The document describes Flottec 2000 Series Collectors, which are acid and aqueous forms of cresylic and alkyl monothiophosphates (MTP) and dithiophosphates (DTP). These products are primarily used for flotation of sulfide ores containing metals like copper, lead, zinc, silver, and gold. The properties and applications of the different products in the series can be modified based on the hydrocarbon chain length and salt used. Typical addition levels are 5-100 grams/ton added to grinding or flotation circuits. Proper safety precautions should be taken when handling and storing these corrosive and potentially hazardous chemicals.
The document describes Flottec 2000 Series Collectors, which are acid and aqueous forms of cresylic and alkyl monothiophosphates (MTP) and dithiophosphates (DTP). These products are primarily used for flotation of sulfide ores containing metals like copper, lead, zinc, silver, and gold. The properties and applications of the different products in the series can be modified based on the hydrocarbon chain length and salt used. Typical addition levels are 5-100 grams/ton added to grinding or flotation circuits. Proper safety precautions should be taken when handling and storing these corrosive and potentially hazardous chemicals.
The document describes Flottec 2000 Series Collectors, which are acid and aqueous forms of cresylic and alkyl monothiophosphates (MTP) and dithiophosphates (DTP). These products are primarily used for flotation of sulfide ores containing metals like copper, lead, zinc, silver, and gold. The properties and applications of the different products in the series can be modified based on the hydrocarbon chain length and salt used. Typical addition levels are 5-100 grams/ton added to grinding or flotation circuits. Proper safety precautions should be taken when handling and storing these corrosive and potentially hazardous chemicals.
The document describes Flottec 2000 Series Collectors, which are acid and aqueous forms of cresylic and alkyl monothiophosphates (MTP) and dithiophosphates (DTP). These products are primarily used for flotation of sulfide ores containing metals like copper, lead, zinc, silver, and gold. The properties and applications of the different products in the series can be modified based on the hydrocarbon chain length and salt used. Typical addition levels are 5-100 grams/ton added to grinding or flotation circuits. Proper safety precautions should be taken when handling and storing these corrosive and potentially hazardous chemicals.
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Flottec 2000 Series Collectors
Product Data Sheet
Flottec 2000 Series products are acid and aqueous forms of cresylic and alkyl monothiophosphates (MTP) and dithiophosphates (DTP). These products are used primarily for the flotation of sulfide ores containing copper, lead, zinc, silver, and gold. The DTPs are especially suited for sulfide flotation in alkaline circuits when selectivity against iron sulfides is needed. MTPs are especially well suited for sulfide flotation in acid circuits and to improve the recovery of gold at any pH. By varying the hydrocarbon chain length and the type of salt created, the collector activity, frothing characteristics and pH operating range can be modified greatly, making MTPs and DTPs a very versatile series of products. Typical Properties
Flottec 2000 Series Collectors Product 2020 2030 2041 2044 2054 2075 Appearance Variable from Colorless to Yellow Liquid Hydrocarbon ethyl isoC3 secC4 isoC4 isoC5 mixed pH 13 13 13 13 13 13 Specific Gravity @ 25C 1.20 1.15 1.12 1.12 1.10 1.15 Boiling Point (C) 103 103 103 103 103 103 Crystallization (C) -4 -10 -12 -13 -4 -12 Water Solubility Completely Water Soluble Frothing Characteristics Very Low Medium High Low
Sodium, Ammonium Dicresyl DTPs* Acid Form* Product 2200 2300 2310 2100 Appearance Variable from Dark Brown to Black Specific Gravity @ 25C 1.19 1.13 1.13 1.12 Water Solubility Yes Yes Above 10% DO NOT Mix with Water
Sodium Dialkyl MTPs Sodium Dicresyl MTP* Product 2644 2600 Appearance Variable from Amber to Red Liquid pH 13 13 Specific Gravity @ 25C 1.15 1.15 Crystallization (C) 2 2 Water Solubility Completely Water Soluble *Available in Both LF (Low Frothing) and HF (High Frothing) Versions
Flottec 2000 Series Collectors Product Data Sheet
Methods of Addition and Uses
Flottec 2000 series collectors (except those supplied in acid form) are aqueous and can be added neat or diluted up to ten times for ease of metering. The products are also stable in both acid and alkaline circuits. Usual treatment levels are 5 100 grams/ton, added either to the grinding circuit or to the flotation circuit. Stage addition will usually enhance performance. Each product has its own frothing characteristic nature. Generally, alkyl DTP exhibit little or no frothing characteristic for C2 and C3 carbon chain length. The frothing characteristic becomes more prevalent with increasing carbon chain length. All cresylic based products contribute to the frothing characteristic of the flotation pulp based on the type of cresylic used in its manufacture. Plant testing is recommended to determine optimum addition points and treatment levels.
The main duty for sodium dialkyl DTPs are the flotation of copper sulfides, copper activated sphalerite, nickel sufides and ores containing gold, silver and PGMs where selectivity is required against iron sulfides in alkaline circuits. They are used as well when selectivity is needed for copper sulfides from galena or non activated sphalerite. Higher carbon chain products are also effective for middlings flotation. The frothing characteristic of the product increases with increasing carbon chain. DTPs exhibit excellent collecting properties for the flotation of iron sulfide minerals in acidic circuits.
The sodium and ammonium dicresylic DTP does behave very similarily to the alkyl products. These products provide an additional benefit in that they are excellent galena and silver collectors and have frothing properties across the range. The frothing characteristic of the products can be varied. The acid form tends to exhibit the highest frothing characteristic. Those properties then decrease relative to the counter ion from sodium to ammonium to finally the organic salt form being least. The strength and frothing characteristic of the products can also be varied similarly to the alkyl DTPs by modifying the grade of cresylic acid used. Purer forms tend to exhibit less frothing characteristic and are more selective than products manufactured with impure forms of cresylic acid.
The sodium dicresyl and dialkyl MTPs were designed originally to be copper collectors in acid circuits and the Leach
Precipitation Flotation (LPF) process. However, they have been found in certain conditions to be superior auxiliary collectors for ores containing free gold in alkaline circuits. The dialkyl MTPs are typically used when excessive frothing in the flotation circuit becomes an issue.
Flottec 2000 series products can be used alone or in conjunction with other collectors, although care must be taken when used in conjunction with xanthates in order to maintain the benefits of the improved selectivity of the DTPs and MTPs.
Toxicology and Industrial Hygiene
The acid forms of the DTPs should not be pre-mixed with water as this will liberate poisonous gases. The products should be added directly to the flotation circuit to avoid gas liberation at the levels used in flotation pulps. These aqueous products are of an alkaline nature. Prolonged contact with skin should be avoided and alkali burns may result if proper protective equipment is not used during handling. If skin contact occurs, the area should be cleansed with copious quantities of water, including the eyes. Vomiting should be induced if taken internally. Please refer to the appropriate MSDS for individual product safety information.
Shipping, Handling and Storage
The products are available in 55 gallon poly drums and returnable 275 gallon totes. Please contact customer service for the net and gross weights.
These products are corrosive to most metals. It is recommended that the product be stored in 316 stainless steel or mild steel tanks with phenolic liners. Mild steel can be used but is not recommended. All components for transferring these materials should be plastic or phenolic or able to withstand alkaline or acid corrosion for both neat and diluted material. Do not use copper, brass or soft rubber in feed or storage systems. Avoid storage near extreme heat. Do not mix with acidic solutions to prevent H 2 S generation.