Paper Magnetita
Paper Magnetita
Paper Magnetita
1 Instituto de Geofı́sica, Universidad Nacional Autónoma de México, Del. Coyoacan 04510 D. F., México
2 Servicio Nacional de Geologı́a y Minerı́a, Chile
(Received July 14, 2000; Revised December 19, 2000; Accepted January 24, 2001)
Rock-magnetic and microscopic studies of the iron ores and associated igneous rocks in the Cerro de Mercado,
Mexico, were carried out to determine the magnetic mineralogy and origin of natural remanent magnetization (NRM),
related to the thermo-chemical processes due to hydrothermalism. Chemical remanent magnetization (CRM) seems
to be present in most of investigated ore and wall rock samples, replacing completely or partially an original
thermoremanent magnetization (TRM). Magnetite (or Ti-poor titanomagnetite) and hematite are commonly found
in the ores. Although hematite may carry a stable CRM, no secondary components are detected above 580◦ , which
probably attests that oxidation occurred soon enough after the extrusion and cooling of the ore-bearing magma.
NRM polarities for most of the studied units are reverse. There is some scatter in the cleaned remanence directions
of the ores, which may result from physical movement of the ores during faulting or mining, or from perturbation of
the ambient field during remanence acquisition by inhomogeneous internal fields within these strongly magnetic ore
deposits. The microscopy study under reflected light shows that the magnetic carriers are mainly titanomagnetite,
with significant amounts of ilmenite-hematite minerals, and goethite-limonite resulting from alteration processes.
Magmatic titanomagnetites, which are found in igneous rocks, show trellis, sandwich, and composite textures,
which are compatible with high temperature (deuteric) oxy-exsolution processes. Hydrothermal alteration in ore
deposits is mainly indicated by martitization in oxide minerals. Grain sizes range from a few microns to >100
µm, and possible magnetic state from single to multidomain, in agreement with hysteresis measurements. Thermal
spectra, continuous susceptibility measurements, and IRM (isothermal remanent magnetization) acquisition suggest
a predominance of spinels as magnetic carriers, most probably titanomagnetites with low-Ti content. For quantitative
modeling of the aeromagnetic anomalies, we used data on bulk susceptibility and natural remanent intensity for
quantifying the relative contributions of induced and remanent magnetization components and allow a better control
of the geometry of source bodies. The position and geometry of this magnetic source are shown as an ENE-striking
tabular body, steeply inclined (75◦ ) to the south.
181
182 L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE
Fig. 1. Simplified geologic map of the regional study area showing the location of the iron-ore mining district Cerro de Mercado. Modified from Consejo
de Recursos Minerales (1985).
parameters were successfully used for modeling the aero- of the iron ore, along with excellent but rapidly disappearing
magnetic anomaly, by providing adequate control of the ge- exposures, make Cerro de Mercado an ideal Fe-ore deposit to
ometry of source bodies. carry out an interdisciplinary project involving geochemistry,
The Cerro de Mercado iron-ore deposit is located in the stable isotopes, and advanced mineralogy in order to clarify
northern sector of Durango city, Mexico (Fig. 1). Conflicting the controversy about the origin (this is a research project
theories of replacement and magmatic injection for the origin in progress whose results will be published soon). In all
L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE 183
genetic models, the ores are interpreted as having originally possible source bodies as free variables to fit the observed
consisted of magnetite, which has oxidized to martite, i.e., magnetic anomaly.
hematite pseudomorphous after magnetite.
A fluid inclusion study in fluorapatite from oxidized ore 2. Geology and Mineralization
and altered footwall rhyolite indicates that the emplacement Since the 70s several researchers have made efforts to de-
of the apatite accompanied a hydrothermal event of moderate fine the stratigraphy and tectonics of the Durango City area
temperature (greater than 350◦ C) at a crustal depth in excess (Fig. 1) (Swanson, 1974; Lyons, 1975, 1988; McDowell and
of 400 m (Leslie, 1975). The oxidation of the iron ores Keiser, 1977; Labarthe et al., 1990). Below we provide a
and the alteration of the footwall are interpreted as having summary of the mining district based on these works.
taken place during the thermal event. This event implies The iron deposits of this area were formed by subaerial vol-
the presence of CRM developed during oxidation. Thus, canic processes during a hiatus between two major eruptive
Cerro de Mercado affords an opportunity to investigate a cycles emanating from the 30 Ma Chupaderos caldera. The
hydrothermal event and its effects on the magnetic properties first major eruption of the Chupaderos caldera produced the
of the iron ores and host rocks, which is the done in this study. hematitic rhyolitic ash-flow tuffs of the Aguila Formation.
Besides, we investigate the magnetic characteristics which During resurgent doming of the caldera floor, the Cacaria
help to constrain the quantitative interpretation by using mea- Formation filled the moat around the central dome of the
sured magnetic properties, leaving size, shape, and depth of Chupaderos caldera. The lower Cacaria, the Leona mem-
184 L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE
ber, consists of extensive rhyolite flow domes, flows, and be applicable to many of them. The volcanic environment
volcanoclastic tuffs. The various facies of the Mercado Iron produces a mixture of intrusive, replacement, and sedimen-
Member were deposited on the surface of the Leona Member tary textures, which may explain the heated debates, found
as well as on the resurgently domed Aguila Formation. A in the literature over the origin of many of these deposits.
minor quartz latite extrusive activity was concurrent with the These systems include the Precambrian Kiruna deposits of
eruption of the Mercado Iron Member. Both units preceded Sweden, the central Missouri iron deposits, and the Olympic
the eruption of a second major welded tuff, the Santuario Dam deposit; the Jurassic deposits of northeast Nevada; and
Formation, which incorporated fragments of iron oxides in the Tertiary deposits of Mexico and Chile (e.g., Bookstrom,
its base. The Durango volcanic sequence (Fig. 2) began with 1977; Frietsch, 1978; Nystrom and Henriquez, 1994;
isolated andesitic flows at 51.6 Ma going through ash flow Travisany et al., 1995).
tuffs, rhyolites, quartz-latite flows, olivine basalts, and Qua-
ternary basalts of the Guadiana valley at 0.1 Ma. 3. Sampling and Methods of Study
The Cerro de Mercado iron deposit consists of four fa- We collected 84 drill-core samples from 14 sites of host-
cies: (1) a martite facies—massive to layered, coarsely crys- rocks and Fe-ore from the cut exposures in the Chupaderos
talline, porous martite (hematite pseudomorphous after mag- caldera area and Cerro de Mercado deposit (Fig. 1). Five to
netite) at the base, with dike and pluglike extensions down- nine cores were taken at each site with a portable gasoline-
ward into the underlying rhyolite, (2) a sandy magnetite powered drill, and oriented with an inclinometer and mag-
facies—unconsolidated, laminated, fine grained sandy mag- netic compass (after testing that it was not affected by the
netite above the martite, (3) a blocky facies—unlaminated remanent magnetization of the outcrop).
sandy magnetite matrix, mixed with blocks of the overlying Remanent magnetization was measured with a Molspin
quartz latite flow, and (4) a mixed iron oxide facies—tabular spinner magnetometer. Separation of secondary magneti-
and dikelike bodies of fine-grained magnetite-hematite inter- zation components from the characteristic component was
growths that cut and cap the sequence. accomplished by thermal demagnetization up to 680◦ C us-
Geologic relationships suggest that the iron deposits ing a non-inductive Schonstedt furnace. Room-temperature
formed as a result of a variety of subaerial volcanic pro- low-field magnetic susceptibility k was measured with a MS-
cesses. The main deposit at Cerro de Mercado apparently 2 Bartington susceptibility meter. Continuous susceptibility
resulted from the eruption of an iron-rich magma with abun- measurements (i.e., k-T curves) were obtained using a High-
dant volatiles of fluorine, chlorine, carbon dioxide, and wa- moor and a Bartington instrument. Isothermal remanent
ter. Sheeted flows and flow breccias formed a volcanic dome magnetization (IRM) acquisition curves with 10–12 steps
above an intrusive feeder system. Iron oxides crystallized as to a maximum field of 600 mT were obtained with a pulse
magnetite, with abundant, clear, yellow-green apatite crys- magnetizer in selected samples, and demagnetization of the
tals forming concurrently in gas cavities and open breccias. IRMs were done by step-wise alternating field (AF) using a
Large volumes of halogen-rich gases streamed up through Schonstedt demagnetization apparatus; using 8–14 steps up
the iron oxide flows and oxidized the magnetite to hematite to a maximum field of 230 mT.
(martite) and redeposited the iron leached from the now- Magnetic hysteresis loops were measured with an alternat-
porous martite as laminated sandy magnetite in an extensive ing gradient force magnetometer, ‘MicroMag’. IRM acqui-
fumarolic blanket. During the later stages of the cooling sition and DC back-field demagnetization curves were also
process, a quartz latite dike intruded and flowed out over the acquired with this instrument. Opaque minerals were exam-
deposit. Basal blocky flow breccias of the quartz latite mixed ined under reflected light to determine composition, texture,
with and disrupted the finely laminated texture of much of oxidation state, and degree of alteration.
the sandy magnetite, creating extensive quartz latite brec-
cias with a sandy magnetite matrix. Late-stage hematite- 4. Microscopy
magnetite dikes cut the entire system and fed flows, which 4.1 Background
capped the mound. In the surrounding of Cerro de Mercado Petrographic and opaque mineral study was done with an
large volumes of iron-rich vapor explosively vented into the ore microscope using thin and polished sections, and oil im-
atmosphere and crystallized as fine-grained hematite dust, mersion, for a sample from each site. Direct observation of
which formed an ash-like blanket covering a large area. Flow opaque minerals may assist in estimating the origin of mag-
textures, interlayered with the ash-like hematite, at the base netization, because we still have no clear magnetic evidence
of Peña Morada deposit, suggests actual flows or welded tuff to distinguish between TRM and CRM (Goguitchaichvili et
flows of this material. The occurrence of a maximum thick- al., 2000). Oxidation of titanomagnetite and magnetite is
ness of the ash-like hematite at Peña Morada indicates its an important phenomenon in rock magnetism. Secondary
proximity to a vent. At Cerro de Mercado the volatile-rich CRM may result, and if the oxidation products are the cation-
nature of the system resulted in extensive replacement of the deficient maghemite and titanomaghemite, the CRM may be
underlying pre-mineralization rhyolites by a mixture of mag- intense, but also very unstable (Storevedt, 1970; Nishitani
netite and pyroxene. Post-mineralization tuffs overlying the and Kono, 1989). At high temperatures (greater than 300◦ C),
iron ore contain iron oxide fragments at their bases with no maghemite inverts to hematite and the inversion resembles
alteration. the passage of a magnetic material through its Curie point.
Comparison of Cerro de Mercado with other apatite-bear- However, upon cooling, the magnetization lost during in-
ing, low titanium iron deposits associated with silicic vol- version is not recoverable. On the other hand, inversion of
canic systems suggests that this volcanogenic model may titanomaghemite at high temperature is more complex. In-
L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE 185
Fig. 3. Photomicrographs representative of the host rocks and iron ores. General scale: 2 cm = 100 microns, except Fig. 3(b) (wide grain size = 350 microns)
and Fig. 3(e) (wide grain size = 150 microns). Labels are as follows: mt = magnetite, hm = hematite, tm = titanomagnetite, th = titanohematite,
apt = apatite, gh = goethite, ilm = ilmenite, pbk = pseudobrookite, mr = martite.
version may produce ilmenite and magnetite, in which case Hydrothermal alteration has played an important role in
magnetization grows during cooling; or it may decompose Cerro de Mercado deposits, producing calcite, epidote, and
into magnetite, hematite, and either rutile or pseudobrookite some mica. The main objective of microscopic observations
(Kobayashi, 1959; Readman and O’Reilly, 1970; Ozdemir was to evaluate how magnetic grains were affected by hy-
and Banerjee, 1984; Ozdemir, 1987). drothermal alteration.
186 L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE
Table 1. Rock magnetic and petrographic results from surficial samples of Cerro de Mercado area.
Note: n, number of samples used for site mean calculation; Dec/Inc, and Mo , direction and intensity of mean characteristic remanent magneti-
zation; K and A95, confidence parameters; k, initial susceptibility; Q, Koenigsberger factor using H = 0.453 Oe. Rock type determined from thin
sections. Alteration types: I, sericitization; II, silicification; III, argilitization; IV, carbonatitization; V, epidotization. Mineralogy: pl, plagioclase;
fd, feldespar; py, pyroxen; hr, hornblende; qz, quartz; ap, apatite.
4.2 Sample description and several alteration processes are detected (sericitization,
In general, the studied samples exhibit two generations of silicification, and epidotization; a hexagonal apatite crystal
Fe-Ti oxides. The larger crystals (more than 30 µm), that appears completely replaced, Fig. 3(c)). Sample CMBO-1 is
can be easily observed are rare, whereas small crystals (3 µm a brecciated ore Fe-rich (Fig. 3(c); magnetite, light grey;
and less) are abundant in all studied samples. hematite, white). CMBO-4 (Fig. 3(d)) shows a massive
Massive Fe-martite-ores (sample CMM-5) are composed hematite with a few relicts of titanomagnetite on the right
of silicified magnetite and hematite and show grain-sizes side, and goethite developed in fractures and pores (hematite,
up to 100 µm in the quartz matrix. Regular oxidation to light grey; titanomagnetite, medium grey; and goethite, dark
hematite (martitization of euhedral magnetite crystals) along grey).
both crystal margins and (111) planes indicates that hematite Rhyolitic tuffs (sample CHU-1) show evidence for il-
is not exsolving from magnetite (Fig. 3(a)). This paragenesis menite, exsolved along (111) planes of the titanomagnetite
generally occurs at low/moderate temperatures (Haggerty, host, which has since oxidized to (titano)hematite (dark grey,
1976), below the Curie point of magnetite and hematite. ilmenite; white, (titano)hematite, Fig. 3(e)). The ilmenite
Thus, observed magnetic grains most probably carry a CRM. occurs as sheets or exsolution lenses, and has a light-grey
In a few cases (e.g., sample CMMC-3, Fig. 3(f)) pseudo- color, with pinkish-light tones, but in the presence of mag-
brookite (dark grey) is intergrown with martite (medium netite it has a white color, with trellis-type textures predom-
grey) and hematite (light grey-white). inantly. Sandwich and composite textures were also ob-
In a skarn sample (CMBC-5, Fig. 3(b)) a single grain served (Haggerty, 1976). These intergrowths develop typi-
of hematite, pseudomorphous after magnetite, could be ob- cally above 600◦ C; consequently, the NRM carried by these
served in the silicified matrix. Less than 5% of magnetite samples is a TRM.
remains, which indicates a higher intensity alteration. Fig-
ures 3(c) to 3(f) demonstrate the progressive oxidation of 5. Magnetic Measurements
massive magnetite. Note the relationships between incipient In order to identify the magnetic carriers responsible for
martitization and crystallographic directions and fractures the remanent magnetization and obtain information about
in the magnetite; the red internal reflections in some areas their magnetic stability, several rock-magnetic experiments
of hematite; and the reflection pleochroism of the hematite. were carried out. These experiments include: a) NRM and
Incipient to medium oxidation of magnetite along fractures initial susceptibility measurements, b) Viscosity index mea-
L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE 187
Fig. 5. Orthogonal vector plots of remanent magnetization (Zijderveld, 1967) for representative samples and corresponding NRM decay curves. The
numbers refer to the temperatures in ◦ C. O, projections into the horizontal plane; X, projections into the vertical plane.
curred during or soon after extrusion and cooling of the ore- susceptibility just below the Curie temperature (the Hopkin-
bearing magma. The low temperature (200◦ –500◦ C) com- son peak), before dropping to relatively small values (Fig. 6,
ponent is well defined for massive-Fe samples (Fig. 5(d)), sample CMF-4). This behavior probably corresponds to SD
and may also correspond to chemical overprint. Alterna- or small PSD magnetic grains (Dunlop and Ozdemir, 1997).
tively, some partial thermoremanence (pTRM) could be ac- The Curie point is 580 ± 5◦ C, which indicates nearly pure
quired from about 300◦ C (the approximate temperature of magnetite as a magnetic carrier. This sample has high suscep-
hydrothermalism) to ambient temperature. This pTRM may tibility, so the contribution of hematite, relative to magnetite,
only be completely removed at higher temperatures (about should be negligible. The curves suggest thermal drift of the
500◦ C) if magnetization is carried by PSD or MD particles zero level of susceptibility. Skarn samples (Fig. 6, sample
(Shcherbakova et al., 1996; Goguitchaichvili et al., 1997). CMSC-3) show also evidence of magnetite with only a minor
Rhyolitic tuffs yield reasonably linear and stable magnetic Hopkinson peak just below the Curie point. This form is char-
components (Fig. 5(c)). A major part of magnetization is re- acteristic of coarse-grained PSD to MD grains. Here, again,
moved above 580◦ C, which probably points to the presence hematite may coexist judging from susceptibility curves but
of magmatic (titano)magnetite as well as (titano)hematite as its contribution is not significant (could be thermal drift).
observed under reflected light microscopy. Rhyolites yielded very noisy curves (not shown). However,
5.4 Continuous susceptibility measurements it can be inferred from thermal demagnetization data that
To study the thermal behavior of susceptibility (k-T nearly pure magnetite carries a major part of magnetization.
curves) in an 80 µT magnetic field, one sample from each 5.5 IRM acquisition and alternating field demagnetiza-
site was progressively heated up to 650◦ C and subsequently tion of SIRM
cooled down. Curie temperatures were determined follow- To determine the isothermal remanent magnetization
ing the method described by Grommé et al. (1969). Rep- curves, previously AF demagnetized samples from all sites
resentative curves are shown in Fig. 6. In some cases k-T were subjected to magnetic fields along one axis. The curves
curves could not be obtained due to weak initial magnetic were found quite similar in all cases (Fig. 4). Saturation is
susceptibilities. Massive-Fe samples show an increase in reached at relatively low field (about 200 mT), which points
L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE 189
Fig. 7. Hysteresis loops (corrected for paramagnetism) for representative samples from Cerro de Mercado. Rock samples and corresponding sites are:
volcanics (CHU), Quartz-monzonite (CMI), Rhyolitic ignimbrite (CME), Mineralized breccia (CMBO), Fe-ore (CMM), and Fe-skarn (CMBC).
of Cerro de Mercado. ples, which probably implies that the ores were oxidized at
Microscopic examination of the Cerro de Mercado ore temperatures above 300◦ C.
samples indicate that they are composed basically of mag- Although observed directly, (titano)hematite does not
netite and (titano)hematite, with minor amounts of goethite, seem to represent a major contributor to total remanence.
apatite, and quartz. Hematite results from partial martiti- In most cases, magnetic signal belong to ‘near magnetite’
zation of original magnetite, which probably occurred dur- phase, which seems to have a wide range of PSD magnetic
ing the hydrothermal event. Generally speaking, no signif- structure. Thus, the dominant magnetic carriers in studied
icant differences were found in the directions of remanence ores correspond to magnetite characterized by highest values
carried by magnetite and hematite, which suggests that the of rock magnetic properties observed in the various litholo-
hydrothermal event occurred soon after the extrusion and gies examined (7.7 A/m), high magnetic susceptibilities (0.25
cooling. Rhyolitic samples seem not have been affected by SI), 0.4 to 55.1 Q coefficients, and low to medium coercivity
hydrothermal alteration, since magnetic grains present ev- under AF demagnetization.
idence for high temperature deuteric oxy-exsolution. (Ti- Figure 9 summarizes the quantitative interpretation of the
tano)maghemite seems to be absent from all studied sam- observed magnetic anomaly. We used the intensity and direc-
L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE 191
Fig. 8. Aeromagnetic anomaly map. Note the presence of a large dipolar anomaly located over the mineralized area. Location of the modeled profile is
shown. Values are given in nanoteslas.
Fig. 9. Magnetic profile and quantitative model. Local geomagnetic field parameters are: declination D = 9.1◦ , inclination I = 51.5◦ , and total magnetic
intensity F = 45300 nT. We used profile stike = 161◦ and 2D bodies that extend infinitely along-strike perpendicular to this profile. Magnetic data for
the large body are: NRM declination = 260◦ , NRM inclination = −37◦ , remanent intensity = 0.6 A/m; magnetic susceptibility = 8 SI; for the small
body: NRM declination = 180◦ , NRM inclination = −60◦ , remanent intensity = 1.2 A/m; and magnetic susceptibility = 0.5 SI.
tion of the NRM, and the induced intensity, for the calculated of the main magnetic source body is shown as a long body
anomaly. The remanence component is greater than the in- being steeply inclined (75◦ ) to the south.
duced component, corresponding to Q coefficients (1.3 < The intensity of remanence contribution is significant in
Q < 4.0) greater than unity. The position and the geometry the interpretation of magnetometric anomalies, particularly
192 L. M. ALVA-VALDIVIA et al.: PETROMAGNETISM OF IRON-ORE
for cases where the remanent component has a direction con- ploration, vol. 23, pp. 303–333, 1985.
siderably different from that of the present-day earth’s mag- Grommé, C. S., T. L. Wright, and D. L. Peck, Magnetic properties and
ixidation of iron-titanium oxide minerals in Alae makaupuki lava lakes,
netic field and a high intensity (Alva-Valdivia et al., 1991; Hawaii, J. Geophys. Res., 74, 5277–5293, 1969.
Alva-Valdivia and Urrutia-Fucugauchi, 1995, 1998). For Haggerty, S. E., Oxidation of opaque mineral oxides in basalts, in Oxide
highly magnetic rocks and mineral deposits its influence is Minerals (Short Course Notes), edited by D. Rumble, Mineral. Soc. Am.,
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Kirschvink, J. L., The least-square line and plane and analysis of palaeo-
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Labarthe, G., J. L. Carreon, and A. Aguillon, Cerro de Mercado, in Minas
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Acknowledgments. We are grateful for the kind cooperation of 1990.
the engineering staff Exploration Division of the Cerro de Mer- Leslie, S. L., Chemical remanent magnetization in iron ores and wall rocks
cado Company. Rock magnetic measurements were carried out of Cerro de Mercado, Durango, Mexico, Unpublished MSc Thesis, Univ.
by J. C. Cruz-Ocampo. This research was funded by the Insti- of Minnesota, 1975.
tuto Panamericano de Geografia e Historia (IPGH) and CONACyT Lyons, J. I., Volcanogenic iron ore of Cerro de Mercado and its setting within
project No. 32756-T. AG gratefully acknowledges the support the Chupaderos Caldera, Durango, Mexico, M.A. Thesis, Austin, Univ.
given by CONACyT project No. J-32727-T. JU thanks support Texas, 119 pp., 1975.
from DGAPA project IN-102897. Lyons, J. I., Volcanogenic iron oxide deposits, Cerro de Mercado and vicin-
ity, Durango, Mexico, Econ. Geol., 83, 1886–1906, 1988.
McDowell, F. W. and R. P. Keizer, Timing of mid-Tertiary volcanism in the
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