0% found this document useful (0 votes)
6 views32 pages

Chapter 1new

Download as pdf or txt
Download as pdf or txt
Download as pdf or txt
You are on page 1/ 32

Dr.

Qana Alsulami
Assistant professor
Contact Info: qalselami@kau.edu.sa

Web Site: http://qalselami.kau.edu.sa


 Locations:
◦ Science tower 07 room 174 first floor
◦ phone 6400000 ext. 23024
◦ email Qalselami@kau.edu.sa
◦ web site: http://qalselami.kau.edu.sa
 Exam schedule:
 1st exam : from lecture 1-11 ( Chapters 1-4) = 30 marks
 2nd exam: from lecture 12-24 (Chapters 5,7-9) = 30 marks
 Final exam: from lecture 1-33 = 40 marks
 (Chapters 1,2,3,4,5,7,8,9,14,15,24 & 25)

Dr. LAILA AL-HARBI


CHEM 110
No. of Units
1 Course No. Course Title Pre-requisites
Th. Pr. Credit
Chem 110 General Chemistry I 3 - 3 -

Course Objectives:
The course aims to introduce students to basic knowledge and principle in chemistry.

Course Description :
It provides an introduction to the general principles of chemistry for students planning a
professional career in chemistry, a related science, the health professions, or
engineering. By the end of this course the student will be able to understand the
following: Significant figures, scientific notation and units, stoichiometry, atomic
structure & periodic table, chemical bonding, gases, ionic equilibrium, basic principles
of organic and basic principles of biochemistry .

Main text books:


 Chemistry, by Chang, 10th. ed., 2007, McGraw-Hill.
 Chemistry, by Steven S. Zumdahl, 6th ed., Houghton Mifflin College Div.

Subsidiary books :
Chemistry, by Mortimer, 6th ed., Wadsworth Inc.
Dr. LAILA AL-HARBI
CHEM 110

Main text book :


 Chemistry, by
Chang, 10th. ed.,
2007, McGraw-
Hill.

Dr. LAILA AL-HARBI


‫المذاكرة أول باول‬ ‫‪‬‬

‫عدم التغيب عن المحاضرات‬ ‫‪‬‬

‫مذاكرة الكتاب الدراسي و المحاضرات‬ ‫‪‬‬

‫حل بنك االسئلة ‪ ...‬حيث يحوي على مجموعة مختلفة من االسئلة بافكار متعدده ‪ ...‬تساعدك‬ ‫‪‬‬

‫على التدرب‬
‫التدرب على االسئلة في الموقع التفاعلي حيث أن الطريقة شبيهة تماما باالختبار االلكتروني‬ ‫‪‬‬

‫‪http://prod.kau.edu.sa/faculties/science/website2/index.aspx‬‬ ‫‪‬‬

‫و أخيرا ‪ ...‬التوفيق بيد هللا سبحانه و تعالي‬ ‫‪‬‬

‫‪Dr. LAILA AL-HARBI‬‬


Measurement
 SI units
 Mass and weight
 Volume
 Temperature scales

Dr. LAILA AL-HARBI


 By the end of this chapter you should:
 Know the 7 SI basic units and their prefixes.
 Be able to convert from one unit to other.
 Know to derive units from the 7 SI basic units.
 Common units (L & mL)
 Know the temperature Scales

Dr. LAILA AL-HARBI


 Chemistry is the study of matter and the changes it
undergoes
 There are three states of matter
gas

liquid
solid

Dr. LAILA AL-HARBI


 used for commerce and science around the world

Dr. LAILA AL-HARBI


Examples
The SI unit of mass is The Kg is the SI unit of

(a) The pound (a) length

(b) The gram (b) mass

(c) The kilogram (c) temperature

(d) The mole (d) current

10
1m

Dr. LAILA AL-HARBI


‫‪‬‬ ‫خط االعداد ‪use numerical line‬‬
‫)‪A‬‬
‫معامل التحويل ‪ B) use transfer factor‬‬

‫للتحويل من الوحده االساسية و مضاعفتها أو المشتقات‬


‫يمكننا استخدام خط االعداد أو استخدام معامل التحويل‬
‫(بضرب الطريفين في الوسطين ) و لكن ال تخلطي بين‬
‫الطريقتيين كما أن الطريقتين يعطوا نفس النتيجة اذا‬
‫استخدموابطريقة صحيحة‪.‬‬

‫‪Dr. LAILA AL-HARBI‬‬


‫معامل التحويل‬ ‫معامل التحويل‬
‫‪1012‬‬ ‫‪1012‬‬
‫‪109‬‬ ‫‪109‬‬
‫‪106‬‬ ‫‪106‬‬
‫‪103‬‬ ‫‪103‬‬
‫‪102‬‬ ‫‪10‬‬
‫‪p‬‬ ‫‪µ m c d SI K M‬‬
‫‪n‬‬ ‫‪G‬‬ ‫‪T‬‬
‫‪103 103 103 10 10 10 103 103 103 103‬‬
‫وحدة صغيرة‬ ‫وحدة كبيرة‬

‫بهذا االتجاه تزيد الوحده‬

‫للتحويل من صغير الى كبير نقسم ÷ ‪ ,‬للتحويل من كبير الى صغير نضرب ×‬

‫للتحويل من الوحده االساسية و مضاعفتها أو المشتقات يمكننا استخدام خط‬


‫االعداد أو استخدام معامل التحويل (بضرب الطريفين في الوسطين ) و لكن ال‬
‫تخلطي بين الطريقتيين كما أن الطريقتين يعطوا نفس النتيجة اذا تم استخدامها‬
‫بنفس بطريقة صحيحة‪.‬‬
‫‪Dr. LAILA AL-HARBI‬‬
‫‪I.‬‬ ‫?‪Convert 134 pm to m‬‬
‫‪II.‬‬ ‫?‪How many meters are in 134 pm‬‬
‫الحل باستخدام خط االعداد‬

‫للتحويل من صغير الى كبير نقسم ÷‬


‫الحل باستخدام الجدول طرفين في وسطين‬
‫= ‪1 pm‬‬ ‫‪1×10-12 m‬‬
‫‪134 pm = ?? m‬‬
‫‪134 ×1×10-12 m = 1.34×10-10 m‬‬
‫‪Dr. LAILA AL-HARBI‬‬
 The SI prefixes giga
and micro represent,
 The SI unit of mass is respectively:
 A. 10-9 and 10-6.
 (a). The pound
 B. 106 and 10-3.
 (b). The gram  C. 103 and 10-3.
 (c). The kilogram  D. 109 and 10-6.

 (d). The mole.

Dr. LAILA AL-HARBI


How many microseconds are in a second?
(a). 1 x 10-1
(b). 1 x 10-6 1 µs= 1 x 10 -6 s
(c). 1 x 10-15 x µs = 1 s
(d). 1 x 10 6
Explanation: Since the prefix micro means 1 x 10-6, there will be
1 x 10 + 6 microseconds in one second.

s µs

1 x 10 6 1 x 10 6 µs

Dr. LAILA AL-HARBI


 Which of the following is the smallest distance?
 (a) 21 m → 21m
 (b) 2.1 x 102 cm → 2.1m
 (c) 21 mm → 0.021 m
 (d) 2.1 x 104 pm → 2.1 x 10-8 m

Put all of them in the same unit

 Explanation: Even though 2.1 x 104 is the largest


number in this question, the units of pm (picometers)
are the smallest units here, making it the smallest
distance.
Dr. LAILA AL-HARBI
 A) 6.0 km is how many
micrometers?

 Solution 1

1 km = 103 m µm
km
6 km = x = 6 × 103 m

1µm = 1× 10-6 m

x = 6 × 103 m
6 × 109 6 × 109
x = 6 × 109µm

Explanation: convert first to meter then from meter to micro


( two steps solution )

Dr. LAILA AL-HARBI


 Example  Example
 The diameter of an atom is
approximately 1  10-7 mm.
 Which of these quantities
What is this diameter when
expressed in nanometers? represents the largest mass?
 A. 1  10-18 nm  A. 2.0  102 mg X10-3
 B. 1  10-15 nm  B. 0.0010 kg X103

 C. 1  10-9 nm  C. 1.0  105 g X10-6


 D. 1  10-1 nm  D. 2.0  102 cg X10-2
 Put all of them in the same
unit A) 0.2 g
 = 1× 10-7 × 1 × 106 =
B)1 g
 1 × 10-1 nm = 0.1 nm C) 0.1 g
D) 2 g
Dr. LAILA AL-HARBI
 are defined in terms of the seven base quantities via a
system of quantity equations.
 The SI derived units for these derived quantities are
obtained from these equations and the seven SI base
units. For example
 Area = width x length
 Unit of width = m Treat units like numbers
 Unit of length = m
 Unit of Area = m× m = m2

Dr. LAILA AL-HARBI


Volume –
Volume = width × length × heights = m × m × m = m3
SI derived unit for volume is cubic meter (m3)
Common unit of volume is liter (L) and milliliter (ml)
The relation ship between liter (L) and ml (1L= 1000mL)
The relation ship between liter (L) and metric system
1 L = 1 dm3
The relation ship between milliliter (ml) and metric system
1 mL = 1 cm3
1 dm3 = (1 x 10-1 m)3 = 1 x 10-3 m3
1 cm3 = (1 x 10-2 m)3 = 1 x 10-6 m3

Dr. LAILA AL-HARBI


Example (3)
Example (1)

 How many liters are in 25


 How many liters are in 250
dm3 ? cm3 ?

 Since 1L = 1 dm3  Since 1L = 1 dm3


 and 1mL = 1 cm3
 25 dm3 = 25L
 250 cm3 = 250 mL
Example (2)
 1L → 1000mL
 250/1000 = 0.25 L
 How many milliliters are in
32 cm3 ?
 Since 1mL = 1 cm3

 32 cm3 = 32 mL
Dr. LAILA AL-HARBI
 How many cubic centimeters are there in exactly
one cubic meter?
 A. 1  10-6 cm3
 B. 1  10-3 cm3
 C. 1  10-2 cm3
 D. 1  106 cm3
 Solution
 (1m )3 = (cm )3
 1m3 = (1  102)3 cm 3
 1m3 = 1  106 cm3

Dr. LAILA AL-HARBI


 Mass is the measure of the amount of
matter in an object.
SI unit of mass is the kilogram (kg)
1 kg = 1000 g = 1 x 103 g

 Weight is the measurement of the pull


of gravity on an object.

weight = c x mass
 The Mass of an object doesn't change
when an object's location changes.
Weight, on the other hand does change The weight of man on earth is 50 pounds.
with location. >> 8.25 pounds on moon
 Chemist are interested primarily in mass

Dr. LAILA AL-HARBI


Density is defined as the amount of
matter in a given amount of space.
mass
density = volume
 SI derived unit for density is kg/m3
 common units of density are g/mL ,
g/L
 Density decrease with temperature
(g/ml )g/cm3 for liquid and solids
g/L = 0.001g/ml for gases

 Because density of gases are very


low The density of copper
is 8.94 g/cm3.

Dr. LAILA AL-HARBI


Given Given
Given
m&V m&d
V&d
?d ?V
?m
d = m/V V = m /d
m=dxV
26
 A piece of Gold metal  A piece of platinum
has a volume of 15.6 metal with a density of
cm3, with a mass of 301 21.5 g/cm3 has a
g What is its density? volume of 4.49 cm3.
What is its mass?
m
d= V m
d= V
301 g/ 15.6 cm3
= 19.3 g/ cm3 m=dxV
= 21.5 g/cm3 x 4.49 cm3
= 96.5 g
Dr. LAILA AL-HARBI
 The density of mercury  The density of sulfuric
is 13.6 g/mL has a acid is 1.41 g/mL has a
volume of 5.50 mL. volume of 242 mL.
What is its mass? What is its mass?
m
d= V
m=dxV m
d= V
= 13.6 g/mL x 5.50 mL m=dxV
= 74.8 g
= 1.41 g/mL x 242 mL
= 341.22 g
Dr. LAILA AL-HARBI
 Fahrenheit °F →°F = [ (9/5) × °C] + 32
 Celsius °C → °C = (5/9) (°F - 32)
 Kelvin ° K → ° K = °C + 273.15

Dr. LAILA AL-HARBI


Temperature Units Conversion
1. Degrees Celsius 0C: Scale 0 → 100 Thus: 100
divisions or 100 degrees
2. Kelvin K: Scale 273 → 373
Thus: 100 divisions or 100 degrees
1K = 1 C
3. Degrees Fahrenheit 0F : Scale from 32→ 212
Thus: 180 divisions or 180 degrees
Thus: the size of degree in 0F scale is only 100/180 or
5/9 of a degree on the 0C scale 10F = (5/9) 10C

30
 Convert 224 0C to degrees Fahrenheit?
 °F = (9 0F /5 0C) × °C + 32
 [°F = (9 0F /5 0C) × 224 °C] + 32 0C = 435 0F

 Convert -452 0F to degrees Celsius.


 °C = (5 0C /9 0F) (°F - 32 0F)
 °C = (5 0C /9 0F) (-452 °F - 32 0F) = -269 0C

 Convert -38.9 0C to degrees Kelvin..


 ° K = [-38.9 °C + 273.15 °C ] × 1 K/ 1 0C = 234.3 K

Dr. LAILA AL-HARBI


 Ammonia boils at -33.4C. What temperature is
this in F?
 A. -60.1F
 B. -92.1F
 C. -28.1F
 D. +13.5F

F = (9 0F /5 0C) × °C + 32
[°F = (9 0F /5 0C) × -33.4 °C] + 32 0C = - 28.1 0F

Dr. LAILA AL-HARBI

You might also like