3 Thermo
3 Thermo
THERMODYNAMICS
Dr. A. Muthuram
Assistant Professor,
SRM Institute of Science and Technology.
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• Unit-1 : FIRST LAW OF THERMODYNAMICS
• Basic Concepts: Microscopic & macroscopic point of
view, Path and point functions. Intensive and
extensive, total and specific quantities. System and
their types. Zeroth law of thermodynamics,
Thermodynamic equilibrium. First law of
Thermodynamics: First law for a closed system
undergoing a cycle, concept of Internal energy,
change of state. Energy and Work Transfer in closed
systems, P-V diagram, PMM1. First law for an Open
system: Conservation of mass, energy, steady flow
energy equation. applications of SFEE to Nozzles,
Diffusers. Types of turbine, compressor, boiler, pump.
Heat exchanger and Throttling process.
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• FIRST LAW FOR AN OPEN SYSTEM:
CONSERVATION OF MASS, ENERGY,
STEADY FLOW ENERGY EQUATION.
APPLICATIONS OF SFEE TO NOZZLES,
DIFFUSERS. TYPES OF TURBINE,
COMPRESSOR, BOILER, PUMP. HEAT
EXCHANGER AND THROTTLING
PROCESS
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• Problem: A rigid tank contains air at 500 kPa and 150°C. As a
result of heat transfer to the surroundings, the temperature
and pressure inside the tank drop to 65°C and 400 kPa,
respectively. Determine the boundary work done during this
process.
• Solution:
• Air in a rigid tank is cooled, and both the pressure and
temperature drop. The boundary work done is to be
determined.
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• This is expected since a rigid tank has a
constant volume and dV = 0 in this equation.
• Therefore, there is no boundary work done
during this process.
• That is, the boundary work done during a
constant-volume process is always zero. This is
also evident from the P-V diagram of the
process (the area under the process curve is
zero).
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• A piston–cylinder device initially contains 0.4 m3 of
air at 100 kPa and 80°C. The air is now compressed
to 0.1 m3 in such a way that the temperature inside
the cylinder remains constant. Determine the work
done during this process.
• Solution:
• Air in a piston–cylinder device is compressed
isothermally. The boundary work done is to be
determined.
• V1 = 0.4 m3 P1 = 100kPa T1 = 100°C
• V2 = 0.1 m3
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• For an ideal gas at constant temperature T0
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Pν = Flow work or Flow energy
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IF THE SYSTEM IS STATIONARY OR THERE IS NO
CHANGE IN VELOCITY AND NO ELEVATION
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Mechanisms of Energy Transfer
• Energy can be transferred to or from a system in
three forms: heat, work,and mass flow.
• Heat Transfer, Q:
• Heat transfer to a system (heat gain) increases
the energy of the molecules and thus the internal
energy of the system, and heat transfer from a
system (heat loss) decreases it since the energy
transferred out as heat comes from the energy of
the molecules of the system.
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Mechanisms of Energy Transfer
• Work Transfer, W :
• An energy interaction that is not caused by a temperature
difference between a system and its surroundings is work. A
rising piston, a rotating shaft, and an electrical wire crossing the
system boundaries are all associated with work interactions.
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• For a cycle ΔE = 0, thus • Various forms of the
ΔQ = W first-law relation for
closed systems.
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1N = 1kgm/s2
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SOME STEADY-FLOW ENGINEERING
DEVICES
• Many engineering devices operate essentially
under the same conditions for long periods of
time.
• The components of a steam power plant
(turbines, compressors, heat exchangers, and
pumps), for example, operate nonstop for
months before the system is shut down for
maintenance.
• Therefore, these devices can be conveniently
analyzed as steady-flow devices.
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Nozzles and Diffusers
• Nozzles and diffusers are
commonly utilized in jet
engines, rockets,
spacecraft, and even
garden hoses.
• A nozzle is a device that
increases the velocity of a
fluid at the expense of
pressure.
• A diffuser is a device that
increases the pressure of
a fluid by slowing it down.
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Nozzles and Diffusers
• That is, nozzles and
diffusers perform
opposite tasks.
• The cross-sectional area
of a nozzle decreases in
the flow direction for
subsonic flows and
increases for supersonic
flows.
• The reverse is true for
diffusers.
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Nozzles and Diffusers
• The rate of heat transfer between
the fluid flowing through a nozzle
or a diffuser and the surroundings
is usually very small (Q = 0) since
the fluid has high velocities, and
thus it does not spend enough
time in the device for any
significant heat transfer to take
place.
• Nozzles and diffusers typically
involve no work (W = 0) and any
change in potential energy is
negligible (Δpe = 0).
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Nozzles and Diffusers
• But nozzles and diffusers
usually involve very high
velocities, and as a fluid
passes through a nozzle
or diffuser, it experiences
large changes in its
velocity.
• Therefore, the kinetic
energy changes must be
accounted for in analyzing
the flow through these
devices (Δ ke ≠ 0).
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Deceleration of Air in a Diffuser
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Turbines and Compressors
• In steam, gas, or hydroelectric power plants, the
device that drives the electric generator is the
turbine.
• As the fluid passes through the turbine, work is
done against the blades, which are attached to
the shaft. As a result, the shaft rotates, and the
turbine produces work.
• Compressors, as well as pumps and fans, are
devices used to increase the pressure of a fluid.
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Turbines and Compressors
• Work is supplied to these devices from an external
source through a rotating shaft. Therefore,
compressors involve work inputs.
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Turbines and Compressors
• Note that turbines produce power output
whereas compressors, pumps, and fans require
power input. Heat transfer from turbines is
usually negligible (Q = 0) since they are typically
well insulated.
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