셀레노갈레이트

Selenogallate

셀레노갈레이트(또는 셀레노갈레이트)는 갈륨에 연결된 셀레늄의 음이온 단위를 포함하는 화학 화합물이다.그것들은 셀레늄이 산소를 대체하는 갤러리로 간주될 수 있다.비슷한 화합물로는 티오갈레이트와 셀레노스타나이트가 있다.그들은 찰코게노트리엘레이트 또는 더 광범위하게 찰코게노메탈레이트 범주에 속한다.[1]

포메이션

셀레노갈레이트는 밀봉된 튜브에서 갈륨 모노셀렌화물과 셀레늄으로 금속 아지드를 가열하여 생산될 수 있다.[1]

SE2 단위를 함유한 셀레노갈레이트는 셀레늄으로 가열하여 형성된다.반대로, 열을 가함으로써 셀레늄 증기는 셀레늄이 적은 화합물을 형성하여 손실될 수 있다.[2]

특성.

대부분의 셀레노갈레이트는 반도체다.그들의 저항은 빛에 노출되면 떨어진다.또한 셀레노갈레이트는 종종 색을 입히는데, 가장 자주 빨간색이다.

셀레노갈레이트 구조는 4-메모리 링([]GaSeGaSe 또는 5-메모리 [])GaSeSeGaSe과 같은 링을 포함할 수 있다.이것들은 사슬로 연결될 수 있다.

사용하다

셀레노갈레이트는 주로 연구에 관심이 있다.20% 이상의 효율이 가능한 태양광 전지,[3] 광전지와 비선형 광학 소자를 대상으로 연구를 진행하고 있다.

리스트

이름을 붙이다 화학 요법을 쓰다 mw 수정 체계 우주군 단위 세포 Ⅱ 부피 밀도 댓글 CAS

아니요.

 참고 문헌
리가세2
[H2dap]4Ga4Se10 dap = 1,2-diaminopropane 단색의 C2/c a 10.821 b 10.820 c 21.255, β 97.265° [4]
[(dienH2)(dienH)]3GaSe510 dien = 디에틸렌트리아민 단색의 P21/c a 6.3116 b 13.748 c 47.890 β 90.168° 쇠사슬을 매다 [5]
[(tetaH2)3(teta)]가세612 테타 = 트리에틸네테트라민 단색의 참조 a 20.566 b 25.896 c 12.785 β 125.568° 쇠사슬을 매다 [5]
[bapPH2][GaSe24] bap =1,4-Bis-(3-aminopropyl)piperazine 657.63 삼두의 P1 a=6.3517 b=7.8498 c=10.7818 α=71.457° β=84.925° β=72.084° Z=1 484.93 2.30 노란색; [6]
[1,3-pdaH2][GaSe22(Se23)] 1,3-pda = 1,3-diaminopropane 단색의 P21 a 7.5724 b 12.3856 c 8.0889 β 94.120° 밴드 갭 2.08 eV; GaSeSeSeGaSe & GaSeSeGaSe 링; 빨간색 [7]
[1,4-bdaH2][Ga2Se3(Se2)] 1,4-bda = 1,4-diaminobutane 단색의 C2/c a 11.7660 b 11.7743 c 10.9763 β 110.170° 밴드 갭 2.32 eV; 오렌지 [7]
[Me2NH2]2[Ga2Se2(Se2)2] 단색의 P21/c a 14.13 b 8.456 c 14.07 β 100.32° 밴드 갭 2.07 eV; 빨간색 [7]
α-[AEPH][2GaSe22(Se2)]2 AEP = N-(2-아미노에틸)피페라진 단색의 PN a 6.981 b 15.436 c 11.831 β 91.462° 밴드 갭 1.93 eV; 빨간색 [7]
β-[AEPH]2[Ga2Se2(Se2)2] 단색의 P21/c a 10.623 b 16.495 c 7.495 β 94.93° 밴드 갭 2.10 eV; 빨간색 [7]
[가(en)][3가세37(en)] · HO2 1090.02 정형외과적 Pna21 a=14.279 b=9.616 c=19.676 Z=4 2701.6 2.680 자전거 가세37 [8]
NaGaaS2 단색의 C2/c a 10.226 b 10.227 c 13.506 β 100.926° 1389.9 [9]
NaGaaS2•HO2 단색의 C2/c a=9.5160 b=113986 c=17.8761 β=101.590 1899 [9]
KGASE2 266.74 단색의 C2/c a = 10.878, b = 10.872, c = 15.380, β = 100.18° Z=16 1790.3 3.959 공기 안정, 연한 노란색, mp=965°C, 시트에 연결된 [GaSe410]8− 유닛, 밴드 간격 2.60 eV [10]
음가세24 밴드 갭 2.7 eV [11]
[Mn(en)3][Ga2Se5] en = 에틸렌디아민 771.51 정형외과적 Pbcn a=9.772 b=15.297 c=13.749 Z=4 2055.2 2.50 빨간색; {[GaSe25]}2-개 체인 GaSe22 및 GaSe23 링 [6]
[Mn(dap)]30.5가세2 정형외과적 Cmcm a 9.645 b 16.754 c 12.891 [4]
[Mn(atep)]GaS24 atep = 4-(2-aminoethyl)트리에틸네테트라민 단색의 P21/n a 9.909 b 11.947 c 14.831, β 102.268° [4]
[Co(en)3]Ga2Se 정형외과적 Cmcm a 9.692 b 15.631 c 12.698 밴드 갭 3.27 eV [5]
{[니(테파)]2SO4}[Ni(테파)(GaS46(SH))]4 tepa = 테트라에틸렌텐타민 단색의 C2/c a 38.829 b 12.471 c 22.471 β 98.398° [4]
컵 모양의 셀레노갈레이트 쿠가세2 291.186 사방형의 a = 5.5963 c = 11.0036 Z=4 344.617 5.612 금속성 회색 [12]
쩡가세24 사방형의 I42m [13]
쩡가세24 입방체의 Fm3m >15.5GPA [13]
나젠가세3224 519.90 사방형의 I41acd a 13.481 c 19.26 Z=16 3500 3.946 적색의 [14]
나젠가세6329 단색의 C2/c a 16.71 b 16.69 c 13.79 β 101.346° [15]
KZngaSe4512 R3 SHG [16]
리개게세26 695.60 정형외과적 Fdd2 a 12.5035 b 23.710 c 7.1177 2110.1 4.336 갈색; 밴드 간격 2.64 eV; mp=710 °C [17][18]
리게스226 정형외과적 Fdd2 a=12.0796 b=22.73 c=6.84048 [19]
나게세38 단색의 P21/c a 7.233 b 11.889 c 17.550 β 101.75° [20]
KGAGeSe4 497.25 단색의 P21/c a=7.3552 b=12.4151 c=17.6213 β=97.026 Z=8 1597.02 4.136 노랑색의 [21]
RbGaSe2 313.11 단색의 C2/c a = 10.954, b = 10.949, c = 16.064, β = 99.841° Z=16 1898.2 4.382 무색, mp=930 °C; [GaSe488−] supertrahedra 층; [1]
RbZngaSe4512 R3 SHG [16]
RbGaGeSe4 543.62 정형외과적 Pnma a=17.5750 b=7.4718 c=12.4449 Z=8 1634.23 4.419 주황색의 [21]
아가세2 사방형의 I42d a = 5.9921, c = 10.883 5.71 0.71 ~ 18µm에서 투명, 대역 간극 ~ 1.7 [22]
아가세58 P42m a=5.50 c=11.04 밴드 갭 2.1 eV [22]
아가세96 P213 밴드 간격 0.56 eV [22]
아가세96 입방체의 F43m a=11.10. [22]
KAggaSe3814 2025.91 단색의 CM a 12.8805 b 11.6857 c 9.6600 β 115.998° Z=2 1306.87 5.148 주황색의 [23]
아가게세512 빨간색, 0.6–16.5μm에 대해 투명, 밴드 간격 2.2 eV [24]
CdGa2Se4 사방형의 I4 a=5.3167 c=10.2858 Z=2 반도체 [25][26]
CdGa2Se4 입방체의 F43m a=5.64 Z=4 >21 GPA 금속 [26]
CdGa2Se4 입방체의 Fm3m a=5.03 Z=4 4-7.4 GPA [26]
KCd4Ga5Se12 삼각형의 R3 a 14.362 b 14.362 c 9.724 [27]
RbCd4Ga5Se12 삼각형의 R3 14.4055 b 14.4055 c 9.7688 밴드 갭 2.19 eV; SHG=19×AgGAS2 [28][27]
인가세2 사방형의 I4/mcm a = 8.051, c = 6.317 Z=4 [29]
SnGa4Se7 622.08 단색의 pc a=7.269 b=6.361 c=12.408 β=106.556 Z=2 549.9 3.757 연한 노란색,SHG 3.8 × AgGaaS2 [30]
KGaSnSe4-cP84 543.35 입방체의 파3 a=13.5555 Z=12 2490.8 4.347 적색의 [21]
RbGaSnSe4-cP84 입방체의 파3 a=13.7200 Z=12 589.72 4.550 [21]
RbGaSn2Se6 866.33 삼각형의 R3 a=10.4697 c=9.476 Z=3 899.5 4.798 진한 빨강 [31]
SnGeSnGaGeSe26 804.48 정형외과적 Fdd2 a = 47.195, b = 7.521, c = 12.183, Z = 16 4324 4.943 빨간색; SHG 1.7 × AgGaaS2
CsGaSe2-mC64 단색의 C2/c a = 11.043, b = 11.015, c = 16.810, β = 99.49°, Z = 16 2016.7 연회색, 수퍼테트라헤드라 층[GaSe484–]; 밴드 간격 3.5 eV [32]
CsGaSe2-mC16 단색의 C2/c a = 7.651, b = 12.552, c = 6.170, β = 113.62°, Z = 4 542.9 610°C 이상, 체인 [GaSe2–] [32]
CsGaSe3 단색의 P21/c a=7.727, b=13.014, c=6.705, β=106.39°, Z=4 빨간색; 체인; 밴드 갭 2.25 eV [33]
Cs2Ga2Se5 800.07 단색의 C2/c a = 15.3911, b = 7.3577, c = 12.9219, β = 126.395°, Z = 4 1177.89 4.51 노란색; [GaSe23(Se2)]2– 밴드 간격 1.95 eV [34]
Cs4Ga6Se11 삼두의 P1 a=9.707 b=9.888 c=16.780 α=76.425° β=77.076° γ=60.876° 1356.3 ∞1[Ga6Se11]4– [35]
Cs6Ga2Se6 단색의 P21/c a=8.480 b=13.644 c=11.115 β=126.22 Z=2 mp=685 °C, 격리된 이중 4면체 [GaSe26]6− [36]
Cs8Ga4Se10 삼두의 P1 a= 7.870 b=9.420 c=11.282 α=103.84° β=93.43° β=80.88° Z=1 4.42 사상의 [37]
Cs10Ga6Se14 단색의 C2/m a=18.233 b=12.889 c=9.668 β=108.20 Z=2 4.39 육각의 [37]
(Cs6Cl)6Cs3[Ga53Se96] 16671.51 삼각형의 R3m a = 11.990, c = 50.012 Z=1 6226.5 4.446 노란색; 밴드 간격 2.74 eV [38]
CszngaSe4512 삼각형의 R3 [16]
CsGaGeSe4 591.06 정형외과적 Pnma a=17.7666 b=7.5171 c=12.6383 Z=8 1687.9 4.652 백색의 [21]
CsGegaSe23614 2007.41 P3m1 a=7.6396 c=13.5866 Z=1 686.72 4.854 검게 하다 [39]
CsAggaSe24 단색의 P21/c a=11.225, b=7.944, c=21.303, β=103.10, Z=8 1850.3 층층이 있는 [40]
CsCd4Ga5Se12 삼각형의 R3 a 14.1684 b 14.1684 c 9.7803 밴드 갭 2.21 eV; SHG=16×AgAgS2 [28][27]
바가세47 단색의 pc a = 7.625, b = 6.511, c = 14.702, β = 121.24° 0.47 ~ 18.0 μm 사이의 투명, 968 °C의 용해, SHG [41][42]
바가세428 132.48 단색의 P21/c a=13.2393 b=6.4305 c=20.6432 β=104.3148 Z=4 1702.90 5.151 검은 공기 안정, 밴드 갭 1.51 eV [43][44]
바가세528 정형외과적 Cmca a 23.433 b 12.461 c 12.214 밴드 갭 2.51 eV [45]
바가세5410 1755.18 사방형의 I4/mcm a = 8.752, c = 13.971 Z = 2 1070.2 5.447 빨간색; 가-가 브리지가 있는 자전거 링, 밴드 갭 2.20 eV [46]
바가세클34 정형외과적 Pnma a 12.691 b 9.870 c 8.716 [47]
바가세브르34 정형외과적 Pnma a = 12.8248, b = 9.9608, c = 8.7690 Z = 4 밴드 갭 1.7 eV [48]
리바가세4512 1852.42 사방형의 P421c 13.591 c 6.515 Z=2 1203.3 5.113 노란색; 밴드 간격 2.44 eV; SHG 1.7×AgAgAs2 [28][49]
나바가세3 정형외과적 Pnma a 20.46 b 9.10 c 7.10 1347 무색의 [50]
(나바0.600.70)가세24 사방형의 I4cm 7.9549 c 6.2836 397.6 4.725 엷은 노랑색 [51]
KBaGaSecCl35102 사방형의 I4 a 8.6341 c 15.644 1166.2 밴드 갭 2.04 eV; SHG=10×AgGAS2 [28][52]
MnBa4Ga4Se10Cl2 사방형의 I4 8.58 c 15.7739 밴드 갭 2.8 eV; SHG=30×AgGAS2 [28][53]
FeBaGaSecCl44102 사방형의 I4 8.578 c 15.717 밴드 갭 1.88 eV [28][53]
코바가세클44102 사방형의 I4 a 8.572 c 15.716 밴드 갭 2.02 eV [28][53]
CuBaGaSecCl0.544.5102 사방형의 I4 8.559 c 15.778 밴드 갭 2.6 eV; SHG=39×AgGAS2 [28][53]
쿠바가세4512 P421c a = 13.598, c = 6.527, Z = 2 밴드 갭 1.45 eV; SHG=3×AgAgS2 [28][54]
ZnBa4Ga4Se10Cl2 사방형의 I4 8.561 c 15.757 밴드 갭 3.08 eV; SHG=59×AgGAS2 [28][53]
반가세107626 사방형의 I42m a 11.2907 c 21.760 Z=2 2774.0 5.151 노랑색의 [55]
바게세4412 1848.35 사방형의 P421c a=13.5468 c=6.4915 Z=2 1191.29 5.153 주황색 노란색, 밴드 간격 2.18 eV [43][56]
바게세26 R3 [57]
RbBa3Ga5Se10Cl2 사방형의 I4 8.6629 c 15.6379 밴드 갭 2.05 eV; SHG=20×AgGAS2 [28][52]
바가이시25 삼두의 P1 a 7.2876å b 8.6597å c 9.3876å, α 103.51° β 103.04° γ 107.43° [58]
바아그가세46 1199.44 정형외과적 Pnma a=9.1006 b=4.472 c=17.7572 Z=2 722.71 5.512 짙은 빨강, 공기 안정, 밴드 간격 2.50 [59]
바아그가세4512 1953.35 사방형의 P421c 13.654 c 6.5215 Z=2 1215.9 5.335 노랑색의 [49]
바아그가세7515 삼각형의 P31c 10.0467 c 18.689 밴드 갭 2.60 eV [60]
CdBa4Ga4Se10Cl2 사방형의 I4 8.611 c 15.805 밴드 갭 3.05 eV; SHG=52×AgGAS2 [28][53]
Ba5CdGa6Se12 2401.82 정형외과적 아마2 a=24.2458 b=19.1582 c=6.6208 Z=4 3075.4 5.187 노란색, 공기 안정적, 밴드 간격 2.60 eV, mp=866 °C [43][61]
바가스네스26 869.23 삼각형의 R3 a = 10.145, c = 9.249 Z = 3 824.4 5.253 빨간색; SHG 5.2×AgGaaS2 [62]
바가스네스4412 1894.45 사방형의 P421c a 13.607 c 6.509 Z=2 1205.2 5.221 빨간색; 밴드 간격 2.16 eV [63]
바가스네스6211 1950.73 단색의 P21/c a 18.715 b 7.12 c 19.29, β 103.29° 2481.5 5.221 빨간색; 나쁜 간격 1.99 eV [63]
바아스가세25 814.12 정형외과적 Pnma a = 12.632, b = 8.973, c = 9.203, Z = 4 1043.1 5.184 검게 하다 [64]
CsBaGaSecCl35102 사방형의 I4 8.734 c 15.697 1197.6 갭 2.08 eV; SHG=100×AgGAS2 [28][52]
나라가세48 정형외과적 Fddd a 21.16 b 21.1625 c 12.7216 [65]
람가세37 1094.11 육각형의 P63 10.5894 c 6.3458 Z=2 616.25 5.896 검게 하다 [66]
라페가세37 육각형의 P63 a=10.5042 c=6.3496 606.74 [67]
라코가세37 육각형의 P63 a=10.1684 c=6.168 609.48 [67]
라니가세37 육각형의 P63 a=10.4826 c=6.3964 608.71 [67]
라쿠가세37 1102.71 육각형의 P63 a=10.626 c=6.392 Z=2 626.0 5.859 [43]
라젠가세37 1104.54 육각형의 P63 a=10.630 c=6.374 Z=2 623.7 5.881 [43]
라아가세30.67 육각형의 P63 a=10.6, c=6.4 Z=2 [68]
La3CdGaSe7 육각형의 P63 a=10.606 c=6.380 Z=2 621.5 6.153 [43]
바가라세25 정형외과적 Pnma a 12.5049 b 9.6288 c 8.7355 [69]
나세가세48 정형외과적 Fddd a 21.10 b 21.10 c 12.712 [65]
체쿠가세37 1106.34 육각형의 P63 a=10.6007 c=6.3775 Z=2 620.65 5.920 [43]
바가체스25 정형외과적 Fddd a 12.494 b 9.599 c 8.738 [69]
프르쿠가세37 1108.71 육각형의 P63 a=10.4181 c=6.3743 Z=2 599.16 6.146 [43]
나은가세48 정형외과적 Fddd a 21.015 b 21.045 c 12.709 [65]
Nd3FeGaSe7 육각형의 P63 10.2453 c 6.4076 Z=2 582.47 [70]
Nd3CoGaSe7 육각형의 P63 a=10.2296 c=6.4272 582.47 [67]
Nd3NiGaSe7 육각형의 P63 a=10.217 c=6.4066 578.57 [67]
Nd3CuGaSe7 1118.70 육각형의 P63 a=10.3426 c=6.3869 Z=2 591.7 6.279 [43]
바간드세25 삼두의 P1 a 7.29å b 8.7914å c 9.47å, α 103.77° β 102.91° γ 107.72° [58]
smgaSe24 마름모꼴의 a=21.34, b=21.60, c=12.74 [71]
Ba2GaSmSe5 삼두의 P1 a 7.3017å b 8.7635å c 9.4554å, α 103.672° β 102.963° γ 107.637° [58]
GdFegaSe37 육각형의 P63 a 10.0762 c 6.4265 Z=2 [70]
바가그드세25 삼두의 P1 a 7.2834å b 8.7062å c 9.4079å, α 103.65° β 103.02° γ 107.52° [58]
디페가세37 육각형의 P63 a 9.9956å c 6.398 Z=2 [70]
바가디세25 삼두의 P1 a 7.2772å b 8.6543å c 9.3792å, α 103.53° β 103.07° γ 107.43° [58]
바가에르세25 삼두의 P1 a 7.2721å b 8.6258å c 9.3621å, α 103.41° β 103.13° γ 107.39° [58]
Ba2GaTbSe5 삼두의 P1 a 7.309 b 8.719 c 9.433, α 103.548° β 103.039° γ 107.168° [69]
바가호세25 삼두의 P1 a 7.2964 b 8.670 c 9.406, α 103.482° β 103.049° γ 107.423° [69]
Ba2GaTmSe5 삼두의 P1 a 7.2884 b 8.6376 c 9.3823, α 103.429° β 103.075° γ 107.360° [69]
바가이브세25 삼두의 P1 a 7.2864 b 8.6257 c 9.3716, α 103.4154° β 103.0369° γ 107.3396° [69]
바가루세25 삼두의 P1 a 7.2829 b 8.6120 c 9.368, α 103.362° β 103.051° γ 107.308° [69]
흐가세24 [72]
KHG가세4512 2137.58 삼각형의 R3 a 14.3203 b 14.3203 c 9.7057 Z=3 1723.7 6.178 밴드 갭 1.61 eV; SHG=20×AgAgAs2 [28][73][74]
TlgaSe2 432.01 단색의 C2/c a=10.760 b=10.762 c=15.626 β=100.19 Z=16 1780.8 6.445 검은색, 수퍼테트라헤드 층, mp 804 °C, 밴드 간격 1.87 eV [75]
TlGaGeSe4 662.52 정형외과적 Pnma a=17.4742 b=7.4105 c=11.9406 Z=8 1546.22 5.692 [21]
Tl2Ga2GeSe6 사방형의 I4/mmc a=8.0770 c=6.2572 Z=4 [76]
Tl0.8Ga0.8Ge1.2Se4-mC112 622.22 단색의 C2/c a=13.5831 b=7.4015 c=30.7410 β =96.066 Z=16 3073.3 5.379 적색의 [21]
TlgaSnSe-mP564 701.04 단색의 P21/c a=7.51 b=12.175 c=18.203 β =97.164 Z=8 1649.4 5.646 적색의 [21]
TlgaSnSe-cP844 708.62 입방체의 파3 a=13.4755 Z=12 2447.0 5.770 적색의 [21]
TlgaSnSe226 사방형의 I4/mmc a=8.095 c=6.402 Z=4 [76]
TlgaSnSe26 R3 a=10.3289 c=9.4340 871.64 5.6301 짙은 회색 덩어리; 마룬 가루 [77]
PbGa2Se4 662.47 정형외과적 Fddd a =12.73 b=21.26 c=21.55 Z=32 5830 6.036 노란색에서 빨간색, mp 780°C, 밴드 간격 1.83 eV [78][79]
Pb0.72Mn2.84Ga2.95Se8 육각형의 P6 17.550 c 3.8916 [80]
PbGa2GeSe6 정형외과적 Fdd2 mp 720 °C 양축(-) [57]
Pb4Ga4GeSe12 사방형의 P421c a = 13.064 c = 6.310 Z=2 [81]
바가비세25 정형외과적 Pnma a=12.691 b=9.190 c=9.245 Z=4 1078.2 5.841 노랑색의 [82]

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