Coondimation

Compounds

TyTyot_Lalk:
uc Con tain
Sals
Caipn m d anu oU e K , JoC
ypR ®
The sallb i ton taims more
GD Mix ed salt:
Cahon Orno uor
then t
onl
a (oc) ^CaLouta
=
Blea
Ble cki ng fosdev
a chi

o c u l a v Salls o6 addihon lonbru nds

kalk cheni calle, tonbine tigsho
ken tro Rianple
Comprunds ari
al ttordmed,
orid.
oacld triorv Comtumds m
Cewlan salS foromid
Ke
matk Conpotunds au
Adltion or
ammUnlo 5 o
Sterc ks6metrn
table tomprtnds ftim togyetkev
No le Ceul sal5

Doube alt CD on ol'mahon lonpotmols

Compex Sall
 Dottble salt: thin
hick loorohn
he moticeelav Snlts
w
lisko1e dd
, 1 9 kon
idenly im aq setulion
ive fesiive thst all i conahtnent
alov,
6,=
: eso +(NH), 3o,- fe ).GH,)_ CmD
té wvs Nmm8ne
Lulphal
(Nsh lalt)

N t n a l t sotn
Nt fruatn)
KaPeCo] elue (F2
ski a tp)
Ball (Cnd,
G a f O , 2- taf a t J
Nt (Kirgentmal

KCl
Mg +6,o K.Na.GHd
Cannalit
24 Ho
KOAl2 (o«).
otcksi m alum
+24 Ha 0
tKa
Alums ome deub salt havin
/No:
gen
Gen fomuula M, So,2 (T).24 H

K N Nt tc A3,
C etc

KS0,.a,so), 2u to (Chonemi u
Llees net t n Malum alu
 * (Compb y sal)
Co oroolimaron Cumprtndp
Adlition tompau ndo
or
To moe cal aw
1a o
Stlation

do nfF o e Thwn adeglil, orN1orrasb0

Kon dikso /Ve d m o aley Thn,

ie,
oeo mw e
0re fsfe lbAt
if nll #u ctitu*

KCN t fe CC), Klhe CCnD ferno cy

u
anide
oTano1

4 PeCc
m a in

intout

sg
D ue LesAoviat0
erOS
tuh
K lonpex,
I. Pevfect Complex
doeo mo 8Te
suution
TY uraon in , ie
tast o a l l H tonoti ta en i o ,
3iHJ
Tkey have v e
Ky (PecÉDe 4uh
He lonplex ,

Comsev
tev gect ai
Bolution t s ihe tat
OuTaton im a have
Kave hizh degrue
kizhadogre
if, tkesy
all it tonsti tu-en ions,
sSou'ationv
 a Conprdidon olopex Conpounols
(i Simmble cation & tonphy anio

Na, Ife (CA)NO 2N RCc N

So dtum mitrpruusaide
Sm

CunCrts0, (na,]+so
2f

Ca )

Comp lex eation i lontak anuon)

(i Neutool umbuk

D Keroendatio tophy
Resihuas
choge
M LL &amv
'on

CUlinhioa
Cerrool onttal
No skne.
okom/ j o
Lig onds gords
 Tefrli'on +2
KaOr dual e hang
Cemtoo al m e t al t o m / = u

= NHa meuto J )
Ligom
N
3
Tofl no f r'n
= +3
Rei du al chnge
CMA P
Ligend NH3, C
No v 1 6
sphore
ant in o- omdi nhn
2 4 NH3

may be ols
bi neol e
a
ET Cosax ion

ehovsed
eVtn a utdal sfeuit i
teCtmCally
tombimation
anod iS towmud y The han C n e meu a
Then
O e eua l

rTh moTu
la Cton
inT
Ionv.
m e culs
on meattR
0T
mutmal atecheo
motecuulbo atacked
anion0
T natad otsm ar
Calles ugends.
to t tomrspl
nvalll, a
Contrsal retal cation
a4
T orshonshlz
1 TH ta0 a roive
roormithm
mtal,
im w i c
kamefal
Conprum as a ah
C o o r o d i n a h i o n

mtfal Cn bs ny
la)
in u0
ck stalg (eg
Tenom tvated im (oodinalion lonfntums:
Ca) Cortal irv /alrn
7h catinn "
7eCon-foal rmfal odun 1o0
hth o mone Tkon vnt noMlgvol mobtul
qV0atlodod,r
ont
im n a n t foos)
aniowo (loion topr-notion,
entta fI Calleol terrlu
TCemdroas ntal 1 rernoit on mefal a brhl
in Whi Votant dlao
d-bI k -eumun
ob oloctrabno
denaid lydem
ant h n t . T J.f
actb modalsod ucb
otsm* kig orn
vncont d- brbitak.
n LPe C),T"ion, f" lon i tho Conrtod

(6) Czond
t 7fo
a fou obctrno
donadomatien
collod uond (Gr Caordin}
Con-tab al atom okar 1 rGn
r t . In Lgormd, dan
otimA nu Vally N, 0, S n d

Th JL'gomd cyn daini en, to, rro m e

dono atms n t kuw a nidn-takt, h iduritnla

opehel,
ulthi den Hals
 (Co-00podimation mumbev CC)
The tetal mo d n c atom atacheol toke
Ccntooal notal CN

TAs CN Ceur's's 4
t Cu (th)"
S
(d) Co- ood inatan sp hane:
TAe Contoal mutal atom/ md ho L'aen d
attacded t if are Colle etisel, ealle
Pzbetly 1
Co o P d i a t i n sf kene. Co orodimaion 8pkn
tmgde uone. rsa cef. eg [o (N H
9 o / tTc

e) lonphx io arm ekchoieolly ehonged

i
Compex n esmld k y The2

m
N
nRR

Cahion
Cation
vih
f h
Con toal
Cmbineho B a
igome peeis
Fham one

o x dationMUM bLv. he
k i c h y nipruaenks
umbev m a t a l akom
a on to Comtral
tlectrmC ckonSe
a CophX
fe
8 f e CCg
o+( x6
+2 0te fe (T)
 2)
Co ('uD

Co im o(U)
k a t do you mean by homaofftic 2
itert epi CompeMd?
lonplux an ands ne
przeantmt homaepC

CoNo.
Conph in ki, Jtf Limds ae

LPHs),u
R
C ic
h h Fle te llaain ckumical Afeerto
Cen F ack e0 a lq on
(a
Id Seito kich meAal
Q: n lenharo
mt 6oi7C Gnd hhich
ide i
y drnv
luas laoic

u (ot), leaat
Co-cpd 9aion lyks drovry
te & atial oÝonemunt f
Tke Th Lpa nd in)
ro a mdal atrm/ o r o hoNV
anetind IKo Len
u 7uCL, atloe heos tThe metal
ig amds aborsfa
Toro m Tko Cogodi naticn ohy hachmi
c6 10TV
COntooal mefos atom
No igane atsm eltahid 4

M
-V
fe tovahedyoal SAJucns plananv
No nand atom attockid =S

,L
L M
M
O6ifyo emiol al Sationt fyro amu'dal
No amad aka attecha d>>

L
M
L

M Conto al metal ato m /on

ith
No q4Te aksm (dra) attached
con t6oal omePal mbm on iam knoyw as 6
Tke mted
NOTE: CN B Some mstal asm
Mefal atm/i
. A C , Au

C , PA2,N, Mn
P d , z , N;°
4t
R R e3, 3", H
(G3t
G N i , TT
CN C S mott Lormot) C.. t h e
7
Ronetry o t a kadro al
Classification o Ligands
Dentici Th mumb f den on alsm
Co-opdiral
a a
lq and,Copabe torommg
rqamd ion
T A The unto6a ontal
atsmm o
i
bonds
kn as dentiul gand
OH3 don-iu :1 ()NH
ClormiCartn
igends
Cnthe basis Onthe On t b ois
Chonse e don ahinj ?
n e utoe denich5 acupkng
Monodedat tnee ncy
positivNe iddee Clasical
meg aive
Polyde mle Non classitl"
Flexidenta e
Ly Ambide ntale
aDr hahen enhe baois

ene lgay da, kich Con danal

one rad
Aeea oaly Io P,
Nn, P 3,0
NO Amnin0)

Negsie (Chloride),
PEluornido), C(Claidk)

cH
CH (aca tohs ), N*(Ntrd
NH(mjdo)

Sdonta tt o Ddentate: Ligenda , stuihean

dlmatr tro en a

Etlenediam ine (er)

c

N ,bguan
Biguanide (Hbiq)

H
 Gycmalt im one

(a mutoas donao () am
Occ. One auJic(amou c)dno

[N anio donoro E acidie daon

O Bfqmidine (bfa)
0 - Phenanthrolime
Cphen
Co pher)
-

Oxa Lata ian (ox

D avdie dsmar ata ms
o=c

G Triolen ta
E Ctta
Diettlenetmanire
Cdien)
H
iv) Te-rsaolen fa
CHa) C) trietfylene
te trra omum
J
- (
(tmien)

YHBRSTGAnz
( Pentadendee

o6- :
- CH N

H -o0:
lanediaminerioe dat
Fthy io

(vi) levadontal7
;

N-CHa-y

lenedi amine te troaacatat 1m

(edta-
(u a i c dgnom& nau toal dmaT
a o)
Biden de to ehalatim J and
at Can tsm A
A f den tal Lsamd
kitk tKo mtal m and p r hbil5 E3
quT me

Cha S-memhudun
L6 memkanldrn

MK S-mumhortd m t s ab
Cam bosm a
LrU a cklatim emo metal iov. Mou uner
AitR TKo
-mmbud uT "

.Thuuot katisfy Lord yatin

uta wth d
prdihon mata atsmion
Simultanviotoh,)twO bm Js ne
Baenjm
8renjng
o an way z e n metal
Lesu9l d lave one Ligo
a t mLas Co fx hao jot mne Afabiuh.
n N,N -brdon1a ekolatirg
Thuo
geno
an not
Two (:s
M<ONEN'
wo Co i n s t i n postono
t sahsfy
Con verae oyo r o v TAus mmelo culans N
anet as
Cn'ftancti
as biale nTa fetiag gand.
cka
t H y h p e z i n e

H2 Cam'f bunthin
r s i6l
rn Tka a

ehalatrima liaand ,as

bi ole nta
be 3-mem botd, t u e h
That iU Le bom mid
i u n s -labl
ao n
a C l a l a tiag mds
Some tAn, ditn, EDTA

6a exe tak
don ta+
kexodon Ligaand.
Lig
L Note: ETA
4t can satótY Elmetallison d
n ofa r m gru aut t be
mtal i .
kigh ztabilil (6-bonds
Compax fvey onodlev
s
b
te
ate
the
7hA
mm
bonker S i m u l t a m i o u a l y
trom Ra epla
g omds aray

P.7-0
 ooc (n-u)
Coo
N
n+K
M
Coo N.

M:edtr /tomsux

Stbil
i tlexi denta fe Lia md tal bserya
Fux den tat, kaviouv
Le multi ti dun
pry lentalz Go b dentala o a oro t i
mt uae all itu danor atomb e qe
J. ind
Coondimaliol ts the Cntwal mta nbsm
ur

hen Cobab skosimA vaia be dentu y

Is Callud afexiden +alz Lg omd

Czloa)(d
OH
ie)] -co
72
Co0 Pend-ent anm
a penta derht

Goo4 g)
o
 Pod (esdta Ha) CooH
Cod
(e&ta bunc tion i
Pd e te frb a denta

Ligomd
N
Coo H

arn n-e
Haf
Ka
A b g in) Leg omd to moru
ttan
omaltse
Com 8irul 4&niot
metal 0
NEN:
oH, eP,
munt ave t l a
brslgir
o lp sKat
Ligomdl
an geh ined bat Le
on
N A z a d e ion
No: M
Rn-on brig inK

M
M -end tond bi dai

LA omol huch Cntauin

Amono den ta b
tham ou lenor ato et one +f.tlo
mo?u
8uaed at a imka fom a Coarlinalt bond
tho Cento0 al mital atbmu 3 callud ambidemale
witk ks cerrtsoa i s and
 C-
= N:
arro N

N
)
mii t-N mitito- O

-CENO
Os-cEN:
TKioeyanatoS
Kioeanato - N

Classibicatien gands cn He
baors dedenei amdency
C) ClaroiCal
wenm y iAon d
mical specieo t a v i lone sau
Cka
eueromo

Nohclanoi cal mon enm

havia m0 LoneoM
CmuCol sfec e
havimg 17-electmncltto dnatt,
ethylne ben en
CH
11 Kaled n

CPA PAs(7*ana)1(zese's selt)

lem&ag)
 c c , 1 ferte CQne
le eP[ NCNA

end
CP aim)

Nofe Liq tiond emetds e N

N2
C.
moro don t a l
:NEN:
( tfe.
M NEN :N ielental beqi8
M
N.(.N. tyf
NEN: merodentalt

. f
. C . N.

NEN biden taa

Noe Vaska's Compound

T CPPhs), Ckom8im
(Synte+c Lleed)
O
T (PPhS Co Ct (o)
 Ph
OC O
I m

6 md
bunetionunan NCNW yi
C02 Ggan d )

Pupon ed mob l o r
amitv1em mphy.

Segustring
Ongemu
(meakmg lgands )
CordinaiaS Lgomds Ket fmmo
iom Omd
wat rtubu Cmplu witk a
matal
ruJants iE trsm tuapmdin to U nal
Ckemi Cal uaLHm

8-hyny quino bne

SuNhsnalt

S0
2

M
ot mankd
D CLlete thect:
Ckla tion igan d
impant stebibk
Shbilh
trsa

me tal Compex e0. T h s

attmibution
ckkk t t ,
6fo bilil kno tkat t s o
&fabilil, i8
olut ki fock
Tke tonds oiU av t be siulenitaly
metal ls and trm
im ondov
ko ate Ta lgene) aany
Trooken
Kmatol. So,
is f kigK stebikh
a Homomu clean ond feyuleon 0P
bmidged Complex es :
slu ch only mtal 's r e bent
Comp ex s im
Cne

are kmo wn
a homonuc l e a Comploxeo.

C l o (rNH 3DeT
ham me metal atam
Compexeo im u c h
moe
nucan or bmdged
isreen n e n a n a ohg
ne
Conplex e0, (Kaae loznsl xas

bomidg gnds
O14.

feChoe
Cn ol
oF Considotd a4
an

: Duih a f+llopoing id
Oaan rnitallue
Cemp Dmd ?
(L Peno Ceme
Ca) Crsflatim b Gosia-nnd reagent
(C) Zeise's a l t CAUiS loole )