Olivine and Garnet Family
Olivine and Garnet Family
Olivine and Garnet Family
Krishna
22/2/2021
Olivine Group
• They belong to nesosilicates
• This group consist of isomorphous
series ie they show solid solution series
• The end members are Forsterite
(Mg2SiO4) and Fayalite (Fe2SiO4). Olivine
= (MgFeSiO4)
• Olive is considered to have
composition of Fo63 Fa37
• General formula R2SiO4 R = Mg and Fe
Members in the olivine group
Physical Properties
Crystal System – Orthorhombic system
Form and Habit – Prismatic crystal modified by domes
and pyramid. Some are massive, grains or compact.
Colour – Shades of green, pale green, olive green
Brownish, white or yellow In forsterite
Brown or black in fayalite
Cleavage – poor
Streak - colourless
Fracture – conchoidal
Hardness – 6 -7
Sp Gravity – Fo 3.2, Fa 4.3 olivine is intermediate
Optical properties
1. Colour – colourless for Fo and faint greenish
for Fa
2. Habit - anhedral in plutonic rock to euhedral
in extrusive rocks
3. Relief – high to very high
4. Birefringence - high with third order
interference colour
5. Interference fig- optically Fo is positive Fa is
negative
Alteration
Very susceptible to hydrothermal alteration, weathering
and the effects of low–grade metamorphism.
Produce serpentine, chlorite, amphibole, talc etc
During alteration hydrogen ion is added to olive structure
which helps oxygen to release Mg, Fe2+ Si and adds Fe3+ Al
Ca
Occurrence
Mg rich olivine associated with ultra basic rock like
perdotite, picrites, dunite. In basic igneous rocks like
gabbro, norite, dolerites baslat
Fe rich occurs in intermediate rock such as larvikites, alkali
basalt where olive occurs with Qtz.
Pure forsterite is found metamorphosed impure dolomite
Olivine in Igneous rock show reaction rim
Rock entirely made of olivine is DUNITE
Mg rich olive is found in meteorites of Moon and Sun. it is
rich in iron, nickel, olivine
Varieties
Peridot – gem variety of olivine, transparent, plae green
Uses
• Gemstone variety is peridot. It is yellow green to green
colour
• Olivine is used in metallorgical process as slag conditioner
• In steel industry forsterite is added in blast furnace to
remove impurities
• It is used as refractory material making refractory brick
• Used as casting sand
GARNET GROUP
• Nesosilicates
• General formula X3Y2Si3O12 X = divalent ions like
Ca, Mg, Fe, Mn and Y= trivalent ions such as Al,
Fe, Cr and Ti
• REE may also substitute in Y position
• Solid solution series within the family are
common. It is a group of six minerals which are
isomorphous in nature. But they never occur
pure
Members of Olivine family
Mainly there are two series
1. Pyralpsite
Pyrope - Mg3Al2Si3O12 Deep crimson
Almandine - Fe3Al2Si3O12 Deep red
Spessartine - Mn3Al2Si3O12 Brownish
red
2. Ugrandite
•Uvarovite Ca3Cr2Si3O12 Emerald green,
yellow or pink
•Grossularite - Ca3Al2Si3O12 Olive green,
•Andradite - Ca3Fe2Si3O12 Dark brown,
yellowish green or brownish green