safety data sheet

Company Name Carco, Inc
10333 Shoemaker
P.O. Box 13859
Detroit, Michigan, USA 48213
Emergency
24 hour Emergency Telephone No. ChemTel 1-800-255-3924 (MIS0001475)
International +01-813-248-0585
Customer Service: Carco, Inc Phone +1 (313) 925-9000
Fax +1 (313) 925-9602
Email: [email protected]

2. Hazard(s) identification

2.1. Classification of the substance or mixture

Flam. Liq. 2;H225 Highly Flammable liquid and vapor.
Eye Dam. 2A;H319 Causes serious eye irritation.
STOT SE 3;H336 May cause drowsiness or dizziness.
2.2. Label elements

Danger
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.
H336 May cause drowsiness and dizziness.
[Prevention]:
P210 Keep away from heat, sparks, open flames, and other ignition sources - No smoking.
P233 Keep container tightly closed.
P240 Ground, bond container and receiving equipment.
P241 Use explosion-proof electrical, ventilating, light, equipment.

Page 1 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust, fume, gas, mist, vapors, spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, eye protection, face protection.
[Response]:
P303+361+353 IF ON SKIN (or hair): Remove, take off immediately all contaminated clothing. Rinse skin with water, shower.
P304+312 IF INHALED: Call a poison center or doctor or physician if you feel unwell.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do -
continue rinsing.
P337+313 If eye irritation persists: Get medical advice or attention.
P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
P405 Store locked up.
[Disposal]:
P501 Dispose of contents or container in accordance with local and national regulations.

3. Composition/information on ingredients

This product contains the following substances that present a hazard within the meaning of the relevant State and Federal
Hazardous Substances regulations.
Ingredient/Chemical Designations Weight % GHS Classification Notes
Isopropyl Alcohol 50 - 75 Flam. Liq. 2;H225 ----
CAS Number: 0000067-63-0 Eye Irrit. 2;H319
STOT SE 3;H336
1-Methoxy-2-propanol 10 - 25 Flam. Liq. 3;H226 ----
CAS Number: 0000107-98-2 STOT SE 3;H336
Cellulose Nitrate 5 - 10 Flam. Sol. 1;H228 ----
CAS Number: 0009004-70-0
Titanium dioxide 5 - 10 Not Classified ----
CAS Number: 0013463-67-7
Ethanol 1-5 Flam. Liq. 2;H225 ----
CAS Number: 0000064-17-5
ETHYL ACETATE，EAC 1-5 Flam. Liq. 2;H225 ----
CAS Number: 0000141-78-6 Eye Irrit. 2;H319
STOT SE 3;H336

Rosin, Fumeric 1-5 Not Classified ----

CAS Number: 800680-57-9
Acetic acid, 1-methylethyl ester 1-5 Flam. Liq. 2;H225 ----
CAS Number: 0000108-21-4 Eye Irrit. 2;H319
STOT SE 3;H336

In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a
trade secret.
*PBT/vPvB - PBT-substance or vPvB-substance.
The full texts of the phrases are shown in Section 16.

Page 2 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

Section 4. First aid measures

4.1. Description of first aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.
Inhalation Move the exposed person to fresh air at once. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen. Get medical attention if any discomfort continues.
Eyes Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with
plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
attention if any discomfort continues.
Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin
cleanser.
Ingestion DO NOT INDUCE VOMITING! If swallowed, vomiting may occur spontaneously. If vomiting
occurs, keep head below hips to prevent aspiration into lungs. Rinse mouth thoroughly. Get medical
attention.
4.2. Most important symptoms and effects, both acute and delayed
Overview Treat symptomatically. Exposure to solvent vapor concentrations from the component solvents in
excess of the stated occupational exposure limits may result in adverse health effects such as mucous
membrane and respiratory system irritation and adverse effects on the kidneys, liver and central
nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be
absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with
possible reversible damage. Check section 2.2 (GHS Label Elements) for further details.
Inhalation May cause drowsiness or dizziness.
Eyes Causes serious eye irritation.

Section 5. Fire-fighting measures

5.1. Extinguishing media

Use foam, extinguishing powder, dry chemicals, or carbon dioxide. Water may be ineffective. Water may be used to keep fire
exposed containers cool.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition: None
Keep away from heat, sparks, open flames, and other ignition sources - No smoking.
Keep container tightly closed.
Ground, bond container and receiving equipment.
Use explosion-proof electrical, ventilating, light, equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust, fume, gas, mist, vapors, spray.

Page 3 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

5.3. Advice for fire-fighters

In the event of fire, wear full protective clothing and NIOSH Approved Self-contained breathing apparatus with full face piece
operated in the pressure demand or other positive pressure mode. Move container from fire area if it can be done without risk.
Use water to keep fire exposed containers cool and disperse vapors.
ERG Guide No. 129

Section 6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill or spillage in
a confined space evacuate the area and check that solvent vapor levels are below the Lower Explosive Limit before re-entering.
6.2. Environmental precautions
Do not allow spills to enter drains or waterways.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled
clothing and wash thoroughly before reuse.
6.3. Methods and material for containment and cleaning up
Avoid sparks, flames, heat and smoking. Ventilate. Wear necessary protective equipment. Absorb in vermiculite, dry sand or
earth and place into containers.
Small Spill: Use a non-combustible material like vermiculite, sand or earth to soak up product and place in a container for later
disposal.

Section 7. Handling and storage

7.1. Precautions for safe handling

Handle containers carefully to prevent damage and spillage.
Keep in containers lightly closed in a cool, well ventilated place. Do not store with oxidizing agents or acids. Keep in the original
container. Avoid direct sunlight
Check section 2.2 (GHS Label Elements) for further details. - [Prevention]:
7.2. Conditions for safe storage, including any incompatibilities
Store in a cool dry area, away from heat, sparks and open flame.
Keep containers sealed when not in use.
Store out of direct sunlight.
Store in a cool dry place.
Incompatible materials: Store away from oxidizers and acids.
Check section 2.2 (GHS Label Elements) for further details. - [Storage]:
7.3. Specific end use(s)
No data available.

Page 4 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

Section 8. Exposure controls / personal protection

8.1. Control parameters

Exposure
CAS No. Ingredient Source Value
0000064-17-5 Ethanol OSHA TWA 1000 ppm (1900 mg/m3)
ACGIH No Established Limit
NIOSH TWA 1000 ppm (1900 mg/m3)
0000067-63-0 Isopropyl Alcohol OSHA TWA 400 ppm (980 mg/m3) STEL 500 ppm
ACGIH TWA: 200 ppm STEL: 400 ppm
NIOSH TWA 400 ppm (980 mg/m3) ST 500 ppm (1225 mg/m3)
0000107-98-2 1-Methoxy-2-propanol OSHA No Established Limit
ACGIH 100 ppm STEL
NIOSH TWA 100 ppm (360 mg/m3) ST 150 ppm (540 mg/m3)
0000108-21-4 Acetic acid, 1-methylethyl ester OSHA TWA 250 ppm (950 mg/m3)
ACGIH TWA: 100 ppm STEL: 200 ppm
NIOSH no established RELs
0000141-78-6 ETHYL ACETATE，EAC OSHA TWA 400 ppm (1400 mg/m3)
ACGIH TWA: 150 ppm
NIOSH TWA 400 ppm (1400 mg/m3)
0009004-70-0 Cellulose Nitrate OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
0013463-67-7 Titanium dioxide OSHA TWA 15 mg/m3
ACGIH TWA: 10 mg/m3
NIOSH Footnote ca
800680-57-9 Rosin, Fumeric OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit

8.2. Exposure controls

Respiratory Atmospheric levels should be maintained below the exposure guideline. When respiratory protection
is required for certain operations, use an approved air-purifying respirator. The following should be
effective types of air purifying respirators: Organic vapor cartridge.
Eyes Wear safety glasses with side shields to protect the eyes. An eye wash station is suggested as a good
workplace practice.
Skin Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. All parts
of the body should be washed after contact. Use gloves chemically resistant to this material when
prolonged or frequently repeated contact could occur. Examples of preferred glove barrier materials
include: Butyl rubber. Polyethylene/ethyl vinyl alcohol laminate ("PE/EVAL"). Examples of
acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene
rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton
Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain

Page 5 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

concentrations of particulates and any vapor below occupational exposure limits suitable respiratory
protection must be worn.
Other Work Practices Do not smoke, or drink in work area. Keep away from foodstuffs and beverages. Avoid contact with
eyes and skin.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet.
Promptly remove soiled clothing and wash thoroughly before reuse.
Check section 2.2 (GHS Label Elements) for further details.

Section 9. Physical and chemical properties

Appearance Colored Liquid

Odor Sweet alcohol like
Odor threshold Not determined
pH Not Measured
Melting point / freezing point Not Measured
Initial boiling point and boiling range 82 C 160 F
Flash Point 13-15C 55-60F Method (Setaflash)
Evaporation rate (Ether = 1) 1.5
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: 3.0
Upper Explosive Limit: 9.0
Vapor pressure (Pa) 4.16 kPa Temperature (C) 20
Vapor Density >2
Relative Density 0.95
Solubility in Water Not Measured
Partition coefficient n-octanol/water (Log Kow) Not Measured
Auto-ignition temperature Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) Not Measured
VOC Content 75 wt-%: 90% vol Approximately 6.0 Lbs/gal
9.2. Other information
No other relevant information.

Section 10. Stability and reactivity

10.1. Reactivity
Hazardous Polymerization will not occur.
10.2. Chemical stability
Stable under normal circumstances.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid

Page 6 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

High temperatures and fires.

10.5. Incompatible materials
Store away from oxidizers and acids.
10.6. Hazardous decomposition products
None

Section 11. Toxicological information

Acute toxicity
Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may
result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in
extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation
and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may
cause irritation and soreness with possible reversible damage.

Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in
the calculation of the product's ATE (Acute Toxicity Estimate).
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation Inhalation
mg/kg mg/kg Vapor LC50, Dust/Mist LC50, Gas LC50,
mg/L/4hr mg/L/4hr ppm
Isopropyl Alcohol - (67-63-0) 5,840.00, Rat - 16,400.00, Rabbit 72.60, Rat - No data No data
Category: NA - Category: NA Category: NA available available
1-Methoxy-2-propanol - (107-98-2) 4,277.00, Rat - > 2,000.00, Rat - No data No data No data
Category: NA Category: 4 available available available
Cellulose Nitrate - (9004-70-0) 5,000.00, Mouse - No data No data No data No data
Category: 5 available available available available
Titanium dioxide - (13463-67-7) >25,000.00, Rat - No data No data 6.82, Rat - No data
Category: NA available available Category: NA available
Ethanol - (64-17-5) 10,470.00, Rat - 17,100.00, Rabbit 124.70, Rat - No data No data
Category: NA - Category: NA Category: NA available available
ETHYL ACETATE，EAC - (141-78-6) 4,934.00, Rat - 20,001.00, Rabbit 58.60, Rat - No data No data
Category: 5 - Category: NA Category: NA available available
Rosin, Fumeric - (800680-57-9) No data No data No data No data No data
available available available available available
Acetic acid, 1-methylethyl ester - (108-21-4) 6,750.00, Rat - 20,000.00, Rabbit 17,129.60, Rabbit No data No data
Category: NA - Category: NA - Category: NA available available

Carcinogen Data
CAS No. Ingredient Source Value
0000064-17-5 Ethanol OSHA Regulated Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: Yes; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH A3

0000067-63-0 Isopropyl Alcohol OSHA Regulated Carcinogen: No

NTP Known: No; Suspected: No

Page 7 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No;
ACGIH A4
0000107-98-2 1-Methoxy-2-propanol OSHA Regulated Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH A4
0000108-21-4 Acetic acid, 1-methylethyl ester OSHA Regulated Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0000141-78-6 ETHYL ACETATE，EAC OSHA Regulated Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0009004-70-0 Cellulose Nitrate OSHA Regulated Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0013463-67-7 Titanium dioxide OSHA Regulated Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No;
ACGIH A4
800680-57-9 Rosin, Fumeric OSHA Regulated Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit

Classification Category Hazard Description

Acute toxicity (oral) --- Not Applicable
Acute toxicity (dermal) --- Not Applicable
Acute toxicity (inhalation) --- Not Applicable
Skin corrosion/irritation --- Not Applicable
Serious eye damage/irritation 2A Causes serious eye irritation.
Respiratory sensitization --- Not Applicable
Skin sensitization --- Not Applicable
Germ cell mutagenicity --- Not Applicable
Carcinogenicity --- Not Applicable
Reproductive toxicity --- Not Applicable
STOT-single exposure 3 May cause drowsiness or dizziness.
STOT-single exposure --- Not Applicable
STOT-repeated exposure --- Not Applicable
Aspiration hazard --- Not Applicable

Page 8 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

Section 12. Ecological information

12.1. Toxicity
No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae,
Ingredient
mg/l mg/l mg/l
Isopropyl Alcohol - (67-63-0) 10,000.00, Pimephales Not Available Not Available
promelas
1-Methoxy-2-propanol - (107-98-2) 6,812.00, Leuciscus idus > 4,600.00, Daphnia > 1,000.00 (96 hr), Pseudokirchneriella
magna subcapitata
Cellulose Nitrate - (9004-70-0) Not Available Not Available 579.00 (96 hr), Pseudokirchneriella
subcapitata
Titanium dioxide - (13463-67-7) 294.00, Oryzias latipes 501.00, Daphnia magna 101.00 (72 hr), Pseudokirchneriella
subcapitata
Ethanol - (64-17-5) 15,400.00, Lepomis > 10,000, Daphnia magna 17.921 (96 hr), Ulva pertusa
macrochirus
ETHYL ACETATE，EAC - (141-78-6) 230.00, Pimephales 100.00, Daphnia magna 101.00 (72 hr), Desmodesmus
promelas subspicatus
Rosin, Fumeric - (800680-57-9) Not Available Not Available Not Available
Acetic acid, 1-methylethyl ester - (108-21-4) Not Available Not Available Not Available

12.2. Persistence and degradability

There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available.

Section 13. Disposal considerations

13.1. Waste treatment methods

Observe all federal, state and local regulations when disposing of this substance.

Section 14. Transport information

DOT (Domestic Surface IMO / IMDG (Ocean ICAO/IATA

Transportation) Transportation)
14.1. UN number UN1210 UN1210 UN1210

Page 9 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

14.2. UN proper shipping Printing ink Printing ink Printing ink

name
14.3. Transport hazard DOT Hazard Class: 3 IMDG: 3 Air Class: 3
class(es) Sub Class: Not Applicable
14.4. Packing group II II II
14.5. Environmental hazards
IMDG Marine Pollutant: No;
14.6. Special precautions for user
Not Applicable

Section 15. Regulatory information

Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are
represented.
Toxic Substance Control All components of this material are either listed or exempt from listing on the TSCA Inventory.
Act ( TSCA)
Note: Ethanol (Ethyl alcohol) has been placed on the California Proposition 65 Cancer and Developmental Lists when in
alcoholic beverages.
EPCRA 302 Extremely Hazardous:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
EPCRA 313 Toxic Chemicals:
Ethanol
Isopropyl Alcohol
Proposition 65 - Carcinogens (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Developmental Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Female Repro Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Male Repro Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 Label Warning:
This product contains no chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information

SDS Revision Date 04/01/2020

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or
warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility
and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this
product must comply with all applicable health and safety laws, regulations, and orders.

Page 10 of 11
 Carco, Inc. - Safety Data Sheet SDS Revision Date: 04/01/2020
MM-150 all except Black, Red

The full text of the phrases appearing in section 3 is:

H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H228 Flammable solid.
H319 Causes serious eye irritation.
H336 May cause drowsiness and dizziness.

This product is RoHS and REACH compliant. It does not contain any of the RoHS listed substances. It does not contain any
chemical from the candidate list of Substances of Very High Concern (SVHC), Annex XIV, or Annex XVII of Reach.

This information is based on our present knowledge. However, it does not constitute a guarantee for any specific product
properties.
Carco urges the recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. The information
herein is provided in good faith and believed to be accurate as of the effective date shown above. The use of this product is
beyond the control Carco or its distributor, therefore, no warranty, express or implied, is given. Regulatory requirements are
subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities
comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped.
Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the
conditions necessary for the safe use of this product.
End of Document

Page 11 of 11