Water: Properties and Behavior

What’s so special about water?

Despite its scarcity across the universe, water is so abundant on Earth that we
aren’t always aware of how special it is. For starters, water is the only
substance that exists naturally on our planet as a solid (ice and
snow), liquid (rivers, lakes, and oceans), and a gas (water in
the atmosphere as humidity). As you might recall (or can read about in our
module on States of Matter), water molecules are in a different energy state
in each phase. The amount of energy required to go from solid to liquid and
liquid to gas is related to how water molecules interact with each other.
Those interactions are, in turn, related to how the atoms within a water
molecule interact with each other.

Our Chemical Bonding: The Nature of the Chemical Bond module discussed
how a dipole forms across a water molecule; in the bond between oxygen
and hydrogen, the electrons are shared unequally, drawn a bit more to the
oxygen. As a result, a partial negative charge (ð-) forms at the oxygen end
of the molecule, and a partial positive charge (ð+) forms at each of the
hydrogen atom ends (Figure 1).

Since the hydrogen and oxygen atoms in the molecule carry opposite
(though partial) charges, nearby water molecules are attracted to each
other like tiny little magnets. The electrostatic attraction between the ð+
hydrogen (ð stands for partial charge, a value less than the charge of an
electron) and the ð- oxygen in adjacent molecules is called
hydrogen bonding.
Hydrogen bonds make water molecules "stick" together. These bonds are
relatively weak compared to other types of covalent or ionic bonds. In fact,
they are often referred to as an attractive force as opposed to a true bond.
Yet, they have a big effect on how water behaves. There are many other
compounds that form hydrogen bonds, but the ones between water
molecules are particularly strong. Figure 2 shows why. If you look at the
central molecule in this figure you see that the oxygen end of the molecule
forms hydrogen bonds with two other water molecules; in addition, each
hydrogen on the central molecule is attracted to a separate water molecule.
As the illustration shows, each water molecule forms attractions with four
other water molecules, a network of connections that makes the
hydrogen bonding in water particularly strong and lends the substance its
many unique properties.

Properties of water that arise from hydrogen bonding

It floats!

Now it’s time to make use of that glass of water. If you have some ice cubes,
drop one in your glass. You’ll notice that it floats. Its ability to bob to the top
of the water line means that the ice (water in its solid state) is
less dense than liquid water. (To review density and buoyancy, see
our Density module) This isn’t a common state of affairs; if you put a chunk of
solid wax into a vat of molten wax, it will sink toward the bottom (and possibly
melt before it gets there).
To understand what causes ice to float but solid wax to sink, let’s think first
about what happens when a liquid turns to a solid (again, the States of
Matter module can be a handy review here). In a liquid, the molecules have
enough kinetic energy to keep moving around. As molecules come near to
each other, they are drawn together by intermolecular forces. At the same
time, molecules have enough kinetic energy to break free of
those forces and be drawn to other nearby molecules. Thus the liquid flows
because intermolecular attractions can be broken and reformed.
A liquid freezes when the kinetic energy is reduced (i.e. the temperature is
reduced) enough that the attractive forces between molecules can no
longer be broken, and the molecules become locked in a static lattice. For
nearly all compounds, the lower energy and lack of movement between
molecules means the molecules in a solid are packed together more tightly
than the liquid state. This is the case with wax and so solid wax is denser than
the liquid and sinks.
In the case of water, though, the shape of the molecule and the strength of
the hydrogen bonds affect the arrangement of the molecules.
In liquid water, hydrogen bonding pulls molecules closely together. As water
freezes, the dipole ends with like charges repel each other, forcing the
molecules into a fixed lattice in which they are farther from each other than
they are in liquid water (Figure 3). More space between molecules makes the
ice less dense than liquid water, and thus it floats.

The universal solvent

Water is sometimes referred to as the “universal solvent,” because it dissolves

more compounds than any other liquid known. The polarity of the water
molecule allows it to readily dissolve other polar molecules, as well as ions.
(See our Solutions, solubility, and colligative properties module for a deeper
discussion of dissolution.) This ability to dissolve substances is one of the
properties that makes water vital for life. Most biological molecules, such as
DNA, proteins, and vitamins are polar, and important ions such as sodium
and potassium are also charged. In order for any of these compounds to
carry out functions in the body, they have to be able to circulate in the blood
and the fluid within and between cells, all of which are mostly water.
Because of its polarity, water is able to dissolve these and other substances,
allowing their free movement around the body. A few biomolecules, such as
fats and cholesterol, aren’t polar, and don’t dissolve in water – however, the
body has developed unique ways to circulate and store these substances.
Water is also able to dissolve gasses such as oxygen, allowing fish, plants, and
other aquatic life to access this dissolved oxygen (Figure 4). O2 isn’t
a polar molecule; it dissolves because the polar charges in the water
molecule induce a dipole in the oxygen, making it soluble and so available
to aquatic life. (Learn more about induced-dipole interactions in
our Properties of Liquids module.)

Cohesion and surface tension

Let’s return to your water glass. Fill the glass just to the rim and stop. Then,
slowly, add a little bit more. You’ll see that you can actually fill the glass a bit
past its rim, and the edges of the water will round out against the glass,
holding the water in.
Once again, hydrogen bonding is behind this act, resulting in cohesion.
Cohesion occurs when molecules of the same kind are attracted to each
other. In the case of water, the molecules form strong hydrogen bonds,
which hold the substance together. As a result, water is highly cohesive, in
fact, it is the most cohesive of all non-metallic liquids.

Cohesion occurs throughout your glass of water, but it’s especially strong at
the surface. Molecules there have fewer neighbors (because they have
none at the very surface), and so create stronger bonds with the molecules
that are near them. The result is called surface tension, or the ability of a
substance to resist disruption to its surface. Dip your finger into your water
glass and then pull it out. The drop that forms at the end of your fingertip is
held together by surface tension.

Surface tension was the misunderstood central player in a

raucous debate between Galileo Galilei and his chief rival, Ludovico delle
Colombe in 1611. Delle Colombe, a philosopher, was at odds with some of
Galileo’s ideas, including his explanation that ice floats on water because it
is less dense. So the philosopher challenged Galileo to a debate, which delle
Colombe believed would prove his own intellectual superiority.

Delle Colombe championed the (incorrect) idea that ice floats not because
of density, but because of its shape, which he saw as broad and flat, as is ice
on a lake. To prove the “truth” of his theory, he used ebony wood, which is
slightly denser than water, in a demonstration before an audience of curious
spectators. He dropped a sphere of the wood into water, and it sank. He then
placed a thin wafer of the wood flat on the water’s surface, and it floated.
Delle Colombe pronounced himself the winner.

Galileo left frustrated. His observations of the world gave him evidence that
his explanation, not delle Colombe’s, was right, but he couldn’t explain
the outcome of delle Colombe’s experiment. Had he known about
molecules and dipoles and hydrogen bonds at the time, Galileo certainly
would have offered this explanation: When delle Colombe floated the thin
ebony disc, he was taking advantage of the cohesive nature of water and
the surface tension that arises from it (Figure 5). As the ebony wafer
appeared to float on the water, the force exerted by its mass was distributed
throughout the surface of the water beneath it. In other words, a single
pinpoint-sized area of surface water only had to support the pinpoint-sized
piece of ebony just above it. The hydrogen bonds between the water
molecules were strong enough to support the weight of the disc. When delle
Colombe placed the sphere in the water, however, the pinpoint-sized area
that first touched the water bore the weight of the entire sphere, which was
more than the water’s surface tension could support. Had Galileo known this
at the time, he could have disproved delle Colombe easily – had he simply
pushed the wafer through the surface to break the surface tension, the wafer
would have sunk

Adhesion and capillary action

For your next observation, take another sip of water, and notice the side of
the glass. Chances are you’ll see a few drops stuck to it. Gravity is pulling
down on these drops, so something else must be keeping them stuck there.
That something else is adhesion, the attraction of water to other kinds of
molecules; in this case, the molecules that make up the glass. Because of the
polarity of the molecule, water exhibits stronger adhesion to
those surfaces that have some net electrical charge, and glass is one such
surface. But place a drop of water on a non-polar surface, such as a piece
of wax paper and you will see it take a different shape than one to which it
adheres. On the wax paper, the water droplets take the shape of a true
droplet because there is little adhesion and the cohesive forces pull the drop
into a sphere. But on glass you will see the droplets flatten and deform a bit
as the adhesive forces draw it more to the surface of the glass.

Both cohesion and adhesion (Figure 7) occur with many compounds besides
water. Pressure sensitive tapes, for example, stick to surfaces because they
are coated with a high viscosity fluid that adheres to the surface to which
they are pressed. Generally, you can overcome this adhesive force by
pulling, for example – you can easily lift a Post-it® Note from a page. But
sometimes the adhesive forces are stronger than the forces holding the
surface together – pull tape off of a piece of paper and you remove pieces
of the paper with the tape.

Let’s return to our glass of water, and look inside to where the
water surface meets the glass. The very edge of the water surface curves
upward slightly on the glass. That’s also adhesion – the water is drawn up the
surface by adhesion with the glass. If you have a clear plastic straw, you can
put one end of it into the water and see that the liquid climbs up the straw a
bit, above the surface of the remaining glass of water. It’s actually moving
upward against gravity! What’s happening in your straw is a phenomenon
called capillary action (Figure 7). Capillary action occurs in small tubes,
where the surface area of the water is small, and the force of adhesion—
water’s attraction to the polar glass or other material—overcomes the force
of cohesion between those surface molecules.
Another way to see the effects of adhesion and cohesion is to compare the
behavior of polar and nonpolar liquids. When you put water in a test tube,
adhesion makes the water along the edges move slightly upward and
creates a concave meniscus. Liquid mercury, on the other hand, is not polar
and therefore not attracted to glass. In a test tube, cohesion at the surface of
the mercury is much stronger than adhesion to the glass. The surface tension
in the mercury forms a convex meniscus, much the same as the way water
forms a slight bulge over the top of your very full glass