Thermodynamics 1 Chapter 6 Presentation
Thermodynamics 1 Chapter 6 Presentation
Thermodynamics 1 Chapter 6 Presentation
Chemical Engineering
Thermodynamics
Seventh Edition
Chapter 6 PowerPoint
Copyright the McGraw-Hill Companies, Inc. Permission required for reproduction or display.
So we can write
(T/V)S = 2U/SV
-(P/S)V =2U/SV
therefore
(T/V)S= -(P/S)V
Eq. 6-13
Above equation is known as Maxwells equation
Similarly for H = H(S,P)
dH = (H/S)P dS + (H/P)SdP
We had dH = TdS + V dP So, T = (H/S)P
V=(H/P)S
(T/P)S = 2H/SP
(V/S)P= 2H/PS
therefore,
(T/P)S = (V/S)P
Eq. 6-14
similarly for A & G we can
write;
(P/T)V = (S/V)T
Eq. 6-15
(V/T)P = - (S/P)T
Eq. 6-16
(T/V)S= -(P/S)V
Eq. 6-13
(T/P)S = (V/S)P
Eq. 6-14
(P/T)V = (S/V)T
Eq. 6-15
(V/T)P = - (S/P)T
Eq. 6-16
Example 1
A cylinder piston device contains saturated liquid
water at 0oC. At constant temperature pressure
on the cylinder is increased, which of statement
given below is correct?
1)Entropy of saturated liquid at 0oC is less
than entropy of compressed liquid.
2) Entropy of saturated liquid at 0oC is
greater than entropy of compressed liquid.
3) Entropy of saturated liquid at 0oC is equal
to entropy of compressed liquid.
4) The change depends on final pressure.
Solution:
Since; (S/P)T = - (V/T)P and @ 0C
(V/T)P is negative therefore at higher
pressure entropy will increase.
Example 2
Example 3
Slope of constant pressure line relative to slope of constant volume
line of water steam on T-S diagram is
1) smaller than one.
2) greater than one.
3) equal to one.
4) it depends on temperature could be smaller than one or greater
than one.
Solution:
We had dS = CP dT/T (V/T)P dP and
dS = CV dT/T + (P/T)V dV @ constant pressure
(V/T)P dP =0 therefore, [T/S]constant pressure = T/CP and @
constant volume (P/T)V dV =0
therefore,
[T/S]constant volume =T/ CV
Residual Properties
Z =0.935
VR = RT(Z 1) / MW P
VR = 8.314x498.15x10-3(0.935 -1)/[18x1600] = -9.33 cm3/g