Gar CA Rodrguez 2007
Gar CA Rodrguez 2007
Gar CA Rodrguez 2007
Abstract
The lack of access to electricity grid and fresh water strongly limits the development and the quality of life to
many rural locations. The distributed solar power generation can be applied to many basic needs, not only electricity
generation, but also desalination, cooling, heating, etc. For this reason it provides opportunity of social and economic
development and therefore promoting employment. This paper is focused on the analysis of distributed solar-
powered generation systems for driving a reverse osmosis desalination process based on solar-heated Rankine
cycles. Three different top temperature ranges are considered in order to consider medium to low temperature solar
thermal collectors. Results presented in this paper points out that desalination systems coupled to solar-powered
organic Rankine cycles exhibit lower specific consumption of solar energy than solar distillation and solar
photovoltaic reverse osmosis systems. Therefore, there are interesting prospects for developing cost-effective solar
desalination systems based on such a technology although intensive experimental research is still needed.
Keywords: Solar desalination; Solar thermal energy; Reverse osmosis; Distillation
0011-9164/07/$ See front matter 2007 Elsevier B.V. All rights reserved.
doi:10.1016/j.desal.2006.10.016
320 L. Garca-Rodrguez, A.M. Delgado-Torres / Desalination 212 (2007) 319327
Table 1
Solar power generation systems based on Rankine cycles using toluene as working fluid
state of the expansion have to be dry steam, Rankine cycle. The heat rejected from the ther-
then the use of dry fluids usually are the most modynamic cycle may be use to preheat the feed
suitable and the superheating of the fluid is water or in any other application.
optional. Nevertheless, if other kind of expan- Table 2 gives some examples of potential can-
sion device is used this condition is not neces- didate fluids for solar thermal collectors from low
sary. to medium temperature ranges (static and one-axis
Thermodynamic states that can be reached at tracking technologies). Some working fluids with
the outlet of the solar field along the day and toxicity problems, as benzene, have been also in-
along the year have to be detailed analysed cluded for comparison. Table 2 shows that some
due to the variability inherent to the solar irra- fluids permit not only the use of mechanical power
diance, which may result in operational generation but also the heat rejected in the cycle.
troubles of the thermodynamic cycle. Very few pilot desalination plants have been
Toxicity and safety of the candidate fluids have coupled to solar power plants (Table 3) or are
to be taken into account by considering safe driven by the shaft power or electricity generated
operation and system maintenance in remote by a solar-heated thermodynamic cycle (Table 4).
areas avoiding any toxic waste generation. Nevertheless, such systems exhibit a high efficient
use of the solar energy as it is pointed out in this
paper. Besides that, seawater desalination by us-
4. Desalination powered by a solar-heated
ing PVRO process has similar high costs than
Rankine cycle
solar distillation [22]. Therefore, there is consid-
Fig. 1 shows a basic diagram of the most simple erable room for developing a more cost-effective
reverse osmosis system powered by a solar-heated solar technology based on solar-powered thermo-
Solar
collector High pressure RO module 8
pump
turbine 6
5
condenser 7
1 4 3
pump
Fig. 1. Basic diagram of a reverse osmosis system powered by a solar-heated Rankine cycle. 1. Working fluid entering the
solar field; 2. Working fluid at its maximum temperature and pressure (steam); 3. Expansioned steam; 4. Condensed
working fluid; 56. Feedwater (brackish water or seawater); 7. Brine; 8. Product.
L. Garca-Rodrguez, A.M. Delgado-Torres / Desalination 212 (2007) 319327 323
Table 2
Estimated main thermodynamic data of some potential candidate cycles (sol: quotient between shaft power production
and solar energy available on the solar collector plane. Points 2 and 4 are referred to previous Fig. 1)
Table 3
Dual purpose solar plants
Table 4
Desalination plants driven by solar-heated thermodynamic cycles
dynamic cycles. The most important item in capi- tion of 1 kg of fresh water is analysed for reverse
tal cost for solar distillation systems is the solar osmosis process driven by different solar-pow-
field. Since distillation units are more expensive ered Rankine cycles from Table 2 in comparison
than reverse osmosis systems, the solar field size with PV-driven reverse osmosis. This analysis is
is even more important in solar thermal-driven based on the following basic assumptions:
reverse osmosis desalination. Therefore, the so- The thermodynamic behaviour of all working
lar thermal consumption required for the produc- fluids considered has been modelled by multi-
324 L. Garca-Rodrguez, A.M. Delgado-Torres / Desalination 212 (2007) 319327
parametric equations of state given in the lit- Performance ratio of membrane distillation
erature. process, 4.
Parabolic trough collector model, LS3 [23]. Auxiliary energy consumption of desalination
Static solar collectors, high efficiency solar col- processes is not considered.
lectors have been selected among collectors
commercially available. Table 5 shows the specific solar energy con-
Isoentropic performance of the pump and the sumption of different desalination processes. Two
steam turbine [14], 0.75 (although the perfor- different condensation temperatures of the Rank-
mance of the steam turbine working with si- ine cyle have been considered if parabolic trough
loxanes is expected to be higher than with other collectors are used in order to analyze the suit-
organic fluids). ability of recovering the heat rejection for driv-
Optimised Rankine cycle with superheating ing a thermal desalination process. Condensation
and regeneration if necessary. Regenerator ef- temperatures of 35C and 115C have been se-
ficiency if any, 0.8. Maximum operational tem- lected in order to cover a wide range of working
perature considered to optimize the Rankine conditions. The different solar desalination sys-
cycle with parabolic trough collector, 400C. tems considered on the analysis performed are the
Solar irradiance, 850 W/m2. following:
Main energy consumption of reverse osmosis Reverse osmosis driven by solar photovoltaic
process with energy recovery, 2 kWh/m3. energy.
Performance ratio of multi-effect distillation Reverse osmosis driven by solar-heated Rank-
process, 10. ine cycle and two possibilities of recover the
Table 5
Specific solar energy consumption of different solar desalination systems (Tmin: minimum temperature of the thermody-
namic cycle, sol: quotient between shaft power production and solar energy available on the solar collector plane)
heat rejection of the Rankine cycle, the cou- climatic conditions of a given location in or-
pling of either, a multi-effect distillation der to calculate the annual production, and
(MED) or a membrane distillation (MD) unit. the cost of the solar collectors, and their in-
stallation, operation and maintenance costs.
In order to compare the specific solar energy
consumption of above systems with that of some 4. Although the coupling of distillation pro-
solar distillation processes, Table 6 [29] is given. cesses in order to recover the heat rejection of the
To sum up, the following results are pointed thermodynamic cycle always reduce the specific
out from the comparison of data displayed in solar energy consumption, the balance between
Tables 5 and 6: increasing of desalination subsystem capital costs
1. The specific solar energy consumption of and decreasing of specific auxiliary energy con-
reverse osmosis process driven by solar-heated sumption have to be analysed to assess the cou-
Rankine cycles could be lower than PVRO sys- pling of the distillation unit.
tems. Then, there are interesting prospects of be- 5. The comparison of specific solar energy
ing more cost-effective than PVRO. Neverthe- consumptions of the systems analyzed with solar
less intensive experimental research is necessary distillation shows the higher efficiency of using
in order to perform a techno-economic assess- solar thermal energy conversion on reverse os-
ment. mosis process instead of the direct thermal en-
2. Some of the working fluid that reaches high ergy use on distillation.
performance exhibit toxicity problems and have
to be discarded, especially benzene. Nevertheless,
siloxanes avoid such problems and permit the op-
5. Research required
eration with parabolic trough collectors and have
better behaviour in the steam turbine, which Little effort has been focused for developing
should increase the performance above that con- solar organic Rankine cycles. For this reason, in-
sidered. tensive research is required for optimizing solar
3. The solar field area required is directly re- collectors, selected working fluids, boundary con-
lated with the specific solar energy consumption ditions of the cycles and heat storages.
but in order to evaluate the cost of the solar field Solar collector designs for organic Rankine
required additional parameters are necessary: cycles. Operation conditions and working fluid
Table 6
Thermodynamic assessment of three different solar distillation systems based on solar thermal collectors and a multi-
effect distillation (MED) unit [29]. PTC: parabolic trough collectors, LTC: low temperature solar collectors; DEAHP:
double effect absorption heat pump
Desalination system Main energy consumption Solar desalination system Solar specific energy
(kJ/kg) consumption(*) (kJ/kg)
DEAHPMED 108 (at 180C) PTCDEAHPMED 142
MED 240 (at 70C) PTCMED 315
MED 240 (at 70C) LTCMED 5451600
333369(**)
(*)
Efficiency of solar collectors at 800 W/m2 (solar irradiance)
(**)
If evacuated absorber tubes are used
326 L. Garca-Rodrguez, A.M. Delgado-Torres / Desalination 212 (2007) 319327