Class 11th JEE

Advanced
PAPER -1
MKJM/11 Milestone Test-3 Phase-4

DURATION
DURATION ::180
90 Minutes
Minutes DATE : 13/10/2024 M. MARKS : 180

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (A, B, C, D) 18. (A, B, C, D) 35. (A, B, C, D)
2. (A, B, D) 19. (A, C) 36. (A, B)
3. (A, B) 20. (A, B, C, D) 37. (A, B, C, D)
4. (A) 21. (C) 38. (A)
5. (C) 22. (B) 39. (A)
6. (D) 23. (C) 40. (B)
7. (B) 24. (A) 41. (A)
8. (10) 25. (160) 42. (5)
9. (1) 26. (2) 43. (3)
10. (7) 27. (3) 44. (6)
11. (4) 28. (3) 45. (1)
12. (1) 29. (6) 46. (8)
13. (1) 30. (8) 47. (1)
14. (A) 31. (D) 48. (C)
15. (B) 32. (C) 49. (B)
16. (B) 33. (A) 50. (C)
17. (D) 34. (D) 51. (B)
 PART-I (PHYSICS)
1. (A, B, C, D) 4. (A)
Velocity = length/time, acceleration Time taken to cross the river
= length/(time)2 For time to be minimum,
(velcocity) 2 v '2 v2 cosθ max ⇒ θ = 0°
⇒ Length= i.e. L'= ,L =
acceleration a' a
L '  v '   a   α2  1
2
⇒ = =   =α3 / β3
L  v   a '   β  αβ
m' F ' a 1 1 1
= = × =
m F a ' αβ αβ α 2β2
Hence, the swimmer should swim due north.
Time = velocity/acceleration, i.e.
v' v
T= and T = 5. (C)
a' a
vdv = ads
T ' v ' a α2 1 α
= = = 2 v
∴ ∫ vdv =
12 m
T v a ' β αβ β 0 ∫ ads 0

Momentum = mass × velocity 2

v
=∴ area=under a-s graph from s 0 to s = 12m
p' m' v' 2
=p ' m= =
' v ', P mv ,
p m v = 2 +12 + 6 + 4
1 α2 α2 1 = 24 m2/s2
= =
α 2β2 β β β3 =
or v =
48 m / s 4 3 m/s

2. (A, B, D) 6. (D)
As the particle is going up, it is slowing down, i.e., A = [M1L2T–1]; [B] = [M–1L3T–2]
speed is decreasing and hence we can say that time
taken by the particle to cover equal distances is 7. (B)
increasing as the particle is going up. The two projectiles attain the same height. It means
Hence, t1 < t2 < t3. u y1 = u y 2
SO, vav1 > vav2 > vav3 uy
Also, u x =
Acceleration throughout the motion remains the tan θ
same from the equation,
   u x1 u y1 / tan θ1 tan θ2
v = u + at , ∆v ∝ t ∴= =
u x 2 u y 2 / tan θ2 tan θ1
So Δν1 < Δv2 < Δv3

3. (A, B)
  
Component of A along B is | A | cos θBˆ for θ
being the angle between the vectors
iˆ + ˆj
Also, Bˆ = , So choice (1) is correct
2
The vector (iˆ − ˆj ) is perpendicular to the vector
2u x u y
(iˆ + ˆj ) Range =
g
So the other resolved components is
R1 u x1 tan θ2
  iˆ − ˆj  ∴ = =
| A− | sin θ   R2 u x 2 tan θ1
 2 
[ 2]
8. (10) 2u 2 sin θ
After t = 4s, velocity of B becomes lesser than R= …(ii)
g
velocity A and distance between the particles start
From equations-(i) and (ii), we get
decreasing.
1
Separation is maximum at t = 4 s R = gT f1T f 2
d max =( X A at t =
4) − ( X B at t =
4) 2

1 1
= × 4 × 10 − × 2 × 10 = 10 m 12. (1)
2 2 Time taken by train in retardation By using
s = u + v2t ⇒ 2 = 60 + 302tl ⇒ tl = 245hr
9. (1)
Time taken by train in accelerated motion
v0
Slope of line APB = − By using u +v2t ⇒ 1 = 30 + 60212 ⇒ t2 = 145h
1
Time taken by train to travel 3 km by uniform
[v0 = velocity at P]
motiont3 = 360 = 120hr
Let slope of tangent at P = m
Time lost = 345 – 120 × 60 = 1 min
 v 
m ×  − 0  =−1
 1  13. (1)
1 2L
m= + t1 =
v0 g
 dv  1
  =
 dx  P v0
 dv  1
∴ aP v=
= P  v0 . =1m/s2
 dx  P v0

10. (7)
Given u =
3iˆ + 4 ˆj , a =
0.4iˆ + 0.3 ˆj
v= u + at
=3iˆ + 4 ˆj + (0.4iˆ + 0.3 ˆj )10
L
= 3iˆ + 4 ˆj + 4iˆ + 3 ˆj = 7iˆ + 7 ˆj t2 =
V
So speed is equal to magnitude of velocity
∴ T =t1 + t2
72 + 72 =
7 2 units
2L L
⇒T
= +
g V
11. (4)
As it is given that the range of the two projectile are 2 1 1
⇒ ∆=
T × ∆L + ∆L
same, thus these must be thrown at complimentary g 2 L V
π  1 1 
angles. If one is thrown at 0. other must be at − θ ⇒ 0.01 =  ×
1
+
2  ∆L
 5 2 × 20 300 
. Thus time of flight for the two projectile we have
 1 1 
arc ⇒ 0.01 =  +  ∆L
2u sin θ 2u cos θ  20 300 
T f1 = and T f 2 =
g g (15 + 1)
⇒ 0.01
= ∆L
Multiplying the two we get 300
4u cos θ cos θ 0.01 × 300
T f1T f 2 = …(i) ⇒ ∆L =
16
g2
∆L 3
Range of projectile we have ∴ × 100
= × 100
= 1%
L 16 × 20

[ 3]
14. (A) Total change in velocity
Average acceleration =
(A) Corresponding v – t graph will Total time
Δv −10 −5
a= = = m / s2
Δt 6 3
av

Total displacement = area under v – t graph (with

sign)
⇒ Speed time curve will be speed decreasing in Area under the v – t graph from t = 0 to t = 6s is
(t3 – t4) given by
1 1
A = × 10 × 2 − × 4 × 10 =−10 m
2 2
Acceleration = slope of v – t graph.
⇒ Slope of the graph at
−10 − 0
( x ) 
dx  (t = 3 s) = = −5 m / s 2
(B)  < 0 to return (P,S,T) 4−2
 dt 
 dx 
(C) x   > 0 i.e. in (Q, R) 17. (D)
 dt 
Comparing with the standard equation of
(D) Speed in increasing in (t1 –t2) (t4 – t5)
projectile,
gx 2
15. (B) =
y xtanθ −
V 2u 2 cosθ
=F ASin( Bt ) +
C ln( Dx) We get, θ =45 and u = 20 2 ms −1
Time period of this projectile is 4 s .
[ Bt ] =  M 0 L0T 0 
  Hence, after 4 s , velocity vector will again make
0 0 −1 
[ B] =  M L T and angle of 45 with horizontal.
 
So, maximum height,
[= =
A] [ F ] MLT −2 

1 =
2 2
u 2sin 2 θ (20 2) sin 45
h =

( )
Pressure = P + ρv 2 + gx and 2g 2 × 10
2
1
1
S= ut + at 3 are dimensionally incorrect 400 × 2 ×
2 =
H = 2 400
= 20 m
20 20
and horizontal range,
16. (B)
Initial velocity vi = +10 m / s
=
2
u 2sin2θ (20 2) sin2 45
R =

( )
and final velocity vf = O g 10
∴ Change in velocity
=Δv =v f − vi =−10 m / s
=
400 × 2 × 1
=
10
(
 sin90 1 )
⇒R=
80 m

[ 4]
 PART-II (CHEMISTRY)
18. (A, B, C, D) 26. (2)
Fact. Energy gap between 2nd I.E. and 3rd I.E. is very
large. Therefore element has 2 valence electron.
19. (A, C)
In both case, readings are far away(± 0.4) from 27. (3)
correct value. Thus, are not accurate. Readings of
h h
X as well as that of Y are precise as close to one =
λ =
mv 2m(KE)
each other.
h2
20. (A, B, C, D)  λ2 =
2m(KE)
Uuo = 118 = [Rn]5f146d107s27p6
h2
(Ununoctium is an inert gas) ∴ KE = 2
2mλ
21. (C) (6.62 × 10−34 ) 2
∆v = 4 cm s–1 = 4 × 10–2 m s–1 =
2 × 9.1 × 10−31 × (287 × 10−9 ) 2
h h h
∆x ⋅ ∆v ≥ ∆x ≥ × = 3 × 10–24
4π 4π m∆v
6.626 × 10−34
∆x= = 1.32 × 10−30 m 28. (3)
4π × 10−3 × 4 × 10−2 Element X can lose its first two outermost electrons
easily. It is most likely bivalent. By similar
22. (B) reasoning element Y is tetravalent. Therefore, the
In H2S, 5.89 g H combines with= 94.11g of S compound may be X2Y.
94.11
1 g H combines with = = 16 g of S
5.89 29. (6)
In SO2, 50 g O combines with = 50 g of S
Zero coming left to a first non-zero digit is not
1 g O combines with = 1 g S
significant.
In H2O, 11.11 g H combines with = 88.89 g of O
88.89
1 g H combines with = 8 g of O 30. (8)
11.11
Fluorine is more E.N than oxygen.
Thus, law of reciprocal proportion is followed.

23. (C) 31. (D)

In case of transition elements (or any elements), the 1 1 1
= v (wave=
number) R H Z2  2 − 2 
order of filling of electrons in various orbital is 3p λ  n1 n 2 
< 4s < 3d. Thus, 3d orbital is filled when 4s orbital
gets completely filled. 1 1
=
I. v R H Z2  2 − 2 
Period number = maximum n of any element  n1 n 2 
(where n = principal quantum number. For α-line in Balmer series (first line), for He+, n1
= 2, n2 = 3. Z = 2.
24. (A)
 1 1 5
For ml = +2 (maximum), l = 2 and n = 3 =
∴ v R H (2) 2  2 − = 2 
⇒v RH
Number of waves in a shell = n = 3 2 3  9
II. For maximum wave number, n2 = ∞
25. (160) In Brackett series, n1 = 4, Li2+ (Z = 3)
Given, x °C = 2x °F
2 1  9
º F − 32 º C =
∴ vmax R= H (3)  2  RH
=  4  16
180 100
III. For minimum wave number n2 = (n1 + 1)
2x − 32 x
∴ = ⇒ x= 160º For Lyman series, n1 = 1
180 100
n2 = 2
[ 5]
 Be3+(Z = 4)  Ga  → Ga
3+

1 1   2 6 10 2 1 
∴= vmin R H (4) 2  2 −= 2
12R H  3s 3p 3d 4s 4p 3s 2 3p6 3d10 
1 2 
IV. For Paschen series, n1 = 3,
IV. Last e– is entered in 4s
n2 = 5 for β-line 1st (alkali metal) 2nd 12th
 1 1  16 (K) (Ca) (Zn)
∴ vmin= R H  2 − 2=  RH
 3 5  225
34. (D)
32. (C) I. Number of Angular nodes =  = 0 (given)
A-(Q, R); B-(S); (C)-(Q,T); (D)-(P,S)  = 0 for s-orbital.
3A + B → 2C + D II. Radial nodes = (n –  – 1) = 0 (given)
A is limiting reagent, 1.33 moles of C and 1.67 For, 4f, n = 4,  = 3
moles of D formed ∴ (n –  – 1) = 0
2A + 3B → 4C + 5D 3d, n = 3.  = –2
B is limiting reagent, 2.67 moles of C and 3.33 ∴ (n –  – 1) = (3 – 2 – 1) = 0
moles of D formed 2p, n = 2
3  =1
A+ B → 2C + D
4 (2 – 1 – 1) = 0
A is limiting reagent, 4 moles of C and two moles 2s, n = 2,  = 0
of D formed ∴ (n –  – 1) = (2 – 0 – 1) = 1
5 2 1s, n = 1,  = 0
A + B → C + 5D
9 3 (n –  – 1) = (1 – 0 – 1) = 0
B is limiting reagent, 1.33 moles of C and 10 moles III. Total number of radial and angular nodes
of D formed. = n –  – 1 +  = (n – 1)
It is zero only for 1s
33. (A) (n – 1) = (1 – 1) = 0
I. Cu = 11th group IV. Azimuthal quantum number =  = 0
II. Hg = 12th group or s-orbital
III. Ga = 13th group Thus, 1s and 2s

PART-III (MATHEMATICS)
35. (A, B, C, D) 36. (A, B)
1
f ( x)= 6cos x 1 + tan 2 x + 2sin x 1 + cot 2 x , sec θ = x +
4x
 π 3π 
x ∈ (0, 2π) − π, ,  =
tan θ sec2 θ − 1
 2 2
2
 1 
= 6cos x ⋅ sec x + 2sin x ⋅ cosec x = x+  −1
 4 x
  π
 6= +2 8 x ∈  0,  1
= x−
  2 4x
 π 
−6 + 2 =−4 x ∈ , π  1  1
∴ sec θ + tan α=  x +  + x −
 2   4x  4x

 −6 − 2 =−8 x ∈  π, 3π   1
 
  2   2 x if x > 4 x
 =
  3π   1 if x ≤ 1
 6 −= 2 4 x ∈ ,2 π
 2   2 x 4x

[ 6]
37. (A, B, C, D) ⇒ Emin =7 ×11×11
x2 – 2ax + a2 – 1 = 0
(x – a)2 = 1 ⇒ x = a + 1, a – 1 ⇒ Emin =×
7 121 =847
Now, –3 < a + 1 < 4 and –3 < a – 1 < 4 Here Emin =847 =7 × 11× 11
⇒ –4 < a < 3 and –2 < a < 5
It is not divisible by prime numbers 2, 3, 5
⇒ a ∈ (–2, 3)
So,= P 2,= Q 3,= R 5
⇒ [a] = –2, –1, 0, 1, 2
So, P + Q + R = 2 + 3 + 5 = 10
38. (A)
We know 42. (5)
sec α – tan α = 1
2 2
⇒ 2secθ = sec (θ – φ) + sec(θ + φ)
(sec α – tan α) (sec α + tan α) = 1 2 1 1
⇒
= +
 b − 4ac   b 
2 cos θ cos(θ − φ) cos(θ + φ)
  − = −1
 a   a  2 cos(θ + φ) + cos(θ − φ)
  ⇒ =
cos θ cos(θ − φ) cos(θ + φ)
Squaring both side
(b2 – 4ac)b2 = a4 2 2cos θ cos φ
⇒ =
a4 – b4 + 4ab2c = 0 cos θ cos 2 θ − sin 2 φ
⇒ cos2 θ – sin2 φ = cos2 θ cos φ
39. (A) ⇒ cos2 θ(1 – cos φ) = sin2 φ
(cosec A ⋅ cosec B + cot A ⋅ cot B)2 – (cosec A ⋅ cot B sin 2 φ
+ cosec B ⋅ cot A)2 ⇒ cos 2 θ =
1 − cos φ
= cosec2A(cosec2B – cot2B) – cot2A (cosec2B – cot2B)
φ φ
= cosec2A – cot2A = 1 4sin 2 cos 2
⇒ cos 2 θ = 2 2
2φ
2sin
40. (B) 2
Since (A ∩ BC ∩ CC) ∩ CC = (A ∩ BC) ∩ (CC ∩ CC) φ
⇒ cos 2 θ ⋅ sec 2 =2
=A∩B ∩C C C
2
Since A ∩ BC ∩ CC ⊂ A ∪ B ∪ C φ
⇒ cos 2 θ ⋅ sec 2 +3= 2+3= 5
Therefore (A ∪ B ∪ C) ∩ (A ∩ B ∩ C ) ∩ C
C C C 2
= A ∩ BC ∩ CC
But this is not given therefore if BC ∩ CC ⊂ A then 43. (3)
A ∩ BC ∩ CC = BC ∩ CC 2m – 2n = 56 ⇒ 8 × 7 = 23 × 7
2n(2m – n – 1) = 23 × 7 ⇒ n = 3
41. (A) 2 m – n = 8 = 23 = m – n = 3

 a 4 + 3a 2 + 4  b 4 + 5b 2 + 9  c 4 + 7c 2 + 4 
E =    44. (6)
 a2  b2  c2 
 4  9  4 
⇒ E =  a 2 + 2 + 3  b 2 + 2 + 5  c 2 + 2 + 7 
 a  b  c 
 2
2
  3
2

⇒ E =  a −  + 7   b −  + 11
 a   b 
 2
2

 c −  + 11
 c 
[ 7]
45. (1) =1
4x99 + 5x98 + 4x97 + 5x96 III. 10log10 3 + log10 tan1° + log10 tan 2° +
x98(4x + 5) + x96(4x + 5) + x94(4x + 5) + ... +1(4x + 5) ...log10 tan 89°
(4x + 5) (x98 + x96 + …+ 1)
= 3 + log10{(tan 1° ⋅ tan 89°)(tan 2° ⋅ tan 88°)
−5
x= as x98 + x96 + …+ 1 ≠ 0 …(tan 44° ⋅ tan 46°) tan45°}
4
=3
∴ Only one solution
IV. cos x + cos2 x = 1 ⇒ cos x = sin2x
∴ 4sin2 x ⋅ (2 – cos2 x)
46. (8)
= 4sin2 x ⋅ (1 + sin2 x) (∴ sin2 x + cos2 x = 1)
π 
5cos x + 3sin  − x  + 4 = 4(sin2 x + sin4 x)
6  = 4(sin2 x + cos2 x)
1 3  =4
= 5cos x + 3  cos x − sin x  + 4
2 2 
13 3 3 49. (B)
= cos x − sin x + 4
2 2 1 + cos θ (1 + cos θ) 2
I. =
169 27 1 − cos θ 1 − cos 2 θ
Maximum value = + +4
4 4 1 + cos θ
= = cosec θ + cot θ
196 sin θ
= +4
4
1 + tan 2 θ sec 2 θ
= 7 + 4 = 11 II. = = tan 2 θ
Minimum value = –7 + 4 = –3 1 + cot θ cosec θ
2 2

2 2
Sum of maximum and minimum value  1 − tan θ  1 − tan θ 
= 11 – 3 = 8 Also,  =   × tan θ 
 1 − cot θ   tan θ − 1 
47. (1) = tan2 θ
x + log10 (2 x=
+ 1) x log10 5 + log10 6 2 tan 2 θ
III. 1 +
x[1 − log10 5] + log10 (2 x + 1) =
log10 6 cos 2 θ
= (sec2 θ – tan2 θ)2 + 2tan2 θ ⋅ sec2 θ
x[log10 10 − log10 5] + log10 (2 x + 1) =
log10 6
= sec4 θ + tan4 θ
x log10 2 + log10 (2 x + 1) =
log10 6 IV. (1 – sin θ – cos θ)2
log10 2 x (2 x + 1) =
log10 6 = 2 – 2 sin θ – 2 cos θ + 2 sin θ ⋅ cos θ
(2 x ) 2 + 2 x − 6 =0 = 2(1 – sin θ) ⋅ (1 – cos θ)
2 x = 2 or 2 x = −3 (rejected)
50. (C)
⇒x=1
So, number of positive integers = 1 x2 – (k – 3)x + k = 0
For roots to be real
48. (C) (k – 3)2 – 4k ≥ 0
I. f (x) = sec2x + cosec2x – 4 ⇒ k2 – 6k + 9 – 4k ≥ 0
sin 2 x + cos 2 x ⇒ k2 – 10k + 9 ≥ 0
= −4
sin 2 x cos 2 x ⇒ (k – 1) (k – 9) ≥ 0
4 ⇒ k ∈ (–∞, 1] ∪ [9, ∞] …(i)
= −4
sin 2 2x I. For both roots to be positive,
fmin = 4 – 4 = 0 k −3
f (0) > 0 and >0
II. f (=
x) sin x − 4 − 3 2
k>0 …(ii)
f max = 0 − 4 − 3
[ 8]
 and k > 3 …(iii)
⇒
( 5 x − 2 )( 4 ) = 3 ⇒ x =1
From (i), (ii) and (iii) 3x + 1
k ∈ [9, ∞]
III. 7
(
log 7 x 2 − 4 x +5
=
) ( x − 1)
II. For both roots to be negative
D≥0 ⇒ x2 − 4 x + 5 = x − 1
k > 0, (k – 3) / 2 < 0,
⇒ k < 3, ⇒ k ∈ (0, 1] ⇒ x2 − 5x + 6 =0
III. For both roots to be real k ∈ (–∞, 1] ∪ [9, ∞) ⇒ ( x − 2 )( x − 3) = 0 ⇒ x = 2 or x = 3
IV. f (–1) < 0, f (1) < 0 Also we must have x 2 − 4 x + 5 > 0 and x − 1 > 0
1 + (k – 3 ) + k < 0 also 1 – (k – 3 ) + k < 0
⇒ 2k – 2 < 0 ⇒ k < 1, 4 < 0 (
⇒ x > 1 as x 2 − 4 x + 5 > 0 is true for all real numbers )
No such value is possible 2
1  log 2 x 
IV. x > 0, log 2 x − 2   +1 > 0
51. (B)
2  2 
⇒ log 2 x − ( log 2 x ) + 2 > 0
2
I. A log 2 log 2 log 4 256 + 2log 2
2

⇒ ( log 2 x ) − log 2 x − 2 < 0

2
log 2 log 2 log 4 44 + 2log 2
21/2
=log 2 log 2 4 + 4log 2 2 =1 + 4 =5 =
Let log 2 x t , we have t 2 − t − 2 < 0
II. log3 ( 5 x − 2 ) − 2log3 3 x + 1 =1 − log3 4 ⇒ ( t − 2 )( t + 1) < 0 ⇒ −1 < t < 2
⇒ log3 ( 5 x − 2 ) − log3 ( 3 x + 1) + log3 4 =
1 1
⇒ −1 < log 2 x < 2 ⇒ <x<4
2
 ( 5 x − 2 )( 4 ) 
⇒ log3  =1 Hence, the number of integers is 3, i.e., {1, 2, 3}
 3x + 1 

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