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    (C-4 A-1) Solution

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    Sachin Dedhia
    1. The document provides sample problems and solutions related to chemical kinetics, solid state chemistry, and nuclear chemistry. 2. It includes 25 multiple choice questions related to these topics, with the correct answer provided for each. 3. The document also includes 5 additional problems related to nuclear chemistry, with the corresponding numerical solutions.

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    (C-4 A-1) Solution

    Uploaded by

    Sachin Dedhia
    10 views4 pages
    1. The document provides sample problems and solutions related to chemical kinetics, solid state chemistry, and nuclear chemistry. 2. It includes 25 multiple choice questions related to these topics, with the correct answer provided for each. 3. The document also includes 5 additional problems related to nuclear chemistry, with the corresponding numerical solutions.

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    (C-4 A-1) SOLUTION

    Original Title

    (C-4 A-1) SOLUTION

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    1. The document provides sample problems and solutions related to chemical kinetics, solid state chemistry, and nuclear chemistry. 2. It includes 25 multiple choice questions related to these topics, with the correct answer provided for each. 3. The document also includes 5 additional problems related to nuclear chemistry, with the corresponding numerical solutions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    10 views4 pages

    (C-4 A-1) Solution

    Uploaded by

    Sachin Dedhia
    1. The document provides sample problems and solutions related to chemical kinetics, solid state chemistry, and nuclear chemistry. 2. It includes 25 multiple choice questions related to these topics, with the correct answer provided for each. 3. The document also includes 5 additional problems related to nuclear chemistry, with the corresponding numerical solutions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

    IIT JEE: 2016 CRASH COURSE DATE:


    TOPIC: CHEMICAL KINETIC , SOLID STATE & NUCLEAR CHEMISTRY

    SOLUTION

    1. (D)
    m n m n
    Rate 1 k A B ; Rate 2 k 2 A B / 2
    rate 2 m 1 n m-n
    Hence, 2 2
    rate 1 2

    2. (B)
    2
    Rate k FeCl3 SnCl2 [reaction being elementary]
    2FeCl3 SnCl2 2FeCl 2 SnCl4
    t 0 1.2 M 0.8 M 0 0
    time t 0.8 M 0.6 M 0.4 M 0.2 M
    2
    Rate 2 k 0.8 0.6 1
    2

    Rate 1 k 1.2 0.8 3

    3. (D)

    Rate SN2 5.0 105 102 R X
    5.0 10 7 R X


    Rate SN1 0.20 105 R X

    4. (B)
    Ea f E a b H 15k cal
    Ea f 15 20 5k cal
    E a E a catalyst 5 3 103
    k catalyst
    e RT
    e 2 400
    e 2.5
    k

    8. (B)
    At radioactive equilibrium, B N B max A N A
    2ln 2
    A 2
    A tmax A
    A N0 e A N0 e A N 0 eln 2
    A N0 N
    N B max A 0
    4 4 B

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1


    9. (D)
    12
    Number of t1/ 2 A 6;
    2
    12
    Number of t1/ 2 B 3
    4
    6 3
    1 1 1 1
    nA left ; nB left
    2 64 2 8
    1 1
    n A : nB : 1: 8
    64 8

    10. (A)
    Radioactive decay is a first order process. Hence the total number of radioactive nuclei will decrease
    exponentially with time.

    11. (BC)

    12. (BCD)

    13. (AC)
    In acid catalysed reaction, the rate constant is directly proportional to the extent of ionization of the
    acid and hence the strength of the acid.
    Relative strength of (I) HX and (II) HY
    I kI 3 10 3
    0.6
    II k II 5 103

    14. (ABC)
    (A) For zero order reaction rate remains constant, independent of concentration.
    t1
    Time for 75% reaction 2 75 1.5t 1 2
    50
    (B) For first order reaction time for any fractional change is independent of initial concentration.
    1 1 1
    (C) For 2nd order reaction, t
    k C C0
    1 1 1 1
    t 12
    k C0 / 2 C0 kC 0
    1 1 1 1
    t 14 3
    k 4 C 0 / 2 C 0 3kC 0

    15. BCD

    16. (AD)
    Half-life of a reaction will decrease only when rate constant increases. Rate constants of all reactions
    (endothermic or exothermic) increases on increasing temperature (except the reaction
    2NO O 2 2NO 2 )

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 2


    17. (D)
    All other statements are incorrect.

    18. (ACD)
    19. (BC)
    Isoelectronic ions have the same scattering power of X-rays. Hence, K+ and Cl ; Rb+ and Br

    20. (ACD)

    21. (BC)

    22. (BC)

    23. (CD)

    24. (BCD)

    25. (ABCD)

    37. (5)
    The magic numbers are 2, 8, 20, 50, 126.

    38. (8)
    E m 931MeV
    0.00859 931
    8 MeV

    39. (5)
    Initial amount of this isotope N 0 100
    Final amount of the isotope N 25
    n
    1
    We know that N N 0
    2
    n
    1
    So 25 100
    2
    n
    25 1
    Or
    100 2
    n
    1 1
    Or
    4 2
    2 n
    1 1
    Or
    2 2
    Or n 2
    Time taken T n t1/ 2 2 2.5 10 5 5 105 year
    Alternatively
    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3
    t1/2 0.3
    We can use
    t x % log a
    ax
    t1/2 0.3

    t 25% log 100
    25
    2.5 105 0.3

    t 25% log 4
    Or t 25% or time required to reduced amount to 25%
    2.5 105
    log 4
    0.3
    2.5 105
    0.602
    0.3
    5.0 105 years

    40. (5)
    a0
    log
    t15/16 a0 x

    t3/4 a0
    log
    a0 x1
    a0
    log
    a0 / 16 log16 4

    a0 log 4 2
    log
    a0 / 14
    t15/16 t3/4 2
    2.5 2 5

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4

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