Chemistry Investigatory Project

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CHEMISTRY INVESTIGATORY

PROJECT
IDENTIFICATION OF ANIONS AND
CATIONS PRESENT IN THE TOOTHPASTE
Aim:-
IDENTIFICATION OF THE
CATIONS AND ANIONS IN
TOOTHPASTE.
Theory:-
Every toothpaste contains the following
ingredients: binders, abrasives, subsers,
humectants, flavours, sweeteners, fluorides,
tooth whiteners, a preservative and water.
Binders thicken toothpaste- they prevent
separation of the solid and liquid component,
especially storage. They also effect the speed
and volume of foam production, rate of flavor
release and product dispersal, the appearance
of toothpaste ribbon on the toothbrush. Some
binders are gum solid alginate, methyl
cellulose, carrageen and magnesium
aluminium silicate.
Identification Of Anions and
Cations Present In The
Toothpaste
• ANIONS IN AN ATOM OR MOLECULE
THAT CARRIES AN ELECTRIC CHARGE.
CATIONS ARE POSITIVELY CHARGED
IONS CREATED BY THE LOSS OF
ELECTRONS.
• TOOTHPASTE IS A PASTE OR GEL
DENTIFRICE USED WITH A
TOOTHBRUSH AS AN ACCESSORY TO
CLEAN AND MAINTAIN THE AESTHETICS
AND HEALTH OF TEETH.
• TOOTHPASTE IS USED TO PROMOTE
ORAL HYGIENE: IT SERVES AS AN
ABRASIVE THAT AIDS IN REMOVINGTHE
DENTAL PLAQUE AND FOOD FROM THE
TEETH, ASSISTS IN SUPPRESSING
HALITOSIS, AND DELIVERS ACTIVE
INGREDIENTS (MOST COMMONLY
FLUORIDE) TO HELP PREVENT TOOTH
AND DISEASE (GINGIVITIS).
• SALT AND SODIUM BICARBONATE
(BAKING SODA) ARE AMONG
MATERIALS THAT CAN BE
SUBISTITUTED FOR COMMERCIAL
TOOTHPASTE.
• TOOTHPASTE IS NOT INTENDED TO BE
SWALLOWED DUE TO THE FLOURIDE
CONTENT, BUT IS GENERALLY NOT
VERY HARMFUL IF ACCIDENTLY
SWALLOWED IN SMALL AMOUNTS.
• HOWEVER ONE SHOULD SEEK
MEDICAL ATTENTION AFTER
SWALOWING ABNORMALLY LARGE
AMOUNTS
Components Used In
Toothpaste:-
HClO4

HNO3 HCl

H2SO4 HI
Ingridents:-
IN ADDITION TO 20%-42% WATER,
TOOTHPASTES ARE DERIVED FROM A
VARIETY OF COMPONENTS, THE THREE
MAIN ONES BEING ABRASIVES, FLUORIDE,
AND DETERGENTS.
Abrasives:-
ABRASIVES CONSTITUTE AT LEAST 50% OF TYPICAL TOOTHPASTE.
THESE INSOLUBLE PARTICLES HELP REMOVE PLAQUE FROM THE
TEETH. THE REMOVAL OF PLAQUE AND CALCULUS HELPS MINIMIZE
CAVITIES AND PERIDONTAL DISEASE. REPRESENT ABRASIVES
INCLUDE PARTICLES OF ALUMINUM HYDROXIDE (Al(OH)2), CALCIUM
CARBONATE(CaCO3),VARIOUS CALCIUM HYDROGEN PHOSPHATES,
VARIOUS SILICAS AND ZEOLITES, AND HYDROXYAPATITE (Ca5(PO4)3
OH).
• ABRASIVES, LIKE THE DENTAL POLISHING Agents
Used in dentists‟ Offices, also cause a Small
Amount Of Enamel Erosion which is termed
“polishing” action. Some BRANDS CONTAIN
POWDERED WHITE MICA, WHICH ACTS AS A MILD
ABRASIVE, AND ALSO ADDS A COSMETICALLY
PLEASING GLITTERY SHIMMER TO THE PASTE.
• THE POLISHING OF TEETH REMOVES STAINS
FROM TOOTH SURFACES, BUT HAS NOT BEEN
SHOWN TO IMPROVE DENTAL HEALTH OVER AND
ABOVE THE EFFECTS OF THE REMOVAL OF
PLAQUE AND CALCULS.
FLUORIDES:-
FLUORIDE IN VARIOUS FORMS IS THE MOST
POPULAR ACTIVE INGREDIENTS IN
TOOTHPASTE TO PREVENT CAVITIES.
FLUORIDES OCCUR IN SMALL AMOUNT IN
PLANTS, ANIMALS AND SOME NATURAL
WATER SOURCES.
THE ADDITIONAL FLUORIDES IN TOOTHPASTE
HAS BENEFICIAL EFFECTS ON THE
FORMATION OF DENTAL ENAMEL AND BONES.
SODIUM FLUORIDE (NaF) IS THE MOST
COMMON SOURCE OF FLUORIDE, BUT
STANNOUS FLUORIDE (SnF), OLAFLURS (AN
ORGANIC SALT OF FLUORIDE), AND SODIUM
MONOFLUROPHOSPHATE (Na2 PO3 F) ARE
ALSO USED.
STANNOUS FLUROIDE HAS BEEN
SHOWN TO BE MORE EFFECTIVE THAN
SODIUM FLUROIDE IN REDUCING THE
INCIDENCE OF DENTAL CARIES AND
CONTROLLING GINGIVITIS.
Much Of The toothpaste sold in the “U.S.
Has 1000 TO 1100 PARTS PER MILLON
FLUROIDE.
IN EUROPEAN COUNTRIES, SUCH AS
THE UK OR GREECE, THE FLUORIDE
CONTENT IS OFTEN HIGHER; A NaF OF
0.312% W/W (1,450 PPM FLUORIDE) IS
NOT UNCOMMON.
TEST ON COLGATE
COLOUR OF THE TOOTHPASTE:- WHITE
EXPERIMENT OBSERVATION INFERENCE
TAKE A PART OF THE FORMATION OF WHITE carbonatE ION
SOLUTION AND ADD OF PPT CONFIRMED
MGSO4 SOLUTION.
TAKE A PART OF FORMATION OF WHITE CaLCIUM ION
SOLUTION AND ADD OF PPT CONFRIMED
AMMONIUM
HYDROXIDE(1-2ML)
TAKE A PART OF FORMATION OF WHITE Phosphate CONFRIMED
SOLUTION AND ADD OF PPT
MAGNESIUM MIXTURE
(MIXTURE OF NH4Cl
AND NH4OH)
ACIDIFY A PORTION OF FORMATION OF YELLOW iodide IS CONFRIMED
AQUEOUS SOLUTION OF PPT WHICH IS
WITH DILUTE HNO3. BOIL SOLUBLE IN ammonium
AND COOL AND ADD hydroxide
AgNO3
TAKE A SMALL NO SMELL OBSERVED CH3COO- aBSENT
QUANTITY OF SOLUTION
AND ADD OXALIC ACID,
THE PASTE OF IT WITH
FEW DROPS OF WATER
RUB AND SMELL
TAKE ONE PART OF NO REACTION PB2+ ABSENT
SOLUTION ADD KI

TO ONE PART OF THE A WHITE PPT IS Mg2+ PRESENT IONS


SOLUTION ADD SOLID FORMED.
NH4OH IN SLIGHT
EXCESS THEN ADD
AMMONIUM PHOSPHATE.

CHEMICAL REACTIONS:-
• CO3+MgSO4→MgCO3+SO4 2- CO3+2CH3COOH→(CH3COO)2Ca+H2O
• (CH3COO)2Ca+(NH4)2C2O4→2CHCOONH4+CaC2O4
NaHPO4+MgCl2+NH4OH→Mg(NH4)PO4+2NaCl+H2O
• I+AgNO3→NO3+AgI (YELLOW PPT)
• (COOH)2+2CH3COONa→NO REACTION
• Pb+2KI→ NO REACTION
MgCL2+NH4OH+(NH3)2HPO4→Mg(NH4)PO4+2NH4+H2O
TEST ON MISWAK
COLOUR OF PASTE:- WHITE
I+AgNO3→NO3+AgI (YELLOW PPT)
(COOH)2+2CH3COONa→NO REACTION
Pb+2KI→ NO REACTION
MgCL2+NH4OH+(NH3)2HPO4→Mg(NH4)PO4+2NH4+H2O

IONS PRESNT :-
1. COLGATE:- Mg2+ , I- , PO4, Ca2+ , CO3 2-
2. MESWAK:- Mg2+ , I- , PO4 , Ca2+ , CO3 2- ,
CH3COO-
CONCLUTION :-
HENCE AFTER TESTING DIFFERENT
SAMPLES OF TOOTHPASTE, WE FIND THAT
COLGATE HAS ALL NECESSARY ANIONS
AND CATIONS FOR STRONGER AND WHITER
TEETH.
SAFETY TIPS WHILE DOING THIS
EXPERIMENT:-

NITRIC ACID CAUSES BURNS.

SODIUM HYDROXIDE CAN CAUSE


BURNS AND IS DANGEROUS TO
. THE EYES.
AMMONIA SOLUTION CAUSES
BURNS AND GIVES OFF AMMONIA
VAPOURS WHICH IRRITATES THE
EYES, LUNGS AND RESPIRATORY
SYSTEM. WEAR EYE
PROTECTION
Bibliography:-
I. NCERT CHEMISRTY
II. PRADEEP’S CHEMISTRY
III. GOOGLE
IV. WIKIPEDIA

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