Hanna Obiado - Soap and Detergent

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Chemicals Present in Soap and Detergent

Consumer Chemistry Quarter 3


Reporter: Hanna Camille DC
Obiado

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Preparation of Soap
Ingredients:
A. Fatty acid from animal fats and vegetable oils

▪ Source of the hydrocarbon chain – hydrophobic


(water-hating end) but attracted to grease and oils
▪ Carboxylate end – hydrophilic (water-loving end)

B. Alkali

▪ Sodium hydroxide (NaOH) or caustic


soda –
produces hard soap-like bath and bar soap
▪ Potassium hydroxide (KOH) or caustic
potash – produces soft soap like in liquid hand
soap

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Chemical Structure of Soap

Saponification
-involves heating plant oils and animal fats, reacting them with a
liquid alkali to produce soap plus water plus glycerine.li
Another way of soap making is the hydrolysis of oils and fats in high-pressure steam to yield crude fatty
acids and glycerine – purification of fatty acids through distillation and neutralization of fatty acids with
alkali to form soap and water

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Preparation of Detergent
Ingredients:

A. Petrochemicals (derived from


petroleum) and oleochemical (derived
from fats and oils – the source of the
hydrocarbon chain, the hydrophobic
end of detergent but attracted to grease and oils

B. Other chemicals like sulfur trioxide,


sulfuric acid, or ethylene oxide
- the source of hydrophilic end of the detergent

C. Alkali
– sodium or potassium hydroxide

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Chemical Structure of Detergent

The chemicals like sulfur trioxide and sulfuric acid react


with the hydrocarbon from petrochemical or oleochemical.
It produces a new acid. The new acid then reacts with the
alkali to produce the anionic surfactant molecule.

Another way to produce detergent is when the


hydrocarbon chain is converted to fatty alcohol
and then reacts with ethylene oxide. It produces
a nonionic surfactant. This nonionic
surfactant can further react to sulfur-
containing acids to form the anionic
surfactant, the active ingredient of detergents.

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How soap and detergent
works
Three types of energy are needed for a good result of cleaning
using soap and detergent:
A. Chemical energy – is provided by the soap and detergent.
The
hydrophilic end (water-loving) mixed up the water, and the
hydrophobic end (water-hating) removes the soil’s grease and
oils.
B. Thermal energy – change in water temperature. Warm water
or hot temperature helps to dissolve the grease and oil of the
soil.

C. Mechanical energy – Machine, hand rubbing, and


another way of agitation help pull the soil free.

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Surface Tension

● Property of water

● The tension is created as the water


molecules at the surface are pulled into the
body of water.

● It slows down the wetting of the surface


and inhibits the cleaning process.

.
Surfactant

● Also called surface-active agents

● Chemicals change the properties of water by


lowering the surface tension

● Enables the cleaning solution to wet a surface more


quickly so the soil can easily be loosened or removed

● Emulsifies the oily soils and keeps them dispersed


and suspended

.
Classificatio
n of
surfactants

.
Chemical Structure of the Different Types of Surfactants

.
Builder
s
● Enhance the cleaning effectiveness of surfactants
● Reduce water hardness (possible formation of scum or film)
● Supply and maintain alkalinity
● It is done either by:

Sequestration or chelation – holding hard materials in the


solution
Examples: complex phosphates and sodium citrate

Precipitation – forming an insoluble substance


Examples: sodium carbonate and sodium silicate

Ion exchange – trading electrically charged particles


Example: sodium aluminosilicate (zeolite)

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Questions?
.
Thank you all for
listening!!!

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