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    Chemical Equations Lesson Presentation in a Blue Bold Style 20241203 (2)

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    Hanan Elmadani

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    © All Rights Reserved
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    Chemical Equations Lesson Presentation in a Blue Bold Style 20241203 (2)

    Uploaded by

    Hanan Elmadani
    0 views14 pages

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    © © All Rights Reserved

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    0 views14 pages

    Chemical Equations Lesson Presentation in a Blue Bold Style 20241203 (2)

    Uploaded by

    Hanan Elmadani

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 14

    Precipitatio

    n Titration
    Student´s name :-Hanan Yheya
    Elmaedani
    Precipitation Titration
    Precipitation titration is a quantitative analytical technique where a
    titrant is added to a solution containing an analyte until a
    precipitate forms. This method is used to determine the
    concentration of ions in a solution based on the formation of an
    insoluble compound. The endpoint is typically indicated by a color
    change or the cessation of precipitate formation, depending on the
    method used
    Methods in Precipitation

    titration
    One Two Thre
    e
    Mohr method Volhard Fajans
    Direct method method
    Indirect Direct
    MOHR METHOD
    Mohr Method : Karl Friedrich Mohr (1806-1879) This method utilizes
    chromate as an indicator. Chromate forms a precipilate with Ag+ but this
    precipitate has a greater solubility than that of AgCl, for example.
    Therefore, AgCl is formed first and after all Cl- is consumed, the first drop of
    Ag+ in excess will react with the chromate indicator giving a reddish
    A Ag precipitate.
    g

    2A Cr Cr
    MOHR TITRATION
    VOLHARD METHOD
    VOLHARD METHOD Used as a procedure for titrating Ag+; determination of
    Cl- requires a back-titration  First, Cl- is precipitated by excess AgNO3 Ag+
    (aq) + Cl-(aq)  AgCl(s)  Excess Ag+ is titrated with KSCN in the presence
    of Fe3+ Ag+(aq) + SCN-(aq)  AgSCN(s)  When Ag+ has been consumed,
    a red complex forms
    (aq) SC(aq) 𝑭𝒆 ¿
    VOLHARD
    TITRATION
    Kasimir-Fajans-1.png.webp

    FAJANS METHOD

    Adsorption-Fajans Method : Kazimierz Fajans (1887-1975) Fluorescein and


    its derivatives are adsorbed to the surface of colloidal AgCl. After all
    chloride is used, the first drop of Ag+ will react with fluorescein (FI-) forming
    a reddish color.
    +¿ ¿
    𝑨𝒈 𝑭𝑰
    −
    𝑨𝒈𝑭
    Among these methods, the Volhard Method is widely used because
    we can detect the end point of precipitation titration very well..
    FAJANS TITRATION
    What Solubility?
    The solubility of a substance is the amount of that substance that
    will dissolve in a given amount of solvent. "Solubility" may be
    considered to be an equilibrium; the equilibrium is between solid
    and ions in solution. Any ionic solid is 100% ionized in aqueous
    solution; once it actually dissolves..

    Example
    +¿ (𝐚𝐪 )¿
    𝑵𝒂 −
    𝑪𝒍 ( 𝐚𝐪 ) NaCl
    What Solubility product?
    In general, solubility product, K, is the mathematical product of its
    dissolved ion concentrations raised to the power of their
    stoichiometric coefficients. This statement is called the solubility
    product principle.

    Example Example
    Most salts dissociate into ions This equilibrium system may be
    when they dissolve. described by the mass-action
    𝟐 +¿( 𝐚𝐪) ¿ 𝑺𝑶 𝟐 − ( 𝐚𝐪 )
    BaS 𝑩𝒂 𝟒 Ksp=
    expression.
    Reference

    1.Daniel Harris,(2007), “Quantitative Chemical Analysis” 7th


    Edition, New York.
    Thanks
    for
    listening!
    Precipitation
    Titration

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