SDS - Jotashield - Marine Protective - Malaysian (My) - Malaysia
SDS - Jotashield - Marine Protective - Malaysian (My) - Malaysia
SDS - Jotashield - Marine Protective - Malaysian (My) - Malaysia
Bahan/Penyediaan : Penyediaan
Nama Ramuan Nombor % Had Pendedahan Data Ketoksikan
CAS Pekerjaan
isoproturon (ISO) 34123-59-6 0-1 Tiada Tiada
benzophenone 119-61-9 0-1 Tiada Ya.
3-iodo-2-propynyl butylcarbamate 55406-53-6 0-1 Tiada Tiada
ammonia 1336-21-6 0-1 Tiada Tiada
reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3- 55965-84-9 0-1 Tiada Ya.
one[EC no. 247-500-7]and 2-methyl-2H-isothiazol-3-
one [EC no. 220-239-6] (3:1)
Had Pendedahan Pekerjaan, jika tersedia, disenaraikan dalam seksyen 9.
* Jika tersedia, maklumat toksikologi disenaraikan dalam seksyen 11
2. Composition/information on ingredients
Substance/preparation : Preparation
Ingredient name CAS % Occupational Toxicity data
number exposure limits
isoproturon (ISO) 34123-59-6 0-1 No. No.
benzophenone 119-61-9 0-1 No. Yes.
3-iodo-2-propynyl butylcarbamate 55406-53-6 0-1 No. No.
ammonia 1336-21-6 0-1 No. No.
reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3- 55965-84-9 0-1 No. Yes.
one[EC no. 247-500-7]and 2-methyl-2H-isothiazol-3-
one [EC no. 220-239-6] (3:1)
Occupational exposure limit(s), if available, are listed in Section 9.
Tarikh keluaran/Date of issue : 1/13
06.01.2012.
Jotashield Jotashield
* Toxicological information, if available, is listed in section 11
3. Sifat-sifat fizikal dan kimia
Maklumat am
Rupa
Keadaan fizikal : Cecair.
Warna : Berbagai warna.
Bau : Ciri-ciri.
Maklumat-maklumat kesihatan, keselamatan dan persekitaran penting
Ketumpatan : 1,26 g/cm3
Kelarutan : Tidak terlarutkan dalam bahan berikut: air sejuk dan air panas.
3. Physical and chemical properties
General information
Appearance
Physical state : Liquid.
Colour : Various colours.
Odour : Characteristic.
Important health, safety and environmental information
Density : 1,26 g/cm3
Solubility : Insoluble in the following materials: cold water and hot water.
4. Pengenalpastian bahaya
Produk ini dikelaskan sebagai berbahaya menurut Arahan 1999/45/EC dan pindaannya.
Klasifikasi : R43
N; R51/53
Bahaya Kesihatan : Boleh menyebakan pemekaan melalui sentuhan kulit.
Bahaya Fizikal/Bahan Kimia : Tidak diklasifikasikan.
Bahaya Alam Sekitar : Toksik kepada organisma-organisma akuatik, mungkin akibatkan kesan-kesan
buruk jangka panjang kepada persekitaran akuatik.
Lihat Seksyen 11 untuk maklumat lebih lanjut tentang kesan-kesan dan gejala-gejala kesihatan.
4. Hazards identification
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : R43
N; R51/53
Health hazards : May cause sensitisation by skin contact.
Physical/chemical hazards : Not classified.
Environmental hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
See Section 11 for more detailed information on health effects and symptoms.
5. Langkah-langkah pertolongan cemas
5. First-aid measures
First-aid measures
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or
wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the
event of any complaints or symptoms, avoid further exposure. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
See Section 11 for more detailed information on health effects and symptoms.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : In a fire or if heated, a pressure increase will occur and the container may burst.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. This material is toxic to aquatic organisms. Fire water contaminated with
this material must be contained and prevented from being discharged to any
waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
Langkah berjaga-jaga diri : Tiada tindakan yang membabitkan risiko peribadi perlu diambil atau tanpa latihan
yang sewajarnya. Kosongkan kawasan persekitaran. Halang kakitangan tidak
berkaitan dan tidak dilindungi daripada masuk. Jangan sentuh atah jalan melalui
bahan tertumpah. Elakkan menyedut wap atau kabus. Sediakan ventilasi yang
mecukupi. Pakai alat pernafasan yang sesuai apabila ventilasi tidak mencukupi.
Pakai kelengkapan perlindungan peribadi bersesuaian (Lihat Seksyen 9).
Peringatan alam sekitar : Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh dengan tanah, jalan
air, longkang dan pembentung. Beritahu pihak berkuasa yang berkaitan jika produk
menyebabkan pencemaran persekitaran (pembentung, aliran air, tanah atau udara).
Bahan mencemar air. Boleh memudaratkan alam sekitar jika terlepas dalam jumlah
yang banyak.
Kaedah pembersihan
Tumpahan kecil : Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan.
Cairkan dengan air dan seka bersih jika terlarut air. Sebagai alternatif, atau jika
tidak terlarut air, serap dengan bahan kering yang lengai dan isikan dalam bekas
pelupusan bahan buangan yang wajar. Buang melalui kontraktor pelupusan sisa
yang berlesen.
Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Avoid breathing vapour or
mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see Section 9).
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.
Methods for cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach the release
from upwind. Prevent entry into sewers, water courses, basements or confined
areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilt product.
Note: see section 9 for personal protective equipment and section 13 for waste disposal.
8. Pengendalian dan penyimpanan
Pengendalian : Pakai kelengkapan perlindungan peribadi bersesuaian (Lihat Seksyen 9). Makan,
minum dan menghisap rokok harus dilarang dalam kawasan di mana bahan ini
dikendalikan, disimpan dan diproses. Para pekerja harus membasuh tangan dan
muka sebelum makan, minum dan menghisap rokok. Orang yang mempunyai latar
belakang masalah pemekaan kulit tidak harus diambil bekerja dalam mana-mana
proses yang menggunakan produk ini. Jangan terkena mata atau pada kulit atau
pakaian. Jangan menyedut wap atau kabus. Jangan inges. Elakkan daripada
melepaskan ke persekitaran. Rujuk kepada arahan khas/risalah data keselamatan.
Simpan di dalam bekas asal atau bekas lain yang diluluskan yang diperbuat
daripada bahan yang sesuai, tutup ketat apabila tidak digunakan. Bekas kosong
mengandungi sisa produk dan boleh menjadi berbahaya. Jangan guna semula
bekas.
Penyimpanan : Simpan mengikut peraturan tempatan. Simpan di dalam bekas asal yang terlindung
dari pancaran terus cahaya matahari dalam kawasan kering, sejuk dan pengudaraan
yang baik, jauh daripada bahan tidak sesuai (lihat seksyen 10) dan makanan dan
minuman. Simpan bekas tertutup rapat dan terkedap sehingga sedia untuk diguna.
Bekas yang telah dibuka mesti dikedap semula dengan teliti dan disimpan menegak
untuk mencegah kebocoran. Jangan simpan dalam bekas tidak berlabel. Gunakan
kaedah pengurungan yang sesuai untuk mengelakkan pencemaran alam sekitar.
Bahan pembungkusan
Penggunaan yang : Guna bekas asal.
disyorkan
8. Handling and storage
International lists - : CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)
Carcinogen by ACGIH [Distillates (petroleum), hydrotreated heavy naphthenic]. Classified 3
(Possible for humans.) by European Union [isoproturon].
12. Maklumat ekologi
Penyediaan telah dinilai mengikut cara konvensional Arahan Penyediaan Berbahaya 1999/45/EC dan diklasifikasi
sepatutnya untuk sifat-sifat eko-toksikologi. Lihat seksyen 3 dan 15 untuk maklumat terperinci.
Keekotoksikan akuatik
Nama produk/bahan Ujian Keputusan Spesis Pendedahan
isoproturon - Akut EC50 0,06 Tumbuhan 7 hari
mg/L Air tawar akuatik -
Duckweed -
Lemna minor
benzophenone - Akut LC50 14,2 Ikan - Fathead 96 jam
mg/L Air tawar minnow -
Pimephales
promelas -
Juvenil (Anak
boleh terbang,
Anak tetasan,
Anak cerai susu)
- 28 kepada 33
hari
- Akut LC50 10,89 Ikan - Fathead 96 jam
Tarikh keluaran/Date of issue : 8/13
06.01.2012.
Jotashield Jotashield
mg/L Air tawar minnow -
Pimephales
promelas - Larva
- <24 jam
- Akut LC50 15300 Ikan - Fathead 96 jam
ug/L Air tawar minnow -
Pimephales
promelas - 31
hari - 21,8 mm -
0,165 g
- Akut LC50 14200 Ikan - Fathead 96 jam
ug/L Air tawar minnow -
Pimephales
promelas - 30
hari - 19,7 mm -
0,091 g
3-iodo-2-propynyl butylcarbamate - Akut EC50 0,16 Crustacea - 48 jam
mg/l Dafnia - Daphnia
magna
- Akut EC50 0,022 Alga - Alga - 72 jam
mg/l Scenedesmus
subspicatus
- Akut LC50 0,067 Ikan - Ikan trout - 96 jam
mg/l Oncorhynchus
mykiss
ammonia - Akut EC50 24 Dafnia - Daphnia 48 jam
mg/l magna
- Akut LC50 0,53 Ikan - 96 jam
mg/l Onchorhynchus
mykiss
mixture of: 5-chloro-2-methyl-4- - Akut EC50 0,16 Dafnia - Daphnia 48 jam
isothiazolin-3-one [ec no. 247-500-7] and mg/l magna
2-methyl-2h-isothiazol-3-one [ec no. 220-
239-6] (3:1)
EPA Akut EC50 0,027 Alga - 72 jam
mg/l Selenastrum
capricornutum
- Akut LC50 0,19 Ikan - Ikan trout - 96 jam
mg/l Oncorhynchus
mykiss
Maklumat Ekologi Lain
Biorosot
Kesimpulan/Ringkasan
Nama produk/bahan Separuh hayat Akuatik Fotolisis Biorosot
isoproturon (ISO) - - Tidak mudah
ammonia - - Tidak mudah
reaction mass of: 5-chloro-2-methyl- - - Tidak mudah
4-isothiazolin-3-one[EC no. 247-500-
7]and 2-methyl-2H-isothiazol-3-one
[EC no. 220-239-6] (3:1)
Kesan-kesan buruk lain : Tiada kesan yang penting atau bahaya kritikal yang diketahui.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is classified for eco-toxicological properties accordingly. See Sections 3 and 15 for details.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
Sisa harus dibuangkan mengikut peraturan persekutuan, negeri dan kawalan alam sekitar tempatan.
Kaedah pembuangan : Penghasilan sisa perlulah dielakkan atau diminimumkan sekiranya boleh. Sisa
keluaran buangan dalam kuantiti besar hendaklah jangan dilupuskan melalui
pembetung yang kotor tetapi diproses dalam loji rawatan efluen yang sesuai.
Pembuangan lebihan dan hasilan yang tidak boleh dikitar semula melalui kontraktor
pelupusan sisa yang berlesen. Pelupusan produk ini, larutan dan sebarang produk
sampingan perlulah pada setiap masa mematuhi keperluan perlindungan alam
sekitar dan perundangan pelupusan sisa dan sebarang keperluan pihak berkuasa
serantau tempatan. Bungkusan buangan harus dikitarkan semula. Penunuan atau
kambus tanah hanya harus dipertimbangkan apabila tidak mungkin dikitar semula.
Bahan ini dan bekasnya hendaklah dilupuskan dengan cara yang selamat. Hati-hati
apabila mengendalikan bekas yang telah dikosongkan tetapi belum dibersihkan atau
dibilas. Bekas atau pelapik kosong mungkin mengandungi sisa-sisa produk.
Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh dengan tanah, jalan
air, longkang dan pembentung.
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Significant quantities of waste product residues should not be disposed of via the
foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilt
material and runoff and contact with soil, waterways, drains and sewers.
"Pengangkutan dalam premis pemilik:" sentiasa mengangkut dalam bekas bertutup yang tegak dan selamat. Pastikan
orang yang mengangkut produk tahu apa yang perlu dilakukan sekiranya berlaku kemalangan atau tumpahan.
Peraturan pengangkutan antarabangsa
Nama penghantaran betul : Environmentally hazardous substance, liquid, n.o.s. (isoproturon)
Bahan polutan marin : isoproturon
Nombor UN : 3082
Kelas : 9
Kumpulan Pembungkusan : III
Label :
Tanda : Tanda merbahaya kepada persekitaran / pencemaran laut hanya diperlukan pada
bungkusan yang mengandungi lebih dari 5 liter untuk cecair dan 5 kg untuk pepejal.
Maklumat Tambahan
ADR (Empty) RID : Tunnel restriction code: (E)
Nombor Identifikasi Bahaya: 90
IMDG : Pencemar Marin: Ya.
Pengangkutan mengikut ADR/RID, IMDG/IMO dan ICAO/IATA dan peraturan negara.
14. Transport information
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (isoproturon)
Marking : The environmental hazardous / marine pollutant mark is only applicable for packages
containing more than 5 litres for liquids and 5 kg for solids.
Additional information
ADR / RID : Tunnel restriction code: (E)
Hazard identification number: 90
IMDG : Marine pollutant: Yes.
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.
Peraturan-Peraturan EU
Simbol bahaya :
Merengsa
Ungkapan risiko : R43- Boleh menyebakan pemekaan melalui sentuhan kulit.
R51/53- Toksik kepada organisma-organisma akuatik, mungkin akibatkan kesan-
kesan buruk jangka panjang kepada persekitaran akuatik.
Ungkapan keselamatan : S2- Jauhkan daripada kanak-kanak.
S23- Jangan menyedut semburan.
S24- Elakkan daripada bersentuhan dengan kulit.
S29- Jangan buang ke dalam longkang.
S37- Pakailah sarung tangan yang sesuai.
S46- Jika tertelan dapatkan nasihat perubatan dengan segera (tunjukkan bekas atau
label).
S51- Gunakan hanya di tempat yang mempunyai pengalihan udara yang baik
sahaja.
S61- Elakkan daripada melepaskan ke persekitaran. Rujuk kepada arahan
khas/risalah data keselamatan.
Mengandungi : reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one[EC
no. 247-500-7]and 2-methyl-2H-isothiazol-3-one [EC no. 220-
239-6] (3:1)
Kegunaan Produk : Aplikasi pengguna, Guna dengan Menyembur.
15. Regulatory information
EU regulations
Hazard symbol or symbols :
Irritant
Risk phrases : R43- May cause sensitisation by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Sejarah
Tarikh cetakan : 06.01.2012.
Tarikh keluaran : 06.01.2012.
Versi : 4
Notis kepada pembaca
Pada pengetahuan terbaik kami, maklumat yang terkandung di dalam adalah tepat. Bagaimanapun, pembekal
yang dinamakan di atas atau sebarang anak syarikatnya tidak bertanggungjawab terhadap ketepatan atau
kelengkapan maklumat yang terkandung di dalam.
Penentuan terakhir kesesuaian sebarang bahan adalah tanggungjawab pengguna. Semua bahan mungkin
mengandungi bahaya yang tidak diketahui dan harus digunakan dengan berhati hati. Walaupun bahaya
tertentu telah diterangkan di sini, kami tidak memberi jaminan bahawa hanya bahaya ini sahaja yang wujud.
History
Date of printing : 06.01.2012.
Date of issue : 06.01.2012.
Version : 4
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.